Y^3+-doped (Bi 1/2 Na 1/2) TiO 3-CaTiO 3-BaTiO 3 (BNCBT) positive temperature coefficient of resistivity (PTCR) ceramics sintered in air atmosphere were investigated in this study. (Bi 1/2 Na 1/2) TiO 3 (BNT...Y^3+-doped (Bi 1/2 Na 1/2) TiO 3-CaTiO 3-BaTiO 3 (BNCBT) positive temperature coefficient of resistivity (PTCR) ceramics sintered in air atmosphere were investigated in this study. (Bi 1/2 Na 1/2) TiO 3 (BNT) component can remarkably increase the onset temperature T c of PTCR ceramics with the expense of the resistivity R 25 increase. CaTiO 3 (9–27 mol%) component can decrease the resistivity, and adjust the effects of BNT phase on the T c point. For the sample containing 3 mol% CaTiO 3 , T c raises from 122 ℃ to 153 ℃ when only 0.6 mol% BNT added, while for the ones with higher CaTiO 3 content (9–27 mol%), T c is only increased by a rate of 8–9℃/1.0 mol% BNT. The effects of BNT and CaTiO 3 components on R25/Rmin (negative temperature coefficient effect) are also discussed.展开更多
将导电微粒与聚合物混合可制备导电聚合物,其室温电阻率可从1Ω·cm到10~7Ω·cm范围进行任意调整,并且其电阻率与温度关系呈线性关系,即PTC(Positive Temperature Coefficient)效应。本文详细讨论不同的掺入导电微粒浓度、聚...将导电微粒与聚合物混合可制备导电聚合物,其室温电阻率可从1Ω·cm到10~7Ω·cm范围进行任意调整,并且其电阻率与温度关系呈线性关系,即PTC(Positive Temperature Coefficient)效应。本文详细讨论不同的掺入导电微粒浓度、聚合物种类以及合成条件对室温电阻率、PTC效应的影响规律,并讨论了这种复合材料在工程技术上的应用前景。展开更多
基金Project supported by the SPAT of Shanghai Committee of Chinese People's Political Consultative Conference and Shanghai Education Development Foundation (Grant No.2008012)
文摘Y^3+-doped (Bi 1/2 Na 1/2) TiO 3-CaTiO 3-BaTiO 3 (BNCBT) positive temperature coefficient of resistivity (PTCR) ceramics sintered in air atmosphere were investigated in this study. (Bi 1/2 Na 1/2) TiO 3 (BNT) component can remarkably increase the onset temperature T c of PTCR ceramics with the expense of the resistivity R 25 increase. CaTiO 3 (9–27 mol%) component can decrease the resistivity, and adjust the effects of BNT phase on the T c point. For the sample containing 3 mol% CaTiO 3 , T c raises from 122 ℃ to 153 ℃ when only 0.6 mol% BNT added, while for the ones with higher CaTiO 3 content (9–27 mol%), T c is only increased by a rate of 8–9℃/1.0 mol% BNT. The effects of BNT and CaTiO 3 components on R25/Rmin (negative temperature coefficient effect) are also discussed.
文摘将导电微粒与聚合物混合可制备导电聚合物,其室温电阻率可从1Ω·cm到10~7Ω·cm范围进行任意调整,并且其电阻率与温度关系呈线性关系,即PTC(Positive Temperature Coefficient)效应。本文详细讨论不同的掺入导电微粒浓度、聚合物种类以及合成条件对室温电阻率、PTC效应的影响规律,并讨论了这种复合材料在工程技术上的应用前景。