In this work,a novel composite material based on β-cyclodextrin-immobilized sodium alginate aerogel(β-CD/NaAlg) was developed utilizing cross-linker of epichlorohydrin and applied as an adsorbent to remove tetracycl...In this work,a novel composite material based on β-cyclodextrin-immobilized sodium alginate aerogel(β-CD/NaAlg) was developed utilizing cross-linker of epichlorohydrin and applied as an adsorbent to remove tetracycline antibiotics from reclaimed wastewater.A series of characterizations were utilized to confirm the successful synthesis of the adsorbent and this β-CD/NaAlg presented a three-dimensional network at the nanoscale or microscale.Under optimal conditions(pH=4,t=8 h,β-CD:NaAlg=9,adsorbent dosage = 1.5 g·L-1),the maximum removal rate of β-CD/NaAlg to tetracycline was 70%.The adsorption behavior of tetracycline on β-CD/NaAlg conformed to the Freundlich isotherm model(R2=0.9977) and the pseudo-second-order kinetic model(R^(2)=0.9993).Moreover,the adsorbent still removed 55.3% of tetracycline after five cycles.Specially,the adsorbent was integrated with ultrafiltration to adsorb tetracycline antibiotics from simulated reclaimed wastewater,and the removal rate of tetracycline reached 78.9% within 2 h.The existence of Cr(Ⅵ) had a negligible impact on tetracycline removal,while the presence of humic acid exhibited a promoting effect.The possible adsorption mechanisms were also elucidated through X-ray photoelectron spectroscopy and density functional theory analysis.In summary,β-CD/NaAlg represents an environmentally friendly,efficient,and sustainable adsorbent for removing tetracycline antibiotics from reclaimed water.展开更多
The bucket wheel reclaimer(BWR) is a key piece of equipment which has been widely used for stacking and reclaiming bulk materials(i.e.iron ore and coal) in places such as ports,iron-steel plants,coal storage areas,and...The bucket wheel reclaimer(BWR) is a key piece of equipment which has been widely used for stacking and reclaiming bulk materials(i.e.iron ore and coal) in places such as ports,iron-steel plants,coal storage areas,and power stations from stockpiles.BWRs are very large in size,heavy in weight,expensive in price,and slow in motion.There are many challenges in attempting to automatically control their motion to accurately follow the required trajectories involving uncertain parameters from factors such as friction,turbulent wind,its own dynamics,and encoder limitations.As BWRs are always heavily engaged in production and cannot be spared very long for motion control studies and associated developments,a BWR model and simulation environment closely resembling real life conditions would be beneficial.The following research focused mainly on the implementation of fuzzy logic to a BWR motion control from an engineer's perspective.First,the modeling of a BWR including partially known parameters such as friction force and turbulence to the system was presented.This was then followed by the design of a fuzzy logic-based control built on a model-based control loop.The investigation provides engineers with an example of applying fuzzy logic in a model based approach to properly control the motion of a large BWR following defined trajectories,as well as to show possible ways of further improving the controller performance.The result indicates that fuzzy logic can be applied easily by engineers to overcome most motion control issues involving a large BWR.展开更多
基金supported by the National Key Research and Development Program of China(2022YFC3801101)National Natural Science Foundation of China(52170028)+1 种基金the State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(2023DX11)National Engineering Research Center for Safe Sludge Disposal and Resource Recovery(2021A003).
文摘In this work,a novel composite material based on β-cyclodextrin-immobilized sodium alginate aerogel(β-CD/NaAlg) was developed utilizing cross-linker of epichlorohydrin and applied as an adsorbent to remove tetracycline antibiotics from reclaimed wastewater.A series of characterizations were utilized to confirm the successful synthesis of the adsorbent and this β-CD/NaAlg presented a three-dimensional network at the nanoscale or microscale.Under optimal conditions(pH=4,t=8 h,β-CD:NaAlg=9,adsorbent dosage = 1.5 g·L-1),the maximum removal rate of β-CD/NaAlg to tetracycline was 70%.The adsorption behavior of tetracycline on β-CD/NaAlg conformed to the Freundlich isotherm model(R2=0.9977) and the pseudo-second-order kinetic model(R^(2)=0.9993).Moreover,the adsorbent still removed 55.3% of tetracycline after five cycles.Specially,the adsorbent was integrated with ultrafiltration to adsorb tetracycline antibiotics from simulated reclaimed wastewater,and the removal rate of tetracycline reached 78.9% within 2 h.The existence of Cr(Ⅵ) had a negligible impact on tetracycline removal,while the presence of humic acid exhibited a promoting effect.The possible adsorption mechanisms were also elucidated through X-ray photoelectron spectroscopy and density functional theory analysis.In summary,β-CD/NaAlg represents an environmentally friendly,efficient,and sustainable adsorbent for removing tetracycline antibiotics from reclaimed water.
基金support through the ARC Linkage LP0989780 grant titled "The study anddevelopment of a 3-D real-time stockpile management system"the support in part from Institute for Mineral and Energy Resources,University of Adelaide 2009-2010,as well as Faculty of Engineering,Computer and Mathematical Sciences strategic research funding,2010
文摘The bucket wheel reclaimer(BWR) is a key piece of equipment which has been widely used for stacking and reclaiming bulk materials(i.e.iron ore and coal) in places such as ports,iron-steel plants,coal storage areas,and power stations from stockpiles.BWRs are very large in size,heavy in weight,expensive in price,and slow in motion.There are many challenges in attempting to automatically control their motion to accurately follow the required trajectories involving uncertain parameters from factors such as friction,turbulent wind,its own dynamics,and encoder limitations.As BWRs are always heavily engaged in production and cannot be spared very long for motion control studies and associated developments,a BWR model and simulation environment closely resembling real life conditions would be beneficial.The following research focused mainly on the implementation of fuzzy logic to a BWR motion control from an engineer's perspective.First,the modeling of a BWR including partially known parameters such as friction force and turbulence to the system was presented.This was then followed by the design of a fuzzy logic-based control built on a model-based control loop.The investigation provides engineers with an example of applying fuzzy logic in a model based approach to properly control the motion of a large BWR following defined trajectories,as well as to show possible ways of further improving the controller performance.The result indicates that fuzzy logic can be applied easily by engineers to overcome most motion control issues involving a large BWR.
基金The National Science Foundation of China (No.52078190)the Natural Science Foundation of Jiangsu Province (No.BK20221501)+1 种基金the Natural Science Youth Fund of Jiangsu Province(No.BK20220983)the Natural Science Foundation of Hebei Province(No.E2019203559)。
