Nitrogen and phosphorous adsorption from post-hydrothermal liquefaction wastewater using three types of zeolites

Hydrothermal liquefaction(HTL)has been studied as a promising technology for converting wet biomass into bio-crude oil and the nutrient-rich post-hydrothermal liquefaction wastewater(PHWW)could be reused for algae and bacteria production.However,the PHWW from HTL contains various types of contaminants that need to be removed before reuse.Too high nutrients(nitrogen and phosphorous)contents,such as ammonium,are inhibitive to algal growth and bacteria species in anaerobic process.It is desirable to reduce nutrients concentration in PHWW to an acceptable level using zeolite adsorption.This study investigated nitrogen and phosphorous adsorption efficiencies from PHWW using three types of zeolites:activated clinoptilolite,natural clinoptilolite and Na-modified zeolite.Effects of ions and pH in the adsorption process were also investigated.Results showed that three zeolite variables affecting ammonium adsorption process could be ranked as follows:zeolite dosage>type>particle size,via an orthogonal experiment design.Activated clinoptilolite,with a particle size of 0.18-0.30 mm and a dosage of 0.4 g/mL demonstrated the highest ammonium adsorption efficiency of 54.92%.Zeolite could also adsorb organic nitrogen and had a high adsorption efficiency of phosphorous(97.85%).This study showed that zeolite is effective to adsorb nutrients in PHWW.The adsorption treated PHWW can then be used for culturing algae or anaerobic treatment,and the adsorbed nutrients can be reused later.

Application of zeolite adsorption and biological anaerobic digestion technology on hydrothermal liquefaction wastewater

The post-hydrothermal liquefaction wastewater(PHWW)was obtained from a conversion process of Spirulina sp.to bio-crude oil via hydrothermal liquefaction(HTL)technology that was rich in organic matter and toxicant.In this study,zeolite was applied to overcome the inhibitions and improve anaerobic digestion(AD)efficiency.Three zeolite adding ways were evaluated:PHWW pretreated with zeolite for 5 h with/without solid-liquid separation before AD process and zeolite added to PHWW AD process directly,in order to find the most ideal way to add zeolite.Results indicated that zeolite had a positive effect on the AD process of the PHWW.The gas potential of PHWW after adding zeolite,as well as the chemical oxygen demand(COD)removal rate,was much higher than those of its initial state.Especially when the PHWW was pretreated by zeolite for 5 h without separation,the biogas yield increased by 73.96%(6170μmol/g CODremoved)compared with the initial PHWW(3546.7μmol/g CODremoved).