A flower-like SnO_(2)–SnO/porous Ga N(FSS/PGaN) heterojunction was fabricated for the first time via a facile spraying process, and the whole process also involved hydrothermal preparation of FSS and electrochemical ...A flower-like SnO_(2)–SnO/porous Ga N(FSS/PGaN) heterojunction was fabricated for the first time via a facile spraying process, and the whole process also involved hydrothermal preparation of FSS and electrochemical wet etching of GaN,and SnO_(2)–SnO composites with p–n junctions were loaded onto PGaN surface directly applied to H_(2)S sensor. Meanwhile,the excellent transport capability of heterojunction between FSS and PGaN facilitates electron transfer, that is, a response time as short as 65 s and a release time up to 27 s can be achieved merely at 150℃ under 50 ppm H_(2)S concentration, which has laid a reasonable theoretical and experimental foundation for the subsequent PGaN-based heterojunction gas sensor.The lowering working temperature and high sensitivity(23.5 at 200 ppm H2S) are attributed to the structure of PGaN itself and the heterojunction between SnO_(2)–SnO and PGaN. In addition, the as-obtained sensor showed ultra-high test stability.The simple design strategy of FSS/PGaN-based H_(2)S sensor highlights its potential in various applications.展开更多
Carbon peaking and carbon neutralization trigger a technical revolution in energy&environment related fields.Development of new technologies for green energy production and storage,industrial energy saving and eff...Carbon peaking and carbon neutralization trigger a technical revolution in energy&environment related fields.Development of new technologies for green energy production and storage,industrial energy saving and efficiency reinforcement,carbon capture,and pollutant gas treatment is in highly imperious demand.The emerging porous framework materials such as metal–organic frameworks(MOFs),covalent organic frameworks(COFs)and hydrogen-bonded organic frameworks(HOFs),owing to the permanent porosity,tremendous specific surface area,designable structure and customizable functionality,have shown great potential in major energy-consuming industrial processes,including sustainable energy gas catalytic conversion,energy-efficient industrial gas separation and storage.Herein,this manuscript presents a systematic review of porous framework materials for global and comprehensive energy&environment related applications,from a macroscopic and application perspective.展开更多
The NO2 gas sensing behavior of porous silicon(PS) is studied at room temperature with and without ultraviolet(UV) light radiation.The PS layer is fabricated by electrochemical etching in an HF-based solution on a...The NO2 gas sensing behavior of porous silicon(PS) is studied at room temperature with and without ultraviolet(UV) light radiation.The PS layer is fabricated by electrochemical etching in an HF-based solution on a p +-type silicon substrate.Then,Pt electrodes are deposited on the surface of the PS to obtain the PS gas sensor.The NO2 sensing properties of the PS with different porosities are investigated under UV light radiation at room temperature.The measurement results show that the PS gas sensor has a much higher response sensitivity and faster response-recovery characteristics than NO2 under the illumination.The sensitivity of the PS sample with the largest porosity to 1 ppm NO2 is 9.9 with UV light radiation,while it is 2.4 without UV light radiation.We find that the ability to absorb UV light is enhanced with the increase in porosity.The PS sample with the highest porosity has a larger change than the other samples.Therefore,the effect of UV radiation on the NO2 sensing properties of PS is closely related to the porosity.展开更多
Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite ...Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.展开更多
Metallic ion-cross-linked polymer of intrinsic microporosity(PIM-1) thin-film composite(TFC) membranes supported on an ultraviolet(UV)-cross-linked porous substrate were fabricated. The UV-cross-linked porous substrat...Metallic ion-cross-linked polymer of intrinsic microporosity(PIM-1) thin-film composite(TFC) membranes supported on an ultraviolet(UV)-cross-linked porous substrate were fabricated. The UV-cross-linked porous substrate was prepared via polymerization-induced phase separation. The PIM-1 TFC membranes were fabricated via a dip-coating procedure. Metallic ion-cross-linked PIM-1 TFC membranes were fabricated by hydrolyzing the PIM-1 TFC membrane in an alkali solution and then cross-linking it in a multivalent metallic ion solution. The pore size and porous structures were evaluated by low-temperature N_2 adsorption–desorption analysis. The membrane structure was investigated by field-emission scanning electron microscopy. The effects of heat treatment and pore-forming additives on the gas permeance of the UV-cross-linked porous substrate are reported. The effects of different pre-coating treatments on the gas permeance of the metallic ion-cross-linked PIM-1 TFC membrane are also discussed. The metallic ion-crosslinked PIM-1 TFC membrane displayed high CO_2/N_2 selectivity(23) and good CO_2 permeance(1058 GPU).展开更多
We report on the fabrication and performance of a room-temperature NO2 gas sensor based on a WO3 nanowires/porous silicon hybrid structure. The W18O49 nanowires are synthesized directly from a sputtered tungsten film ...We report on the fabrication and performance of a room-temperature NO2 gas sensor based on a WO3 nanowires/porous silicon hybrid structure. The W18O49 nanowires are synthesized directly from a sputtered tungsten film on a porous silicon (PS) layer under heating in an argon atmosphere. After a carefully controlled annealing treatment, WO3 nanowires are obtained on the PS layer without losing the morphology. The morphology, phase structure, and crystallinity of the nanowires are investigated by using field emission scanning electron microscopy (FESEM), X-ray diffractometer (XRD), and high-resolution transmission electron microscopy (HRTEM). Comparative gas sensing results indicate that the sensor based on the WO3 nanowires exhibits a much higher sensitivity than that based on the PS and pure WO3 nanowires in detecting NO2 gas at room temperature. The mechanism of the WO3 nanowires/PS hybrid structure in the NO2 sensing is explained in detail.展开更多
The performance of gas diffusion porous electrode starved of electrolyte solution can be significantly increased by decreasing the thickness of uneven liquid film covering the catalyst agglomerates.
Carbon dioxide geological sequestration is an effective method to reduce the content of greenhouse gases in the atmosphere of our planet.This process can also be used to improve the production of oil reservoirs by mix...Carbon dioxide geological sequestration is an effective method to reduce the content of greenhouse gases in the atmosphere of our planet.This process can also be used to improve the production of oil reservoirs by mixing carbon dioxide and crude oil.In the present study,a differential separation experiment(DL)based on actual crude oil components is used to simulate such a process.The results show that after mixing,the viscosity and density of reservoir fluid decrease and the volume coefficient increase,indicating that the pre buried gas induces fluid expansion and an improvement of the fluid rheological properties.These effects are interpreted using a pore scale model based on real scanning electron microscopy(SEM).The results show that increasing the pressure and reducing the viscosity are beneficial to increasing the micro oil displacement efficiency.Moreover,these effects can improve the production in the target area and slow down the decline of the formation pressure.Furthermore,in the case of fracture development in the reservoir(due to CO_(2)injection before exploitation),the risk of gas channelling,induced by the displacement pressure difference between injection and production wells,is avoided.展开更多
Heat and mass transfer of a porous permeable wall in a high temperature gas dynamical flow is considered. Numerical simulation is conducted on the ground of the conjugate mathematical model which includes filtration a...Heat and mass transfer of a porous permeable wall in a high temperature gas dynamical flow is considered. Numerical simulation is conducted on the ground of the conjugate mathematical model which includes filtration and heat transfer equations in a porous body and boundary layer equations on its surface. Such an approach enables one to take into account complex interaction between heat and mass transfer in the gasdynamical flow and in the structure subjected to this flow. The main attention is given to the impact of the intraporous heat transfer intensity on the transpiration cooling efficiency.展开更多
The present work reports the synthesis and application of sulfur doped into porous activated carbon for removing elemental mercury from natural gas using a bench-scale fixed-bed reactor. A series of experiments were c...The present work reports the synthesis and application of sulfur doped into porous activated carbon for removing elemental mercury from natural gas using a bench-scale fixed-bed reactor. A series of experiments were carried out to investigate the optimization of Hg0 capture. Furthermore, our experimental results about optimum conditions to remove Hg0 were 1:10 of sulfur to activated carbon impregnation ratio, 350°C of impregnation temperature, and 3 hours of impregnation time. This research showed that the prepared adsorbents were capable to remove remarkable amount of Hg0 (23.615 mg/g) at high adsorption efficiency. This study may serve as reference on natural gas power plants for the removal of Hg0 using the same conditions.展开更多
As an emerging zero-dimensional nano crystalline porous material,porous organic cages(POCs)with soluble properties in organic solvents,are promising candidates as molecular fillers in mixed matrix membranes(MMMs).The ...As an emerging zero-dimensional nano crystalline porous material,porous organic cages(POCs)with soluble properties in organic solvents,are promising candidates as molecular fillers in mixed matrix membranes(MMMs).The pore structure of POCs should be adjusted to trigger efficient gas separation performance,and the interaction between filler and matrix should be optimized.In this work,ionic liquid(IL)was introduced into the molecular fillers of CC3,to construct the IL@CC3/PIM-1 membrane to effectively separate CO_(2) from CH_(4).The advantages of doping IL include:(1)narrowing the cavity size of POCs from 4.4 to 3.9Åto enhance the diffusion selectivity,(2)strengthening the CO_(2) solubility to heighten the gas permeability,and(3)improving the compatibility between filler and matrix to upgrade membrane stability.After the optimization of the membrane composite,the IL@CC3/PIM-1-10%membrane possesses the CO_(2) permeability of 7868 Barrer and the CO_(2)/CH_(4) selectivity of 73.4,which compared to the CC3/PIM-1-10%membrane,improved by 15.9%and 106.2%,respectively.Furthermore,the membrane has maintained a stable separation performance at varied temperatures and pressures during the long-term test.The proposed method offers an efficient way to improve the performance of POCs-based MMMs in gas separation.展开更多
Since the discovery of graphene, many efforts have been done to modify the graphene structure for integrating this novel material to nanoelectronics, fuel cells, energy storage devices and in many other applications. ...Since the discovery of graphene, many efforts have been done to modify the graphene structure for integrating this novel material to nanoelectronics, fuel cells, energy storage devices and in many other applications. This leads to the production of different types of graphene-based materials, which possess properties different from those of pure graphene. Porous graphene is an example of this type of materials. It can be considered as a graphene sheet with some holes/pores within the atomic plane. Due to its spongy structure, porous graphene can have potential applications as membranes for molecular sieving, energy storage components and in nanoelectronics. In this review, we present the recent progress in the synthesis of porous graphene. The properties and the potential applications of this new material are also discussed.展开更多
Fluid flow characteristics in a four-strand tundish with gas blowing were studied by water modeling experiments.It is found that gas blowing can greatly improve the flow characteristics in the tundish with a turbulenc...Fluid flow characteristics in a four-strand tundish with gas blowing were studied by water modeling experiments.It is found that gas blowing can greatly improve the flow characteristics in the tundish with a turbulence inhibitor.It dramatically increases the peak concentration time,and greatly decreases the dead volume,and reduces the minimum residence time.The gas blowing location,gas flow rate,and porous plug area greatly influence the flow characteristics in the tundish; the gas blowing location near the baffle,smaller gas flow rate,and smaller porous plug area are better for improving the fluid flow characteristics.Using gas blowing can reduce the difference of flows at the middle outlets and side outlets for the multi-strand tundish.Bubbles produced by gas blowing can absorb small inclusions and provide the condition for inclusion collision and aggregation.Therefore,introducing gas blowing into a tundish and combining the turbulence inhibitor can improve inclusion floating and removal,and the cleanness of molten steel can be advanced.展开更多
In order to simulate the behavior of gas hydrate formation and decomposition,a 3-Dimension experimental device was built,consisting of a high-pressure reactor with an inner diameter of 300 mm,effective height of 100 m...In order to simulate the behavior of gas hydrate formation and decomposition,a 3-Dimension experimental device was built,consisting of a high-pressure reactor with an inner diameter of 300 mm,effective height of 100 mm,and operation pressure of 16 MPa.Eight thermal resistances were mounted in the porous media at different depthes and radiuses to detect the temperature distribution during the hydrate formation/decomposition.To collect the pressure,temperature,and flux of gas production data,the Monitor and Control Generated System(MCGS) was used.Using this device,the formation and decomposition behavior of methane hydrate in the 20 ~ 40 mesh natural sand with salinity of 3.35 wt% was examined.It was found that the front of formation or decomposition of hydrate can be judged by the temperature distribution.The amount of hydrate formation can also be evaluated by the temperature change.During the hydrate decomposition process,the temperature curves indicated that the hydrate in the top and bottom of reactor dissociated earlier than in the inner.The hydrate decomposition front gradually moved from porous media surface to inner and kept a shape of column form,with different moving speed at different surface position.The proper decomposition pressure was also determined.展开更多
One of the major technical challenges in using carbon dioxide( CO2) as part of the cushion gas of the underground gas storage reservoir( UGSR) is the mixture of CO2and natural gas. To decrease the mixing extent and ma...One of the major technical challenges in using carbon dioxide( CO2) as part of the cushion gas of the underground gas storage reservoir( UGSR) is the mixture of CO2and natural gas. To decrease the mixing extent and manage the migration of the mixed zone,an understanding of the mechanism of CO2and natural gas mixing and the diffusion of the mixed gas in aquifer is necessary. In this paper,a numerical model based on the three dimensional gas-water two-phase flow theory and gas diffusion theory is developed to understand this mechanism. This model is validated by the actual operational data in Dazhangtuo UGSR in Tianjin City,China.Using the validated model,the mixed characteristic of CO2and natural gas and the migration mechanism of the mixed zone in an underground porous reservoir is further studied. Particularly,the impacts of the following factors on the migration mechanism are studied: the ratio of CO2injection,the reservoir porosity and the initial operating pressure. Based on the results,the optimal CO2injection ratio and an optimal control strategy to manage the migration of the mixed zone are obtained. These results provide technical guides for using CO2as cushion gas for UGSR in real projects.展开更多
In order to devoid the hard work and factitious error in selecting charts while analyzing and interpreting hydraulic fracturing fracture parameters, on the basis of the non-Darcy flow factor, this paper put out the no...In order to devoid the hard work and factitious error in selecting charts while analyzing and interpreting hydraulic fracturing fracture parameters, on the basis of the non-Darcy flow factor, this paper put out the non-Darcy flow mathematical model of real gas in the formation and fracture, established the production history automatic matching model to identify fracture parameters, and offered the numerical solutions of those models, which took the variation of fracture conductivity in production process. These results offered a precise and reliable method to understand formation, analyze and evaluate the fracturing treatment quality of gas well.展开更多
To further ascertain the origin of the Ordovician Majiagou Formation reservoirs in the Ordos Basin,the M54-M51 sub-members of the Ordovician Majiagou Formation in the eastern Sulige gasfield of Ordos Basin were taken ...To further ascertain the origin of the Ordovician Majiagou Formation reservoirs in the Ordos Basin,the M54-M51 sub-members of the Ordovician Majiagou Formation in the eastern Sulige gasfield of Ordos Basin were taken as examples to analyze the vertical development characteristics of eogenetic karst and to discover the dissolution mechanism and its control on reservoirs through observation of a large number of cores and thin sections.According to detailed analysis of petrologic characteristics,the reservoir rock types include micritic dolomite,grain dolomite and microbialite which have mainly moldic pore,intergranular(dissolved)pore,and(dissolved)residual framework pore as main reservoir space respectively.The study area developed upward-shallowing sequences,with an exposure surface at the top of a single upward-shallowing sequence.The karst systems under the exposure surface had typical exposure characteristics of early dissolution and filling,indicating these reservoirs were related to the facies-controlled eogenetic karstification.With the increase of karstification intensity,the reservoirs became worse in physical properties.展开更多
Porous Zn O was obtained by hydrothermal method. The results of scanning electron microscope revealed the porous structure in the as-prepared materials. The acetone sensing test results of porous Zn O show that porous...Porous Zn O was obtained by hydrothermal method. The results of scanning electron microscope revealed the porous structure in the as-prepared materials. The acetone sensing test results of porous Zn O show that porous Zn O possesses excellent acetone gas sensing properties. The response is 35.5 at the optimum operating temperature of 320?C to 100 ppm acetone. The response and recovery times to 50 ppm acetone are 2 s and 8 s, respectively. The lowest detecting limit to acetone is 0.25 ppm, and the response value is 3.8. Moreover, the sensors also exhibit excellent selectivity and long-time stability to acetone.展开更多
基金supported by the Natural Science Research Start-up Foundation of Recruiting Talents of Nanjing University of Posts and Telecommunications (Grant Nos. XK1060921115 and XK1060921002)Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 62204125)+1 种基金the National Key R&D Program of China (Grant No. 2022YFB3605404)the Natural Science Foundation of Guangdong Province, China (Grant No. 2019A1515010790)。
文摘A flower-like SnO_(2)–SnO/porous Ga N(FSS/PGaN) heterojunction was fabricated for the first time via a facile spraying process, and the whole process also involved hydrothermal preparation of FSS and electrochemical wet etching of GaN,and SnO_(2)–SnO composites with p–n junctions were loaded onto PGaN surface directly applied to H_(2)S sensor. Meanwhile,the excellent transport capability of heterojunction between FSS and PGaN facilitates electron transfer, that is, a response time as short as 65 s and a release time up to 27 s can be achieved merely at 150℃ under 50 ppm H_(2)S concentration, which has laid a reasonable theoretical and experimental foundation for the subsequent PGaN-based heterojunction gas sensor.The lowering working temperature and high sensitivity(23.5 at 200 ppm H2S) are attributed to the structure of PGaN itself and the heterojunction between SnO_(2)–SnO and PGaN. In addition, the as-obtained sensor showed ultra-high test stability.The simple design strategy of FSS/PGaN-based H_(2)S sensor highlights its potential in various applications.
基金the financial support from the National Natural Science Foundation of China(22090062,21922810,21825802,22138003,22108083,and 21725603)the Guangdong Pearl River Talents Program(2021QN02C8)+3 种基金the Science and Technology Program of Guangzhou(202201010118)Zhejiang Provincial Natural Science Foundation of China(LR20B060001)National Science Fund for Excellent Young Scholars(22122811)China Postdoctoral Science Foundation(2022M710123)。
文摘Carbon peaking and carbon neutralization trigger a technical revolution in energy&environment related fields.Development of new technologies for green energy production and storage,industrial energy saving and efficiency reinforcement,carbon capture,and pollutant gas treatment is in highly imperious demand.The emerging porous framework materials such as metal–organic frameworks(MOFs),covalent organic frameworks(COFs)and hydrogen-bonded organic frameworks(HOFs),owing to the permanent porosity,tremendous specific surface area,designable structure and customizable functionality,have shown great potential in major energy-consuming industrial processes,including sustainable energy gas catalytic conversion,energy-efficient industrial gas separation and storage.Herein,this manuscript presents a systematic review of porous framework materials for global and comprehensive energy&environment related applications,from a macroscopic and application perspective.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 60771019 and 60801018)the Tianjin Key Research Program of Application Foundation and Advanced Technology,China (Grant No. 11JCZDJC15300)
文摘The NO2 gas sensing behavior of porous silicon(PS) is studied at room temperature with and without ultraviolet(UV) light radiation.The PS layer is fabricated by electrochemical etching in an HF-based solution on a p +-type silicon substrate.Then,Pt electrodes are deposited on the surface of the PS to obtain the PS gas sensor.The NO2 sensing properties of the PS with different porosities are investigated under UV light radiation at room temperature.The measurement results show that the PS gas sensor has a much higher response sensitivity and faster response-recovery characteristics than NO2 under the illumination.The sensitivity of the PS sample with the largest porosity to 1 ppm NO2 is 9.9 with UV light radiation,while it is 2.4 without UV light radiation.We find that the ability to absorb UV light is enhanced with the increase in porosity.The PS sample with the highest porosity has a larger change than the other samples.Therefore,the effect of UV radiation on the NO2 sensing properties of PS is closely related to the porosity.
基金Projects(51304035,50974030)supported by the National Natural Science Foundation of ChinaProject(20110491512)supported by the Postdoctoral Science Foundation of China+2 种基金Project(20130042120034)supported by the Specialized Research Fund for the Doctoral Program of Higher Education(New Teachers),ChinaProject(120401008)supported by the Fundamental Research Funds for Central Universities,ChinaProject(L20150173)supported by the Scientific Research Fund of Liaoning Provincial Education Department,China
文摘Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.
基金Supported by the National Natural Science Foundation of China(21506160,21776217)the Science and Technology Plans of Tianjin(16PTSYJC00110)
文摘Metallic ion-cross-linked polymer of intrinsic microporosity(PIM-1) thin-film composite(TFC) membranes supported on an ultraviolet(UV)-cross-linked porous substrate were fabricated. The UV-cross-linked porous substrate was prepared via polymerization-induced phase separation. The PIM-1 TFC membranes were fabricated via a dip-coating procedure. Metallic ion-cross-linked PIM-1 TFC membranes were fabricated by hydrolyzing the PIM-1 TFC membrane in an alkali solution and then cross-linking it in a multivalent metallic ion solution. The pore size and porous structures were evaluated by low-temperature N_2 adsorption–desorption analysis. The membrane structure was investigated by field-emission scanning electron microscopy. The effects of heat treatment and pore-forming additives on the gas permeance of the UV-cross-linked porous substrate are reported. The effects of different pre-coating treatments on the gas permeance of the metallic ion-cross-linked PIM-1 TFC membrane are also discussed. The metallic ion-crosslinked PIM-1 TFC membrane displayed high CO_2/N_2 selectivity(23) and good CO_2 permeance(1058 GPU).
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61271070,61274074,and 60771019)the Key Research Program of Application Foundation and Advanced Technology of Tianjin,China(Grant No.11JCZDJC15300)
文摘We report on the fabrication and performance of a room-temperature NO2 gas sensor based on a WO3 nanowires/porous silicon hybrid structure. The W18O49 nanowires are synthesized directly from a sputtered tungsten film on a porous silicon (PS) layer under heating in an argon atmosphere. After a carefully controlled annealing treatment, WO3 nanowires are obtained on the PS layer without losing the morphology. The morphology, phase structure, and crystallinity of the nanowires are investigated by using field emission scanning electron microscopy (FESEM), X-ray diffractometer (XRD), and high-resolution transmission electron microscopy (HRTEM). Comparative gas sensing results indicate that the sensor based on the WO3 nanowires exhibits a much higher sensitivity than that based on the PS and pure WO3 nanowires in detecting NO2 gas at room temperature. The mechanism of the WO3 nanowires/PS hybrid structure in the NO2 sensing is explained in detail.
文摘The performance of gas diffusion porous electrode starved of electrolyte solution can be significantly increased by decreasing the thickness of uneven liquid film covering the catalyst agglomerates.
基金Thanks for the support of a major national special project during the 13th Five-Year Plan period,“Chemical Flooding Technology for Offshore Oil Fields”(No.2016ZX05025-003)“Heavy Oil Chemical Flooding Mechanism and Simulation Technology Research”(No.2019-YXKJ-008)Research on Source Sink Matching Technology and Scheme of Regional CCUs Project(2021-ZYZL-XNY-01),etc.
文摘Carbon dioxide geological sequestration is an effective method to reduce the content of greenhouse gases in the atmosphere of our planet.This process can also be used to improve the production of oil reservoirs by mixing carbon dioxide and crude oil.In the present study,a differential separation experiment(DL)based on actual crude oil components is used to simulate such a process.The results show that after mixing,the viscosity and density of reservoir fluid decrease and the volume coefficient increase,indicating that the pre buried gas induces fluid expansion and an improvement of the fluid rheological properties.These effects are interpreted using a pore scale model based on real scanning electron microscopy(SEM).The results show that increasing the pressure and reducing the viscosity are beneficial to increasing the micro oil displacement efficiency.Moreover,these effects can improve the production in the target area and slow down the decline of the formation pressure.Furthermore,in the case of fracture development in the reservoir(due to CO_(2)injection before exploitation),the risk of gas channelling,induced by the displacement pressure difference between injection and production wells,is avoided.
基金The project supported by the National Natural Science Foundation of China (19889209)Russian Foundation for Basic Research (97-02-16943)
文摘Heat and mass transfer of a porous permeable wall in a high temperature gas dynamical flow is considered. Numerical simulation is conducted on the ground of the conjugate mathematical model which includes filtration and heat transfer equations in a porous body and boundary layer equations on its surface. Such an approach enables one to take into account complex interaction between heat and mass transfer in the gasdynamical flow and in the structure subjected to this flow. The main attention is given to the impact of the intraporous heat transfer intensity on the transpiration cooling efficiency.
文摘The present work reports the synthesis and application of sulfur doped into porous activated carbon for removing elemental mercury from natural gas using a bench-scale fixed-bed reactor. A series of experiments were carried out to investigate the optimization of Hg0 capture. Furthermore, our experimental results about optimum conditions to remove Hg0 were 1:10 of sulfur to activated carbon impregnation ratio, 350°C of impregnation temperature, and 3 hours of impregnation time. This research showed that the prepared adsorbents were capable to remove remarkable amount of Hg0 (23.615 mg/g) at high adsorption efficiency. This study may serve as reference on natural gas power plants for the removal of Hg0 using the same conditions.
基金supported by the National Natural Science Foundation of China(Nos.21875285,22171288,22005340)the Key Research and Development Projects of Shandong Province(No.2019JZZY010331)+2 种基金the Natural Science Foundation of Shandong Province(Nos.ZR2020MB017,ZR2022MB009)the Fundamental Research Funds for the Central Universities(No.23CX07004A)the Outstanding Youth Science Fund Projects of Shandong Province(Nos.2022HWYQ-070,ZR2022YQ15).
文摘As an emerging zero-dimensional nano crystalline porous material,porous organic cages(POCs)with soluble properties in organic solvents,are promising candidates as molecular fillers in mixed matrix membranes(MMMs).The pore structure of POCs should be adjusted to trigger efficient gas separation performance,and the interaction between filler and matrix should be optimized.In this work,ionic liquid(IL)was introduced into the molecular fillers of CC3,to construct the IL@CC3/PIM-1 membrane to effectively separate CO_(2) from CH_(4).The advantages of doping IL include:(1)narrowing the cavity size of POCs from 4.4 to 3.9Åto enhance the diffusion selectivity,(2)strengthening the CO_(2) solubility to heighten the gas permeability,and(3)improving the compatibility between filler and matrix to upgrade membrane stability.After the optimization of the membrane composite,the IL@CC3/PIM-1-10%membrane possesses the CO_(2) permeability of 7868 Barrer and the CO_(2)/CH_(4) selectivity of 73.4,which compared to the CC3/PIM-1-10%membrane,improved by 15.9%and 106.2%,respectively.Furthermore,the membrane has maintained a stable separation performance at varied temperatures and pressures during the long-term test.The proposed method offers an efficient way to improve the performance of POCs-based MMMs in gas separation.
基金partially supported by the Natural Science and Engineering Council of Canada (NSERC, Canada)the financial support from the high level overseas talent project of Beijing, P. R. China
文摘Since the discovery of graphene, many efforts have been done to modify the graphene structure for integrating this novel material to nanoelectronics, fuel cells, energy storage devices and in many other applications. This leads to the production of different types of graphene-based materials, which possess properties different from those of pure graphene. Porous graphene is an example of this type of materials. It can be considered as a graphene sheet with some holes/pores within the atomic plane. Due to its spongy structure, porous graphene can have potential applications as membranes for molecular sieving, energy storage components and in nanoelectronics. In this review, we present the recent progress in the synthesis of porous graphene. The properties and the potential applications of this new material are also discussed.
文摘Fluid flow characteristics in a four-strand tundish with gas blowing were studied by water modeling experiments.It is found that gas blowing can greatly improve the flow characteristics in the tundish with a turbulence inhibitor.It dramatically increases the peak concentration time,and greatly decreases the dead volume,and reduces the minimum residence time.The gas blowing location,gas flow rate,and porous plug area greatly influence the flow characteristics in the tundish; the gas blowing location near the baffle,smaller gas flow rate,and smaller porous plug area are better for improving the fluid flow characteristics.Using gas blowing can reduce the difference of flows at the middle outlets and side outlets for the multi-strand tundish.Bubbles produced by gas blowing can absorb small inclusions and provide the condition for inclusion collision and aggregation.Therefore,introducing gas blowing into a tundish and combining the turbulence inhibitor can improve inclusion floating and removal,and the cleanness of molten steel can be advanced.
基金supported by the National Natural Science Foundation of China (Grant numbers: 20676145, U0633003)973 program (No. 2009CB219504)NCET-07-0842
文摘In order to simulate the behavior of gas hydrate formation and decomposition,a 3-Dimension experimental device was built,consisting of a high-pressure reactor with an inner diameter of 300 mm,effective height of 100 mm,and operation pressure of 16 MPa.Eight thermal resistances were mounted in the porous media at different depthes and radiuses to detect the temperature distribution during the hydrate formation/decomposition.To collect the pressure,temperature,and flux of gas production data,the Monitor and Control Generated System(MCGS) was used.Using this device,the formation and decomposition behavior of methane hydrate in the 20 ~ 40 mesh natural sand with salinity of 3.35 wt% was examined.It was found that the front of formation or decomposition of hydrate can be judged by the temperature distribution.The amount of hydrate formation can also be evaluated by the temperature change.During the hydrate decomposition process,the temperature curves indicated that the hydrate in the top and bottom of reactor dissociated earlier than in the inner.The hydrate decomposition front gradually moved from porous media surface to inner and kept a shape of column form,with different moving speed at different surface position.The proper decomposition pressure was also determined.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51276048)
文摘One of the major technical challenges in using carbon dioxide( CO2) as part of the cushion gas of the underground gas storage reservoir( UGSR) is the mixture of CO2and natural gas. To decrease the mixing extent and manage the migration of the mixed zone,an understanding of the mechanism of CO2and natural gas mixing and the diffusion of the mixed gas in aquifer is necessary. In this paper,a numerical model based on the three dimensional gas-water two-phase flow theory and gas diffusion theory is developed to understand this mechanism. This model is validated by the actual operational data in Dazhangtuo UGSR in Tianjin City,China.Using the validated model,the mixed characteristic of CO2and natural gas and the migration mechanism of the mixed zone in an underground porous reservoir is further studied. Particularly,the impacts of the following factors on the migration mechanism are studied: the ratio of CO2injection,the reservoir porosity and the initial operating pressure. Based on the results,the optimal CO2injection ratio and an optimal control strategy to manage the migration of the mixed zone are obtained. These results provide technical guides for using CO2as cushion gas for UGSR in real projects.
文摘In order to devoid the hard work and factitious error in selecting charts while analyzing and interpreting hydraulic fracturing fracture parameters, on the basis of the non-Darcy flow factor, this paper put out the non-Darcy flow mathematical model of real gas in the formation and fracture, established the production history automatic matching model to identify fracture parameters, and offered the numerical solutions of those models, which took the variation of fracture conductivity in production process. These results offered a precise and reliable method to understand formation, analyze and evaluate the fracturing treatment quality of gas well.
基金Supported by the China National Science and Technology Major Project(2016ZX05004006-001-002)CNPC-Southwest Petroleum University Innovation Consortium Technology Cooperation Project
文摘To further ascertain the origin of the Ordovician Majiagou Formation reservoirs in the Ordos Basin,the M54-M51 sub-members of the Ordovician Majiagou Formation in the eastern Sulige gasfield of Ordos Basin were taken as examples to analyze the vertical development characteristics of eogenetic karst and to discover the dissolution mechanism and its control on reservoirs through observation of a large number of cores and thin sections.According to detailed analysis of petrologic characteristics,the reservoir rock types include micritic dolomite,grain dolomite and microbialite which have mainly moldic pore,intergranular(dissolved)pore,and(dissolved)residual framework pore as main reservoir space respectively.The study area developed upward-shallowing sequences,with an exposure surface at the top of a single upward-shallowing sequence.The karst systems under the exposure surface had typical exposure characteristics of early dissolution and filling,indicating these reservoirs were related to the facies-controlled eogenetic karstification.With the increase of karstification intensity,the reservoirs became worse in physical properties.
基金Projected supported by the Project of Challenge Cup for College Students,China(Grant No.450060497053)
文摘Porous Zn O was obtained by hydrothermal method. The results of scanning electron microscope revealed the porous structure in the as-prepared materials. The acetone sensing test results of porous Zn O show that porous Zn O possesses excellent acetone gas sensing properties. The response is 35.5 at the optimum operating temperature of 320?C to 100 ppm acetone. The response and recovery times to 50 ppm acetone are 2 s and 8 s, respectively. The lowest detecting limit to acetone is 0.25 ppm, and the response value is 3.8. Moreover, the sensors also exhibit excellent selectivity and long-time stability to acetone.