A novel compound 5-o-[1-（3-ethoxymethyl-4-phenyl-5-ethoxycarbonyl-6-methyl-3,4-dihydropyrimidin-2-one）butoxy]phenyl-10,15,20-triphenyl zinc porphyrin（C_（65）H_（56）N_6O_5Zn） was synthesized and characterized by ...A novel compound 5-o-[1-（3-ethoxymethyl-4-phenyl-5-ethoxycarbonyl-6-methyl-3,4-dihydropyrimidin-2-one）butoxy]phenyl-10,15,20-triphenyl zinc porphyrin（C_（65）H_（56）N_6O_5Zn） was synthesized and characterized by NMR,FT-IR and MS. The compound crystallizes out from chloroform and methanol mixture solution,and its crystal structure was measured by single-crystal X-ray diffraction,monoclinic system,space group P2_1/c with a = 17.2741（6）,b = 16.3797（6）,c = 41.0919（16） A,b = 93.810（3）°,V = 11601.0（7） A^3,Z = 4,S = 1.021,F（000） = 5000,R = 0.0749 and wR = 0.1771. Additionally,it has been revealed by X-ray analysis that Zn of porphyrin is coordinated with carbonyl O of dihydropyrimidinone,thus the porphyrin and pyrimidinone rings are distorted by the Zn–O coordination bond.展开更多
基金supported by the National Natural Science Foundation of China(Nos.20942008,21172065)the Scientific Research Fund of Hunan Provincial Education Department(No.11K024)
文摘A novel compound 5-o-[1-（3-ethoxymethyl-4-phenyl-5-ethoxycarbonyl-6-methyl-3,4-dihydropyrimidin-2-one）butoxy]phenyl-10,15,20-triphenyl zinc porphyrin（C_（65）H_（56）N_6O_5Zn） was synthesized and characterized by NMR,FT-IR and MS. The compound crystallizes out from chloroform and methanol mixture solution,and its crystal structure was measured by single-crystal X-ray diffraction,monoclinic system,space group P2_1/c with a = 17.2741（6）,b = 16.3797（6）,c = 41.0919（16） A,b = 93.810（3）°,V = 11601.0（7） A^3,Z = 4,S = 1.021,F（000） = 5000,R = 0.0749 and wR = 0.1771. Additionally,it has been revealed by X-ray analysis that Zn of porphyrin is coordinated with carbonyl O of dihydropyrimidinone,thus the porphyrin and pyrimidinone rings are distorted by the Zn–O coordination bond.
