Three kinds of polypyrrolones (PMDA-DAB, PMDA-TADPE and DEDA-DAB) were pyrolyzed at high temperature in order to study the effect of the chain structure of polypyrrolones on the electrical properties of the pyrolyzed ...Three kinds of polypyrrolones (PMDA-DAB, PMDA-TADPE and DEDA-DAB) were pyrolyzed at high temperature in order to study the effect of the chain structure of polypyrrolones on the electrical properties of the pyrolyzed polymers. Results show that the number of fusing rings in the main chain of polymers has a little effect on the pyrolysis process, whereas, the ether bond in the main chain plays an important role during pyrolysis. Structure characterizations by elemental analysis, XPS spectra, X-ray diffraction and SEM images indicate that because the ether bond is easy to break, it is difficult to form large area planar network. This hampers the formation of the graphite-like structure in the polypyrrolones containing ether bond even after being pyrolyzed at 1200 degrees C.展开更多
A new type of aromatic tetraarnine containing biphenyl moiety in the side chain was synthesized via a modified Chichibabin＇s reaction. 3-Nitro-4-acetamidoacetophenone was reacted with 4-phenyl benzaldehyde in the pre...A new type of aromatic tetraarnine containing biphenyl moiety in the side chain was synthesized via a modified Chichibabin＇s reaction. 3-Nitro-4-acetamidoacetophenone was reacted with 4-phenyl benzaldehyde in the presence of ammonium acetate to obtain 2,6-bis（3＇,4＇-diaminophenyl）-4-biphenyl pyridine （DPPA）. A series of polypyrrolones （PPys） were prepared using tetraamine and various aromatic dianhydrides via a two-step cyclization procedure. All the PPys show excellent high temperature stabilities with the initial decomposition temperatures of 530-549℃ and residual weight ratio of 49%-80% at 750℃ in nitrogen. The polymers exhibit no apparent glass transition temperatures （Tgs） except PPy-1 （Tg= 327℃）, which is derived from tetraamine DPPA and 2,2-bis[4-（3＇,4＇-dicarboxyphenoxy）-phenyl]propane dianhydride （BPADA）. In addition, the polymers have acceptable mechanical properties with the tensile strength of 65-94 MPa. The PPy films show excellent hydrolysis-resistance in alkaline aqueous medium and could maintain most of the properties even after boiling in 10% aqueous sodium hydroxide solution for a week.展开更多
基金The project supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences Foundation.
文摘Three kinds of polypyrrolones (PMDA-DAB, PMDA-TADPE and DEDA-DAB) were pyrolyzed at high temperature in order to study the effect of the chain structure of polypyrrolones on the electrical properties of the pyrolyzed polymers. Results show that the number of fusing rings in the main chain of polymers has a little effect on the pyrolysis process, whereas, the ether bond in the main chain plays an important role during pyrolysis. Structure characterizations by elemental analysis, XPS spectra, X-ray diffraction and SEM images indicate that because the ether bond is easy to break, it is difficult to form large area planar network. This hampers the formation of the graphite-like structure in the polypyrrolones containing ether bond even after being pyrolyzed at 1200 degrees C.
基金This project was supported by the National Natural Science Foundation of China(No.50403025).
文摘A new type of aromatic tetraarnine containing biphenyl moiety in the side chain was synthesized via a modified Chichibabin＇s reaction. 3-Nitro-4-acetamidoacetophenone was reacted with 4-phenyl benzaldehyde in the presence of ammonium acetate to obtain 2,6-bis（3＇,4＇-diaminophenyl）-4-biphenyl pyridine （DPPA）. A series of polypyrrolones （PPys） were prepared using tetraamine and various aromatic dianhydrides via a two-step cyclization procedure. All the PPys show excellent high temperature stabilities with the initial decomposition temperatures of 530-549℃ and residual weight ratio of 49%-80% at 750℃ in nitrogen. The polymers exhibit no apparent glass transition temperatures （Tgs） except PPy-1 （Tg= 327℃）, which is derived from tetraamine DPPA and 2,2-bis[4-（3＇,4＇-dicarboxyphenoxy）-phenyl]propane dianhydride （BPADA）. In addition, the polymers have acceptable mechanical properties with the tensile strength of 65-94 MPa. The PPy films show excellent hydrolysis-resistance in alkaline aqueous medium and could maintain most of the properties even after boiling in 10% aqueous sodium hydroxide solution for a week.
