Over the past decades, two-dimensional（2D） nanomaterials possessing planar layered architecture and unique electronic structures have been being quickly developed, due to their wide potential application in the fiel...Over the past decades, two-dimensional（2D） nanomaterials possessing planar layered architecture and unique electronic structures have been being quickly developed, due to their wide potential application in the fields of chemistry, physics, and materials science. As a new family of 2D nanomaterials, 2D polymerbased nanosheets, featuring excellent characters, such as tunable framework structures, light weight, flexibility, high specific surface, and good semiconducting properties, have been emerging as one kind of promising functional materials for optoelectronics, gas separation, catalysis and sensing, etc. In this review, the recent progress in synthetic approach and characterization of 2D polymer-based nanosheets were summarized, and their current advances in electrochemical energy storage and conversion including second batteries, supercapacitors, oxygen reduction and hydrogen evolution were discussed systematically.展开更多
A polymeric nanopore membrane with selective ionic transport has been proposed as a potential device to convert the chemical potential energy in salinity gradients to electrical power. However, its energy conversion e...A polymeric nanopore membrane with selective ionic transport has been proposed as a potential device to convert the chemical potential energy in salinity gradients to electrical power. However, its energy conversion efficiency and power density are often limited due to the challenge in reliably controlling the size of the nanopores with the conventional chemical etching method. Here we report that without chemical etching, polyimide （PI） membranes irradiated with GeV heavy ions have negatively charged nanopores, showing nearly perfect selectivity for cations over anions, and they can generate electrical power from salinity gradients. We further demonstrate that the power generation efficiency of the PI membrane approaches the theoretical limit, and the maximum power density reaches 130m W/m2 with a modified etching method, outperforming the previous energy conversion device that was made of polymeric nanopore membranes.展开更多
The free radical polymerization of styrene in water in the presence of β-cyclodextrin (β-CD) is described. It is found that β-CD could greatly accelerate the polymerization, enhance the final conversion of monomer....The free radical polymerization of styrene in water in the presence of β-cyclodextrin (β-CD) is described. It is found that β-CD could greatly accelerate the polymerization, enhance the final conversion of monomer. The particle-size distribution of the final polymer is also improved than that without β-CD in the system.展开更多
Silicone-acrylate copolymer latex was prepared through three different polymerization processes, i.e., the batch process, preemulsified monomer addition and the monomer addition process. The results revealed that the ...Silicone-acrylate copolymer latex was prepared through three different polymerization processes, i.e., the batch process, preemulsified monomer addition and the monomer addition process. The results revealed that the monomer addition process is a desirable approach to produce narrow particle size distribution latex with higher polymerization conversion and less amount of coagulum. The effect of silicone content on the glossiness and water absorption of latex film was investigated and the results showed that the glossiness of latex film is improved up to a silicone content of 10% of total monomers, but becomes impaired thereafter, whereas water absorption is reduced accordingly.展开更多
In this study, we report narrow-size distribution Zn_2SnO_4（ZSO） nanoparticles, which are produced by low-temperature solution-processed used as the electron extraction layer（EEL） in the inverted polymer solar ce...In this study, we report narrow-size distribution Zn_2SnO_4（ZSO） nanoparticles, which are produced by low-temperature solution-processed used as the electron extraction layer（EEL） in the inverted polymer solar cells（i-PSCs）. Moreover, poly[（9,9-bis（30-（N,N-dimethylamino）propyl）-2,7-fluorene）-alt-2,7-（9,9-dioctylfluorene）]（PFN） is used to modify the surface properties of ZSO thin film. By using the ZSO NPs/PFN as the EEL, the i-PSCs fabricated by poly[4,8-bis（2-ethylhexyloxyl）benzo[1,2-b：4,5-b0] dithio-phene-2,6-diyl-altethylhexyl-3-fluorothithieno [3,4-b]thiophene-2-carboxylate-4,6-diyl]（PTB7） blended with（6,6）-phenyl-C_（71）-butyric acid methylester（PC_（71）BM） bulk heterojunction（BHJ） composite, exhibits a power conversion efficiency（PCE） of 8.44%, which is nearly 10% enhancement as compared with that of7.75% observed from the i-PSCs by PTB7：PC_（71）BM BHJ composite using the ZnO/PFN EEL. The enhanced PCE is originated from improved interfacial contact between the EEL with BHJ active layer and good energy level alignment between BHJ active layer and the EEL. Our results indicate that we provide a simple way to boost efficiency of i-PSCs.展开更多
基金financially supported by the National Natural Science Foundation of China(51403126,21574080,61306018 and 21504057)Shanghai Committee of Science and Technology(15JC1490500,16JC1400703,and 17ZR1441700)+1 种基金Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment(SKLPEE-KF201702,Fuzhou University)State Key Laboratory of Supramolecular Structure and Materials(sklssm201732,Jinlin University)
文摘Over the past decades, two-dimensional（2D） nanomaterials possessing planar layered architecture and unique electronic structures have been being quickly developed, due to their wide potential application in the fields of chemistry, physics, and materials science. As a new family of 2D nanomaterials, 2D polymerbased nanosheets, featuring excellent characters, such as tunable framework structures, light weight, flexibility, high specific surface, and good semiconducting properties, have been emerging as one kind of promising functional materials for optoelectronics, gas separation, catalysis and sensing, etc. In this review, the recent progress in synthetic approach and characterization of 2D polymer-based nanosheets were summarized, and their current advances in electrochemical energy storage and conversion including second batteries, supercapacitors, oxygen reduction and hydrogen evolution were discussed systematically.
基金Supported by the National Natural Science Foundation of China under Grant No 11335003
文摘A polymeric nanopore membrane with selective ionic transport has been proposed as a potential device to convert the chemical potential energy in salinity gradients to electrical power. However, its energy conversion efficiency and power density are often limited due to the challenge in reliably controlling the size of the nanopores with the conventional chemical etching method. Here we report that without chemical etching, polyimide （PI） membranes irradiated with GeV heavy ions have negatively charged nanopores, showing nearly perfect selectivity for cations over anions, and they can generate electrical power from salinity gradients. We further demonstrate that the power generation efficiency of the PI membrane approaches the theoretical limit, and the maximum power density reaches 130m W/m2 with a modified etching method, outperforming the previous energy conversion device that was made of polymeric nanopore membranes.
文摘The free radical polymerization of styrene in water in the presence of β-cyclodextrin (β-CD) is described. It is found that β-CD could greatly accelerate the polymerization, enhance the final conversion of monomer. The particle-size distribution of the final polymer is also improved than that without β-CD in the system.
文摘Silicone-acrylate copolymer latex was prepared through three different polymerization processes, i.e., the batch process, preemulsified monomer addition and the monomer addition process. The results revealed that the monomer addition process is a desirable approach to produce narrow particle size distribution latex with higher polymerization conversion and less amount of coagulum. The effect of silicone content on the glossiness and water absorption of latex film was investigated and the results showed that the glossiness of latex film is improved up to a silicone content of 10% of total monomers, but becomes impaired thereafter, whereas water absorption is reduced accordingly.
基金supported by National Natural Science Foundation of China (No. 51329301)
文摘In this study, we report narrow-size distribution Zn_2SnO_4（ZSO） nanoparticles, which are produced by low-temperature solution-processed used as the electron extraction layer（EEL） in the inverted polymer solar cells（i-PSCs）. Moreover, poly[（9,9-bis（30-（N,N-dimethylamino）propyl）-2,7-fluorene）-alt-2,7-（9,9-dioctylfluorene）]（PFN） is used to modify the surface properties of ZSO thin film. By using the ZSO NPs/PFN as the EEL, the i-PSCs fabricated by poly[4,8-bis（2-ethylhexyloxyl）benzo[1,2-b：4,5-b0] dithio-phene-2,6-diyl-altethylhexyl-3-fluorothithieno [3,4-b]thiophene-2-carboxylate-4,6-diyl]（PTB7） blended with（6,6）-phenyl-C_（71）-butyric acid methylester（PC_（71）BM） bulk heterojunction（BHJ） composite, exhibits a power conversion efficiency（PCE） of 8.44%, which is nearly 10% enhancement as compared with that of7.75% observed from the i-PSCs by PTB7：PC_（71）BM BHJ composite using the ZnO/PFN EEL. The enhanced PCE is originated from improved interfacial contact between the EEL with BHJ active layer and good energy level alignment between BHJ active layer and the EEL. Our results indicate that we provide a simple way to boost efficiency of i-PSCs.
