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Nanopore structure comparison between shale oil and shale gas:examples from the Bakken and Longmaxi Formations 被引量:7
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作者 Kouqi Liu Liang Wang +3 位作者 Mehdi Ostadhassan Jie Zou Bailey Bubach Reza Rezaee 《Petroleum Science》 SCIE CAS CSCD 2019年第1期77-93,共17页
In order to analyze and compare the differences in pore structures between shale gas and shale oil formations, a few samples from the Longmaxi and Bakken Formations were collected and studied using X-ray diffraction, ... In order to analyze and compare the differences in pore structures between shale gas and shale oil formations, a few samples from the Longmaxi and Bakken Formations were collected and studied using X-ray diffraction, LECO TOC measurement, gas adsorption and field-emission scanning electron microscope. The results show that samples from the Bakken Formation have a higher TOC than those from the Longmaxi Formation. The Longmaxi Formation has higher micropore volume and larger micropore surface area and exhibited a smaller average distribution of microsize pores compared to the Bakken Formation. Both formations have similar meso-macropore volume. The Longmaxi Formation has a much larger meso-macropore surface area, which is corresponding to a smaller average meso-macropore size. CO_2 adsorption data processing shows that the pore size of the majority of the micropores in the samples from the Longmaxi Formation is less than 1 nm, while the pore size of the most of the micropores in the samples from the Bakken Formation is larger than 1 nm. Both formations have the same number of pore clusters in the 2–20 nm range, but the Bakken Formation has two additional pore size groups with mean pore size diameters larger than 20 nm. Multifractal analysis of pore size distribution curves that was derived from gas adsorption indicates that the samples from the Longmaxi Formation have more significant micropore heterogeneity and less meso-macropore heterogeneity. Abundant micropores as well as mesomacropores exist in the organic matter in the Longmaxi Formation, while the organic matter of the Bakken Formation hosts mainly micropores. 展开更多
关键词 SHALE GAS SHALE oil - pore structure GAS adsorption pore family MULTIFRACTAL analysis
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Experimental investigation of enhancement of carbon dioxide foam stability, pore plugging, and oil recovery in the presence of silica nanoparticles 被引量:5
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作者 Abdul Rahim Risal Muhammad A.Manan +3 位作者 Nurudeen Yekeen Nur Bashirah Azli Ali Mohamed Samin Xin Kun Tan 《Petroleum Science》 SCIE CAS CSCD 2019年第2期344-356,共13页
The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated fro... The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated from the pressure drop induced during foam propagation in porous media. The results clearly showed that the modified Si02 nanoparticlestabilized foam exhibited high stability, and the differential pressure increased in porous media by as much as three times.The addition of SiO_2 nanoparticles to the foaming dispersions further mitigated the adverse effect of oil toward the foam pore plugging ability. Consequently, the oil recovery increased in the presence of nanoparticles by approximately 15%during the enhanced oil recovery experiment. The study suggested that the addition of surface-modified silica nanoparticles to the surfactant solution could considerably improve the conventional foam stability and pore plugging performance in porous media. 展开更多
关键词 Foam pore plugging Surface-modified NANOPARTICLE Enhanced oil RECOVERY
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Three-Dimensional Imaging of Pore-Scale Water Flooding Phenomena in Water-Wet and Oil-Wet Porous Media 被引量:2
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作者 Arief Setiawan Tetsuya Suekane +1 位作者 Yoshihiro Deguchi Koji Kusano 《Journal of Flow Control, Measurement & Visualization》 2014年第2期25-31,共7页
The penetration of water during water flooding has been observed over many years using several methods. A microfocused X-ray computed tomography scanner can be used to directly observe 3D water flooding in a nondestru... The penetration of water during water flooding has been observed over many years using several methods. A microfocused X-ray computed tomography scanner can be used to directly observe 3D water flooding in a nondestructive manner. To eliminate the possibility of false images being produced because of X-ray broadening effects, we developed a visualization method by arranging the brightness distribution of all phases involved. Water flooding experiments were conducted using oil-wet and water-wet porous media. The water phase was injected upward into packed glass beads containing an oil phase, and the process was scanned every minute until steady state was reached. Using this scheme, real-time, the water invasion pattern and oil trapping process in clusters of pores and individual pores can be observed clearly. By eliminating false images, the boundary of each phase could be identified with high precision, even in a single pore. Porelevel phenomena, including snap off (which has never before been captured in a real 3D porous medium), piston-like displacement, and the curvature of the interface, were also observed. Direct measurement of the pore throat radius and the contact angle between the wetting and nonwetting phases gave an approximation of the capillary pressure during the piston-like displacement and snap-off processes. 展开更多
关键词 Visualization Porous Medium pore-Scale WATER FLOODING oil Trapping X-Ray CT Scanner
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Effects of microscopic pore structure heterogeneity on the distribution and morphology of remaining oil 被引量:4
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作者 LI Junjian LIU Yang +3 位作者 GAO Yajun CHENG Baoyang MENG Fanle XU Huaimin 《Petroleum Exploration and Development》 2018年第6期1112-1122,共11页
Waterflooding experiments were performed using Micro-CT on four cores of different pore structures from Donghe sandstone reservoirs in the Tarim Basin. The water, oil and grains were accurately separated by the advanc... Waterflooding experiments were performed using Micro-CT on four cores of different pore structures from Donghe sandstone reservoirs in the Tarim Basin. The water, oil and grains were accurately separated by the advanced image processing technology, the pore network model was established, and parameters such as the number of throats and the throat size distribution were calculated to characterize the microscopic heterogeneity of pore structure, the flow of oil phase during displacement, and the morphology and distribution of remaining oil after displacement. The cores with the same macroscopic porosity-permeability have great differences in microscopic heterogeneity of pore structure. Both macro porosity-permeability and micro heterogeneity of pore structure have an influence on the migration of oil phase and the morphology and distribution of remaining oil. When the heterogeneity is strong, the water phase will preferentially flow through the dominant paths and the remaining oil clusters will be formed in the small pores. The more the number of oil clusters(droplets) formed during displacement process, the smaller the average volume of cluster is, and the remaining oil is dominated by the cluster continuous phase with high saturation. The weaker the heterogeneity, the higher the pore sweep efficiency is, and the remaining oil clusters are mainly trapped in the form of non-continuous phase. The distribution and morphology of micro remaining oil are related to the absolute permeability, capillary number and micro-heterogeneity. So, the identification plate of microscopic residual oil continuity distribution established on this basis can describe the relationship between these three factors and distribution of remaining oil and identify the continuity of the remaining oil distribution accurately. 展开更多
关键词 SANDSTONE WATERFLOODING CT scan image processing MICROSCOPIC pore structure reservoir HETEROGENEITY REMAINING oil DISTRIBUTION
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Numerical Calculation of Viscous-Elastic Fluid Flooding Residual Oil Film in the Complex Pore
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作者 Lili Liu Chao Yu +1 位作者 Lihui Wang Lu Liu 《Open Journal of Fluid Dynamics》 2013年第3期147-151,共5页
In order to analyze the stress and deformation of different permeability of residual oil film in the complex pore, which are affected by the viscous-elasticity of the fluid, the hydrodynamic displacement mechanism is ... In order to analyze the stress and deformation of different permeability of residual oil film in the complex pore, which are affected by the viscous-elasticity of the fluid, the hydrodynamic displacement mechanism is explored from the stand-point of hydrodynamics, that is, the residual oil film displaced by alternating injection of different concentrations of the polymer solution, viscous-elastic fluid flow equation is established in the complex pore by choosing continuity equation, motion equation and the upper convected Maxwell constitutive equation. The flow field is computed by using the method of numerical analysis. Not only the stress and deformation of residual oil film on the different permeability of micro pores, but also the analysis of the flooding mechanism of alternating injection of different concentrations of the polymer solution is got. The results show that the larger the viscous-elasticity of polymer solution is, the bigger the normal deviatoric stress acting on the residual oil film is;the distribution of normal deviatoric stress has the abrupt change. The stronger the viscous-elasticity of the polymer solution is, the bigger the horizontal stress difference acting on the residual oil film is and the more obvious the deformation is;the high-concentration polymer solution is suitable for high-permeability micro pores. Low-concentration polymer solution is suitable for medium and low-permeability micro pores. Alternating injection of polymer solution can improve Volumetric Sweep Efficiency and increase the deformation of residual oil film, which is conducive to enhancing oil recovery. 展开更多
关键词 COMPLEX pore RESIDUAL oil Film Deformation Viscous-Elasticity Permeability
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Pore structure differences of the extra-low permeability sandstone reservoirs and the causes of low resistivity oil layers: A case study of Block Yanwumao in the middle of Ordos Basin, NW China 被引量:3
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作者 WANG Jianmin ZHANG San 《Petroleum Exploration and Development》 2018年第2期273-280,共8页
The influence of pore structure difference on rock electrical characteristics of reservoir and oil reservoir was analyzed taking Triassic Chang 6 reservoir in Block Yanwumao in the middle of Ordos Basin as an example.... The influence of pore structure difference on rock electrical characteristics of reservoir and oil reservoir was analyzed taking Triassic Chang 6 reservoir in Block Yanwumao in the middle of Ordos Basin as an example. The relationship between the pore structure difference and the low resistivity oil layer was revealed and demonstrated through core observation, lab experiments, geological research, well log interpretation and trial production etc. The results show that there were two kinds of oil layers in Chang 6 oil layer set, normal oil layer and low resistivity oil layer in the region, corresponding to two types of pore structures, pore type mono-medium and micro-fracture-pore type double-medium; the development of micro-fracture changed greatly the micro-pore structure of the reservoir, and the pore structure difference had an important influence on the rock electrical characteristics of the extra-low permeability sandstone reservoir and oil reservoir; the normal oil layers had obvious characteristics of pore-type mono-medium, and were concentrated in Chang 61, Chang 6232 and Chang 62; the low resistivity oil layers had obvious characteristics of micro-fracture-pore type double-medium, which were mainly distributed in Chang 612 and Chang 63. The mud filtrate penetrated deep into the oil layers along the micro-cracks, leading to sharp reduction of resistivity, and thus low resistivity of the oil layer; the low resistivity oil layers had better storage capacity and higher productivity than the normal oil layers. 展开更多
关键词 ORDOS Basin Chang 6 oil layers extra-low permeability reservoir LOW RESISTIVITY oil layer pore structure MUD invasion LOW RESISTIVITY cause
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Classification of microscopic pore-throats and the grading evaluation on shale oil reservoirs 被引量:2
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作者 LU Shuangfang LI Junqian +5 位作者 ZHANG Pengfei XUE Haitao WANG Guoli ZHANG Jun LIU Huimin LI Zheng 《Petroleum Exploration and Development》 2018年第3期452-460,共9页
On the basis of the characterization of microscopic pore-throats in shale oil reservoirs by high-pressure mercury intrusion technique, a grading evaluation standard of shale oil reservoirs and a lower limit for reserv... On the basis of the characterization of microscopic pore-throats in shale oil reservoirs by high-pressure mercury intrusion technique, a grading evaluation standard of shale oil reservoirs and a lower limit for reservoir formation were established. Simultaneously, a new method for the classification of shale oil flow units based on logging data was established. A new classification scheme for shale oil reservoirs was proposed according to the inflection points and fractal features of mercury injection curves: microscopic pore-throats(less than 25 nm), small pore-throats(25-100 nm), medium pore-throats(100-1 000 nm) and big pore-throats(greater than 1 000 nm). Correspondingly, the shale reservoirs are divided into four classes, I, II, III and IV according to the number of microscopic pores they contain, and the average pore-throat radii corresponding to the dividing points are 150 nm, 70 nm and 10 nm respectively. By using the correlation between permeability and pore-throat radius, the permeability thresholds for the reservoir classification are determined at 1.00× 10^(-3) μm^2, 0.40×10^(-3) μm^2 and 0.05×10^(-3) μm^2 respectively. By using the exponential relationship between porosity and permeability of the same hydrodynamic flow unit, a new method was set up to evaluate the reservoir flow belt index and to identify shale oil flow units with logging data. The application in the Dongying sag shows that the standard proposed is suitable for grading evaluation of shale oil reservoirs. 展开更多
关键词 SHALE oil MICROSCOPIC pore-throat high pressure mercury injection lower limit of reservoir formation GRADING EVALUATION Bohai Bay Basin Dongying SAG
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Effects of pore structure on surfactant/polymer floodingbased enhanced oil recovery in conglomerate reservoirs 被引量:2
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作者 LIU Zheyu LI Yiqiang +3 位作者 LENG Runxi LIU Zhenping CHEN Xin HEJAZI Hossein 《Petroleum Exploration and Development》 2020年第1期134-145,共12页
To understand the displacement characteristics and remaining oil displacement process by the surfactant/polymer(SP) flooding in cores with different pore structures, the effects of pore structure on the enhanced oil r... To understand the displacement characteristics and remaining oil displacement process by the surfactant/polymer(SP) flooding in cores with different pore structures, the effects of pore structure on the enhanced oil recovery of SP flooding was investigated at the pore, core and field scales through conducting experiments on natural core samples with three typical types of pore structures. First, the in-situ nuclear magnetic resonance core flooding test was carried out to capture the remaining oil variation features in the water flooding and SP flooding through these three types of cores. Subsequently, at the core scale, displacement characteristics and performances of water flooding and SP flooding in these three types of cores were evaluated based on the full-size core flooding tests. Finally, at the field scale, production characteristics of SP flooding in the bimodal sandstone reservoir and multimodal conglomerate reservoir were compared using the actual field production data. The results show: as the pore structure gets more and more complex, the water flooding performance gets poorer, but the incremental recovery factor by SP flooding gets higher;the SP flooding can enhance the producing degree of oil in 1-3 μm pores in the unimodal and bimodal core samples, while it produces largely oil in medium and large pores more than 3 μm in pore radius in the multimodal core sample. The core flooding test using full-size core sample demonstrates that the injection of SP solution can significantly raise up the displacement pressure of the multimodal core sample, and greatly enhance recovery factor by emulsifying the remaining oil and enlarging swept volume. Compared with the sandstone reservoir, the multimodal conglomerate reservoir is more prone to channeling. With proper profile control treatments to efficiently enlarge the microscopic and macroscopic swept volumes, SP flooding in the conglomerate reservoir can contribute to lower water cuts and longer effective durations. 展开更多
关键词 CONGLOMERATE RESERVOIR pore structure surfactant/polymer FLOODING DISPLACEMENT effect oil recovery enhancement
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页岩基质孔隙油微观赋存及可动性定量表征——以东营凹陷沙河街组为例 被引量:4
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作者 李俊乾 宋兆京 +2 位作者 王民 张鹏飞 蔡建超 《石油科学通报》 CAS 2024年第1期1-20,共20页
页岩基质孔隙油微观赋存特征及可动性是制约陆相页岩油高效开采的关键要素。本文针对页岩基质孔隙内不同相态油的含量、比例、分布及可动性开展定量化表征研究,从理论上提出了页岩油吸附量、游离量、可动量评价模型以及吸附油占比评价模... 页岩基质孔隙油微观赋存特征及可动性是制约陆相页岩油高效开采的关键要素。本文针对页岩基质孔隙内不同相态油的含量、比例、分布及可动性开展定量化表征研究,从理论上提出了页岩油吸附量、游离量、可动量评价模型以及吸附油占比评价模型(即吸附比例方程),建立了基于饱和—离心—核磁共振联合实验的孔隙油微观赋存及可动性评价方法。上述模型与方法在渤海湾盆地济阳坳陷东营凹陷沙河街组页岩油储层中进行了应用,揭示了实验条件(20℃、常压)下页岩基质孔隙中轻质油(正十二烷)微观赋存与可动性特征。结果显示:(1)富有机质页岩吸附油、游离油含量普遍大于含有机质页岩,吸/游比主体介于1~2,不同类型页岩中吸附油、游离油赋存空间具有差异性。(2)富有机质页岩吸附油平均密度(0.8331 g/cm^(3))略大于含有机质页岩(0.8067 g/cm^(3)),富有机质页岩吸附油平均厚度(1.7475 nm)约为含有机质页岩(0.5734 nm)的3倍,富有机质页岩具有更强的油—岩相互作用。(3)游离油赋存孔隙直径下限(d_(min))数值上等于吸附油平均厚度与孔隙形状因子的乘积,富有机质页岩d_(min)介于3.5~10.5 nm,开始主要富集游离油的孔隙直径约为100 nm;含有机质页岩d_(min)介于1.1~3.4 nm,开始主要富集游离油的孔隙直径约为30 nm。(4)富有机质页岩孔隙油可动性相对更好,其可动性指数(平均6.24 mg·g^(-1)·MPa^(-1))高于含有机质页岩(平均5.20 mg·g^(-1)·MPa^(-1)),孔隙油吸/游比约为1.5时具有较好可动性。(5)以油—岩相互作用为纽带,构建了页岩含油性、储集性及页岩油可动性之间的耦合关系,并数学描述了它们之间的内在联系,为寻找优质页岩油储层奠定了理论基础。 展开更多
关键词 陆相页岩 孔隙油 微观赋存 可动性 定量表征 东营凹陷
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页岩油藏注CO_(2)驱孔隙动用特征研究 被引量:1
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作者 张志超 柏明星 杜思宇 《油气藏评价与开发》 CSCD 北大核心 2024年第1期42-47,共6页
CO_(2)在页岩油藏驱油时的孔隙动用特征是评价其应用于提高页岩油藏采收率效果的一项重要指标。因此,开展了超临界CO_(2)驱替页岩岩心室内实验,并以核磁共振(NMR)在线岩心扫描技术为手段对CO_(2)驱页岩油藏的孔隙动用特征和规律进行研... CO_(2)在页岩油藏驱油时的孔隙动用特征是评价其应用于提高页岩油藏采收率效果的一项重要指标。因此,开展了超临界CO_(2)驱替页岩岩心室内实验,并以核磁共振(NMR)在线岩心扫描技术为手段对CO_(2)驱页岩油藏的孔隙动用特征和规律进行研究。结果表明,超临界CO_(2)非混相驱油主要动用页岩中孔隙半径在0.1~3.0µm范围内的油,而此过程中小于0.008µm孔隙半径内的油量反而增加,分析原因主要是CO_(2)在页岩层中通过压差和扩散作用将大孔隙内页岩油带入小孔隙中并发生吸附滞留,在驱替时间5 h后,CO_(2)驱替页岩油采收率达到35.7%,驱油效果较好。 展开更多
关键词 超临界CO_(2) 页岩油 核磁共振 孔隙动用特征 采收率
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Mechanical Analysis of Viscous-Elastic Fluid Acting on Residual Oil in the Micro Pore
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作者 Lili Liu Chao Yu +2 位作者 Lihui Wang Chengchuyue Fu Peixiang Li 《Open Journal of Fluid Dynamics》 2013年第4期248-251,共4页
In order to analyze the normal deviatoric stress that viscous-elastic fluid acting on the residual oil under the situation of different flooding conditions and different permeabilities, Viscous-elastic fluid flow equa... In order to analyze the normal deviatoric stress that viscous-elastic fluid acting on the residual oil under the situation of different flooding conditions and different permeabilities, Viscous-elastic fluid flow equation is established in the micro pore by choosing the continuity equation, motion equation and the upper-convected Maxwell constitutive equation, the flow field is computed by using numerical analysis, the forces that driving fluid acting on the residual oil in micro pore are got, and the influence of flooding conditions, pore width and viscous-elasticity of driving fluid on force is compared and analyzed. The results show that: the more viscous-elasticity of driving fluid increases, the greater the normal deviatoric stress acting on the residual oil increases;using constant pressure gradient flooding, the lager the pore width is, the greater normal deviatoric stress acting on the residual oil will be. 展开更多
关键词 Viscous-Elastic FLUID Residual oil Normal Deviatoric Stress Micro pore
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鄂尔多斯盆地长7_(3)亚段储层微观孔隙结构和固液作用力
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作者 沈瑞 徐蕾 +5 位作者 李洋 杨航 曾旭 徐锐 董庆浩 艾信 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第6期2208-2221,共14页
针对鄂尔多斯盆地长7_(3)亚段页岩储层孔隙结构和固液作用力问题,首先,通过聚焦离子束电子显微镜、计算机断层扫描技术和原子力显微镜对纯页岩储层样品开展研究;其次,结合Avizo软件建立页岩多尺度三维重构模型,定量分析页岩孔隙结构特征... 针对鄂尔多斯盆地长7_(3)亚段页岩储层孔隙结构和固液作用力问题,首先,通过聚焦离子束电子显微镜、计算机断层扫描技术和原子力显微镜对纯页岩储层样品开展研究;其次,结合Avizo软件建立页岩多尺度三维重构模型,定量分析页岩孔隙结构特征;最后,提出页岩储层固液相互作用黏附力测试方法,测定原油与孔隙壁面之间的黏附力。研究结果表明:长7_(3)储层发育有粒间孔、粒内孔和有机质孔隙,有机质孔隙形状主要有条状、弯月状和椭圆状;在微米尺度下,可以清晰看到层理缝;在纳米尺度下,不同页岩结构的样品孔隙结构特征无明显差异,孔喉形态多为片状和条状;有机质与原油之间的黏附力最大,长英质与原油之间的黏附力次之,层理面与原油之间的黏附力最小,3种平均黏附力分别为0.098、0.063和0.041μN,长7_(3)页岩储层中壁面原油启动难度较大,这从力学角度解释了该区为原位转化重点区域的原因。 展开更多
关键词 页岩油 孔隙结构 渗流 黏附力 有机质孔 原子力显微镜
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页岩储层孔隙结构表征及物性下限确定方法及应用
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作者 周志军 张国青 +3 位作者 崔春雪 暴赫 任帅 王静怡 《特种油气藏》 CAS CSCD 北大核心 2024年第4期96-102,共7页
针对页岩储层孔隙结构和物性下限认识不清,严重制约了页岩油储量计算及高效开发的问题,以济阳坳陷古近系沙河街组新义深9、利页1、樊页1井为研究对象,利用N_(2)吸附、高压压汞、物性测定等实验方法,对页岩储层的孔隙结构进行全尺寸表征... 针对页岩储层孔隙结构和物性下限认识不清,严重制约了页岩油储量计算及高效开发的问题,以济阳坳陷古近系沙河街组新义深9、利页1、樊页1井为研究对象,利用N_(2)吸附、高压压汞、物性测定等实验方法,对页岩储层的孔隙结构进行全尺寸表征,并综合运用束缚水饱和度法、压汞排驱压力法、最小流动孔喉半径法和试油法确定页岩储层的物性下限。研究表明:N_(2)吸附实验主要表征页岩样品的小孔,研究区孔隙形态主要有墨水瓶形、过渡形及平板状夹缝形,主要发育纳米级孔隙,孔隙半径为1.50~40.00 nm,平均孔隙半径为16.00 nm;高压压汞实验主要表征页岩样品的中孔和宏孔,孔喉半径为0.03~66.13μm;综合计算页岩储层孔隙度下限为1.30%~3.82%,渗透率下限为0.03~0.12 mD,最小流动孔喉半径为14.60~23.50 nm,平均值为17.76 nm。研究成果可为济阳坳陷页岩油的储量计算及储层评价提供参数指标和技术支撑。 展开更多
关键词 页岩油 孔隙结构 物性下限 济阳坳陷
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鄂尔多斯盆地长6和长8段致密油储层驱渗特征研究
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作者 李书恒 王永宏 +2 位作者 邓秀芹 孙栋 杨子清 《非常规油气》 2024年第2期80-91,共12页
鄂尔多斯盆地致密油储量丰富,主要富集在延长组三叠系长6和长8油层组,是目前增储上产的重要目标。为了推动该类油藏的规模效益开发,以深化储层特征与渗流规律认识为目的,在前期研究基础上,引入核磁共振、高压压汞、纳米CT扫描和高精度... 鄂尔多斯盆地致密油储量丰富,主要富集在延长组三叠系长6和长8油层组,是目前增储上产的重要目标。为了推动该类油藏的规模效益开发,以深化储层特征与渗流规律认识为目的,在前期研究基础上,引入核磁共振、高压压汞、纳米CT扫描和高精度流体计量等新技术,系统开展了致密油储层微观孔隙结构、原油赋存状态以及水驱与渗吸动用规律研究。研究成果表明,致密油储层发育多尺度孔隙,孔隙结构以小孔-细喉型为主且连通性较好。物理模拟研究表明,原油在致密油储层的各类孔隙中均有分布,但大、中孔隙中原油的含量远高于小孔隙中的原油含量,且多以游离态存在,流动性好,是油田开发的主要对象。水驱油实验表明,致密油储层虽然存在启动压力梯度,但当驱替压力大于启动压力之后能够建立有效驱替系统,且随着驱替压力的增大水驱油效率会有所提高。核磁共振技术与水驱油实验或渗吸实验相结合,清楚地表明了不论采用水驱方式还是渗吸方式开发,致密油储层优先动用的都是较大孔隙中赋存的原油,小孔隙中赋存的原油动用难度较大。这些研究成果为探索更加有效的开发技术提供了依据。 展开更多
关键词 致密油储层 孔隙结构 水驱油实验 渗吸实验 鄂尔多斯盆地
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页岩油储层压裂液渗吸驱油机理研究
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作者 刘绪钢 李国锋 +2 位作者 李雷 王锐霞 方彦明 《油气藏评价与开发》 CSCD 北大核心 2024年第5期756-763,共8页
压裂液渗吸驱油是当前页岩油储层提高采收率的重要技术手段。通过评价压裂液润湿改性处理剂对渗吸驱油效率的影响,研究页岩油储层压裂渗吸驱油机理。测试了处理剂的表面张力、界面张力和润湿性,考察了处理剂与常规压裂液的配伍性,评价... 压裂液渗吸驱油是当前页岩油储层提高采收率的重要技术手段。通过评价压裂液润湿改性处理剂对渗吸驱油效率的影响,研究页岩油储层压裂渗吸驱油机理。测试了处理剂的表面张力、界面张力和润湿性,考察了处理剂与常规压裂液的配伍性,评价了不同孔隙尺寸岩样的渗吸驱油效率。结果表明:阴离子表面活性剂AOS(α-烯基磺酸钠)为最佳压裂液润湿改性处理剂,颗粒、基质和裂缝岩样的渗吸驱油效率分别为8.17%、17.55%和37.37%。证实渗吸驱油动力包括浮力、浮力-毛细管力和毛细管力,改性剂通过改变岩石润湿性增强毛细管力提高驱油效率,较常规压裂液渗吸驱油效率提高约152.9%。孔隙结构影响渗吸驱油的主导作用力,小孔以毛细管力为主,天然、水力裂缝则以浮力为主。通过研究压裂液渗吸驱油机理,对致密页岩油高效开发具有指导意义。 展开更多
关键词 页岩油 渗吸驱油 润湿改性 孔隙结构 毛细管力
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高邮凹陷花庄地区阜二段页岩储层孔喉结构特征研究
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作者 付茜 段宏亮 +4 位作者 刘世丽 仇永峰 杨艳 周进峰 刘志敏 《复杂油气藏》 2024年第2期131-138,共8页
高邮凹陷深凹-内坡带花庄地区阜二段(E_(1)f_(2))是苏北盆地页岩油勘探的有利地区和层段,为进一步明确花庄地区E_(1)f_(2)页岩储层特征,以有利区内系统取心井HY1井为依托,通过岩心观察,运用薄片鉴定、氩离子剖光-扫描电镜、高压压汞、... 高邮凹陷深凹-内坡带花庄地区阜二段(E_(1)f_(2))是苏北盆地页岩油勘探的有利地区和层段,为进一步明确花庄地区E_(1)f_(2)页岩储层特征,以有利区内系统取心井HY1井为依托,通过岩心观察,运用薄片鉴定、氩离子剖光-扫描电镜、高压压汞、氮气吸附以及核磁共振等多种方法联合精细表征页岩孔隙结构,分析了HY1井E_(1)f_(2)取心页岩段页岩的孔隙度、孔隙类型及连通性、孔喉特征、全尺度孔径大小等。研究表明,花庄地区E_(1)f_(2)发育3类10种孔隙类型,以无机孔为主;其中纹层状长英质灰云质混积页岩和灰云页岩孔隙度相对较大,碳酸盐岩粒间(内)孔和颗粒边缘孔更为发育,孔隙多为H2-H3型和H3型,连通性较好,喉道相对略大,孔隙结构呈三峰特征,中-大孔占比较高,孔径主体分布大于100 nm,储层条件最为有利,其发育层段可作为高邮凹陷花庄地区阜二段页岩油勘探“甜点”层之一。 展开更多
关键词 孔隙结构 储层评价 页岩油 阜宁组二段 高邮凹陷 苏北盆地
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古龙页岩油高温高压注CO_(2)驱动用效果 被引量:1
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作者 李斌会 邓森 +4 位作者 张江 曹胜 郭天娇 徐全 霍迎冬 《大庆石油地质与开发》 CAS 北大核心 2024年第1期42-51,共10页
为了明确古龙页岩油高温高压注CO_(2)驱动用效果,首先根据页岩压汞和氮气吸附实验结果,给出页岩T2值与孔喉半径转换系数,根据饱和页岩的T2谱特征,将页岩孔隙分为小孔、中大孔和页理缝;然后通过计算页岩油采出程度,考察吞吐周期、闷井时... 为了明确古龙页岩油高温高压注CO_(2)驱动用效果,首先根据页岩压汞和氮气吸附实验结果,给出页岩T2值与孔喉半径转换系数,根据饱和页岩的T2谱特征,将页岩孔隙分为小孔、中大孔和页理缝;然后通过计算页岩油采出程度,考察吞吐周期、闷井时间、裂缝对吞吐驱油效果的影响,并且分析吞吐后岩心孔隙结构的改变程度;最后对比页岩油CO_(2)吞吐和CO_(2)驱替的驱油效果,并给出最优的驱油方式。结果表明:吞吐动用幅度最大的是中大孔和页理缝中的页岩油,小孔中的页岩油采出程度最低,增加闷井时间,页岩油采出程度仅提高0.81百分点,压裂可以使小孔中的页岩油采出程度提高11.33百分点,使小孔中的页岩油得到有效动用;吞吐比驱替可以使页岩油采出程度提高30.98百分点,并且可以动用干岩样中的页岩油,效果优于驱替;驱吞结合驱油方式比只进行吞吐可以使页岩油采出程度提高12.88百分点以上,并且可以大幅度提高小孔中页岩油的采出程度;吞吐后岩心孔隙结构发生明显变化,页岩砂砾含量不同是导致页岩吞吐前后孔隙结构变化差异大的重要原因。研究成果可为古龙页岩油矿场实践提供重要的基础参数。 展开更多
关键词 古龙页岩油 孔隙结构 CO_(2)驱替 CO_(2)吞吐 高温高压 核磁共振
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黔北地区五峰组—龙马溪组海相页岩储层非均质性特征及其控制因素 被引量:1
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作者 李一鸣 刘达东 +9 位作者 冯霞 赵福平 陈祎 王奕松 林瑞钦 杜威 范青青 宋岩 姜振学 张子亚 《中国地质》 CAS CSCD 北大核心 2024年第3期780-798,共19页
【研究目的】页岩非均质性是其自身固有属性,研究页岩的微观非均质性特征对明确页岩气富集机制研究及优质储层段优选具有重要的指导意义。【研究方法】本文以黔北地区五峰组—龙马溪组海相页岩为研究对象,通过XRD、低温N_(2)吸附、高压... 【研究目的】页岩非均质性是其自身固有属性,研究页岩的微观非均质性特征对明确页岩气富集机制研究及优质储层段优选具有重要的指导意义。【研究方法】本文以黔北地区五峰组—龙马溪组海相页岩为研究对象,通过XRD、低温N_(2)吸附、高压压汞等实验方法,重点分析了研究区海相页岩的宏观与微观孔隙结构非均质性特征。【研究结果】黔北地区五峰组—龙马溪组页岩主要发育硅质页岩岩相,其次为混合质页岩、黏质页岩岩相;不同岩相页岩在总有机碳含量、矿物组分、微观孔隙结构特征等方面具有较强的非均质性。采用N_(2)吸附曲线FHH分形模型,及高压压汞岩石多孔结构分形理论,计算得到N_(2)吸附低压分形维数D_(1)(0<P/P_(0)<0.45)为2.5351~2.6722,高压分形维数D_(2)(0.45<P/P_(0)<1)为2.8311~2.9113,另外,高压压汞分形维数D_(Hg)为2.0904~2.3736,表明黔北地区五峰组—龙马溪组不同孔径范围内孔隙结构均具有较强的非均质性,分形维数越大,则页岩储层孔隙结构越复杂,对页岩气的吸附作用越强。同时,不同类型孔隙分形维数与TOC、矿物组分、孔隙结构参数等影响因素之间的相关性存在明显差异。分形维数D_(Hg)与矿物含量之间相关性较强,表明宏孔孔隙分形特征主要受矿物组分的控制;分形维数D_(1)、D_(2)与页岩TOC含量及孔隙比表面积参数之间呈现良好相关性,表明微孔和中孔孔隙非均质性的主要影响因素为有机碳的富集程度与有机质孔的发育规模。【结论】综合分析发现,硅质页岩具有高TOC含量、高脆性矿物含量、高分形维数的特征,证明硅质页岩为黔北地区五峰组—龙马溪组优质页岩岩相,其次为混合质页岩岩相;同时有机质含量越高,则该岩相在具备优质生烃条件的同时,也具备良好的开发开采条件。该研究可为指导黔北地区海相页岩储层有利开发层段的优选提供理论和实践支撑。 展开更多
关键词 页岩气 五峰组 龙马溪组 非均质性 孔隙结构 分形维数 油气勘查工程
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高黏土陆相页岩实验技术及其应用
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作者 冯子辉 张居和 +4 位作者 邵红梅 霍秋立 金玮 贾忠伟 苏勇 《大庆石油地质与开发》 CAS 北大核心 2024年第3期75-87,共13页
页岩储层“四性”实验评价是页岩油勘探开发的重要基础及核心。现有实验技术存在页岩含油量检测不准、微纳米孔隙测量视域小及代表性差、流动性直接测量参数缺乏等难题,不适应古龙页岩油生产需求。通过研发实验装备、确定实验条件,建立... 页岩储层“四性”实验评价是页岩油勘探开发的重要基础及核心。现有实验技术存在页岩含油量检测不准、微纳米孔隙测量视域小及代表性差、流动性直接测量参数缺乏等难题,不适应古龙页岩油生产需求。通过研发实验装备、确定实验条件,建立基于保压密闭岩心“四性”实验技术及流程。结果表明:古龙高成熟和成熟页岩含油量测定较国标法可减少损失71%和50%,应用新建不同成熟度页岩含油量恢复模型,恢复了国标法现场录井页岩含油量数据;高成熟与低成熟阶段页岩中干酪根有机质、不同赋存状态油和水定量特征差别明显,受干酪根有机质向页岩油转化及演化程度的控制;页岩孔缝组合构成规模储集空间及流动网络通道,储集空间分为2大类7亚类12种类型,总孔隙度高于粉砂质岩、灰质岩、云质岩;确定页岩油上部、中部、下部油层组含油性与流动性特征,圆柱状页岩样品驱替油率为16%~43%,同一地层温度(100℃)不同驱替压力(10~50 MPa)下的超临界CO_(2)驱替使孔隙度增加4.51百分点、渗透率增加0.53×10^(-3)μm^(2)。研究成果为页岩油规模增储和效益上产提供了实验依据。 展开更多
关键词 高黏土陆相页岩 “四性”实验技术 古龙页岩油 保压密闭岩心 含油量 孔缝组合 驱替油率
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致密储层孔隙结构对渗吸的影响研究进展
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作者 杨宸 杨二龙 +2 位作者 安艳明 李忠君 赵雪微 《特种油气藏》 CAS CSCD 北大核心 2024年第4期10-18,共9页
随着传统油气资源的逐渐枯竭,以致密油资源为代表的非常规油气资源在能源开发和利用方面具有越来越重要的地位。然而,相较于常规储层,致密油储层的孔隙结构非常复杂,其孔隙尺寸分布广泛、孔隙类型多样且孔喉发育,这些因素给致密油储层... 随着传统油气资源的逐渐枯竭,以致密油资源为代表的非常规油气资源在能源开发和利用方面具有越来越重要的地位。然而,相较于常规储层,致密油储层的孔隙结构非常复杂,其孔隙尺寸分布广泛、孔隙类型多样且孔喉发育,这些因素给致密油储层的开采提出了极大挑战。对致密油储层的孔隙结构及其自发渗吸机制进行深入研究对于提高致密油采收率具有非常重要的意义。基于此,通过文献调研,对致密油储层的孔隙结构和渗吸机理研究进行了综述,从孔隙结构的表征手段、致密油孔隙结构的研究进展、孔隙结构与致密油渗吸机理之间的影响机制等方面进行介绍,并对该领域的研究进展进行了总结和展望。该研究可为致密油储层原油开发提供了借鉴,助推致密油采收技术的发展。 展开更多
关键词 致密油 孔隙结构 自发渗吸 综述
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