KTiOPO-4(KTP) crystal is a nonlinear optical material with superior properties. The KTP structure, point group mm2, is typified by the chemical form {K++}〔Ti 4+〕O(P 5+)O-4, where the curly brackets indicate nine or ...KTiOPO-4(KTP) crystal is a nonlinear optical material with superior properties. The KTP structure, point group mm2, is typified by the chemical form {K++}〔Ti 4+〕O(P 5+)O-4, where the curly brackets indicate nine or eightfold coordination, the square brackets sixfold octahedral coordination and the parentheses fourfold tetrahedral coordination. Different isovalent and aliovalent substitutions in a given structure is quite interesting. The KTP-type structure is extremely accommodating with respect to partial or complete isomorphous substitution which may be especially significant in optical devices such as waveguides. A monographic review of the structure-property relationship of KTP isomorphous substitution is briefly and precisely presented. It is shown that the properties of KTP are very sensitive to its structure. Among the composition, structure and properties of KTP-type crystal, the structure is the core because it is a link between the composition and properties.展开更多
As early as the end of the 1960s, people already put forward an idea of LSFD crystal.In 1979 V. G. Dmitriev et al. first produced LSFD Nd:LN crystal and observed thephenomenon of LSFD in their laboratory. In 1981 L. M...As early as the end of the 1960s, people already put forward an idea of LSFD crystal.In 1979 V. G. Dmitriev et al. first produced LSFD Nd:LN crystal and observed thephenomenon of LSFD in their laboratory. In 1981 L. M. Dorozhkin et al. reportedthe LSFD effect of NYAB crystal from 1.32μm to 0.66μm. In 1990 N. Y. Chou etal. first briefly reported the investigation on the third LSFD Cr:KTP crystal. Be-fore 1990 we had begun to study the Cr:KTP crystal in our laboratory.展开更多
文摘KTiOPO-4(KTP) crystal is a nonlinear optical material with superior properties. The KTP structure, point group mm2, is typified by the chemical form {K++}〔Ti 4+〕O(P 5+)O-4, where the curly brackets indicate nine or eightfold coordination, the square brackets sixfold octahedral coordination and the parentheses fourfold tetrahedral coordination. Different isovalent and aliovalent substitutions in a given structure is quite interesting. The KTP-type structure is extremely accommodating with respect to partial or complete isomorphous substitution which may be especially significant in optical devices such as waveguides. A monographic review of the structure-property relationship of KTP isomorphous substitution is briefly and precisely presented. It is shown that the properties of KTP are very sensitive to its structure. Among the composition, structure and properties of KTP-type crystal, the structure is the core because it is a link between the composition and properties.
基金Project supported by the National Natural Science Foundation of China.
文摘As early as the end of the 1960s, people already put forward an idea of LSFD crystal.In 1979 V. G. Dmitriev et al. first produced LSFD Nd:LN crystal and observed thephenomenon of LSFD in their laboratory. In 1981 L. M. Dorozhkin et al. reportedthe LSFD effect of NYAB crystal from 1.32μm to 0.66μm. In 1990 N. Y. Chou etal. first briefly reported the investigation on the third LSFD Cr:KTP crystal. Be-fore 1990 we had begun to study the Cr:KTP crystal in our laboratory.
