In this research work, it has been designed a bionic robot fish structure, can swim underwater. The active compact body is powered by eight sets of symmetric PVC gel actuators with a caudal fin. The robot’s 200 mm-lo...In this research work, it has been designed a bionic robot fish structure, can swim underwater. The active compact body is powered by eight sets of symmetric PVC gel actuators with a caudal fin. The robot’s 200 mm-long, fish structure design incorporates a 55.52 angle to optimize the fish dynamics movement. It’s a fast and smooth operation and can swim. The robot can swim fast and quietly by using the right positions and the appropriate actuators on PVC gel actuators. This design entails a unique architecture that enables the robot to move safely and unobtrusively at the same time, which makes it suitable equipment for different exploration and surveillance missions in the water with speed and silent operation as the foremost concern.展开更多
Plasticizers are essential additives in the processing of polyvinyl chloride(PVC),with phthalate plasticizers being widely used.However,these conventional plasticizers have been shown to be harmful to human health and...Plasticizers are essential additives in the processing of polyvinyl chloride(PVC),with phthalate plasticizers being widely used.However,these conventional plasticizers have been shown to be harmful to human health and environmentally unfriendly,necessitating the exploration of eco-friendly bio-based alternatives.In this study,Camellia oleifera seed oil,a specialty resource in China,was utilized as a raw material and reacted with 4,4′-Methylenebis(N,N-diglycidylaniline)(AG-80)to synthesize Phenyl Camellia seed Oil Ester(PCSOE).PCSOE was employed as a plasticizer to prepare modified PVC films with varying concentrations,with the conventional plasticizer dioctyl phthalate(DOP)serving as a control.Experimental results demonstrate that PSCOE-plasticized PVC films exhibit enhanced hydrophilicity,tensile strength,and thermal stability compared to DOP-modified PVC films.The contact angle of PSCOE-plasticized PVC films ranges from 66.26°to 78.48°,which is generally lower than the contact angle of DOP-modified PVC films at 78.40°,indicating improved hydrophilicity due to the modification with PCSOE.The tensile strength of PSCOE-plasticized PVC films ranges from 17.73 to 20.17 MPa,all surpassing the value of 16.41 MPa for DOP-modified PVC films.Moreover,the temperatures corresponding to 5%,10%,and 50%weight loss for PVC samples modified with PCSOE are higher than those for DOP.Hence,PCSOE presents a viable alternative to DOP as a plasticizer for PVC materials.展开更多
The copolymers were formed by the graft copolymerization of PVC with acrylic rare earth. The principle and method of the graft copolymerization of PVC and acrylic rare earth were discussed. The graft copolymers were c...The copolymers were formed by the graft copolymerization of PVC with acrylic rare earth. The principle and method of the graft copolymerization of PVC and acrylic rare earth were discussed. The graft copolymers were characterized by FT-IR spectra and scanning electron microscope (SEM).The thermal stability of the graft-copolymers was studied by thermogravimetric analysis (TG). The experiment results show that the thermal resistance and toughness of the graft copolymers are obviously enhanced.展开更多
For obtaining the drying curve of powder under fluidized drying, a normal fluidized-bed dryer is designed to study the drying kinetics of PVC （polyvinyl chloride） powder in the experiment. A new measure system is de...For obtaining the drying curve of powder under fluidized drying, a normal fluidized-bed dryer is designed to study the drying kinetics of PVC （polyvinyl chloride） powder in the experiment. A new measure system is derived for drying dynamics testing. In the small fluidized-bed dryer, fluidization parameter of PVC powder is tested, and the operating air velocity can be chosen in the range of 0. 41 to 0. 55 m/s. Accordingly, the fluidized number Ua/Umf is from 1.24 to 1.67. A promising drying model is used to describe the drying process, and then the characteristic drying curve of PVC powder derived from a suspension method can be expressed as f = [-0. 622 6 ＋ 1. 254 6exp（2. 561 5Φ -0. 707 2） /[1 ＋ exp（2. 561 5Φ -0. 707 2）] Based on the experiments, the critical moisture content xc and the mass transfer coefficient K are determined to be 0. 02 kg/kg and 6. 0 × 10^-4 kg/（ m2 · s）, respectively. The experimental results in the small fluidized-bed dryer are similar to those of the real fluidized drying process, so the descried method can also be used in determining drying kinetics of powder materials such as PVC powder.展开更多
Series of PVC/ABS and PVC/SBS blends of composition 20/ 80. 40/ 60, 60 / 40 and 80 / 20were prepared in a screw extruder. The phase morphology, miscibility and rheological behaviour of two systems were investigated. T...Series of PVC/ABS and PVC/SBS blends of composition 20/ 80. 40/ 60, 60 / 40 and 80 / 20were prepared in a screw extruder. The phase morphology, miscibility and rheological behaviour of two systems were investigated. The viscosity-composition plots were represented by sub-cluster equation, the various differences between two systems are interpreted with the equation parameters展开更多
本文采用指数组合近 S 型过程逼近的理论方法。确定了在不同容剂下 PVC 与硫酚钠亲核反应的动力学方程。并将动力学参数与溶剂性质相比较,发现溶剂的偶极矩、介电常数分别与不同的动力学参数具有明显的相关性。溶剂的偶极矩、介电常数越...本文采用指数组合近 S 型过程逼近的理论方法。确定了在不同容剂下 PVC 与硫酚钠亲核反应的动力学方程。并将动力学参数与溶剂性质相比较,发现溶剂的偶极矩、介电常数分别与不同的动力学参数具有明显的相关性。溶剂的偶极矩、介电常数越大,越有利于该反应的进行。展开更多
Three new 'tailed' porphyrins and their corresponding Mn(Ⅲ) metalloporphyrins were synthesized and characterized. The potentiometric response characteristics of the PVC membrane electrode based on the Mn(Ⅲ...Three new 'tailed' porphyrins and their corresponding Mn(Ⅲ) metalloporphyrins were synthesized and characterized. The potentiometric response characteristics of the PVC membrane electrode based on the Mn(Ⅲ) complexes of the three new 'tailed' porphyrins toward SCN- have been studied.展开更多
文摘In this research work, it has been designed a bionic robot fish structure, can swim underwater. The active compact body is powered by eight sets of symmetric PVC gel actuators with a caudal fin. The robot’s 200 mm-long, fish structure design incorporates a 55.52 angle to optimize the fish dynamics movement. It’s a fast and smooth operation and can swim. The robot can swim fast and quietly by using the right positions and the appropriate actuators on PVC gel actuators. This design entails a unique architecture that enables the robot to move safely and unobtrusively at the same time, which makes it suitable equipment for different exploration and surveillance missions in the water with speed and silent operation as the foremost concern.
基金funded by the Scarce and Quality Economic Forest Engineering Technology Research Center(2022GCZX002)the Key Lab.of Biomass Energy and Material,Jiangsu Province(Grant No.JSBEM-S-202305).
文摘Plasticizers are essential additives in the processing of polyvinyl chloride(PVC),with phthalate plasticizers being widely used.However,these conventional plasticizers have been shown to be harmful to human health and environmentally unfriendly,necessitating the exploration of eco-friendly bio-based alternatives.In this study,Camellia oleifera seed oil,a specialty resource in China,was utilized as a raw material and reacted with 4,4′-Methylenebis(N,N-diglycidylaniline)(AG-80)to synthesize Phenyl Camellia seed Oil Ester(PCSOE).PCSOE was employed as a plasticizer to prepare modified PVC films with varying concentrations,with the conventional plasticizer dioctyl phthalate(DOP)serving as a control.Experimental results demonstrate that PSCOE-plasticized PVC films exhibit enhanced hydrophilicity,tensile strength,and thermal stability compared to DOP-modified PVC films.The contact angle of PSCOE-plasticized PVC films ranges from 66.26°to 78.48°,which is generally lower than the contact angle of DOP-modified PVC films at 78.40°,indicating improved hydrophilicity due to the modification with PCSOE.The tensile strength of PSCOE-plasticized PVC films ranges from 17.73 to 20.17 MPa,all surpassing the value of 16.41 MPa for DOP-modified PVC films.Moreover,the temperatures corresponding to 5%,10%,and 50%weight loss for PVC samples modified with PCSOE are higher than those for DOP.Hence,PCSOE presents a viable alternative to DOP as a plasticizer for PVC materials.
文摘The copolymers were formed by the graft copolymerization of PVC with acrylic rare earth. The principle and method of the graft copolymerization of PVC and acrylic rare earth were discussed. The graft copolymers were characterized by FT-IR spectra and scanning electron microscope (SEM).The thermal stability of the graft-copolymers was studied by thermogravimetric analysis (TG). The experiment results show that the thermal resistance and toughness of the graft copolymers are obviously enhanced.
文摘For obtaining the drying curve of powder under fluidized drying, a normal fluidized-bed dryer is designed to study the drying kinetics of PVC （polyvinyl chloride） powder in the experiment. A new measure system is derived for drying dynamics testing. In the small fluidized-bed dryer, fluidization parameter of PVC powder is tested, and the operating air velocity can be chosen in the range of 0. 41 to 0. 55 m/s. Accordingly, the fluidized number Ua/Umf is from 1.24 to 1.67. A promising drying model is used to describe the drying process, and then the characteristic drying curve of PVC powder derived from a suspension method can be expressed as f = [-0. 622 6 ＋ 1. 254 6exp（2. 561 5Φ -0. 707 2） /[1 ＋ exp（2. 561 5Φ -0. 707 2）] Based on the experiments, the critical moisture content xc and the mass transfer coefficient K are determined to be 0. 02 kg/kg and 6. 0 × 10^-4 kg/（ m2 · s）, respectively. The experimental results in the small fluidized-bed dryer are similar to those of the real fluidized drying process, so the descried method can also be used in determining drying kinetics of powder materials such as PVC powder.
文摘Series of PVC/ABS and PVC/SBS blends of composition 20/ 80. 40/ 60, 60 / 40 and 80 / 20were prepared in a screw extruder. The phase morphology, miscibility and rheological behaviour of two systems were investigated. The viscosity-composition plots were represented by sub-cluster equation, the various differences between two systems are interpreted with the equation parameters
文摘Three new 'tailed' porphyrins and their corresponding Mn(Ⅲ) metalloporphyrins were synthesized and characterized. The potentiometric response characteristics of the PVC membrane electrode based on the Mn(Ⅲ) complexes of the three new 'tailed' porphyrins toward SCN- have been studied.
