Influence of heat treatment on microstructure,mechanical and corrosion behavior of WE43 alloy fabricated by laser-beam powder bed fusion

Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.However,the as-built part usually exhibits undesirable microstructure and unsatisfactory performance.In this work,WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment.Although a high densification rate of 99.91%was achieved using suitable processes,the as-built parts exhibited anisotropic and layeredmicrostructure with heterogeneously precipitated Nd-rich intermetallic.After heat treatment,fine and nano-scaled Mg24Y5particles were precipitated.Meanwhile,theα-Mg grainsunderwent recrystallization and turned coarsened slightly,which effectively weakened thetexture intensity and reduced the anisotropy.As a consequence,the yield strength and ultimate tensile strength were significantly improved to(250.2±3.5)MPa and(312±3.7)MPa,respectively,while the elongation was still maintained at a high level of 15.2%.Furthermore,the homogenized microstructure reduced the tendency of localized corrosion and favoredthe development of uniform passivation film.Thus,the degradation rate of WE43 parts was decreased by an order of magnitude.Besides,in-vitro cell experiments proved their favorable biocompatibility.

Interface property of dissimilar Ti-6Al-4V/AA1050 composite laminate made by non-equal channel lateral co-extrusion and heat treatment

The purpose of this paper is to examine the effect of processing parameters and subsequent heat treatments on the microstructures and bonding strengths of Ti-6Al-4V/AA1050 laminations formed via a non-equal channel lateral co-extrusion process.The microstructural evolution and growth mechanism in the diffusion layer were discussed further to optimize the bonding quality by appropriately adjusting process parameters.Scanning electron microscopes(SEM),energy dispersive spectrometer(EDS),and X-ray diffraction(XRD)were used to characterize interfacial diffusion layers.The shear test was used to determine the mechanical properties of the interfacial diffusion layer.The experimental results indicate that it is possible to co-extrusion Ti-6Al-4V/AA1050 compound profiles using non-equal channel lateral co-extrusion.Different heat treatment processes affect the thickness of the diffusion layer.When the temperature and time of heat treatment increase,the thickness of the reaction layers increases dramatically.Additionally,the shear strength of the Ti-6Al-4V/AA1050 composite interface is proportional to the diffusion layer thickness.It is observed that a medium interface thickness results in superior mechanical performance when compared to neither a greater nor a lesser interface thickness.Microstructural characterization of all heat treatments reveals that the only intermetallic compound observed in the diffusion layers is TiAl_(3).Due to the inter-diffusion of Ti and Al atoms,the TiAl_(3) layer grows primarily at AA1050/TiAl_(3) interfaces.

Effect of heat treatment on the microstructure,mechanical properties and fracture behaviors of ultra-high-strength SiC/Al-Zn-Mg-Cu composites

A high-zinc composite,12vol%SiC/Al-13.3 Zn-3.27 Mg-1.07Cu(wt%),with an ultra-high-strength of 781 MPa was success-fully fabricated through a powder metallurgy method,followed by an extrusion process.The effects of solid-solution and aging heat treat-ments on the microstructure and mechanical properties of the composite were extensively investigated.Compared with a single-stage sol-id-solution treatment,a two-stage solid-solution treatment(470℃/1 h+480℃/1 h)exhibited a more effective solid-solution strengthen-ing owing to the higher degree of solid-solution and a more uniform microstructure.According to the aging hardness curves of the com-posite,the optimized aging parameter(100℃/22 h)was determined.Reducing the aging temperature and time resulted in finer and more uniform nanoscale precipitates but only yielded a marginal increase in tensile strength.The fractography analysis revealed that intergranu-lar cracking and interface debonding were the main fracture mechanisms in the ultra-high-strength SiC/Al-Zn-Mg-Cu composites.Weak regions,such as the SiC/Al interface containing numerous compounds and the precipitate-free zones at the high-angle grain boundaries,were identified as significant factors limiting the strength enhancement of the composite.Interfacial compounds,including MgO,MgZn2,and Cu5Zn8,reduced the interfacial bonding strength,leading to interfacial debonding.

Customized heat treatment process enabled excellent mechanical properties in wire arc additively manufactured Mg-RE-Zn-Zr alloys

Customized heat treatment is essential for enhancing the mechanical properties of additively manufactured metallic materials,especially for alloys with complex phase constituents and heterogenous microstructure.However,the interrelated evolutions of different microstructure features make it difficult to establish optimal heat treatment processes.Herein,we proposed a method for customized heat treatment process exploration and establishment to overcome this challenge for such kind of alloys,and a wire arc additively manufactured(WAAM)Mg-Gd-Y-Zn-Zr alloy with layered heterostructure was used for feasibility verification.Through this method,the optimal microstructures(fine grain,controllable amount of long period stacking ordered(LPSO)structure and nano-scaleβ'precipitates)and the corresponding customized heat treatment processes(520°C/30 min+200°C/48 h)were obtained to achieve a good combination of a high strength of 364 MPa and a considerable elongation of 6.2%,which surpassed those of other state-of-the-art WAAM-processed Mg alloys.Furthermore,we evidenced that the favorable effect of the undeformed LPSO structures on the mechanical properties was emphasized only when the nano-scaleβ'precipitates were present.It is believed that the findings promote the application of magnesium alloy workpieces and help to establish customized heat treatment processes for additively manufactured materials.

Effect of Heat Treatment on Microstructure and Mechanical Properties of Multiscale SiC_p Hybrid Reinforced 6061 Aluminum Matrix Composites

The performance of solid solution aging treatment on aluminum matrix composites prepared by powder metallurgy and reinforced with 6061 aluminum alloy powder as matrix;meanwhile, nano silicon carbide particles(nm Si Cp), submicron silicon carbide particles(1 μm Si Cp) and Ti particles were studied. The Al/Si Cp composite powder was prepared by high-energy ball milling, and then cold-pressed, sintered, hotextruded, and then heat-treated with different solution temperatures and aging times for the extruded composites. Optical microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy(EDS), X-ray diffractometer(XRD) and extrusion testing were used to analyze and test the microstructure and mechanical properties of aluminum matrix composites. The results show that after the multi-stage solid solution at 530 ℃×2 h+535 ℃×2 h+540 ℃×2 h, the particles are mainly equiaxed grains and uniformly distributed. There is no reinforcement agglomeration, and the surface is dense and the insoluble phase is basically dissolved. In the matrix, the strengthening effect is good, and the hardness and compressive strength are 179.43 HV and 680.42 MPa, respectively. Under this solution process, when the aluminum matrix composites are aged at 170 ℃ for 10 h, the hardness and compressive strength can reach their peaks and increase to 195.82 HV and 721.48 MPa, respectively.

The Impact of Heat Treatment and Surface Treatment on Thermal Conductivity of Heat Sinks Made of Aluminium Die Casting Alloys

This research contributes to understand the thermal management capabilities of Plate Fin Heat Sinks(PFHS)fabricated from AlSi10Mg.The uniqueness in this study is that the heat sinks were exposed to abrasive blasting,heat treatment,and graphene coating,and a full evaluation of the influence of the aforementioned treatments on the thermal management capacities of PFHS was found.Untreated PFHS is compared with 1)abrasive blasted and graphene coated heat sink,and 2)heat treated and graphene coated heat sink.To assess the thermal efficiency of the PFHS variants,a dedicated experimental set up was meticulously constructed.It is noteworthy that a junction temperature of 60℃was assumed as the reference point for the analysis.The results revealed that the charging cycle time which denotes the time required attaining the junction temperature,increased 1.3 times for the sample being abrasive-blasted at 0.5 MPa pressure and graphene-coated for 0.5 mm when the maximum heat input of 45 W is evaluated.When low heat input of 15 W is evaluated,the results revealed that there is no significant difference in charging cycle when compared to the untreated heat sink.The charging cycle time increased 2 times for the sample which is heat-treated at 450℃and graphene-coated for 0.5 mm at heat input of 15 W.This finding unequivocally underscores the heightened capacity of the heat treated and graphene coated PFHS made of AlSi10Mg to withstand elevated junction temperatures.

Discussion on the Free Quenching Heat Treatment Process of Automotive Leaf Springs

Free quenching of automotive leaf springs is a new technology that has gradually started to be applied in the industry in China in recent years.Only a few manufacturers are applying it in the industry.Through more than half a year of on-site practice,the changes in the hot forming of spring plates before free quenching have been explored,and finally a heat treatment process that meets the production requirements of our company has been developed,achieving normal production.

Effect of welding heat input and post-welded heat treatment on hardness of stir zone for friction stir-welded 2024-T3 aluminum alloy

The microstructure and hardness of the stir zone （SZ） with different welding heat inputs were investigated for friction stir-welded 2024-T3 aluminum by transmission electron microscopy, differential scanning calorimeter and Vickers micro-hardness test. The results show that welding heat input has a significant effect on the hardness of the SZ. Under high welding heat input condition, a higher welding speed is beneficial for improving the hardness of the SZ. However, when the welding heat input is low, the hardness of the SZ elevates with increasing the rotation speed. The hardness of the SZ decreases after post-welded heat treatment due to overaging. The joints welded at 500 r/min and 100 mm/min show a high resistance to overaging. The reduction of hardness in the SZ is only 3.8%, while in other joints, the reduction is more than 10%. The morphology of strengthening precipitates plays important roles for the improvement of hardness.

Effect of heat treatment on the microstructure and mechanical properties of a multidirectionally forged Mg-Gd-Y-Zn-Zr-Ag alloy

Multidirectional forging(MDF)was successfully applied to fabricate large-size Mg-Gd-Y-Zn-Zr-Ag alloy in this work and effects of T4,T5 and T6 treatments on the microstructure and mechanical properties of the as-forged alloy were analyzed.Results show that dynamic recrystallization(DRX)occurs and second phase particles precipitate along the grain boundary during the MDF process.After annealing treatment(T4),the volume fraction and size of dynamic precipitates slightly increase at a lower temperature(430℃)compared with those of MDFed sample,while they are dissolved into theα-Mg matrix at a higher temperature(450℃).At the meantime,short plate-shaped long-period stacking ordered(LPSO)phases are observed in the DRX grains of the MDFed sample and then dissolved into theα-Mg matrix during annealing at both temperatures.Typical basal texture is identified in the MDFed sample,but the basal pole tilts away from final forging direction and rare-earth texture component with<1121>orientation parallel to penultimate forging direction becomes visible after annealing.The T6 sample annealing at 430℃for 4 h and ageing at 200℃for 34 h exhibits the superior strength and ductility in this study.The ultimate tensile strength,tensile yield strength and elongation to failure,which is 455 MPa,308 MPa and 7.7%,respectively,are overall improved compared with the directly-aged(T5)sample.This paper provides a superior heat treatment schedule to manufacture high-performance large-scale Mg-Gd-Y-Zn-Zr-Ag components for industrial production.

Effect of heat treatment on microstructure,mechanical and tribological properties of in-situ (TiC+TiB)/TC4 composites by casting

To enhance the performance of in-situ synthesized 6vol.%(Ti C+Ti B)/TC4 titanium matrix composites fabricated by casting,a variety of heat treatment processes were carried out.Upon conducting microstructure observations following various heat treatments,it was found that the composites exhibit a basketweave microstructure,consisting of an α phase and a transformed β phase.The sizes of(α+β) phases were found to be refined to varying degrees after the heat treatment processes,while the morphology of Ti B remains largely unchanged and Ti C becomes granulated.Compressive testing revealed that all composites subjected to different heat treatments demonstrate a notable increase in ultimate compressive strength as well as a slight improvement in plasticity compared to the as-cast state.The results of the tribological performance test indicated that the heat-treated composites exhibit lower average friction coefficient,specific wear rate,and worn surface roughness compared to the as-cast composite.Among the heat treatment processes studied,the composite solution heated at 1,150 °C/1 h followed by air cooling,then 950 °C/1 h followed by air cooling,and finally 500 °C/4 h followed by air cooling,demonstrates the highest levels of hardness,compressive strength,and wear resistance.These improvements are attributed to the combined effects of solid solution strengthening,grain refinement,and the pinning of dislocation slip.

Effect of post-weld heat treatment on microstructure and mechanical properties of welded joints of 6061-T6 aluminum alloy

6061 aluminum alloy T-joints were welded by double-pulsed MIG welding process. Then, the post-weld heat treatment was performed on the welded T-joints. The weld microstructure under different aging temperature and time was investigated by transmission electron microscopy and scanning electron microscopy. The mechanical properties were examined by hardness test and tensile test. The results showed that the micro-hardness was sensitive to heat treatment temperature and time. Increasing temperature was beneficial to the shortening of peak aging time. There were a large number of dislocations and few precipitates in the welded joints. With the increase of post-weld heat treatment temperature and time, the density of dislocation decreased. Meanwhile, the strengthening phase precipitated and grew up gradually. When the post-weld heat treatment temperature increased up to 200℃, large Q' phases were observed. And they were responsible for the peak value of the micro-hardness in the welded joints.

Insights into the relations between cell wall integrity and in vitro digestion properties of granular starches in pulse cotyledon cells after dry heat treatment

Natural foods,such as whole pulses,are recommended in the dietary guidelines of the US and China.The plant cell wall structure in whole pulses has important implications for the nutritional functionalities of starch.In this study,garbanzo bean cells with varying degrees of cell wall integrity were subjected to dry heat treatment(DHT)and used to elucidate the food structure-starch digestion properties of pulse food.The morphological features suggested that all cell samples do not exhibit remarkable changes after being subjected to DHT.Molecular rearrangement and the crystallite disruption of starch granules entrapped in cells occurred during DHT as assessed by the crystal structure and thermal properties.DHT decreased the inhibitory effects of enzymes of both the soluble and insoluble components,but the digestion rate and extent of slightly and highly damaged cell samples did not exhibit significant differences compared with their native counterparts.We concluded that the starch digestion of pulse cotyledon cells is primarily determined by the intactness of the cellular structure.This study reveals the role of food structure on the ability to retain the desirable nutritional properties of starch after subjection to physical modification.

Effect of post-weld heat treatment on microstructure and properties of Ti-23Al-17Nb alloy laser beam welding joints

The mechanical properties of Ti-23Al-17Nb (mole fraction,%) laser beam welding alloy joint at room temperature are comparable to that of the base materials.However,the strength and ductility of the as-welded joint deteriorate seriously after high temperature circulation.The effect of post-welded heat treatment on the microstructure and mechanical properties of the joint was investigated.The heat treatment was taken at 980 ℃ for 1.5 h,then furnace cooling and air cooling were performed separately.The results indicate that proper post-welded heat treatment improves the ductility of the joint at high temperature.

Effect of post-weld heat treatment on joint properties of dissimilar friction stir welded 2024-T4 and 7075-T6 aluminum alloys

The effect of post-weld heat treatment on dissimilar friction stir welded AA7075 and AA2024 joints was studied. After welding in constant parameters, solution heat treatment and various aging treatments were given to the welded joints. Microstructural and phase characterizations were done using optical microscope, SEM, FE-SEM, XRD and EDS techniques. Finally, mechanical properties of post-weld heat treated joints were evaluated and compared with as-welded joints. Results show that both 2024-T6 and 7075-T6 post-weld heat treatment procedures considerably improve the mechanical strength of the welded joint, with higher strength obtained for the 7075-T6 procedure, in comparison with the as-welded joint. This is explained by the formation of fine precipitates during the aging process, despite the abnormal grain growth. Fracture occurs at the interface between thermo-mechanical affected zone（TMAZ） and heat affected zone（HAZ） on the retreating side（AA7075） of as-welded joint, while by applying post-weld heat treatment fracture location shifts towards the stir zone（SZ） of the welded joint. Also, for post-weld heat treated samples, fracture surface is predominantly inter-granular, while in as-weld joint, fracture surface is mostly trans-granular. This is explained by dissolution and coarsening of precipitates within grains in post-weld heat treated joints.

Effect of Post-weld Heat Treatment on Microstructure and Mechanical Properties of Friction Stir Welded SSM7075 Aluminium Alloy

7XXX series aluminium alloys generally present low weldability by fusion welding methods because of the sensitivity to weld solidification cracking, vaporization of strengthening alloys and other defects in the fusion zone. Friction stir welding（FSW） can be deployed successfully with aluminium alloys. We presented the effect of post-weld heat treatment（PWHT） on the microstructure and mechanical properties of SSM7075 joints. Semi solid plates were butt-welded by FSW at a rotation speed of 1110 r/min, welding speeds of 70 and 110 mm/min. Solution treatment, artificial aging, and T6（solution treatment and artificial aging combined） were applied to the welded joints, each with three samples. It was found that the T6 joints at the speed of 70 mm/min yielded the highest tensile strength of 459.23 MPa. This condition best enhanced the mechanical properties of FSW SSM7075 aluminium alloy joints.

Microstructure characterization of electron beam welded joints of Ti_3Al after post-weld heat treatment

The effect of post-weld heat treatment on the microstructure characterization of electron beam welded(EBW) joints of Ti3Al-Nb was investigated.The results show that the microstructure of the weld is predominantly metastable,the columnar crystal metastructure of B2 phase.The microstructure morphology of the weld is significantly influenced by the method of the heat treatment.The microstructure of the weld is laminar structure(Widmanstaten structure) consisted of interphase α2 and B2 after post-weld heat treatment of 1000 ℃/2 h.The mechanism of the post-weld heat treatment makes the hardness distribution of joints homogeneous,but makes the whole joint somehow softened.

Influence of post-weld heat treatment on the microstructure and hardness of laser weld seams on hot-rolled TRIP 800 steel

The transformation induced plasticity (TRIP) steels effect occurs because of the martensitic transformation of retained austenite during plastic deformation,and it provides the steel with excellent strength and ductility.While welding remains a vital part of auto body manufacturing,the weldability of TRIP steels is problematic,and this prevents its adoption for many applications in the automotive industry.This present work studies the effects of welding and post-weld heat treatment on the microstructure of TRIP steels.It is found that the microstructures of the fusion zone and the heat affected zone (HAZ) are changed after high-temperature heat treatment.Hardness tests revealed that fusion zone hardness decreased with increasing of temperatures in the post-weld heat treatment on the laser weld seam.The rolling performance of the welding seam and the seam of post-weld heat treatment were also studied.

Improving corrosive wear resistance of Mg-Zn-Y-Zr alloys through heat treatment

The wear behavior of an as-received Mg-Zn-Y-Zr alloy before and after a facile heat treatment was investigated under sliding in air and 0.5 wt.%NaCl solution.Results revealed that the wear resistance of the alloy was remarkably enhanced after the heat treatment,irrespective of testing condition.The wear mechanism was predominantly abrasive wear accompanied by oxidation under the dry sliding condition,while corrosive wear was dominant under sliding in the NaCl solution.The superior corrosive wear resistance was attributed to the homogenous distribution of fine I-phase precipitates in the alloy by the heat treatment,leading to a reduction in wear,corrosion as well as wear-corrosion synergy.The wear-accelerated corrosion rate was remarkably alleviated after the heat treatment.

Hot Corrosion Resistance of TB8 Titanium Alloy after ECAP and Heat Treatment

The metastableβtitanium alloy TB8(Ti-12.76Mo-2.13Nb-2.73A1-0.16Si)was used as the original material,and the secondary processing method combining equal channel angular pressing(ECAP)and heat treatment was adopted.With the help of optical microscope(OM),scanning electron microscope(SEM)and X-ray diffractometer(XRD),the corrosion behavior of TB8 titanium alloy after different secondary processing(800℃/850℃solid solution-520℃aging,ECAP-800℃/850℃solid solution-520℃aging,and800℃/850℃solid solution-ECAP-520℃aging)was studied.The experimental results show that the hot corrosion products of the six samples are similar,mainly Na_(2)Si_(2)O_(5),MoS_(2),TiCl_(2),Ti(SO_(4))_(2),and TiS.Due to the grains of the TB8 titanium alloy treated by 850℃solid solution-ECAP-520℃aging are obviously refined,the surface structure is the most smooth and dense,forming a continuous Al2O3protective film,and the surface defects are the least after corrosion.Its corrosion layer thickness is the lowest(102.3μm),only 36.5%-81.4%of that of other secondary processing titanium alloys.In addition,the corrosion kinetics curves of the six materials all follow parabolic laws,and the minimum corrosion weight gain of the samples after 850℃solutionECAP-520℃aging treatment is 0.7507 mg·mm^(-2),showing better hot corrosion resistance.

Influence of heat treatments on incipient melting structures of DD5 nickel-based single crystal superalloy

The evolution of microstructure and formation mechanism of incipient melting microstructure of DD5 single crystal superalloy during solution heat treatment were studied by scanning electron microscopy(SEM),electron probe microanalysis(EPMA),and energy dispersive spectroscopy(EDS).The solidus and liquidus of single crystal alloy were obtained by differential scanning calorimetry(DSC).Results show that the mosaic-like eutectic and fan-like eutectic are dissolved at first,and the coarseγ'phase is dissolved later during the solution heat treatment of 1,390°C/2 h+1,310°C/4 h+1,320°C/10 h+air cooling(AC).The composition segregations of Al,Ta,W and Re are 0.99,0.96,1.04 and 1.16,respectively,which close to 1.The incipient melting is caused by the low local temperature of the alloy,and the micropore region with a lower melting point is the preferred position for incipient melting.