Oil transport is greatly affected by heterogeneous pore–throat structures present in shale.It is therefore very important to accurately characterize pore–throat structures.Additionally,it remains unclear how pore–t...Oil transport is greatly affected by heterogeneous pore–throat structures present in shale.It is therefore very important to accurately characterize pore–throat structures.Additionally,it remains unclear how pore–throat structures affect oil transport capacity.In this paper,using finite element(FE)simulation and mathematical modeling,we calculated the hydrodynamic resistance for four pore–throat structure.In addition,the influence of pore throat structure on shale oil permeability is analyzed.According to the results,the hydrodynamic resistance of different pore throat structures can vary by 300%.The contribution of additional resistance caused by streamline bending is also in excess of 40%,even without slip length.Fur-thermore,Pore–throat structures can affect apparent permeability by more than 60%on the REV scale,and this influence increases with heterogeneity of pore size distribution,organic matter content,and organic matter number.Clearly,modeling shale oil flow requires consideration of porous–throat structure and additional resistance,otherwise oil recovery and flow capacity may be overestimated.展开更多
Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the ef...Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the effects of complex pore structures and wettability.To address this issue,based on the digital rock of low permeability sandstone,a direct numerical simulation is performed considering the interphase drag and boundary slip to clarify the microscopic water-oil displacement process.In addition,a dual-porosity pore network model(PNM)is constructed to obtain the water-oil relative permeability of the sample.The displacement efficiency as a recovery process is assessed under different wetting and pore structure properties.Results show that microscopic displacement mechanisms explain the corresponding macroscopic relative permeability.The injected water breaks through the outlet earlier with a large mass flow,while thick oil films exist in rough hydrophobic surfaces and poorly connected pores.The variation of water-oil relative permeability is significant,and residual oil saturation is high in the oil-wet system.The flooding is extensive,and the residual oil is trapped in complex pore networks for hydrophilic pore surfaces;thus,water relative permeability is lower in the water-wet system.While the displacement efficiency is the worst in mixed-wetting systems for poor water connectivity.Microporosity negatively correlates with invading oil volume fraction due to strong capillary resistance,and a large microporosity corresponds to low residual oil saturation.This work provides insights into the water-oil flow from different modeling perspectives and helps to optimize the development plan for enhanced recovery.展开更多
Experimental methods,including mercury pressure,nuclear magnetic resonance(NMR)and core(wateroil)displacement,are used to examine the effects of high-multiple water injection(i.e.water injection with high injected por...Experimental methods,including mercury pressure,nuclear magnetic resonance(NMR)and core(wateroil)displacement,are used to examine the effects of high-multiple water injection(i.e.water injection with high injected pore volume)on rock properties,pore structure and oil displacement efficiency of an oilfield in the western South China Sea.The results show an increase in the permeability of rocks along with particle migration,an increase in the pore volume and the average pore throat radius,and enhanced heterogeneity after high-multiple water injection.Compared with normal water injection methods,a high-multiple water injection is more effective in improving the oil displacement efficiency.The degree of recovery increases faster in the early stage due to the expansion of the swept area,and the transition from oil-wet to water-wet.The degree of recovery increases less in the late stage due to various factors,including the enhancement of heterogeneity in the rocks.Considering both the economic aspect and the production limit of water flooding,it is recommended to adopt other technologies to further enhance oil recovery after 300 PV water injection.展开更多
Both sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs)are considered as promising candidates in grid-level energy storage devices.Unfortunately,the larger ionic radii of K+and Na+induce poor diffusion kineti...Both sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs)are considered as promising candidates in grid-level energy storage devices.Unfortunately,the larger ionic radii of K+and Na+induce poor diffusion kinetics and cycling stability of carbon anode materials.Pore structure regulation is an ideal strategy to promote the diffusion kinetics and cyclic stability of carbon materials by facilitating electrolyte infiltration,increasing the transport channels,and alleviating the volume change.However,traditional pore-forming agent-assisted methods considerably increase the difficulty of synthesis and limit practical applications of porous carbon materials.Herein,porous carbon materials(Ca-PC/Na-PC/K-PC)with different pore structures have been prepared with gluconates as the precursors,and the amorphous structure,abundant micropores,and oxygen-doping active sites endow the Ca-PC anode with excellent potassium and sodium storage performance.For PIBs,the capacitive contribution ratio of Ca-PC is 82%at 5.0 mV s^(-1) due to the introduction of micropores and high oxygen-doping content,while a high reversible capacity of 121.4 mAh g^(-1) can be reached at 5 A g^(-1) after 2000 cycles.For SIBs,stable sodium storage capacity of 101.4 mAh g^(-1) can be achieved at 2 A g^(-1) after 8000 cycles with a very low decay rate of 0.65%for per cycle.This work may provide an avenue for the application of porous carbon materials in the energy storage field.展开更多
Hot water flooding is an effective way to develop heavy oil reservoirs.However,local channeling channels may form,possibly leading to a low thermal utilization efficiency and high water cut in the reservoir.The pore s...Hot water flooding is an effective way to develop heavy oil reservoirs.However,local channeling channels may form,possibly leading to a low thermal utilization efficiency and high water cut in the reservoir.The pore structure heterogeneity is an important factor in forming these channels.This study proposes a method that mixes quartz sand with different particle sizes to prepare weakly heterogeneous and strongly heterogeneous models through which hot water flooding experiments are conducted.During the experiments,computer tomography(CT)scanning identifies the pore structure and micro remaining oil saturation distribution to analyze the influence of the pore structure heterogeneity on the channeling channels.The oil saturation reduction and average pore size are divided into three levels to quantitatively describe the relationship between the channeling channel distribution and pore structure heterogeneity.The zone where oil saturation reduction exceeds 20%is defined as a channeling channel.The scanning area is divided into 180 equally sized zones based on the CT scanning images,and threedimensional(3D)distributions of the channeling channels are developed.Four micro remaining oil distribution patterns are proposed,and the morphology characteristics of micro remaining oil inside and outside the channeling channels are analyzed.The results show that hot water flooding is more balanced in the weakly heterogeneous model,and the oil saturation decreases by more than 20%in most zones without narrow channeling channels forming.In the strongly heterogeneous model,hot water flooding is unbalanced,and three narrow channeling channels of different lengths form.In the weakly heterogeneous model,the oil saturation reduction is greater in zones with larger pores.The distribution range of the average pore size is larger in the strongly heterogeneous model.The network remaining oil inside the channeling channels is less than outside the channeling channels,and the hot water converts the network remaining oil into cluster,film,and droplet remaining oil.展开更多
Understanding the impact of mining disturbances and creep deformation on the macroscopic deformation and the microscopic pore and fracture structures(MPFS)of coal is paramount for ensuring the secure extraction of coa...Understanding the impact of mining disturbances and creep deformation on the macroscopic deformation and the microscopic pore and fracture structures(MPFS)of coal is paramount for ensuring the secure extraction of coal resources.This study conducts cyclic loading-unloading and creep experiments on coal using a low-field nuclear magnetic resonance(NMR)experimental apparatus which is equipped with mechanical loading units,enabling real-time monitoring the T2spectrum.The experiments indicated that cyclic loading-unloading stress paths initiate internal damage within coal samples.Under identical creep stress conditions,coal samples with more initial damages had more substantial instantaneous deformation and creep deformation during the creep process.After undergoing nearly 35 h of staged creep,the total strains for coal samples CC01,CC02,and CC03 reach 2.160%,2.261%,and 2.282%,respectively.In the creep stage,the peak area ratio of seepage pores and microfractures(SPM)gradually diminishes.A higher degree of initial damage leads to a more pronounced compaction trend in the SPM of coal samples.Considering the porosity evolution of SPM during the creep process,this study proposes a novel fractional derivative model for the porosity evolution of SPM.The efficacy of the proposed model in predicting porosity evolution of SPM is substantiated through experimental validation.Furthermore,an analysis of the impact mechanisms on key parameters in the model was carried out.展开更多
The cyclic hydraulic stimulation(CHS) has proven as a prospective technology for enhancing the permeability of unconventional formations such as coalbeds. However, the effects of CHS on the microstructure and gas sorp...The cyclic hydraulic stimulation(CHS) has proven as a prospective technology for enhancing the permeability of unconventional formations such as coalbeds. However, the effects of CHS on the microstructure and gas sorption behavior of coal remain unclear. In this study, laboratory tests including the nuclear magnetic resonance(NMR), low-temperature nitrogen sorption(LTNS), and methane sorption isotherm measurement were conducted to explore changes in the pore structure and methane sorption characteristics caused by CHS on an anthracite coal from Qinshui Basin, China. The NMR and LTNS tests show that after CHS treatment, meso- and macro-pores tend to be enlarged, whereas micropores with larger sizes and transition-pores may be converted into smaller-sized micro-pores. After the coal samples treated with 1, 3, 5 and 7 hydraulic stimulation cycles, the total specific surface area(TSSA)decreased from 0.636 to 0.538, 0.516, 0.505, and 0.491 m^(2)/g, respectively. Fractal analysis based on the NMR and LTNS results show that the surface fractal dimensions increase with the increase in the number of hydraulic stimulation cycles, while the volume fractal dimensions exhibit an opposite trend to the surface fractal dimensions, indicating that the pore surface roughness and pore structure connectivity are both increased after CHS treatment. Methane sorption isothermal measurements show that both the Langmuir volume and Langmuir pressure decrease significantly with the increase in the number of hydraulic stimulation cycles. The Langmuir volume and the Langmuir pressure decrease from 33.47 cm^(3)/g and 0.205 MPa to 24.18 cm^(3)/g and 0.176 MPa after the coal samples treated with 7 hydraulic stimulation cycles, respectively. The increments of Langmuir volume and Langmuir pressure are positively correlated with the increment of TSSA and negatively correlated with the increments of surface fractal dimensions.展开更多
Tectonism is one of the dominant factors affecting the shale pore structure.However,the control of shale pore structure by tectonic movements is still controversial,which limits the research progress of shale gas accu...Tectonism is one of the dominant factors affecting the shale pore structure.However,the control of shale pore structure by tectonic movements is still controversial,which limits the research progress of shale gas accumulation mechanism in the complex tectonic region of southern China.In this study,34 samples were collected from two exploratory wells located in different tectonic locations.Diverse experiments,e.g.,organic geochemistry,XRD analysis,FE-SEM,low-pressure gas adsorption,and high-pressure mercury intrusion,were conducted to fully characterize the shale reservoir.The TOC,Ro,and mineral composition of the shale samples between the two wells are similar,which reflects that the shale samples of the two wells have proximate pores-generating capacity and pores-supporting capacity.However,the pore characteristics of shale samples from two wells are significantly different.Compared with the stabilized zone shale,the porosity,pore volume,and specific surface area of the deformed zone shale were reduced by 60.61%,64.85%,and 27.81%,respectively.Moreover,the macroscopic and fine pores were reduced by 54.01%and 84.95%,respectively.Fault activity and uplift denudation are not conducive to pore preservation,and the rigid basement of Huangling uplift can promote pore preservation.These three factors are important reasons for controlling the difference in pore structure between two wells shales.We established a conceptual model of shale pores evolution under different tectonic preservation conditions.This study is significant to clarify the scale of shale gas formation and enrichment in complex tectonic regions,and helps in the selection of shale sweet spots.展开更多
The efficient pyrolysis and conversion of organic matter in organic-rich shale,as well as the effective recovery of pyrolysis shale oil and gas,play a vital role in alleviating energy pressure.The state of carbon diox...The efficient pyrolysis and conversion of organic matter in organic-rich shale,as well as the effective recovery of pyrolysis shale oil and gas,play a vital role in alleviating energy pressure.The state of carbon dioxide(CO_(2))in the pyrolysis environment of shale reservoirs is the supercritical state.Its unique supercritical fluid properties not only effectively heat organic matter,displace pyrolysis products and change shale pore structure,but also achieve carbon storage to a certain extent.Shale samples were made into powder and three sizes of cores,and nitrogen(N_(2))and supercritical carbon dioxide(ScCO_(2))pyrolysis experiments were performed at different final pyrolysis temperatures.The properties and mineral characteristics of the pyrolysis products were studied based on gas chromatography analysis,Xray diffraction tests,and mass spectrometry analysis.Besides,the pore structure characteristics at different regions of cores before and after pyrolysis were analyzed using N_(2) adsorption tests to clarify the impact of fracturing degree on the pyrolysis effect.The results indicate that the optimal pyrolysis temperature of Longkou shale is about 430℃.Compared with N_(2),the oil yield of ScCO_(2) pyrolysis is higher.The pyrolysis oil obtained by ScCO_(2) extraction has more intermediate fractions and higher relative molecular weight.The ScCO_(2) can effectively improve the pore diameter of shale and its effect is better than that of N_(2).The micropores are produced in shale after pyrolysis,and the macropores only are generated in ScCO_(2) pyrolysis environments with temperatures greater than 430℃.The pore structure has different development characteristics at different pyrolysis temperatures,which are mainly affected by the pressure holding of volatile matter and products blocking.Compared to the surface of the core,the pore development effect inside the core is better.With the decrease in core size,the pore diameter,specific surface area,and pore volume of cores all increase after pyrolysis.展开更多
The lamellar hydrates of CAC were designed with the introduction of nano CaCO_(3)or Mg-Al hydrotalcite(M-A-H),and the effects on the green strength,pore structures,and high-temperature fracture behavior of alumina-spi...The lamellar hydrates of CAC were designed with the introduction of nano CaCO_(3)or Mg-Al hydrotalcite(M-A-H),and the effects on the green strength,pore structures,and high-temperature fracture behavior of alumina-spinel castables were investigated.The results show that nano CaCO_(3)or M-A-H stimulates rapidly the hydration of CAC and the formation of lamellar C_(4)AcH_(11)or coexistence of C_(2)AH_(8)and C_(4)AcH_(11)at 25℃.The formation of lamellar hydrates can contribute to a more complicated pore structure,especially in the range of 400-2000 nm.Meanwhile,the incorporation of well-distributed CaO or MgO sources from nano CaCO_(3)or M-A-H also regulates the distribution of CA_(6)and spinel(pre-formed and in-situ).Consequently,the optimized microstructure and complicated pore structure can induce the deflection and bridging of cracks,thus facilitating the consumption of fracture energy and enhancing the resistance to thermal stress damage.展开更多
The methods of nuclear magnetic resonance(NMR)spectroscopy,mercury injection porosimetry(MIP),and gas-water relative permeability(GWRP)were used to reveal the pore structure and permeability characteristics of high-ra...The methods of nuclear magnetic resonance(NMR)spectroscopy,mercury injection porosimetry(MIP),and gas-water relative permeability(GWRP)were used to reveal the pore structure and permeability characteristics of high-rank coal reservoirs in the Bide-Santang basin,western Guizhou,South China,to provide guidance for coalbed methane(CBM)exploration and exploitation and obtain direct insights for the development of CBM wells.The results indicate that the coal reservoirs in the study area are characterized by well-developed adsorption pores and poorly developed seepage pores.The bimodal NMR transverse relaxation time(T2)spectra and the mutation in the fractal characteristic of the MIP pore volume indicate poor connectivity between the adsorption pores and the seepage pores.As a result,the effective porosity is relatively low,with an average of 1.70%.The irreducible water saturation of the coal reservoir is relatively high,with an average of 66%,leading to a low gas relative permeability under irreducible water saturation.This is the main reason for the low recovery of high-rank CBM reservoirs,and effective enhanced CBM recovery technology urgently is needed.As a nondestructive and less time-consuming technique,the NMR is a promising method to quantitatively characterize the pores and fractures of coals.展开更多
Due to seasonal climate alterations,the microstructure and permeability of granite residual soil are easily affected by multiple dry-wet cycles.The X-ray micro computed tomography(micro-CT)acted as a nondestructive to...Due to seasonal climate alterations,the microstructure and permeability of granite residual soil are easily affected by multiple dry-wet cycles.The X-ray micro computed tomography(micro-CT)acted as a nondestructive tool for characterizing the microstructure of soil samples exposed to a range of damage levels induced by dry-wet cycles.Subsequently,the variations of pore distribution and permeability due to drywet cycling effects were revealed based on three-dimensional(3D)pore distribution analysis and seepage simulations.According to the results,granite residual soils could be separated into four different components,namely,pores,clay,quartz,and hematite,from micro-CT images.The reconstructed 3D pore models dynamically demonstrated the expanding and connecting patterns of pore structures during drywet cycles.The values of porosity and connectivity are positively correlated with the number of dry-wet cycles,which were expressed by exponential and linear functions,respectively.The pore volume probability distribution curves of granite residual soil coincide with the χ^(2)distribution curve,which verifies the effectiveness of the assumption of χ^(2)distribution probability.The pore volume distribution curves suggest that the pores in soils were divided into four types based on their volumes,i.e.micropores,mesopores,macropores,and cracks.From a quantitative and visual perspective,considerable small pores are gradually transformed into cracks with a large volume and a high connectivity.Under the action of dry-wet cycles,the number of seepage flow streamlines which contribute to water permeation in seepage simulation increases distinctly,as well as the permeability and hydraulic conductivity.The calculated hydraulic conductivity is comparable with measured ones with an acceptable error margin in general,verifying the accuracy of seepage simulations based on micro-CT results.展开更多
Permeability is a key parameter for coalbed methane development.Although the absolute permeability of coal has been extensively studied,wettability and pore structure properties continue to challenge the microscopic d...Permeability is a key parameter for coalbed methane development.Although the absolute permeability of coal has been extensively studied,wettability and pore structure properties continue to challenge the microscopic description of water-gas flow in coal.For this purpose,we reconstructed the microstructures of low-rank coal using micro-computed tomography(micro-CT)images.Pore geometry and pore-throat parameters are introduced to establish a relationship with absolute permeability.A dual-porosity pore network model is developed to study water-gas displacement under different wetting and pore structure properties.Results show that absolute permeability is significantly affected by pore geometry and can be described using a binary quadratic function of porosity and fractal dimension.Water-gas relative permeability varies significantly and the residual gas saturation is lower;the crossover saturation first decreased and then increased with increasing porosity under hydrophobic conditions.While the water relative permeability is lower and a certain amount of gas is trapped in complex pore-throat networks;the crossover saturation is higher under hydrophilic conditions.Models with large percolating porosity and well-developed pore networks have high displacement efficiency due to low capillary resistance and avoidance of trapping.This work provides a systematic description of absolute permeability and water-gas relative permeability in coal microstructure for enhanced gas recovery.展开更多
The influence of pore structure difference on rock electrical characteristics of reservoir and oil reservoir was analyzed taking Triassic Chang 6 reservoir in Block Yanwumao in the middle of Ordos Basin as an example....The influence of pore structure difference on rock electrical characteristics of reservoir and oil reservoir was analyzed taking Triassic Chang 6 reservoir in Block Yanwumao in the middle of Ordos Basin as an example. The relationship between the pore structure difference and the low resistivity oil layer was revealed and demonstrated through core observation, lab experiments, geological research, well log interpretation and trial production etc. The results show that there were two kinds of oil layers in Chang 6 oil layer set, normal oil layer and low resistivity oil layer in the region, corresponding to two types of pore structures, pore type mono-medium and micro-fracture-pore type double-medium; the development of micro-fracture changed greatly the micro-pore structure of the reservoir, and the pore structure difference had an important influence on the rock electrical characteristics of the extra-low permeability sandstone reservoir and oil reservoir; the normal oil layers had obvious characteristics of pore-type mono-medium, and were concentrated in Chang 61, Chang 6232 and Chang 62; the low resistivity oil layers had obvious characteristics of micro-fracture-pore type double-medium, which were mainly distributed in Chang 612 and Chang 63. The mud filtrate penetrated deep into the oil layers along the micro-cracks, leading to sharp reduction of resistivity, and thus low resistivity of the oil layer; the low resistivity oil layers had better storage capacity and higher productivity than the normal oil layers.展开更多
In this study, the differences in reservoir parameters, such as pore radius, throat radius, and pore-throat ratio, between the east and west subsags of the Lishui Sag are analyzed by using data obtained from a constan...In this study, the differences in reservoir parameters, such as pore radius, throat radius, and pore-throat ratio, between the east and west subsags of the Lishui Sag are analyzed by using data obtained from a constant-rate mercury injection experiment. Furthermore, the quality of the reservoirs in the two subsags is systematically evaluated. Results show that the throat radius of the Lishui west subsag is larger than that of the east subsag, and this parameter has a positive correlation with reservoir quality. However, the pore-throat ratio of the east subsag is larger than that of the west subsag, which has an inverse relationship with reservoir quality. The main reasons for this reservoir difference can be attributed to sedimentation and diagenesis. The sedimentary facies types of the Lishui east subsag are the fan delta, shore lake, shallow lake, and shore shallow lake;their sandstone composition maturity is low;the clay mineral content is high;and the rock has undergone strong diagenesis. Therefore, the physical conditions of the reservoir are poor. However, the sandstones in the Lishui west subsag have weak cementation and compaction, mainly with an intergranular pore structure type, which leads to good connectivity between pores. Therefore, the storage performance and seepage capacity of the Lishui west subsag are better than those of the east subsag;the west subsag is the main area of oil and gas accumulation, as confirmed in the process of exploration and development.展开更多
The pore structure of coal plays a key role in controlling the storage and migration of CH4/N2.The pore structure of coal is an important indicator to measure the gas extraction capability and the gas displacement efe...The pore structure of coal plays a key role in controlling the storage and migration of CH4/N2.The pore structure of coal is an important indicator to measure the gas extraction capability and the gas displacement efect of N2 injection.The deformation characteristic of coal during adsorption–desorption of CH4/N2 is an important factor afecting CH4 pumpability and N2 injectability.The pore structure characteristics of low-permeability coal were obtained by fuid intrusion method and photoelectric radiation technology.The multistage and connectivity of coal pores were analyzed.Subsequently,a simultaneous test experiment of CH4/N2 adsorption–desorption and coal deformation was carried out.The deformation characteristics of coal were clarifed and a coal strain model was constructed.Finally,the applicability of low-permeability coal to N2 injection for CH4 displacement technology was investigated.The results show that the micropores and transition pores of coal samples are relatively developed.The pore morphology of coal is dominated by semi-open pores.The pore structure of coal is highly complex and heterogeneous.Transition pores,mesopores and macropores of coal have good connectivity,while micropores have poor connectivity.Under constant triaxial stress,the adsorption capacity of the coal for CH4 is greater than that for N2,and the deformation capacity of the coal for CH4 adsorption is greater than that for N2 adsorption.The axial strain,circumferential strain,and volumetric strain during the entire process of CH4 and N2 adsorption/desorption in the coal can be divided into three stages.Coal adsorption–desorption deformation has the characteristics of anisotropy and gas-diference.A strain model for the adsorption–desorption of CH4/N2 from coal was established by considering the expansion stress of adsorbed gas on the coal matrix,the compression stress of free gas on the coal matrix,and the expansion stress of free gas on micropore fractures.N2 has good injectability in low-permeability coal seams and has the dual functions of improving coal seam permeability and enhancing gas fow,which can signifcantly improve the efectiveness of low-permeability coal seam gas control and promote the efcient utilization of gas resources.展开更多
The oil and gas potential of the Yan'an Formation in the Ordos Basin has yet to be fully tapped. In this study, the pore structure, mobile fluid saturation, and water flooding micro-mechanism of the Yan'an For...The oil and gas potential of the Yan'an Formation in the Ordos Basin has yet to be fully tapped. In this study, the pore structure, mobile fluid saturation, and water flooding micro-mechanism of the Yan'an Formation sandstone are systematically studied through the application of a series of rock physics and fluid experiments. The results show that there is a good positive correlation between porosity and permeability, and the reservoirs are divided into types Ⅰ, Ⅱ, and Ⅲ. Mercury injection tests show that the average pore throat radius of the oil-bearing reservoir ranges from 1 to 7 μm. The displacement pressure of the Yan'an Formation is also relatively low, and it decreases from 0.1 MPa to 0.01 MPa as the rock porosity increases from 11% to 18%. NMR tests show that small (diameter <0.5 μm) and medium pores (diameter ranging from 0.5 to 2.5 μm) are predominant in the reservoir. Different types of reservoirs have different characteristics of relative permeability curve. In addition, when the average oil recovery rate is less than 1 ml/min, the oil displacement efficiency increases faster. However, when the average oil recovery rate is between 1–3.5 ml/min, the oil displacement efficiency is maintained at around 27%–30%. Physical properties of the reservoir, pore-throat structure, experimental pressure difference, and pore volume injected — all have significant effects on oil displacement efficiency. For Type Ⅰ and Type Ⅱ reservoirs, the increase of the pore volume injected has a significant effect on oil displacement efficiency. However, for Type Ⅲ reservoirs, the change of pore volume injected has insignificant effect on oil displacement efficiency. This study provides a reference for the formulation of estimated ultimate recovery (EUR) measures for similar sandstone reservoirs.展开更多
Two different freeze-thaw cycles(FTC)are considered in this study to assess the related impact on gas permeability and micro-pore structure of a mortar.These are the water-freezing/water-thawing(WF-WT)and the air-free...Two different freeze-thaw cycles(FTC)are considered in this study to assess the related impact on gas permeability and micro-pore structure of a mortar.These are the water-freezing/water-thawing(WF-WT)and the air-freezing/air-thawing(AF-AT)cycles.The problem is addressed experimentally through an advanced nuclear magnetic resonance(NMR)technique able to provide meaningful information on the relationships among gas permeability,pore structure,mechanical properties,and the number of cycles.It is shown that the mortar gas permeability increases with the number of FTCs,the increase factor being 20 and 12.83 after 40 cycles for the WF-WT and AF-AT,respectively.The results also confirm that gas permeability hysteresis phenomena occur during the confining pressure loading and unloading process.展开更多
Permeability prediction using linear regression of porosity always has poor performance when the reservoir with complex pore structure and large variation of lithofacies.A new method is proposed to predict permeabilit...Permeability prediction using linear regression of porosity always has poor performance when the reservoir with complex pore structure and large variation of lithofacies.A new method is proposed to predict permeability by comprehensively considering pore structure,porosity and lithofacies.In this method,firstly,the lithofacies classification is carried out using the elastic parameters,porosity and shear frame flexibility factor.Then,for each lithofacies,the elastic parameters,porosity and shear frame flexibility factor are used to obtain permeability from regression.The permeability prediction test by logging data of the study area shows that the shear frame flexibility factor that characterizes the pore structure is more sensitive to permeability than the conventional elastic parameters,so it can predict permeability more accurately.In addition,the permeability prediction is depending on the precision of lithofacies classification,reliable lithofacies classification is the precondition of permeability prediction.The field data application verifies that the proposed permeability prediction method based on pore structure parameters and lithofacies is accurate and effective.This approach provides an effective tool for permeability prediction.展开更多
According to the capillary theory,an equivalent capillary model of micro-resistivity imaging logging was built.On this basis,the theoretical models of porosity spectrum(Ф_(i)),permeability spectrum(K_(i))and equivale...According to the capillary theory,an equivalent capillary model of micro-resistivity imaging logging was built.On this basis,the theoretical models of porosity spectrum(Ф_(i)),permeability spectrum(K_(i))and equivalent capillary pressure curve(pe)were established to reflect the reservoir heterogeneity.To promote the application of the theoretical models,the Archie's equation was introduced to establish a general model for quantitatively characterizing bi,K,and pei.Compared with the existing models,it is shown that:(1)the existing porosity spectrum model is the same as the general equation of gi;(2)the Ki model can display the permeability spectrum as compared with Purcell's permeability model;(3)the per model is constructed on a theoretical basis and avoids the limitations of existing models that are built only based on the component of porosity spectrum,as compared with the empirical model of capillary pressure curve.The application in the Permian Maokou Formation of Well TsX in the Central Sichuan paleo-uplift shows that the Ф_(i),K_(i),and p_(ci) models can be effectively applied to the identification of reservoir types,calculation of reservoir properties and pore structure parameters,and evaluation of reservoir heterogeneity.展开更多
基金supported by the National Natural Science Foundation of China(52274056,U22B2075).
文摘Oil transport is greatly affected by heterogeneous pore–throat structures present in shale.It is therefore very important to accurately characterize pore–throat structures.Additionally,it remains unclear how pore–throat structures affect oil transport capacity.In this paper,using finite element(FE)simulation and mathematical modeling,we calculated the hydrodynamic resistance for four pore–throat structure.In addition,the influence of pore throat structure on shale oil permeability is analyzed.According to the results,the hydrodynamic resistance of different pore throat structures can vary by 300%.The contribution of additional resistance caused by streamline bending is also in excess of 40%,even without slip length.Fur-thermore,Pore–throat structures can affect apparent permeability by more than 60%on the REV scale,and this influence increases with heterogeneity of pore size distribution,organic matter content,and organic matter number.Clearly,modeling shale oil flow requires consideration of porous–throat structure and additional resistance,otherwise oil recovery and flow capacity may be overestimated.
基金supported by National Natural Science Foundation of China(Grant No.42172159)Science Foundation of China University of Petroleum,Beijing(Grant No.2462023XKBH002).
文摘Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the effects of complex pore structures and wettability.To address this issue,based on the digital rock of low permeability sandstone,a direct numerical simulation is performed considering the interphase drag and boundary slip to clarify the microscopic water-oil displacement process.In addition,a dual-porosity pore network model(PNM)is constructed to obtain the water-oil relative permeability of the sample.The displacement efficiency as a recovery process is assessed under different wetting and pore structure properties.Results show that microscopic displacement mechanisms explain the corresponding macroscopic relative permeability.The injected water breaks through the outlet earlier with a large mass flow,while thick oil films exist in rough hydrophobic surfaces and poorly connected pores.The variation of water-oil relative permeability is significant,and residual oil saturation is high in the oil-wet system.The flooding is extensive,and the residual oil is trapped in complex pore networks for hydrophilic pore surfaces;thus,water relative permeability is lower in the water-wet system.While the displacement efficiency is the worst in mixed-wetting systems for poor water connectivity.Microporosity negatively correlates with invading oil volume fraction due to strong capillary resistance,and a large microporosity corresponds to low residual oil saturation.This work provides insights into the water-oil flow from different modeling perspectives and helps to optimize the development plan for enhanced recovery.
文摘Experimental methods,including mercury pressure,nuclear magnetic resonance(NMR)and core(wateroil)displacement,are used to examine the effects of high-multiple water injection(i.e.water injection with high injected pore volume)on rock properties,pore structure and oil displacement efficiency of an oilfield in the western South China Sea.The results show an increase in the permeability of rocks along with particle migration,an increase in the pore volume and the average pore throat radius,and enhanced heterogeneity after high-multiple water injection.Compared with normal water injection methods,a high-multiple water injection is more effective in improving the oil displacement efficiency.The degree of recovery increases faster in the early stage due to the expansion of the swept area,and the transition from oil-wet to water-wet.The degree of recovery increases less in the late stage due to various factors,including the enhancement of heterogeneity in the rocks.Considering both the economic aspect and the production limit of water flooding,it is recommended to adopt other technologies to further enhance oil recovery after 300 PV water injection.
基金The authors are grateful for the financial support provided by the National Natural Science Foundation of China(52362010,52304326,22305055,and 52274297)the Start-up Research Foundation of Hainan University(KYQD(ZR)-23069,20008,23067,and 23073)the specific research fund of the Innovation Platform for Academicians of Hainan Province(YSPTZX202315).
文摘Both sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs)are considered as promising candidates in grid-level energy storage devices.Unfortunately,the larger ionic radii of K+and Na+induce poor diffusion kinetics and cycling stability of carbon anode materials.Pore structure regulation is an ideal strategy to promote the diffusion kinetics and cyclic stability of carbon materials by facilitating electrolyte infiltration,increasing the transport channels,and alleviating the volume change.However,traditional pore-forming agent-assisted methods considerably increase the difficulty of synthesis and limit practical applications of porous carbon materials.Herein,porous carbon materials(Ca-PC/Na-PC/K-PC)with different pore structures have been prepared with gluconates as the precursors,and the amorphous structure,abundant micropores,and oxygen-doping active sites endow the Ca-PC anode with excellent potassium and sodium storage performance.For PIBs,the capacitive contribution ratio of Ca-PC is 82%at 5.0 mV s^(-1) due to the introduction of micropores and high oxygen-doping content,while a high reversible capacity of 121.4 mAh g^(-1) can be reached at 5 A g^(-1) after 2000 cycles.For SIBs,stable sodium storage capacity of 101.4 mAh g^(-1) can be achieved at 2 A g^(-1) after 8000 cycles with a very low decay rate of 0.65%for per cycle.This work may provide an avenue for the application of porous carbon materials in the energy storage field.
基金supported by the National Key Research and Development Program of China (Grant No.2018YFA0702400)the National Natural Science Foundation of China (Grant No.52174050)+1 种基金the Natural Science Foundation of Shandong Province (Grant No.ZR2020ME088)the National Natural Science Foundation of Qingdao (Grant No.23-2-1-227-zyyd-jch)。
文摘Hot water flooding is an effective way to develop heavy oil reservoirs.However,local channeling channels may form,possibly leading to a low thermal utilization efficiency and high water cut in the reservoir.The pore structure heterogeneity is an important factor in forming these channels.This study proposes a method that mixes quartz sand with different particle sizes to prepare weakly heterogeneous and strongly heterogeneous models through which hot water flooding experiments are conducted.During the experiments,computer tomography(CT)scanning identifies the pore structure and micro remaining oil saturation distribution to analyze the influence of the pore structure heterogeneity on the channeling channels.The oil saturation reduction and average pore size are divided into three levels to quantitatively describe the relationship between the channeling channel distribution and pore structure heterogeneity.The zone where oil saturation reduction exceeds 20%is defined as a channeling channel.The scanning area is divided into 180 equally sized zones based on the CT scanning images,and threedimensional(3D)distributions of the channeling channels are developed.Four micro remaining oil distribution patterns are proposed,and the morphology characteristics of micro remaining oil inside and outside the channeling channels are analyzed.The results show that hot water flooding is more balanced in the weakly heterogeneous model,and the oil saturation decreases by more than 20%in most zones without narrow channeling channels forming.In the strongly heterogeneous model,hot water flooding is unbalanced,and three narrow channeling channels of different lengths form.In the weakly heterogeneous model,the oil saturation reduction is greater in zones with larger pores.The distribution range of the average pore size is larger in the strongly heterogeneous model.The network remaining oil inside the channeling channels is less than outside the channeling channels,and the hot water converts the network remaining oil into cluster,film,and droplet remaining oil.
基金the National Science Fund for Distinguished Young Scholars(No.52225403)the Natural Science Foundation of Shanxi Province(No.202303021212073)the National Natural Science Foundation of China(No.52104210)。
文摘Understanding the impact of mining disturbances and creep deformation on the macroscopic deformation and the microscopic pore and fracture structures(MPFS)of coal is paramount for ensuring the secure extraction of coal resources.This study conducts cyclic loading-unloading and creep experiments on coal using a low-field nuclear magnetic resonance(NMR)experimental apparatus which is equipped with mechanical loading units,enabling real-time monitoring the T2spectrum.The experiments indicated that cyclic loading-unloading stress paths initiate internal damage within coal samples.Under identical creep stress conditions,coal samples with more initial damages had more substantial instantaneous deformation and creep deformation during the creep process.After undergoing nearly 35 h of staged creep,the total strains for coal samples CC01,CC02,and CC03 reach 2.160%,2.261%,and 2.282%,respectively.In the creep stage,the peak area ratio of seepage pores and microfractures(SPM)gradually diminishes.A higher degree of initial damage leads to a more pronounced compaction trend in the SPM of coal samples.Considering the porosity evolution of SPM during the creep process,this study proposes a novel fractional derivative model for the porosity evolution of SPM.The efficacy of the proposed model in predicting porosity evolution of SPM is substantiated through experimental validation.Furthermore,an analysis of the impact mechanisms on key parameters in the model was carried out.
基金financially supported by the National Natural Science Foundation of China (51904319)the Fundamental Research Funds for the Central Universities (21CX06029A)。
文摘The cyclic hydraulic stimulation(CHS) has proven as a prospective technology for enhancing the permeability of unconventional formations such as coalbeds. However, the effects of CHS on the microstructure and gas sorption behavior of coal remain unclear. In this study, laboratory tests including the nuclear magnetic resonance(NMR), low-temperature nitrogen sorption(LTNS), and methane sorption isotherm measurement were conducted to explore changes in the pore structure and methane sorption characteristics caused by CHS on an anthracite coal from Qinshui Basin, China. The NMR and LTNS tests show that after CHS treatment, meso- and macro-pores tend to be enlarged, whereas micropores with larger sizes and transition-pores may be converted into smaller-sized micro-pores. After the coal samples treated with 1, 3, 5 and 7 hydraulic stimulation cycles, the total specific surface area(TSSA)decreased from 0.636 to 0.538, 0.516, 0.505, and 0.491 m^(2)/g, respectively. Fractal analysis based on the NMR and LTNS results show that the surface fractal dimensions increase with the increase in the number of hydraulic stimulation cycles, while the volume fractal dimensions exhibit an opposite trend to the surface fractal dimensions, indicating that the pore surface roughness and pore structure connectivity are both increased after CHS treatment. Methane sorption isothermal measurements show that both the Langmuir volume and Langmuir pressure decrease significantly with the increase in the number of hydraulic stimulation cycles. The Langmuir volume and the Langmuir pressure decrease from 33.47 cm^(3)/g and 0.205 MPa to 24.18 cm^(3)/g and 0.176 MPa after the coal samples treated with 7 hydraulic stimulation cycles, respectively. The increments of Langmuir volume and Langmuir pressure are positively correlated with the increment of TSSA and negatively correlated with the increments of surface fractal dimensions.
基金supported by the National Natural Science Foundation of China (42122017,41821002)the Hubei Provincial Natural Science Foundation of China (2020CFB501)+1 种基金the Shandong Provincial Key Research and Development Program (2020ZLYS08)the Independent innovation research program of China University of Petroleum (East China) (21CX06001A)。
文摘Tectonism is one of the dominant factors affecting the shale pore structure.However,the control of shale pore structure by tectonic movements is still controversial,which limits the research progress of shale gas accumulation mechanism in the complex tectonic region of southern China.In this study,34 samples were collected from two exploratory wells located in different tectonic locations.Diverse experiments,e.g.,organic geochemistry,XRD analysis,FE-SEM,low-pressure gas adsorption,and high-pressure mercury intrusion,were conducted to fully characterize the shale reservoir.The TOC,Ro,and mineral composition of the shale samples between the two wells are similar,which reflects that the shale samples of the two wells have proximate pores-generating capacity and pores-supporting capacity.However,the pore characteristics of shale samples from two wells are significantly different.Compared with the stabilized zone shale,the porosity,pore volume,and specific surface area of the deformed zone shale were reduced by 60.61%,64.85%,and 27.81%,respectively.Moreover,the macroscopic and fine pores were reduced by 54.01%and 84.95%,respectively.Fault activity and uplift denudation are not conducive to pore preservation,and the rigid basement of Huangling uplift can promote pore preservation.These three factors are important reasons for controlling the difference in pore structure between two wells shales.We established a conceptual model of shale pores evolution under different tectonic preservation conditions.This study is significant to clarify the scale of shale gas formation and enrichment in complex tectonic regions,and helps in the selection of shale sweet spots.
基金supported by the National Natural Science Foundation of China (Nos.U22B6004,51974341)State Key Laboratory of Deep Oil and Gas (No.SKLDOG2024-ZYTS-14)the Fundamental Research Funds for the Central Universities (No.20CX06070A)。
文摘The efficient pyrolysis and conversion of organic matter in organic-rich shale,as well as the effective recovery of pyrolysis shale oil and gas,play a vital role in alleviating energy pressure.The state of carbon dioxide(CO_(2))in the pyrolysis environment of shale reservoirs is the supercritical state.Its unique supercritical fluid properties not only effectively heat organic matter,displace pyrolysis products and change shale pore structure,but also achieve carbon storage to a certain extent.Shale samples were made into powder and three sizes of cores,and nitrogen(N_(2))and supercritical carbon dioxide(ScCO_(2))pyrolysis experiments were performed at different final pyrolysis temperatures.The properties and mineral characteristics of the pyrolysis products were studied based on gas chromatography analysis,Xray diffraction tests,and mass spectrometry analysis.Besides,the pore structure characteristics at different regions of cores before and after pyrolysis were analyzed using N_(2) adsorption tests to clarify the impact of fracturing degree on the pyrolysis effect.The results indicate that the optimal pyrolysis temperature of Longkou shale is about 430℃.Compared with N_(2),the oil yield of ScCO_(2) pyrolysis is higher.The pyrolysis oil obtained by ScCO_(2) extraction has more intermediate fractions and higher relative molecular weight.The ScCO_(2) can effectively improve the pore diameter of shale and its effect is better than that of N_(2).The micropores are produced in shale after pyrolysis,and the macropores only are generated in ScCO_(2) pyrolysis environments with temperatures greater than 430℃.The pore structure has different development characteristics at different pyrolysis temperatures,which are mainly affected by the pressure holding of volatile matter and products blocking.Compared to the surface of the core,the pore development effect inside the core is better.With the decrease in core size,the pore diameter,specific surface area,and pore volume of cores all increase after pyrolysis.
基金supported financially by the Natural Science Foundation of Qinghai(2022-ZJ-928)the Special Project for Transformation of Scientific and Technological Achievements of Qinghai Province(2023-GX-102).
文摘The lamellar hydrates of CAC were designed with the introduction of nano CaCO_(3)or Mg-Al hydrotalcite(M-A-H),and the effects on the green strength,pore structures,and high-temperature fracture behavior of alumina-spinel castables were investigated.The results show that nano CaCO_(3)or M-A-H stimulates rapidly the hydration of CAC and the formation of lamellar C_(4)AcH_(11)or coexistence of C_(2)AH_(8)and C_(4)AcH_(11)at 25℃.The formation of lamellar hydrates can contribute to a more complicated pore structure,especially in the range of 400-2000 nm.Meanwhile,the incorporation of well-distributed CaO or MgO sources from nano CaCO_(3)or M-A-H also regulates the distribution of CA_(6)and spinel(pre-formed and in-situ).Consequently,the optimized microstructure and complicated pore structure can induce the deflection and bridging of cracks,thus facilitating the consumption of fracture energy and enhancing the resistance to thermal stress damage.
基金a National Science and Technology Major Special Project of China(Grant No.2016ZX05044)a Postdoctoral Science Foundation of China(Grant No.2018M631181)+3 种基金a Natural Science Foundation of Shaanxi Province of China(Grant No.2019JQ-192)a Special Scientific Research Project of Natural Science of Education Department of Shaanxi Province(Grant No.2020-016)a Foundation Research Project of Shaanxi Provincial Key Laboratory of Geological Support for Coal Green Exploitation(Grant No.MTy2019-08)the Independent Projects of the Key Laboratory of Coal Resources Exploration and Comprehensive Utilization,Ministry of Land and Resources of China(Grant No.ZKF2018-1,ZP2018-2).
文摘The methods of nuclear magnetic resonance(NMR)spectroscopy,mercury injection porosimetry(MIP),and gas-water relative permeability(GWRP)were used to reveal the pore structure and permeability characteristics of high-rank coal reservoirs in the Bide-Santang basin,western Guizhou,South China,to provide guidance for coalbed methane(CBM)exploration and exploitation and obtain direct insights for the development of CBM wells.The results indicate that the coal reservoirs in the study area are characterized by well-developed adsorption pores and poorly developed seepage pores.The bimodal NMR transverse relaxation time(T2)spectra and the mutation in the fractal characteristic of the MIP pore volume indicate poor connectivity between the adsorption pores and the seepage pores.As a result,the effective porosity is relatively low,with an average of 1.70%.The irreducible water saturation of the coal reservoir is relatively high,with an average of 66%,leading to a low gas relative permeability under irreducible water saturation.This is the main reason for the low recovery of high-rank CBM reservoirs,and effective enhanced CBM recovery technology urgently is needed.As a nondestructive and less time-consuming technique,the NMR is a promising method to quantitatively characterize the pores and fractures of coals.
基金supported by the National Natural Science Foundation of China (Grant Nos. 12102312 and 41372314)State Key Laboratory of Geohazard Prevention and Geoenvironment Protection Open Foundation, Chengdu University of Technology, China (Grant No. SKLGP2021K011)
文摘Due to seasonal climate alterations,the microstructure and permeability of granite residual soil are easily affected by multiple dry-wet cycles.The X-ray micro computed tomography(micro-CT)acted as a nondestructive tool for characterizing the microstructure of soil samples exposed to a range of damage levels induced by dry-wet cycles.Subsequently,the variations of pore distribution and permeability due to drywet cycling effects were revealed based on three-dimensional(3D)pore distribution analysis and seepage simulations.According to the results,granite residual soils could be separated into four different components,namely,pores,clay,quartz,and hematite,from micro-CT images.The reconstructed 3D pore models dynamically demonstrated the expanding and connecting patterns of pore structures during drywet cycles.The values of porosity and connectivity are positively correlated with the number of dry-wet cycles,which were expressed by exponential and linear functions,respectively.The pore volume probability distribution curves of granite residual soil coincide with the χ^(2)distribution curve,which verifies the effectiveness of the assumption of χ^(2)distribution probability.The pore volume distribution curves suggest that the pores in soils were divided into four types based on their volumes,i.e.micropores,mesopores,macropores,and cracks.From a quantitative and visual perspective,considerable small pores are gradually transformed into cracks with a large volume and a high connectivity.Under the action of dry-wet cycles,the number of seepage flow streamlines which contribute to water permeation in seepage simulation increases distinctly,as well as the permeability and hydraulic conductivity.The calculated hydraulic conductivity is comparable with measured ones with an acceptable error margin in general,verifying the accuracy of seepage simulations based on micro-CT results.
基金the National Natural Science Foundation of China(Nos.51934004,51974176)the Natural Science Foundation for Distinguished Young Scholars of Shandong Province(No.ZR2020JQ22)+1 种基金the Youth Science and Technology Innovation of Shandong Province(No.2019KJH006)the Special Funds for Taishan Scholar Project(No.TS20190935).
文摘Permeability is a key parameter for coalbed methane development.Although the absolute permeability of coal has been extensively studied,wettability and pore structure properties continue to challenge the microscopic description of water-gas flow in coal.For this purpose,we reconstructed the microstructures of low-rank coal using micro-computed tomography(micro-CT)images.Pore geometry and pore-throat parameters are introduced to establish a relationship with absolute permeability.A dual-porosity pore network model is developed to study water-gas displacement under different wetting and pore structure properties.Results show that absolute permeability is significantly affected by pore geometry and can be described using a binary quadratic function of porosity and fractal dimension.Water-gas relative permeability varies significantly and the residual gas saturation is lower;the crossover saturation first decreased and then increased with increasing porosity under hydrophobic conditions.While the water relative permeability is lower and a certain amount of gas is trapped in complex pore-throat networks;the crossover saturation is higher under hydrophilic conditions.Models with large percolating porosity and well-developed pore networks have high displacement efficiency due to low capillary resistance and avoidance of trapping.This work provides a systematic description of absolute permeability and water-gas relative permeability in coal microstructure for enhanced gas recovery.
基金Supported by the Natural Science Foundation of Shaanxi Province,China(2010JM5003)
文摘The influence of pore structure difference on rock electrical characteristics of reservoir and oil reservoir was analyzed taking Triassic Chang 6 reservoir in Block Yanwumao in the middle of Ordos Basin as an example. The relationship between the pore structure difference and the low resistivity oil layer was revealed and demonstrated through core observation, lab experiments, geological research, well log interpretation and trial production etc. The results show that there were two kinds of oil layers in Chang 6 oil layer set, normal oil layer and low resistivity oil layer in the region, corresponding to two types of pore structures, pore type mono-medium and micro-fracture-pore type double-medium; the development of micro-fracture changed greatly the micro-pore structure of the reservoir, and the pore structure difference had an important influence on the rock electrical characteristics of the extra-low permeability sandstone reservoir and oil reservoir; the normal oil layers had obvious characteristics of pore-type mono-medium, and were concentrated in Chang 61, Chang 6232 and Chang 62; the low resistivity oil layers had obvious characteristics of micro-fracture-pore type double-medium, which were mainly distributed in Chang 612 and Chang 63. The mud filtrate penetrated deep into the oil layers along the micro-cracks, leading to sharp reduction of resistivity, and thus low resistivity of the oil layer; the low resistivity oil layers had better storage capacity and higher productivity than the normal oil layers.
基金supported by the National Natural Science Foundation of China (Nos. 51504143 and 51674156)the SDUST Research Fund (No. 2015DJH101)the Major National R&D Projects of China (No. 2016ZX0 5027-001-006)。
文摘In this study, the differences in reservoir parameters, such as pore radius, throat radius, and pore-throat ratio, between the east and west subsags of the Lishui Sag are analyzed by using data obtained from a constant-rate mercury injection experiment. Furthermore, the quality of the reservoirs in the two subsags is systematically evaluated. Results show that the throat radius of the Lishui west subsag is larger than that of the east subsag, and this parameter has a positive correlation with reservoir quality. However, the pore-throat ratio of the east subsag is larger than that of the west subsag, which has an inverse relationship with reservoir quality. The main reasons for this reservoir difference can be attributed to sedimentation and diagenesis. The sedimentary facies types of the Lishui east subsag are the fan delta, shore lake, shallow lake, and shore shallow lake;their sandstone composition maturity is low;the clay mineral content is high;and the rock has undergone strong diagenesis. Therefore, the physical conditions of the reservoir are poor. However, the sandstones in the Lishui west subsag have weak cementation and compaction, mainly with an intergranular pore structure type, which leads to good connectivity between pores. Therefore, the storage performance and seepage capacity of the Lishui west subsag are better than those of the east subsag;the west subsag is the main area of oil and gas accumulation, as confirmed in the process of exploration and development.
基金supported by the Natural Science Foundation of China(51874236 and 52174207)Shaanxi Provincial Department of Science and Technology(2020JC-48 and 2022TD-02)China Postdoctoral Science Foundation(2021M693879).
文摘The pore structure of coal plays a key role in controlling the storage and migration of CH4/N2.The pore structure of coal is an important indicator to measure the gas extraction capability and the gas displacement efect of N2 injection.The deformation characteristic of coal during adsorption–desorption of CH4/N2 is an important factor afecting CH4 pumpability and N2 injectability.The pore structure characteristics of low-permeability coal were obtained by fuid intrusion method and photoelectric radiation technology.The multistage and connectivity of coal pores were analyzed.Subsequently,a simultaneous test experiment of CH4/N2 adsorption–desorption and coal deformation was carried out.The deformation characteristics of coal were clarifed and a coal strain model was constructed.Finally,the applicability of low-permeability coal to N2 injection for CH4 displacement technology was investigated.The results show that the micropores and transition pores of coal samples are relatively developed.The pore morphology of coal is dominated by semi-open pores.The pore structure of coal is highly complex and heterogeneous.Transition pores,mesopores and macropores of coal have good connectivity,while micropores have poor connectivity.Under constant triaxial stress,the adsorption capacity of the coal for CH4 is greater than that for N2,and the deformation capacity of the coal for CH4 adsorption is greater than that for N2 adsorption.The axial strain,circumferential strain,and volumetric strain during the entire process of CH4 and N2 adsorption/desorption in the coal can be divided into three stages.Coal adsorption–desorption deformation has the characteristics of anisotropy and gas-diference.A strain model for the adsorption–desorption of CH4/N2 from coal was established by considering the expansion stress of adsorbed gas on the coal matrix,the compression stress of free gas on the coal matrix,and the expansion stress of free gas on micropore fractures.N2 has good injectability in low-permeability coal seams and has the dual functions of improving coal seam permeability and enhancing gas fow,which can signifcantly improve the efectiveness of low-permeability coal seam gas control and promote the efcient utilization of gas resources.
基金supported by the Guiding Science and Technology Planning Project of Daqing(Grant No.zd-2021-36)Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province,China(Grant No.LBH-Z21084)Natural Science Foundation of Heilongjiang Province(Grant No.LH 2022E019).
文摘The oil and gas potential of the Yan'an Formation in the Ordos Basin has yet to be fully tapped. In this study, the pore structure, mobile fluid saturation, and water flooding micro-mechanism of the Yan'an Formation sandstone are systematically studied through the application of a series of rock physics and fluid experiments. The results show that there is a good positive correlation between porosity and permeability, and the reservoirs are divided into types Ⅰ, Ⅱ, and Ⅲ. Mercury injection tests show that the average pore throat radius of the oil-bearing reservoir ranges from 1 to 7 μm. The displacement pressure of the Yan'an Formation is also relatively low, and it decreases from 0.1 MPa to 0.01 MPa as the rock porosity increases from 11% to 18%. NMR tests show that small (diameter <0.5 μm) and medium pores (diameter ranging from 0.5 to 2.5 μm) are predominant in the reservoir. Different types of reservoirs have different characteristics of relative permeability curve. In addition, when the average oil recovery rate is less than 1 ml/min, the oil displacement efficiency increases faster. However, when the average oil recovery rate is between 1–3.5 ml/min, the oil displacement efficiency is maintained at around 27%–30%. Physical properties of the reservoir, pore-throat structure, experimental pressure difference, and pore volume injected — all have significant effects on oil displacement efficiency. For Type Ⅰ and Type Ⅱ reservoirs, the increase of the pore volume injected has a significant effect on oil displacement efficiency. However, for Type Ⅲ reservoirs, the change of pore volume injected has insignificant effect on oil displacement efficiency. This study provides a reference for the formulation of estimated ultimate recovery (EUR) measures for similar sandstone reservoirs.
基金supported by the National Natural Science Foundation of China(Grant No.51709097).
文摘Two different freeze-thaw cycles(FTC)are considered in this study to assess the related impact on gas permeability and micro-pore structure of a mortar.These are the water-freezing/water-thawing(WF-WT)and the air-freezing/air-thawing(AF-AT)cycles.The problem is addressed experimentally through an advanced nuclear magnetic resonance(NMR)technique able to provide meaningful information on the relationships among gas permeability,pore structure,mechanical properties,and the number of cycles.It is shown that the mortar gas permeability increases with the number of FTCs,the increase factor being 20 and 12.83 after 40 cycles for the WF-WT and AF-AT,respectively.The results also confirm that gas permeability hysteresis phenomena occur during the confining pressure loading and unloading process.
基金Supported by the Youth Foundation of National Natural Science Foundation of China(41804126)Scientific Research and Technology Development Project of CNPC(2017D-3503,2018D-4407).
文摘Permeability prediction using linear regression of porosity always has poor performance when the reservoir with complex pore structure and large variation of lithofacies.A new method is proposed to predict permeability by comprehensively considering pore structure,porosity and lithofacies.In this method,firstly,the lithofacies classification is carried out using the elastic parameters,porosity and shear frame flexibility factor.Then,for each lithofacies,the elastic parameters,porosity and shear frame flexibility factor are used to obtain permeability from regression.The permeability prediction test by logging data of the study area shows that the shear frame flexibility factor that characterizes the pore structure is more sensitive to permeability than the conventional elastic parameters,so it can predict permeability more accurately.In addition,the permeability prediction is depending on the precision of lithofacies classification,reliable lithofacies classification is the precondition of permeability prediction.The field data application verifies that the proposed permeability prediction method based on pore structure parameters and lithofacies is accurate and effective.This approach provides an effective tool for permeability prediction.
基金Supported by the National Natural Science Foundation of China(U2003102,41974117)China National Science and Technology Major Project(2016ZX05052001).
文摘According to the capillary theory,an equivalent capillary model of micro-resistivity imaging logging was built.On this basis,the theoretical models of porosity spectrum(Ф_(i)),permeability spectrum(K_(i))and equivalent capillary pressure curve(pe)were established to reflect the reservoir heterogeneity.To promote the application of the theoretical models,the Archie's equation was introduced to establish a general model for quantitatively characterizing bi,K,and pei.Compared with the existing models,it is shown that:(1)the existing porosity spectrum model is the same as the general equation of gi;(2)the Ki model can display the permeability spectrum as compared with Purcell's permeability model;(3)the per model is constructed on a theoretical basis and avoids the limitations of existing models that are built only based on the component of porosity spectrum,as compared with the empirical model of capillary pressure curve.The application in the Permian Maokou Formation of Well TsX in the Central Sichuan paleo-uplift shows that the Ф_(i),K_(i),and p_(ci) models can be effectively applied to the identification of reservoir types,calculation of reservoir properties and pore structure parameters,and evaluation of reservoir heterogeneity.