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FINE CONTROL OF HZSM-5'S PORE-OPENING SIZE BY A NEW CVD METHOD
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作者 董飞 王桂茹 王祥生 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1995年第4期25-31,共7页
A new CVD method without vacuum condition(CVDWV)was designed in this study,ithad been found that by modifying the flow rate of the carrier gas(N<sub>2</sub>)and the temperature of sur-face reaction,sil... A new CVD method without vacuum condition(CVDWV)was designed in this study,ithad been found that by modifying the flow rate of the carrier gas(N<sub>2</sub>)and the temperature of sur-face reaction,silicon saturator and sample tube,the amount of silica deposited on the external sur-face of the zeolite could be precisely controlled,The changes in the physicochemical properties ofzeolite,such as pore-opening size,acidity and reaction property were investigated.The results ob-tained showed that:modification of the improved CVD method did not change the internal structureand acidity of the zeolite,but could bring about significant change of pore-opening size and reactionproperty as desired. 展开更多
关键词 HZSM-5 CVD ZEOLITE pore-opening SIZE silica adsorption external surface DEPOSIT
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