The effect of different sulfonation degree on properties of sulfonated syndiotactic polystyrene(S s PS) was investigated by 1H NMR, 13 C NMR,FTIR,DSC and WAXD.The results of 13 C NMR showed that a peak at δ =145 5 ap...The effect of different sulfonation degree on properties of sulfonated syndiotactic polystyrene(S s PS) was investigated by 1H NMR, 13 C NMR,FTIR,DSC and WAXD.The results of 13 C NMR showed that a peak at δ =145 5 appeared in all S s PS spectra,which proved that the syndiotactic structure of syndiotactic polystyrene( s PS) still existed in S s PS.With increasing degree of sulfonition,the chemical shifts of C 1 and C\|3 for sulfonated benzene ring turned out to be wider. 1 H NMR spectra showed that C\|3 for sulfonated benzene ring had a chemical shift of 7 66.FTIR spectra showed that sulfonic acid groups were introduced on the para position of benzene rings and with increasing sulfonation degree,the absorption strength of 612/1600 cm 1 ,834/1600cm -1 increased,but the absorption strength of 1078/1600cm -1 decreased.The absorption of ～1030cm -1 ,～1179cm -1 ,～1217cm -1 appeared when the sulfonation degree was higher that 6%. s PS and S s PS H 2 2 had absorption at 975 and 943cm -1 and also had double peaks around ～1175cm -1 ;DSC showed that with increasing sulfonation degree, the glass transition temperature increased, the melt temperature,crystallization temperature and crystallization degree decreased;S s PS couldn’t crystallize when sulfonation degree was higher that 6mol%;WAXD proved that s PS had the α and β crystal types, however,S s PS with 2 2% sulfonation degree only had the β crystal type, and S s PS with 6 1% sulfonation degree didn’t crystallize.展开更多
利用奇异值分解和可能满意度方法,提出了一种新的层次分析法权重计算、一致性检验与改进过程.根据矩阵最优近似定理和K u llback-Leib ler信息法则,指出奇异值分解所得结果是对决策偏好的最优近似,根据可能满意度方法,利用判断矩阵的最...利用奇异值分解和可能满意度方法,提出了一种新的层次分析法权重计算、一致性检验与改进过程.根据矩阵最优近似定理和K u llback-Leib ler信息法则,指出奇异值分解所得结果是对决策偏好的最优近似,根据可能满意度方法,利用判断矩阵的最大特征值及其F roben ius范数,定义判断矩阵的可能度与满意度,分别考察一致性改进程度和相对原始判断矩阵的信息偏离程度,并将两者并合为一个能够全面衡量一致性改善效果的综合指标:判断矩阵的可能满意度.通过与加权几何平均改进方法相结合,在最大限度保留决策者原始判断信息条件下,逐步达到可接受的一致性.给出了改进算法的收敛性证明,并利用典型算例进行对比分析.展开更多
文摘The effect of different sulfonation degree on properties of sulfonated syndiotactic polystyrene(S s PS) was investigated by 1H NMR, 13 C NMR,FTIR,DSC and WAXD.The results of 13 C NMR showed that a peak at δ =145 5 appeared in all S s PS spectra,which proved that the syndiotactic structure of syndiotactic polystyrene( s PS) still existed in S s PS.With increasing degree of sulfonition,the chemical shifts of C 1 and C\|3 for sulfonated benzene ring turned out to be wider. 1 H NMR spectra showed that C\|3 for sulfonated benzene ring had a chemical shift of 7 66.FTIR spectra showed that sulfonic acid groups were introduced on the para position of benzene rings and with increasing sulfonation degree,the absorption strength of 612/1600 cm 1 ,834/1600cm -1 increased,but the absorption strength of 1078/1600cm -1 decreased.The absorption of ～1030cm -1 ,～1179cm -1 ,～1217cm -1 appeared when the sulfonation degree was higher that 6%. s PS and S s PS H 2 2 had absorption at 975 and 943cm -1 and also had double peaks around ～1175cm -1 ;DSC showed that with increasing sulfonation degree, the glass transition temperature increased, the melt temperature,crystallization temperature and crystallization degree decreased;S s PS couldn’t crystallize when sulfonation degree was higher that 6mol%;WAXD proved that s PS had the α and β crystal types, however,S s PS with 2 2% sulfonation degree only had the β crystal type, and S s PS with 6 1% sulfonation degree didn’t crystallize.
