In this article,the experimental and finite element analysis is utilized to investigate the quasi-static compression features of sandwich constructions built with tapered tubes.3D printing technology was utilized to c...In this article,the experimental and finite element analysis is utilized to investigate the quasi-static compression features of sandwich constructions built with tapered tubes.3D printing technology was utilized to create the hollow centers of the tapering tubes,with and without corrugations.The results demonstrate that the energy absorption(EA)and specific energy absorption(SEA)of the single corrugated tapered tube sandwich are 51.6% and 19.8% higher,respectively,than those of the conical tube sandwich.Furthermore,the results demonstrate that energy absorbers can benefit from corrugation in order to increase their efficiency.Additionally,the tapered corrugated tubes'resistance to oblique impacts was studied.Compared to a straight tube,the tapered tube is more resistant to oblique loads and has a lower initial peak crushing force(PCF),according to numerical simulations.After conducting a parametric study,it was discovered that the energy absorption performance of the sandwich construction is significantly affected by the amplitude,number of corrugations,and wall thickness.EA and SEA of DTS with corrugation number of 8 increased by 17.4%and 29.6%,respectively,while PCF decreased by 9.2% compared to DTS with corrugation number of 10.展开更多
In this paper,the numerical simulation method is used to study the ballistic performances of hourglass lattice sandwich structures with the same mass under the vertical incidence of fragments.Attention is paid to eluc...In this paper,the numerical simulation method is used to study the ballistic performances of hourglass lattice sandwich structures with the same mass under the vertical incidence of fragments.Attention is paid to elucidating the influences of rod cross-section dimensions,structure height,structure layer,and rod inclination angle on the deformation mode,ballistic performances,and ability to change the ballistic direction of fragments.The results show that the ballistic performances of hourglass lattice sandwich structures are mainly affected by their structural parameters.In this respect,structural parameters optimization of the hourglass lattice sandwich structures enable one to effectively improve their ballistic limit velocity and,consequently,ballistic performances.展开更多
Biomass‐derived carbon is a promising electrode material in energy storage devices.However,how to improve its low capacity and stability,and slow diffusion kinetics during lithium storage remains a challenge.In this ...Biomass‐derived carbon is a promising electrode material in energy storage devices.However,how to improve its low capacity and stability,and slow diffusion kinetics during lithium storage remains a challenge.In this research,we propose a“self‐assembly‐template”method to prepare B,N codoped porous carbon(BN‐C)with a nanosandwich structure and abundant pyridinic N‐B species.The nanosandwich structure can increase powder density and cycle stability by constructing a stable solid electrolyte interphase film,shortening the Li^(+)diffusion pathway,and accommodating volume expansion during repeated charging/discharging.The abundant pyridinic N‐B species can simultaneously promote the adsorption/desorption of Li^(+)/PF_(6)^(−)and reduce the diffusion barrier.The BN‐C electrode showed a high lithium‐ion storage capacity of above 1140 mAh g^(−1)at 0.05 A g^(−1)and superior stability(96.5%retained after 2000 cycles).Moreover,owing to the synergistic effect of the nanosandwich structure and pyridinic N‐B species,the assembled symmetrical BN‐C//BN‐C full cell shows a high energy density of 234.7Wh kg^(−1),high power density of 39.38 kW kg−1,and excellent cycling stability,superior to most of the other cells reported in the literature.As the density functional theory simulation demonstrated,pyridinic N‐B shows enhanced adsorption activity for Li^(+)and PF_(6)^(−),which promotes an increase in the capacity of the anode and cathode,respectively.Meanwhile,the relatively lower diffusion barrier of pyridinic N‐B promotes Li^(+)migration,resulting in good rate performance.Therefore,this study provides a new approach for the synergistic modulation of a nanostructure and an active site simultaneously to fabricate the carbon electrode material in energy storage devices.展开更多
The sandwich structure of cushioning packaging has an important influence on the cushioning performance.Mathematical fractal theory is an important graphic expression.Based on Hilbert fractal theory,a new sandwich str...The sandwich structure of cushioning packaging has an important influence on the cushioning performance.Mathematical fractal theory is an important graphic expression.Based on Hilbert fractal theory,a new sandwich structure was designed.The generation mechanism and recurrence formula of theHilbert fractal were expressed by Lin’s language,and the second-orderHilbert sandwich structure was constructed fromthermoplastic polyurethane.The constitutive model of the hyperelastic body was established by using the finite element method.With the unit mass energy absorption as the optimization goal,the fractal sandwich structure was optimized,and the best result was obtained when the order was 2.5 and the unit layer thickness was 0.75 mm.TheHilbert sandwich structure was compared with the rice-shaped sandwich structure commonly used in industry,and the Hilbert fractal structure had better energy absorption.This has practical significance for the development and application of newcushioning packaging structures.展开更多
Potential damage in composite structures caused by hail ice impact is an essential safety threat to the aircraft in flight.In this study,a nonlinear finite element(FE)model is developed to investigate the dynamic resp...Potential damage in composite structures caused by hail ice impact is an essential safety threat to the aircraft in flight.In this study,a nonlinear finite element(FE)model is developed to investigate the dynamic response and damage behavior of hybrid corrugated sandwich structures subjected to high velocity hail ice impact.The impact and breaking behavior of hail are described using the FE-smoothed particle hydrodynamics(FE-SPH)method.A rate-dependent progressive damage model is employed to capture the intra-laminar damage response;cohesive element and surface-based cohesive contact are implemented to predict the inter-laminar delamination and sheet/core debonding phenomena respectively.The transient processes of sandwich structure under different hail ice impact conditions are analyzed.Comparative analysis is conducted to address the influences of core shape and impact position on the impact performance of sandwich structures and the corresponding energy absorption characteristics are also revealed.展开更多
In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gu...In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gun.A sharp conical nosed projectile was impacted normally and with some offset distance(20 mm and 40 mm).The deformation,failure mode and energy dissipation characteristics were obtained for both kinds of loading.Moreover,the explicit solver was run in Abaqus to create the finite element model.The numerically obtained test results were compared with the experimental to check the accuracy of the modelling.The numerical result was further employed to obtain strain energy dissipation in each element by externally running user-defined code in Abaqus.Furthermore,the influence of inscribe circle diameter and cell wall and face sheet thickness on the energy dissipation,deformation and failure mode was examined.The result found that ballistic resistance and deformation were higher against offset impact compared to the normal impact loading.Sandwich panel impacted at 40 mm offset distance required 3 m/s and 1.9 m/s more velocity than 0 and 20 mm offset distance.Also,increasing the face sheet and wall thickness had a positive impact on the ballistic resistance in terms of a higher ballistic limit and energy absorption.However,inscribe circle diameter had a negative influence on the ballistic resistance.Also,the geometrical parameters of the sandwich structure had a significant influence on the energy dissipation in the different deformation directions.The energy dissipation in plastic work was highest for circumferential direction,regardless of impact condition followed by tangential,radial and axial directions.展开更多
Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water...Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water.Herein,a sandwich composite structure(designed as MS-Mo2C@NCNS)ofβ-Mo2C hollow nanotubes(HNT)and N-doped carbon nanosheets(NCNS)is designed and prepared using a binary NaCl–KCl molten salt(MS)strategy for HER.The temperature-dominant Kirkendall formation mechanism is tentatively proposed for such a three-dimensional hierarchical framework.Due to its attractive structure and componential synergism,MS-Mo2C@NCNS exposes more effective active sites,confers robust structural stability,and shows significant electrocatalytic activity/stability in HER,with a current density of 10 mA cm-2 and an overpotential of only 98 mV in 1 M KOH.Density functional theory calculations point to the synergistic effect of Mo2C HNT and NCNS,leading to enhanced electronic transport and suitable adsorption free energies of H*(ΔGH*)on the surface of electroactive Mo2C.More significantly,the MS-assisted synthetic methodology here provides an enormous perspective for the commercial development of highly active non-noble metal electrocatalysts toward efficient hydrogen evolution.展开更多
Novel sandwich structure-like nanofiber multilayered meshes were fabricated via electrospinning. The purpose of the present work was to control zoledronic acid release via the novel structure of sandwich structure-lik...Novel sandwich structure-like nanofiber multilayered meshes were fabricated via electrospinning. The purpose of the present work was to control zoledronic acid release via the novel structure of sandwich structure-like meshes. The in vitro release experiments reveal that the drug release speed and initial burst release were controllable by adjusting the thicknesses of electrospun barrier mesh and drug-loaded mesh. Compared with those of other drug delivery systems, the main advantages of the sandwich structure-like fiber meshes are facile preparation conditions and the generality for hydrophobic and hydrophilic pharmaceuticals.展开更多
Due to the incompatibility of the interlaminar deformations,the interface debonding or cracking usually happens in a layered magnetoelectric(ME)structure under an applied load.In this paper,the transient responses of ...Due to the incompatibility of the interlaminar deformations,the interface debonding or cracking usually happens in a layered magnetoelectric(ME)structure under an applied load.In this paper,the transient responses of the anti-plane interface cracks in piezoelectric(PE)-piezomagnetic(PM)sandwich structures are studied by the standard methods of the integral transform and singular integral equation.Discussion on the numerical examples indicates that the PE-PM-PE structure under electric impact is more likely to fracture than the PM-PE-PM structure under a magnetic impact.The dynamic stress intensity factors(DSIFs)are more sensitive to the variation of the active layer thickness.The effects of the material constants on the DSIFs are dependent on the roles played by PE and PM media during the deformation process.展开更多
Aircraft laminated composite components often suffer a variety of high velocity impacts with large quantity of energy,which usually affects aircraft behavior and would incur component damages,even disastrous consequen...Aircraft laminated composite components often suffer a variety of high velocity impacts with large quantity of energy,which usually affects aircraft behavior and would incur component damages,even disastrous consequences.Therefore,one investigates the impact resistance of a new type of composite material,Ti/CFRP/Ti sandwich structure,and launches impact tests by using an air gun test system.Then one acquires the critical breakthrough rate of the structure and analyzes the damages.The results show that the main failure mode of the front titanium sheet is shear plugging and brittle fracture of adhesive layer with fiber breakage,while the back titanium sheet is severely ripped.The rear damage is worse than the front one.Compared with traditional CFRP laminates,the critical breakthrough rate of Ti/CFRP/Ti sandwich structure is improved by 69.9% when suffered the impact of a bearing ball with 2mm radius.展开更多
Ship collision accidents are catastrophic accidents, and as the main energy-absorbing structure, the anti-collision capacity of the side structure has an important influence on the crashworthiness of the ship. It is n...Ship collision accidents are catastrophic accidents, and as the main energy-absorbing structure, the anti-collision capacity of the side structure has an important influence on the crashworthiness of the ship. It is necessary to improve the crashworthiness of the ship by increasing energy absorption of the side structure, in such ways as adding a filling sandwich in a single hull. The aim of the present study is to discuss the crashworthiness of the side structure stressed under lateral dynamic loads through simulation with the finite element code MSC/Dytran. The collision force, the damage deformation, the critical collision speed as well as the energy absorption of a side structure improved with a filling sandwich are compared to the standard structure through numerical simulations. The results indicate that a sandwich panel structure is an advanced ship protection structure that can remarkably improve the ability of the side structure to withstand collisions; the effect of the tube-style sandwich panel structure has the best results. The outcome of this study provides a reference for the crashworthiness assessment of side structures and the crashworthiness optimization design of new side structures.展开更多
The so-called″X-cor sandwich structure″is a highly promising novel material as an alternative to honeycomb used in aircraft.Although much work has been conducted on the performance of the X-cor sandwich structure,th...The so-called″X-cor sandwich structure″is a highly promising novel material as an alternative to honeycomb used in aircraft.Although much work has been conducted on the performance of the X-cor sandwich structure,the gap is still hardly bridged between experimental results and theoretical analyses.Therefore,a method has been innovated to establish semi-empirical formula for the prediction of compressive and shear moduli of X-cor sandwich structure composites,by combining theoretical analyses and experimental data.In addition,aprediction software was first developed based on the proposed method,of which the accuracy was verified through confirmatory experiments.This software can offer a direct reference or guide for engineers in structural designing.展开更多
The propagation of acoustic waves in a homogeneous isotropic semiconducting layer sandwiched between two homogeneous transversely isotropic piezoelectric halfspaces has been investigated. The mathematical model of the...The propagation of acoustic waves in a homogeneous isotropic semiconducting layer sandwiched between two homogeneous transversely isotropic piezoelectric halfspaces has been investigated. The mathematical model of the problem is depicted by a set of partial differential equations of motion, Gauss equation in piezoelectric material and electron diffusion equation in semiconductor along with the boundary conditions to be satisfied at the piezoelectric-semiconductor interfaces. The secular equations describing the symmetric and asymmetric modes of wave propagation have been derived in compact form after obtaining the analytical expressions for various field quantities that govern the wave motion. The complex secular equation has been solved numerically using functional interaction method along with irreducible cardano method. The computer simulated results are obtained with the help of MATLAB software for 6 mm cadmium selenide (CdSe) piezoelectric material and n-type silicon (Si) semiconductor in respect of dispersion curve, attenuation and specific loss factor of energy dissipation for symmetric (sym) and asymmetric (asym) modes of wave propagation. The study may find applications in non-destructive testing, resonators, waveguides etc.展开更多
A wood-based X-type lattice sandwich structure was manufactured by insertion-glue method.The birch was used as core,and Oriented Strand Board was used as panel of the sandwich structure.The short beam shear properties...A wood-based X-type lattice sandwich structure was manufactured by insertion-glue method.The birch was used as core,and Oriented Strand Board was used as panel of the sandwich structure.The short beam shear properties and the failure modes of the wood-based X-type lattice sandwich structure with different core direction(vertical and parallel),unit specification(120 mm×60 mm and 60 mm×60 mm),core size(50 mm and 60 mm),and drilling depth(9 mm and 12 mm)were investigated by a short beam shear test and the establishment of a theoretical model to study the equivalent shear modulus and deflection response of the X-type lattice sandwich structure.Results from the short beam shear test and the theoretical model showed that the failure modes of the wood-based X-type lattice sandwich structure were mainly the wrinkling and crushing of the panels under three-point bending load.The experimental values of deflection response of various type specimens were higher than the theoretical values of them.For the core direction of parallel,the smaller the unit specification is,the shorter the core size is,and the deeper the drilling depth is,the greater the short beam shear properties of the wood-based X-type lattice sandwich structure is.展开更多
Ion transport of sandwich cementitious materials(SCM) exposed to chloride environment was investigated by accelerated diffusion method and natural diffusion method. Pore structure and micromorphology of SCM were inv...Ion transport of sandwich cementitious materials(SCM) exposed to chloride environment was investigated by accelerated diffusion method and natural diffusion method. Pore structure and micromorphology of SCM were investigated by MIP and SEM-EDS. In comparison with the monolayer structural high performance concrete(HPC), conductive charge for 6 hours, chloride diffusion coefficient, and apparent chloride diffusion coeffi cient of SCM were decreased by 30%-40%, two orders of magnitude and 40%-50%, respectively. Pore structure of ultra low ion permeability cementitious materials(ULIPCM) prepared for the facesheet is superior to that of HPC prepared for the core. As for porosity, the most probable pore radius, the content of pores with radius 50 nm and the surface area of pores, the order is ULIPCM展开更多
This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (...This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (SEM). As the world is garnering attention towards renewable resources for environmental purposes, studies of natural fibre have been increasing as well as the application of natural fibre throughout various industries such as aerospace, automobiles, and construction sectors. This paper is started with brief information regarding the honeycomb sandwich structure, introduction to natural fibre, its applications as well as the factors affecting the performances of the structure. Next, the mechanical testing methods are listed out as well as the expected outcomes obtained from the respective testing. The mechanical properties are also identified by conducting lab tests according to the ASTM standard for sandwich and core structures. The microstructure of the deformed samples is then examined under Scanning Electron Microscope (SEM) by using different magnifications to study the failure mechanisms of the samples. The images obtained from the SEM test are analyzed by using fractography which will show the failure modes of the samples. This article is based on past research conducted by professional on the related topic.展开更多
Natural Fiber Honeycomb (NFH) sandwiched structure composite is a type of composite that uses natural fiber as the reinforcement material and honeycomb structure in the form of a sandwich panel. The demand for commerc...Natural Fiber Honeycomb (NFH) sandwiched structure composite is a type of composite that uses natural fiber as the reinforcement material and honeycomb structure in the form of a sandwich panel. The demand for commercial use of natural fiber-based composites is increasing in the past few years in many industrial sectors. The increase in popularity of natural fibers is because of their particular properties, price, health benefits, and recyclability. This paper aims to analyze the data and analysis of the past research about NFH sandwiched structure composite in terms of the materials used to make the NFH, the physical and mechanical properties, and their applications. Based on the literature review conducted, there were many types of materials used to make the NFH sandwiched structure composite. Some experimental tests were planned and conducted to analyze the mechanical properties of the NFH and its potential to be used in the desired industries. However, there are not many implementations of NFH composite in the construction industry. This is due to the concern related to the issue of the structural integrity of the NFH composite. From the literature review conducted, most of the research shows a positive analysis of the mechanical properties and the potential of the developed NFH to be used for the targeted industry in the study. Therefore, it can be observed that the material used in this study has a high potential to be used in the construction industry.展开更多
In order to make a breakthrough in Mesozoic-Paleozoic shale gas exploration in the South Yellow Sea Basin,a comparison of the preservation conditions was made within the Barnett shale gas reservoirs in the Fortworth B...In order to make a breakthrough in Mesozoic-Paleozoic shale gas exploration in the South Yellow Sea Basin,a comparison of the preservation conditions was made within the Barnett shale gas reservoirs in the Fortworth Basin,the Jiaoshiba shale gas reservoirs in Sichuan Basin and potential shale gas reservoirs in Guizhou Province.The results show that the "Sandwich"structure is of great importance for shale gas accumulation.Therein to,the "Sandwich"structure is a kind of special reservoir-cap rock assemblage which consist of limestone or dolomite on the top,mudstone or shale layer in the middle and limestone or dolomite at the bottom.In consideration of the Mesozoic-Paleozoie in the Lower Yangtze,and Laoshan Uplift with weak Paleozoic deformation and thrust fault sealing On both flanks of the Laoshan Uplift,a conclusion can be drawn that the preservation conditions of shale gas probably developed "Sandwich" structures in the Lower Cambrian and Permian,which are key layers for the breakthrough of shale gas in the South Yellow Sea.Moreover,the preferred targets for shale gas drilling probably locate at both flanks of the Laoshan Uplift.展开更多
An idea to develop a family of cellular cores for sandwich panels using a technology of prepreg folding is presented. Polar folded quadra structures are regarded as a geometric basis for these cores whose standard fra...An idea to develop a family of cellular cores for sandwich panels using a technology of prepreg folding is presented. Polar folded quadra structures are regarded as a geometric basis for these cores whose standard frag ment has lhe fourlh degree of axial symmelry. The classification of the polar strucluresaredeseribedanda method of various quadra slrueture synthesis is developed. A possibilily to provide high strength of lhe structure due m preservation of faces reinforcement pattern is presented. Arrangemen! of the plane core on a bi curvature surface is also introduced. Besides, provision of isotropyof the core in two or three directions are described. Finally, exam ples of cellular folded cores manufaclured from basalt reinforced plaslic are demonslrated.展开更多
The title compound {[Cu(abpy)2](H3bptc)·(H2O)}n, an ion-pair complex of [Cu(abpy)2]+ with [(H3bptc)]- (abpy = 3,3'-dimethyl-2,2'-bipyridine and H4bptc = 1,1'-biphenyl-2,2',3,3'-tetracarboxylic a...The title compound {[Cu(abpy)2](H3bptc)·(H2O)}n, an ion-pair complex of [Cu(abpy)2]+ with [(H3bptc)]- (abpy = 3,3'-dimethyl-2,2'-bipyridine and H4bptc = 1,1'-biphenyl-2,2',3,3'-tetracarboxylic acid), has been synthesized by a hydrothermal reaction, and its structure was deter- mined by X-ray diffraction and characterized by elemental analysis and IR spectrum. The crystal is of triclinic, space group P1 with a = 8.4955(12), b = 15.164(2), c = 15.303(2), α = 105.704(3), β = 97.374(3), γ = 96.764(3)o, CuC40H35N4O9, Mr = 779.26, V = 1857.9(4)3, Dc = 1.393 g/cm3, F(000) = 808, μ = 0.649 mm-1, S = 1.026 and Z = 2. The final R = 0.0493 and wR = 0.1034 for 4026 observed reflections with I 2σ(I). The copper(I) coordination polymer demonstrates a 3-D sandwich-type structure containing 2-D double H3bptc-chain layers intercalated with the [Cu(abpy)2]+ layers by extensive hydrogen bonding interactions.展开更多
基金the grants from the National Natural Science Foundation of China(Nos.52078152 and 12002095)Guangzhou Government-University Union Fund(No.202201020532)。
文摘In this article,the experimental and finite element analysis is utilized to investigate the quasi-static compression features of sandwich constructions built with tapered tubes.3D printing technology was utilized to create the hollow centers of the tapering tubes,with and without corrugations.The results demonstrate that the energy absorption(EA)and specific energy absorption(SEA)of the single corrugated tapered tube sandwich are 51.6% and 19.8% higher,respectively,than those of the conical tube sandwich.Furthermore,the results demonstrate that energy absorbers can benefit from corrugation in order to increase their efficiency.Additionally,the tapered corrugated tubes'resistance to oblique impacts was studied.Compared to a straight tube,the tapered tube is more resistant to oblique loads and has a lower initial peak crushing force(PCF),according to numerical simulations.After conducting a parametric study,it was discovered that the energy absorption performance of the sandwich construction is significantly affected by the amplitude,number of corrugations,and wall thickness.EA and SEA of DTS with corrugation number of 8 increased by 17.4%and 29.6%,respectively,while PCF decreased by 9.2% compared to DTS with corrugation number of 10.
基金supported by the Defense Industrial Technology Development Program(Grant No.JCKY2018604B004)the National Natural Science Foundation of China(Grant No.11972007)。
文摘In this paper,the numerical simulation method is used to study the ballistic performances of hourglass lattice sandwich structures with the same mass under the vertical incidence of fragments.Attention is paid to elucidating the influences of rod cross-section dimensions,structure height,structure layer,and rod inclination angle on the deformation mode,ballistic performances,and ability to change the ballistic direction of fragments.The results show that the ballistic performances of hourglass lattice sandwich structures are mainly affected by their structural parameters.In this respect,structural parameters optimization of the hourglass lattice sandwich structures enable one to effectively improve their ballistic limit velocity and,consequently,ballistic performances.
基金Jiangsu Key Lab of Biomass Energy and Material,Grant/Award Number:JSBEMS‐202101National Natural Science Foundation of China,Grant/Award Numbers:51902162,51902162+4 种基金National Key R&D Program of China,Grant/Award Number:2022YFB4201904Foundation of Jiangsu Key Lab of Biomass Energy and Material,Grant/Award Number:JSBEM‐S‐202101National Key R&D Program,Grant/Award Number:2022YFB4201904Jiangsu Co‐Innovation Center of Efficient Processing and Utilization of Forest Resources,the International Innovation Center for Forest Chemicals and Materialsanjing Forestry University。
文摘Biomass‐derived carbon is a promising electrode material in energy storage devices.However,how to improve its low capacity and stability,and slow diffusion kinetics during lithium storage remains a challenge.In this research,we propose a“self‐assembly‐template”method to prepare B,N codoped porous carbon(BN‐C)with a nanosandwich structure and abundant pyridinic N‐B species.The nanosandwich structure can increase powder density and cycle stability by constructing a stable solid electrolyte interphase film,shortening the Li^(+)diffusion pathway,and accommodating volume expansion during repeated charging/discharging.The abundant pyridinic N‐B species can simultaneously promote the adsorption/desorption of Li^(+)/PF_(6)^(−)and reduce the diffusion barrier.The BN‐C electrode showed a high lithium‐ion storage capacity of above 1140 mAh g^(−1)at 0.05 A g^(−1)and superior stability(96.5%retained after 2000 cycles).Moreover,owing to the synergistic effect of the nanosandwich structure and pyridinic N‐B species,the assembled symmetrical BN‐C//BN‐C full cell shows a high energy density of 234.7Wh kg^(−1),high power density of 39.38 kW kg−1,and excellent cycling stability,superior to most of the other cells reported in the literature.As the density functional theory simulation demonstrated,pyridinic N‐B shows enhanced adsorption activity for Li^(+)and PF_(6)^(−),which promotes an increase in the capacity of the anode and cathode,respectively.Meanwhile,the relatively lower diffusion barrier of pyridinic N‐B promotes Li^(+)migration,resulting in good rate performance.Therefore,this study provides a new approach for the synergistic modulation of a nanostructure and an active site simultaneously to fabricate the carbon electrode material in energy storage devices.
基金supported by the Natural Science Foundation of Tianjin Munici-pality[21YDTPJC00480]the Science and Technology Project of Tianjin[20YDTPJC00830].
文摘The sandwich structure of cushioning packaging has an important influence on the cushioning performance.Mathematical fractal theory is an important graphic expression.Based on Hilbert fractal theory,a new sandwich structure was designed.The generation mechanism and recurrence formula of theHilbert fractal were expressed by Lin’s language,and the second-orderHilbert sandwich structure was constructed fromthermoplastic polyurethane.The constitutive model of the hyperelastic body was established by using the finite element method.With the unit mass energy absorption as the optimization goal,the fractal sandwich structure was optimized,and the best result was obtained when the order was 2.5 and the unit layer thickness was 0.75 mm.TheHilbert sandwich structure was compared with the rice-shaped sandwich structure commonly used in industry,and the Hilbert fractal structure had better energy absorption.This has practical significance for the development and application of newcushioning packaging structures.
基金supported by the Natural Science Foundation of Jiangsu Province(Grant No.BK20180855)Research Fund of State Key Laboratory of Mechanics and Control of Mechanical Structures(Grant No.MCMS-E-0219Y01)Research and Practice Innovation Program of postgraduates in Jiangsu Province(Grant No.KYCX20-3076)。
文摘Potential damage in composite structures caused by hail ice impact is an essential safety threat to the aircraft in flight.In this study,a nonlinear finite element(FE)model is developed to investigate the dynamic response and damage behavior of hybrid corrugated sandwich structures subjected to high velocity hail ice impact.The impact and breaking behavior of hail are described using the FE-smoothed particle hydrodynamics(FE-SPH)method.A rate-dependent progressive damage model is employed to capture the intra-laminar damage response;cohesive element and surface-based cohesive contact are implemented to predict the inter-laminar delamination and sheet/core debonding phenomena respectively.The transient processes of sandwich structure under different hail ice impact conditions are analyzed.Comparative analysis is conducted to address the influences of core shape and impact position on the impact performance of sandwich structures and the corresponding energy absorption characteristics are also revealed.
文摘In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gun.A sharp conical nosed projectile was impacted normally and with some offset distance(20 mm and 40 mm).The deformation,failure mode and energy dissipation characteristics were obtained for both kinds of loading.Moreover,the explicit solver was run in Abaqus to create the finite element model.The numerically obtained test results were compared with the experimental to check the accuracy of the modelling.The numerical result was further employed to obtain strain energy dissipation in each element by externally running user-defined code in Abaqus.Furthermore,the influence of inscribe circle diameter and cell wall and face sheet thickness on the energy dissipation,deformation and failure mode was examined.The result found that ballistic resistance and deformation were higher against offset impact compared to the normal impact loading.Sandwich panel impacted at 40 mm offset distance required 3 m/s and 1.9 m/s more velocity than 0 and 20 mm offset distance.Also,increasing the face sheet and wall thickness had a positive impact on the ballistic resistance in terms of a higher ballistic limit and energy absorption.However,inscribe circle diameter had a negative influence on the ballistic resistance.Also,the geometrical parameters of the sandwich structure had a significant influence on the energy dissipation in the different deformation directions.The energy dissipation in plastic work was highest for circumferential direction,regardless of impact condition followed by tangential,radial and axial directions.
基金the National Natural Science Foundation of China(Nos.52072151,52171211,52102253,52271218,U22A20145)the Jinan Independent Innovative Team(2020GXRC015)+1 种基金the Major Program of Shandong Province Natural Science Foundation(ZR2021ZD05)the Science and Technology Program of University of Jinan(XKY2119).
文摘Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water.Herein,a sandwich composite structure(designed as MS-Mo2C@NCNS)ofβ-Mo2C hollow nanotubes(HNT)and N-doped carbon nanosheets(NCNS)is designed and prepared using a binary NaCl–KCl molten salt(MS)strategy for HER.The temperature-dominant Kirkendall formation mechanism is tentatively proposed for such a three-dimensional hierarchical framework.Due to its attractive structure and componential synergism,MS-Mo2C@NCNS exposes more effective active sites,confers robust structural stability,and shows significant electrocatalytic activity/stability in HER,with a current density of 10 mA cm-2 and an overpotential of only 98 mV in 1 M KOH.Density functional theory calculations point to the synergistic effect of Mo2C HNT and NCNS,leading to enhanced electronic transport and suitable adsorption free energies of H*(ΔGH*)on the surface of electroactive Mo2C.More significantly,the MS-assisted synthetic methodology here provides an enormous perspective for the commercial development of highly active non-noble metal electrocatalysts toward efficient hydrogen evolution.
文摘Novel sandwich structure-like nanofiber multilayered meshes were fabricated via electrospinning. The purpose of the present work was to control zoledronic acid release via the novel structure of sandwich structure-like meshes. The in vitro release experiments reveal that the drug release speed and initial burst release were controllable by adjusting the thicknesses of electrospun barrier mesh and drug-loaded mesh. Compared with those of other drug delivery systems, the main advantages of the sandwich structure-like fiber meshes are facile preparation conditions and the generality for hydrophobic and hydrophilic pharmaceuticals.
基金Project supported by the National Natural Science Foundation of China(Nos.11272222,11502108,and 11611530686)the Natural Science Foundation for Distinguished Young Scholars of Jiangsu Province of China(No.BK20140037)
文摘Due to the incompatibility of the interlaminar deformations,the interface debonding or cracking usually happens in a layered magnetoelectric(ME)structure under an applied load.In this paper,the transient responses of the anti-plane interface cracks in piezoelectric(PE)-piezomagnetic(PM)sandwich structures are studied by the standard methods of the integral transform and singular integral equation.Discussion on the numerical examples indicates that the PE-PM-PE structure under electric impact is more likely to fracture than the PM-PE-PM structure under a magnetic impact.The dynamic stress intensity factors(DSIFs)are more sensitive to the variation of the active layer thickness.The effects of the material constants on the DSIFs are dependent on the roles played by PE and PM media during the deformation process.
基金funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘Aircraft laminated composite components often suffer a variety of high velocity impacts with large quantity of energy,which usually affects aircraft behavior and would incur component damages,even disastrous consequences.Therefore,one investigates the impact resistance of a new type of composite material,Ti/CFRP/Ti sandwich structure,and launches impact tests by using an air gun test system.Then one acquires the critical breakthrough rate of the structure and analyzes the damages.The results show that the main failure mode of the front titanium sheet is shear plugging and brittle fracture of adhesive layer with fiber breakage,while the back titanium sheet is severely ripped.The rear damage is worse than the front one.Compared with traditional CFRP laminates,the critical breakthrough rate of Ti/CFRP/Ti sandwich structure is improved by 69.9% when suffered the impact of a bearing ball with 2mm radius.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51579202)
文摘Ship collision accidents are catastrophic accidents, and as the main energy-absorbing structure, the anti-collision capacity of the side structure has an important influence on the crashworthiness of the ship. It is necessary to improve the crashworthiness of the ship by increasing energy absorption of the side structure, in such ways as adding a filling sandwich in a single hull. The aim of the present study is to discuss the crashworthiness of the side structure stressed under lateral dynamic loads through simulation with the finite element code MSC/Dytran. The collision force, the damage deformation, the critical collision speed as well as the energy absorption of a side structure improved with a filling sandwich are compared to the standard structure through numerical simulations. The results indicate that a sandwich panel structure is an advanced ship protection structure that can remarkably improve the ability of the side structure to withstand collisions; the effect of the tube-style sandwich panel structure has the best results. The outcome of this study provides a reference for the crashworthiness assessment of side structures and the crashworthiness optimization design of new side structures.
基金supported by the Aviation Science Fund of China(Nos.2015ZE52049,2015ZE521049)
文摘The so-called″X-cor sandwich structure″is a highly promising novel material as an alternative to honeycomb used in aircraft.Although much work has been conducted on the performance of the X-cor sandwich structure,the gap is still hardly bridged between experimental results and theoretical analyses.Therefore,a method has been innovated to establish semi-empirical formula for the prediction of compressive and shear moduli of X-cor sandwich structure composites,by combining theoretical analyses and experimental data.In addition,aprediction software was first developed based on the proposed method,of which the accuracy was verified through confirmatory experiments.This software can offer a direct reference or guide for engineers in structural designing.
文摘The propagation of acoustic waves in a homogeneous isotropic semiconducting layer sandwiched between two homogeneous transversely isotropic piezoelectric halfspaces has been investigated. The mathematical model of the problem is depicted by a set of partial differential equations of motion, Gauss equation in piezoelectric material and electron diffusion equation in semiconductor along with the boundary conditions to be satisfied at the piezoelectric-semiconductor interfaces. The secular equations describing the symmetric and asymmetric modes of wave propagation have been derived in compact form after obtaining the analytical expressions for various field quantities that govern the wave motion. The complex secular equation has been solved numerically using functional interaction method along with irreducible cardano method. The computer simulated results are obtained with the help of MATLAB software for 6 mm cadmium selenide (CdSe) piezoelectric material and n-type silicon (Si) semiconductor in respect of dispersion curve, attenuation and specific loss factor of energy dissipation for symmetric (sym) and asymmetric (asym) modes of wave propagation. The study may find applications in non-destructive testing, resonators, waveguides etc.
基金supported by National Natural Science Foundation of China(31470581)Fundamental Research Funds for the Central Universities(2572016EBJ1).
文摘A wood-based X-type lattice sandwich structure was manufactured by insertion-glue method.The birch was used as core,and Oriented Strand Board was used as panel of the sandwich structure.The short beam shear properties and the failure modes of the wood-based X-type lattice sandwich structure with different core direction(vertical and parallel),unit specification(120 mm×60 mm and 60 mm×60 mm),core size(50 mm and 60 mm),and drilling depth(9 mm and 12 mm)were investigated by a short beam shear test and the establishment of a theoretical model to study the equivalent shear modulus and deflection response of the X-type lattice sandwich structure.Results from the short beam shear test and the theoretical model showed that the failure modes of the wood-based X-type lattice sandwich structure were mainly the wrinkling and crushing of the panels under three-point bending load.The experimental values of deflection response of various type specimens were higher than the theoretical values of them.For the core direction of parallel,the smaller the unit specification is,the shorter the core size is,and the deeper the drilling depth is,the greater the short beam shear properties of the wood-based X-type lattice sandwich structure is.
基金Funded by the National Natural Science Foundation of China(Nos.51002072 and 51562024)the Jiangxi Science and Technology Support Project(Nos.20133BBE50027 and 20143BBM26055)
文摘Ion transport of sandwich cementitious materials(SCM) exposed to chloride environment was investigated by accelerated diffusion method and natural diffusion method. Pore structure and micromorphology of SCM were investigated by MIP and SEM-EDS. In comparison with the monolayer structural high performance concrete(HPC), conductive charge for 6 hours, chloride diffusion coefficient, and apparent chloride diffusion coeffi cient of SCM were decreased by 30%-40%, two orders of magnitude and 40%-50%, respectively. Pore structure of ultra low ion permeability cementitious materials(ULIPCM) prepared for the facesheet is superior to that of HPC prepared for the core. As for porosity, the most probable pore radius, the content of pores with radius 50 nm and the surface area of pores, the order is ULIPCM
文摘This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (SEM). As the world is garnering attention towards renewable resources for environmental purposes, studies of natural fibre have been increasing as well as the application of natural fibre throughout various industries such as aerospace, automobiles, and construction sectors. This paper is started with brief information regarding the honeycomb sandwich structure, introduction to natural fibre, its applications as well as the factors affecting the performances of the structure. Next, the mechanical testing methods are listed out as well as the expected outcomes obtained from the respective testing. The mechanical properties are also identified by conducting lab tests according to the ASTM standard for sandwich and core structures. The microstructure of the deformed samples is then examined under Scanning Electron Microscope (SEM) by using different magnifications to study the failure mechanisms of the samples. The images obtained from the SEM test are analyzed by using fractography which will show the failure modes of the samples. This article is based on past research conducted by professional on the related topic.
文摘Natural Fiber Honeycomb (NFH) sandwiched structure composite is a type of composite that uses natural fiber as the reinforcement material and honeycomb structure in the form of a sandwich panel. The demand for commercial use of natural fiber-based composites is increasing in the past few years in many industrial sectors. The increase in popularity of natural fibers is because of their particular properties, price, health benefits, and recyclability. This paper aims to analyze the data and analysis of the past research about NFH sandwiched structure composite in terms of the materials used to make the NFH, the physical and mechanical properties, and their applications. Based on the literature review conducted, there were many types of materials used to make the NFH sandwiched structure composite. Some experimental tests were planned and conducted to analyze the mechanical properties of the NFH and its potential to be used in the desired industries. However, there are not many implementations of NFH composite in the construction industry. This is due to the concern related to the issue of the structural integrity of the NFH composite. From the literature review conducted, most of the research shows a positive analysis of the mechanical properties and the potential of the developed NFH to be used for the targeted industry in the study. Therefore, it can be observed that the material used in this study has a high potential to be used in the construction industry.
基金the Project of China Geological Survey (DD20160512, DD20160346)Science and Technology Development Fund Project of Shinan District (2018-4-006-ZH)+2 种基金Key Laboratory of Marine Hydrocarbon Resources and Environmental Geology,Ministry of Land and Resources (MRE201311)National Natural Science Foundation (41776075,41702162)Natural Science Foundation of Shandong Province of China (ZR2017BD034).
文摘In order to make a breakthrough in Mesozoic-Paleozoic shale gas exploration in the South Yellow Sea Basin,a comparison of the preservation conditions was made within the Barnett shale gas reservoirs in the Fortworth Basin,the Jiaoshiba shale gas reservoirs in Sichuan Basin and potential shale gas reservoirs in Guizhou Province.The results show that the "Sandwich"structure is of great importance for shale gas accumulation.Therein to,the "Sandwich"structure is a kind of special reservoir-cap rock assemblage which consist of limestone or dolomite on the top,mudstone or shale layer in the middle and limestone or dolomite at the bottom.In consideration of the Mesozoic-Paleozoie in the Lower Yangtze,and Laoshan Uplift with weak Paleozoic deformation and thrust fault sealing On both flanks of the Laoshan Uplift,a conclusion can be drawn that the preservation conditions of shale gas probably developed "Sandwich" structures in the Lower Cambrian and Permian,which are key layers for the breakthrough of shale gas in the South Yellow Sea.Moreover,the preferred targets for shale gas drilling probably locate at both flanks of the Laoshan Uplift.
基金supported by the Ministry of Education and Science of Russian Federation (No.RFMEFI57414X0078)
文摘An idea to develop a family of cellular cores for sandwich panels using a technology of prepreg folding is presented. Polar folded quadra structures are regarded as a geometric basis for these cores whose standard frag ment has lhe fourlh degree of axial symmelry. The classification of the polar strucluresaredeseribedanda method of various quadra slrueture synthesis is developed. A possibilily to provide high strength of lhe structure due m preservation of faces reinforcement pattern is presented. Arrangemen! of the plane core on a bi curvature surface is also introduced. Besides, provision of isotropyof the core in two or three directions are described. Finally, exam ples of cellular folded cores manufaclured from basalt reinforced plaslic are demonslrated.
基金supported by the National Natural Science Foundation of China (No. 10947162)the Natural Science Foundation of Henan Province (No. 2010A140009)the International Technology Cooperation Project of Science and Technology Department of Henan Province (No. 104300510044)
文摘The title compound {[Cu(abpy)2](H3bptc)·(H2O)}n, an ion-pair complex of [Cu(abpy)2]+ with [(H3bptc)]- (abpy = 3,3'-dimethyl-2,2'-bipyridine and H4bptc = 1,1'-biphenyl-2,2',3,3'-tetracarboxylic acid), has been synthesized by a hydrothermal reaction, and its structure was deter- mined by X-ray diffraction and characterized by elemental analysis and IR spectrum. The crystal is of triclinic, space group P1 with a = 8.4955(12), b = 15.164(2), c = 15.303(2), α = 105.704(3), β = 97.374(3), γ = 96.764(3)o, CuC40H35N4O9, Mr = 779.26, V = 1857.9(4)3, Dc = 1.393 g/cm3, F(000) = 808, μ = 0.649 mm-1, S = 1.026 and Z = 2. The final R = 0.0493 and wR = 0.1034 for 4026 observed reflections with I 2σ(I). The copper(I) coordination polymer demonstrates a 3-D sandwich-type structure containing 2-D double H3bptc-chain layers intercalated with the [Cu(abpy)2]+ layers by extensive hydrogen bonding interactions.