The hollow strontium carbonate pompons was synthesized for the first time by a controlled reaction precipitation method with sodium dodecyl benzene sulfonate(SDBS)and polyvinyl pyrrolidone(PVP)work together as templat...The hollow strontium carbonate pompons was synthesized for the first time by a controlled reaction precipitation method with sodium dodecyl benzene sulfonate(SDBS)and polyvinyl pyrrolidone(PVP)work together as template.The sampled particles were characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen adsorption-desorption measurement,X-ray diffraction(XRD),Energy dispersive X-Ray spectroscopy(EDX),Fourier transform infrared spectroscopy(FTIR),Thermogravimetric analysis and differential scanning calorimetry(TGA-DSC),etc.It is shown that the assynthesized hollow strontium carbonate pompons with the size of about 2μm consist of flake-like particles under the optimal reaction conditions.The formation mechanism of hollow strontium carbonate pompons was preliminarily explored.展开更多
The application of TiO2-based devices is mainly dependent on their crystalline structure, morphology, size, and exposed facets. Two kinds of TiO2 with different structures, namely TiO2 pompons and TiO2 nanotubes, have...The application of TiO2-based devices is mainly dependent on their crystalline structure, morphology, size, and exposed facets. Two kinds of TiO2 with different structures, namely TiO2 pompons and TiO2 nanotubes, have been prepared by the hydrothermal method. TiO2 with different structures is characterized by scanning electron microscopy （SEM）, X-ray diffraction （XRD）, and Brunauer Emmett-Teller （BET） surface area analysis. Solar cells based on poly（3-hexylthiophene） （P3HT） and TiO2 with different structures are fabricated. In the device ITO/TiO2/P3HT/Au, the P3HT is designed to act as the electron donor, and TiO2 pompons and TiO2 nanotubes act as the electron acceptor. The effects of the TiO2 structure on the performance of hybrid heterojunction solar cells are investigated. The device with TiO2 pompons has an open circuit voltage （Voc） of 0.51 V, a short circuit current （Jsc） of 0.21 mA/cm2, and a fill factor （FF） of 28.3%. Another device with TiO2 nanotubes has a Voc of 0.5 V, Jsc of 0.27 mA/cm2, and FF of 28.4%. The results indicate that the TiO2 nanotubes with a unidimensional structure have better carrier transport and light absorption properties than TiO2 pompons. Consequently, the solar cell based on TiO2 nanotubes has a better performance.展开更多
基金Funded by the National Natural Science Foundation of China(No.22002143)the Natural Science Foundation of Shanxi Province of China(No.201901D211223)the Postgraduate Students Scientific Research Project of North University of China(No.20201766)。
文摘The hollow strontium carbonate pompons was synthesized for the first time by a controlled reaction precipitation method with sodium dodecyl benzene sulfonate(SDBS)and polyvinyl pyrrolidone(PVP)work together as template.The sampled particles were characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen adsorption-desorption measurement,X-ray diffraction(XRD),Energy dispersive X-Ray spectroscopy(EDX),Fourier transform infrared spectroscopy(FTIR),Thermogravimetric analysis and differential scanning calorimetry(TGA-DSC),etc.It is shown that the assynthesized hollow strontium carbonate pompons with the size of about 2μm consist of flake-like particles under the optimal reaction conditions.The formation mechanism of hollow strontium carbonate pompons was preliminarily explored.
基金Project supported by the Ministry of Science and Technology of China (Grant No. 2011CB932802)the National Natural Science Foundation of China (Grant No. 60978060)the Beijing Municipal Science & Technology Commission,China (Grant No. Z090803044009001)
文摘The application of TiO2-based devices is mainly dependent on their crystalline structure, morphology, size, and exposed facets. Two kinds of TiO2 with different structures, namely TiO2 pompons and TiO2 nanotubes, have been prepared by the hydrothermal method. TiO2 with different structures is characterized by scanning electron microscopy （SEM）, X-ray diffraction （XRD）, and Brunauer Emmett-Teller （BET） surface area analysis. Solar cells based on poly（3-hexylthiophene） （P3HT） and TiO2 with different structures are fabricated. In the device ITO/TiO2/P3HT/Au, the P3HT is designed to act as the electron donor, and TiO2 pompons and TiO2 nanotubes act as the electron acceptor. The effects of the TiO2 structure on the performance of hybrid heterojunction solar cells are investigated. The device with TiO2 pompons has an open circuit voltage （Voc） of 0.51 V, a short circuit current （Jsc） of 0.21 mA/cm2, and a fill factor （FF） of 28.3%. Another device with TiO2 nanotubes has a Voc of 0.5 V, Jsc of 0.27 mA/cm2, and FF of 28.4%. The results indicate that the TiO2 nanotubes with a unidimensional structure have better carrier transport and light absorption properties than TiO2 pompons. Consequently, the solar cell based on TiO2 nanotubes has a better performance.
