The Friction and Wear Properties of the Spherical Plain Bearings with Self-lubricating Composite Liner in Oscillatory Movement

A test method based on the condition simulation and a friction and wear test machine featuring in oscillatory movement were set up for self-lubricating spherical plain bearings (SPB). In the machine the condition parameters such as load, angle and frequency of oscillation and number of test cycles can be properly controlled. The data relating to the tribological properties of the bearing, in terms of friction coefficient, linear wear amount, temperature near friction surface and applied load, can be monitored and recorded simultaneously during test process by a computerized measuring system of the machine. Efforts were made to improve the measurement technology of the friction coefficient in oscillating motion. In result, a well-designed bearing torque mechanism was developed, which could reveal the relation between the friction coefficient and the displacement of oscillating angle in any defined cycle while the curve of friction coefficient vs number of testing cycles was continuously plotted. The tribological properties and service life of four kinds of the bearings, i.e, the sampleⅠ-Ⅳ with different self-lubricating composite liners, including three kinds of polytetrafluoroethylene (PTFE) fiber weave/epoxy resin composite liners and a PTFE plastic/copper grid composite liner, were evaluated by testing, and the wear mechanisms of the liner materials were analyzed.

Friction and Wear of Polymer Composites Filled by Nano-Particles: A Review

Composites formed by adding nano-scale particles to a polymer matrix results in improving electrical, mechanical, and thermal properties of the composite. Good tribological properties can be obtained for polymers filled with nano-scale fillers compared to that filled with micro-scale particles. The friction and wear resistance of these composites is found to increase with increasing filler concentration. It is also possible to use multi-functional fillers to develop high performance composites which cannot be achieved by using a single filler.

Effects of Friction Heat on the Tribological Properties of the Woven Self-lubricating Liner

In the dry-sliding process of the woven self-lubricating liner which is used in the self-lubricating spherical plain bearing, the friction heat plays an important role in the tribological performances of the liner. It has important value to study on the relationship between tribological performances of the liner and the friction heat. Unforttmately, up to now, published work on this relationship is quite scarce. Therefore, the effect of friction heat on the tribological performances of the liner was investigated in the present work. The tribological behaviors of the liner were evaluated by using the high temperature end surface wear tester. Scanning electron microscopy （SEM） was utilized to examine the morphologies of worn surfaces of the liner and study the failure modes. Differential scanning calorimetry （DSC） measurement and X-ray diffraction （XRD） analysis were performed to study the behaviors of the wear debris. The temperature rise on the worn surface was calculated according to classical models. SEM observation shows that the dominating wear mechanism for the liner is mainly affected by friction shear force, contact pressure and friction heat. Higher fusion heat for the wear debris than that for the pure polytetrafluroethylene （PTFE） indicates that the PTFE is the main portion of the wear debris, and, the PTFE in the wear debris shows a higher crystallisation degree owing to the effects of friction shear force and the friction heat. Combining the calculated temperature rise results with the wear rate of the liner, it can be concluded that the effects of temperature rise o n the tribological performances of the liner become more obvious when the temperature rise exceeds the glass transition temperature （Tg） of the PTFE. The wear resistance of the liner deteriorates dramatically when the temperature rise approaches to the melting point （Ton） of the PTFE. The tribological performances of the liner can be improved when the temperature rise exceeds Tg but is far lower than Ton- The present study on the relationship between the temperature rise and the tribological performances of the liner may provide the basis for further understanding of the wear mechanisms of the liner as well as the relationship between the formation of the PTFE transfer film and the friction heat during the dry-sliding of the Finer.

Static/dynamic friction and wear of some selected polymeric materials for conformal tribo-pairs under boundary lubrication conditions

This work is aimed at investigating the friction and wear performance of different polymeric materials having potential for hydraulic system components under lubricated sliding conditions against a steel counter face.A pin-on-disc test configuration was used for the experimental study.The different polymeric materials selected for these studies were commercial polyimides(PI),polyether ether ketone(PEEK),and flouropolymers.Some of these materials were bulk materials whereas others were used as coatings applied on to the cast iron substrate.The tribological characteristics of the polymers were compared with a reference grey cast iron.The frictional characteristics were evaluated in both static and dynamic conditions.The results have shown that by using polymeric materials it is possible to reduce breakaway friction by an order of magnitude compared to grey cast iron.However,the breakaway friction increased significantly after the wear tests.The polymeric materials having lowest breakaway friction have shown the highest wear with the exception of the PEEK-PTFE coating which showed low wear.PI with graphite fillers also showed low wear but it resulted in relatively high friction.The carbon fibre reinforced materials resulted in unstable friction as well as higher wear compared to the PI materials with graphite fillers.

Lows of Wear Process of the Friction Pair “0.45% Carbon Steel—Polytetrafluoroethylene” during Sliding from the Position of Fracture Mechanics

The results of the tests for a friction pair “a cylindrical specimen made of 0.45% carbon steel—a counter specimen-liner made of polytetrafluoroethyleneF4-B” during sliding friction are presented. The test results at different levels of contact load are analyzed using the Archard’s equation and are presented as a friction fatigue curve. The concept of the frictional stress intensity factor during sliding friction is introduced, and an expression that relates the wear rate to this factor and is close in shape to the Paris equation in fracture mechanics is proposed.

Wear and transfer characteristics of carbon fiber reinforced polymer composites under water lubrication

The tribological characteristics of carbon fiber reinforced polymer composites under distilled-water-lubricated-sliding and dry-sliding against stainless steel were comparatively investigated. Scanning electron microscopy (SEM) was utilized to examine composite microstructures and modes of failure. The typical chemical states of elements of the transfer film on the stainless steel were examined with X-ray photoelectron spectroscopy (XPS). Wear testing and SEM analysis show that all the composites hold the lowered friction coefficient and show much better wear resistance under water lubricated sliding against stainless steel than those under dry sliding. The wear of composites is characterized by plastic deformation, scuffing, micro cracking, and spalling under both dry-sliding and water lubricated conditions. Plastic deformation, scuffing, micro cracking, and spalling, however, are significantly abated under water-lubricated condition. XPS analysis conforms that none of the materials produces transfer films on the stainless steel counterface with the type familiar from dry sliding, and the transfer of composites onto the counterpart ring surface is significantly hindered while the oxidation of the stainless steel is speeded under water lubrication. The composites hinder transfer onto the steel surface and the boundary lubricating action of water accounts for the much smaller wear rate under water lubrication compared with that under dry sliding. The easier transfer of the composite onto the counterpart steel surface accounts for the larger wear rate of the polymer composite under dry sliding.

Mechanism of thermoviscoelasticity driven solid-liquid interface reducing friction for polymer alloy coating

High-temperature ablation is a common failure phenomenon that limits the service life of the transmission parts on heavy-duty machines used in heavy load,high temperature,high shock conditions due to in-sufficient supply of lubricating oil and grease.Traditional self-lubricating coatings prepared by inorganic,organic or organic-inorganic hybrid methods are prone to be oxidated at high temperatures to lose their friction reducing function,so that it is difficult to meet the engineering requirements of high-temperature lubrication.We design viscoelastic polymer coatings by a high-temperature self-lubricating and wear-resistant strategy.Polytetrafluoroethylene(PTFE,T_(m)=329℃)and polyphenylene sulfide(PPS,T_(g)=84℃,T_(m)=283℃)are used to prepare a PTFE/PPS polymer alloy coating.As the temperature increases from 25 to 300℃,the PTFE/PPS coating softens from glass state to viscoelastic state and viscous flow state,which is owing to the thermodynamic transformation characteristic of the PPS component.Additionally the friction coefficient(μ)decreased from 0.096 to 0.042 with the increasing of temperature from 25 to 300℃.The mechanism of mechanical deformation and surface morphology evolution for the PTFE/PPS coating under the multi-field coupling action of temperature(T),temperature–centrifugal force(T–F_(ω)),temperature–centrifugal force–shearing force(T–F_(ω)–F_(τ))were investigated.The physical model of“thermoviscoelasticity driven solid–liquid interface reducing friction”is proposed to clarify the self-lubricating mechanism determined by the high-temperature viscoelastic properties of polymers.The high-temperature adjusts the viscosity(η)of the coating,increases interface slipping and intensifies shear deformation(τ),reducing the friction coefficient.The result is expected to provide a new idea for designing anti-ablation coatings served in high temperature friction and wear conditions.

Tribological Properties of Self-lubricating Laminated Ceramic Materials

In order to improve the tribological properties of ceramic composites, Al2O3/TiC-Al2O3/ TiC/CaF2 self-lubricating laminated ceramic composites were prepared by vacuum hot pressing sintering. Experiments were conducted to get mechanical properties and the friction and wear properties were also measured with friction and wear tester. The worn surfaces were observed by scanning electron microscope （SEM） and energy dispersion spectrum （EDS）. The wear resistance properties and the self-lubricating effect of ceramic composites were analyzed. Results show that the Al2O3/TiC-Al2O3/TiC/CaF2 self-lubricating laminated ceramic composites layers are well-defined with a higher bonding strength and the mechanical performances are uniform enough to overcome the anisotropy of weak laminated ceramic composites. In addition, the fracture toughness of Al2O3/TiC layers is also improved. Its friction coefficient and wear rates decrease with the increase of rotation speed and load. Al2O3/TiC-Al2O3/TiC/CaF2 self-lubricating laminated ceramic composites have good wear resistance because of the tribofilm formed by the CaF2 solid lubricants. The wear mechanisms of Al2O3/TiC/ CaF2 layers are abrasive wear and Al2O3/TiC layers are adhesive wear.

Sliding Wear of the Hybrid Kevlar/PTFE Fabric Reinforced Phenolic Composite Filled with Nano-titania

The Kevlar/polytetrafluroethylene（Kevlar/PTFE） fabric composite can be used as a self-lubricating liner of the self-lubricating bearing.Many types of nano-particles can improve the tribological performance of the polymer-based composite.Unfortunately,up to now,published work on the effect of nano-particles on the tribological performance of the fabric composite which can be used as a self-lubricating liner is quite scarce.Therefore,for the purpose of exploring a way to significantly improve the tribological performance of the fabric composite,the tribological performance of the Kevlar/PTFE fabric composite filled with nano-titania is evaluated by using the block-on-ring wear tester.The scanning electron microscopy is utilized to observe the morphologies of worn surfaces of the fabric composites and the counterparts.The tensile properties of the composites are evaluated on the universal material testing machine.The test results show that the addition of nano-titania at a proper mass fraction of the matrix resin improves the wear resistance and the tensile strength,decreases the friction coefficient,and makes the wear volume of the composite reach a relative steady state more quickly;plastic deformation and microcutting are important for the wear of the fabric composite;a lubricating layer is formed on the worn surface of the composite during sliding,and the lubricating layer is critical for the tribological performance of the composite;the formation and properties of the lubricating layer are influenced by the nano-titania particles.The proposed study on the effect of nano-titania on the tribological performance of the Kevlar/PTFE fabric composite,especially on the evolution of the worn surface of the composite,provides the basis for further understanding of the influence mechanism of the nano-particles on the tribological performance of the composite and explores a method of improving the tribological performance of the composite.

In-situ preparation of robust self-lubricating composite coating from thermally sprayed ceramic template

The self-lubricating ceramic coatings that can control friction and wear have attracted researchers’widespread attention.However,the poor interfacial bonding between lubricants and ceramics and the deterioration of mechanical properties due to a tribological design limit their practical applications.Here,a robust self-lubricating coating was fabricated by an in-situ synthesis of MoS_(2)/C within inherent defects of thermally sprayed yttria-stabilized zirconia(YSZ)coatings.The edge-pinning by noncoherent endows hybrid coatings with excellent interfacial strength,increasing their hardness(HV)and cohesive strength.Furthermore,owing to the formation of a well-covered robust lubricating film at a frictional interface,a coefficient of friction(COF)can be reduced by 79.6%to 0.15,and a specific wear rate(W)drops from 1.36×10^(−3) to 6.27×10^(−7) mm^(3)·N^(−1)·m^(−1).Combining outstanding mechanical properties and tribological performance,the hybrid coating exhibits great application potential in controlling friction and wear.Importantly,this strategy of introducing the target materials into the inherent defects of the raw materials to improve the relevant properties opens new avenues for the design and preparation of composite materials.

Tribological behavior of shape memory cyanate ester materials and their tunable friction mechanism

High-performance polymer friction materials with tunable tribological behavior to fit varied work conditions remain a challenge of widespread interest for a variety of applications.Shape memory polymer exhibits morphing and modulus changing over temperature changing provides a promising material to adjust the friction process.Herein,we investigated the tribological properties of shape memory cyanate ester(SMCE)under different conditions.The SMCE exhibits the tribological behavior of good friction material with stable high coefficient of friction(COF)and a low wear rate.Besides,the COF increases and wear rate decreases with the temperature increasing show the tunable friction property of the SMCE.We propose a new model of wear-compensation through shape recovery to explain the adjustable friction behavior of thermal-responsive polymer from the aspect of shape recovery and energy conversion.This study provides a high-performance friction material and paves the route for the application of shape memory polymer(SMP)in tribology field with tunable property.

Combined effect of the use of carbon fiber and seawater and the molecular structure on the tribological behavior of polymer materials

The combined effect of the use of carbon fiber and seawater and the molecular structure on the tribological behavior of various polymer materials under natural seawater lubrication was investigated. After the investigation, the wear morphology of the contact surface was observed by a laser scanning confocal microscope, and the texture of the wear scars and tracks were presented in 3 D profiles. Moreover, the mechanism of mixed lubrication and wear resistance was analyzed. The results demonstrated that the friction coefficient of carbon fiber-reinforced polyetheretherketone(CFRPEEK) is the lowest and fluctuates at approximately 0.11. Moreover, the seven polymer materials in ascending order of friction coefficients are CFRPEEK, carbon fiber-reinforced polyamide-imide, polytetrafluoroethylene, polyoxymethylene, polyetheretherketone(PEEK), acrylonitrile butadiene styrene resin, and glass fiber–epoxy resin. More critically, the simultaneous incorporation of deposition, polymeric scrap, hydrophilic groups, and seawater resulted in a decrease in the friction and wear of polymer materials under seawater lubrication. This observation implies that a synergistic friction-reducing and wear-resistant effect exists between carbon fiber, seawater, and the molecular structure of PEEK. As a result, a highly effective polymer material was discovered, CFRPEEK, which has the lowest friction coefficient of 0.11 and lowest wear rate of 2 × 10^(–5) mm^3?(N?m)^(-1) among the polymer materials; this validates the selection of dual friction pairs for seawater hydraulic components.

Bioinspired PcBN/hBN fibrous monolithic ceramic:High-temperature crack resistance responses and self-lubricating performances

The high strength and toughness of natural materials are mainly determined by a combination of mechanisms operating at different length scales,which can be used as a strategy to reduce the intrinsic brittleness of ceramics.Inspired by the architectures of bamboo,the polycrystalline cubic boron nitride/hexagonal boron nitride(PcBN/hBN)fibrous monolithic ceramics with a long fiber arrangement structure was constructed with PcBN fiber cells and hBN cell boundaries,and its crack resistance responses and tribological performances were investigated.The composite ceramic failed in a non-brittle manner with the rising resistance curve(R-curve)behavior,which was attributed to multiscale crack effects in the hierarchical architecture.The maximum crack growth toughness was extremely high(approximately 21 MPa×m^(1/2)),corresponding to a 270%increase over the crack initiation toughness.Excellent fracture resistance could be retained even above 1000℃.Moreover,the composite ceramic exhibited low and stable friction coefficients(approximately 0.33)when paired with a Si_(3)N_(4)pin at high temperature(1000℃),owing to the lubrication function of hBN cell boundaries with weak van der Waals forces and a small amount of liquid B_(2)O_(3)produced.As a result,a synergistic improvement of mechanical and tribological properties at high temperature(1000℃)was realized by combining bionic structure and tribological design.It provides important theoretical and technical support for expanding the application of self-lubricating composite ceramics in harsh environments.

PEEK及其PEEK/CF复合材料的高温摩擦磨损性能

聚醚醚酮(PEEK)因其独特的结构而具有优异的综合性能,但纯PEEK材料因耐磨性能较差限制了其更广泛的应用,可通过填充改性来提高PEEK的摩擦磨损性能。利用真空热压烧结技术制备了纯PEEK及碳纤维(CF)增强聚醚醚酮(PEEK/CF)复合材料。采用X射线衍射、傅里叶变换红外光谱、热重分析等表征手段对材料的结构、力学性能和热学性能进行表征,并利用多功能摩擦磨损试验机、三维轮廓仪、扫描电子显微镜等对材料的高温摩擦磨损性能进行表征和分析。结果表明,CF的加入并没有改变PEEK的结构。与纯PEEK材料相比,PEEK/CF复合材料的硬度稍有增加,拉伸性能有所降低。PEEK材料的磨损率先降低后增加,然而PEEK/CF复合材料的磨损率先增加后降低。在相对较低环境温度条件下,PEEK及PEEK/CF复合材料的磨损机理为磨粒磨损和黏着磨损;在200℃高温条件下,纯PEEK材料表现为黏着磨损和疲劳磨损,而PEEK/CF复合材料为轻微的黏着磨损。

高分子聚合物材料微动摩擦磨损行为

组合密封中塑料环的耐磨特性对其密封性能有重要作用,为优选合适对摩材料,研究超高分子量聚乙烯(UHMWPE)、聚四氟乙类(PTFE)+40%铜粉、PTFE+7%碳纤维、PTFE+7%碳纤维+5%MoS_(2)、聚醚醚酮(PEEK)5种高分子聚合物材料与QT500对摩的微动摩擦磨损性能。从中筛选出PTFE+7%碳纤维、UHMWPE 2种材料进行不同微动行程、润滑条件下的对比试验。结果表明:无论是在干摩擦还是油润滑条件下,UHMWPE材料的平均摩擦因数随着微动行程的增大而增加,PTFE+7%碳纤维材料达到稳定状态时摩擦因数随着循环次数的波动较小。综合试验结果,当微动行程小于等于0.2 mm时建议选用PTFE+7%碳纤维,微动行程大于0.2 mm时建议选用超高分子量聚乙烯材料。

石墨烯强化自润滑高分子聚合物摩擦性能研究现状

石墨烯由于其优异的摩擦学性能常作为添加剂改善润滑剂摩擦性能。基于此,综述了石墨烯添加环氧树脂(EP)、聚酰亚胺(PI)、聚四氟乙烯(PTFE)这3种高分子聚合物摩擦性能研究现状,简要介绍了石墨烯的性质以及3种高分子聚合物的用途和优缺点。重点总结了石墨烯添加3种高分子聚合物所得复合材料在摩擦过程中的摩擦机理。提出了石墨烯增强高分子聚合物的摩擦学性能关键在于石墨烯在基体中的分散性和它们之间的界面强度,以及选择合适的材料进行多元添加可以产生多种材料之间的协同作用。

对磨材料对树脂渗透陶瓷Vita Enamic磨损的实验研究

目的探究树脂渗透陶瓷(PICN)分别与二氧化锆陶瓷、钴铬合金以及复合树脂材料配副情况下的磨损行为。方法分别制作尺寸为18 mm×14 mm×3.0 mm PICN试件30片,直径为4 mm的二氧化锆、钴铬合金及复合树脂磨头各10个。相互配副,在干燥环境及人工唾液条件下进行载荷5 N、频率5 HZ,磨程3 mm的线性往复循环磨损试验30 min。实时记录摩擦系数,绘制摩擦系数曲线。利用三维表面形貌仪定量分析磨痕尺寸,计算磨损量。双因素方差分析评估磨头材料及干湿环境对磨痕尺寸及磨损体积的影响。各组抽取试件利用扫描电镜观察磨损区表面微观结构。结果磨头材料及干湿环境对于PICN磨痕尺寸及磨损体积具有显著影响(P<0.05),且存在相互作用。在人工唾液中,PICN与树脂磨头的摩擦系数为0.26±0.03,显著低于其他各组(P<0.05),但树脂磨头反而产生较高的磨损量(P<0.05)。此外二氧化锆磨头对PICN造成的磨损体积为(9.2±5)×10^(-2)mm^(3),显著高于其余各组(P<0.05)。结论当对颌为二氧化锆修复体时,应慎重选择PICN材料,避免其过度磨损;当复合树脂与PICN互为对颌时,树脂材料可能存在高磨损风险。

Preparation and tribological performances of Ni-P-multi-walled carbon nanotubes composite coatings

Multi-walled carbon nanotubes （MWNTs） were wet-milled in the presence of ammonia and cationic surfactant and then used as reinforcements to prepare Ni-P-MWNTs composite coatings by electroless plating. The tribological performances of the composite coatings under dry condition were investigated in comparison with 45 steel and conventional Ni-P coating, Micrographs show that short MWNTs with uniform length and open tips were obtained through the wet-milling process. The results of wear test reveal that the Ni-P-MWNTs composite coatings posses much better friction reduction and anti-wear performances when compared with 45 steel and Ni-P coating. Within the MWNTs content range of 0.74%-1.97%, the friction coefficient and the volume wear rate of the composite coatings decrease gradually and reach the minimum values of 0.08 and 6.22x10-15 m3/（N.m）, respectively. The excellent tribological performances of the composite coatings can be attributed to the introduction of MWNTs, which play both roles of reinforcements and solid lubricant during the wear process.

Surface Functionalized Carbon Nanofibers and Their Effect on the Dispersion and Tribological Property of Epoxy Nanocomposites

Surface functionalization of carbon nanofibers（CNFs） was carried out, i e, CNFs were firstly oxidized and then the surface was silanized by 3-Aminopropyltriethoxysilane（APTES） via an assembly method. A new kind of high wear resistance s-CNFs/epoxy composite was fabricated by in-situ reaction. FTIR spectroscopy was used to detect the changes of the functional groups produced by silane on the surface of CNFs. The tribological properties and microstructures of modified and unmodified CNFs/epoxy composites were studied, respectively. The expremental results indicate that APTES is covalently linked to the surface of CNFs successfully and improves the dispersion of CNF in epoxy matrix. The friction coefficients and the wear rates of s-CNFs/epoxy composites are evidently lower than those of u-CNFs/epoxy composites under the same loads. Investigations also indicate that abrasive wear is the main wear mechanism for u-CNFs/epoxy composite, with slight adhesive wear for s-CNFs/epoxy composite under the same sliding wear condition.