Resistivity log responses are different when the oil layers is filled by a polymer solution or water and it seriously affects the log interpretation of the water flooded layer. In this paper, we first analyze the elec...Resistivity log responses are different when the oil layers is filled by a polymer solution or water and it seriously affects the log interpretation of the water flooded layer. In this paper, we first analyze the electrical properties of the polymer solution. Then, according to the different processes for polymer flooding the reservoir, we perform rock resistivity experiments and analyze the rock resistivity variations in different displacement phases. We also compare the resistivity log responses of oil layers filled with the polymer solution to those filled with water. The results show that when displacing the oil-bearing core by different polymers, the resistivity changes monotonously decrease and show either ＂W＂ type or ＂S＂ type. The resistivity log responses are weak when displacing water and there is no flooded show if the oil layer is injected by a fresh water polymer solution. If the oil layer is injected by a sewage polymer solution, the resistivity log response has similar characteristic as a polluted water flooded layer.展开更多
The two-photon fluorescence properties and ultrafast responses of a hyperbranched polyyne （hb-DPP-J2） with triphenylamine as the central core, Diketo-Pyrrolo-Pyrrole as the connecting unit and electron acceptor are ...The two-photon fluorescence properties and ultrafast responses of a hyperbranched polyyne （hb-DPP-J2） with triphenylamine as the central core, Diketo-Pyrrolo-Pyrrole as the connecting unit and electron acceptor are studied. The polymer has a D-π-A-π-D conjugated structure along the extended polyyne w-bridge systems, and the effective condugated unit repeats itself in the whole hyperbranehed polymer chain. The polymer exhibits a large two-photon absorption cross section and high fluorescence quantum yields. The ultrafast dynamic results give a deep understanding of the excited energy transfer processes under excitation, and reveal a long relaxation lifetime of the intramolecular charge transfer （ICT） state.展开更多
基金sponsored by the Major National Oil&Gas Specific Project (Grant No.2011ZX05020 008)
文摘Resistivity log responses are different when the oil layers is filled by a polymer solution or water and it seriously affects the log interpretation of the water flooded layer. In this paper, we first analyze the electrical properties of the polymer solution. Then, according to the different processes for polymer flooding the reservoir, we perform rock resistivity experiments and analyze the rock resistivity variations in different displacement phases. We also compare the resistivity log responses of oil layers filled with the polymer solution to those filled with water. The results show that when displacing the oil-bearing core by different polymers, the resistivity changes monotonously decrease and show either ＂W＂ type or ＂S＂ type. The resistivity log responses are weak when displacing water and there is no flooded show if the oil layer is injected by a fresh water polymer solution. If the oil layer is injected by a sewage polymer solution, the resistivity log response has similar characteristic as a polluted water flooded layer.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11404048,61205154 and 11375034the Fundamental Research Funds for the Central Universities under Grant Nos 3132015233,3132013104,3132014337,3132015144 and3132015152+1 种基金the State Key Laboratory of Fine Chemicals(KF1409)the Program for Liaoning Excellent Talents in University under Grant No LJQ2014051
文摘The two-photon fluorescence properties and ultrafast responses of a hyperbranched polyyne （hb-DPP-J2） with triphenylamine as the central core, Diketo-Pyrrolo-Pyrrole as the connecting unit and electron acceptor are studied. The polymer has a D-π-A-π-D conjugated structure along the extended polyyne w-bridge systems, and the effective condugated unit repeats itself in the whole hyperbranehed polymer chain. The polymer exhibits a large two-photon absorption cross section and high fluorescence quantum yields. The ultrafast dynamic results give a deep understanding of the excited energy transfer processes under excitation, and reveal a long relaxation lifetime of the intramolecular charge transfer （ICT） state.
