Despite substantial efforts in developing high-performance catalysts for the oxygen reduction reaction(ORR),the persistent challenge lies in the high onset overpotential of the ORR,and the effect of the elec-trolyte s...Despite substantial efforts in developing high-performance catalysts for the oxygen reduction reaction(ORR),the persistent challenge lies in the high onset overpotential of the ORR,and the effect of the elec-trolyte solution cannot be ignored.Consequently,we have systematically investigated the impact of adsorbate species and concentration,as well as solution pH,on the ORR activity on Pt(111)and Pt(poly)electrodes.The results all tend to establish a linear quantitative relationship between the onset potential for ORR and the adsorption equilibrium potential of the adsorbate.This finding indicates the decisive role of adsorbates in the onset potential for ORR,suggesting that the adsorption potential of adsorbates can serve as an intuitive criterion for ORR activity.Additional support for this conclusion is derived from experimental results obtained from the oxygen evolution reaction on Pt(poly)with different adsorbate species and from the hydrogen evolution reaction on Pt(111)with iodine adsorption.We further propose both an empirical equation for the onset potential for ORR and the concept of a potential-regulated adsor-bate shielding effect to elucidate the influence of adsorbates on ORR activity.This study provides new insights into the high onset overpotential of the ORR and offers potential strategies for predicting and enhancingORRactivity inthefuture.展开更多
A PT-symmetric Hamiltonian associated with a trigonometric Razhavi potential is analyzed. Along the same lines of the general quasi-exactly solvable analytic method considered in the [1] [2] [3], three necessary and s...A PT-symmetric Hamiltonian associated with a trigonometric Razhavi potential is analyzed. Along the same lines of the general quasi-exactly solvable analytic method considered in the [1] [2] [3], three necessary and sufficient algebraic conditions for this Hamiltonian to have a finite-dimensional invariant vector space are established. This PT-symmetric 2 x 2 -matrix Hamiltonian is called quasi-exactly solvable (QES).展开更多
In this paper the application of image enhancement techniques to potential field data is briefly described and two improved enhancement methods are introduced. One method is derived from the histogram equalization tec...In this paper the application of image enhancement techniques to potential field data is briefly described and two improved enhancement methods are introduced. One method is derived from the histogram equalization technique and automatically determines the color spectra of geophysical maps. Colors can be properly distributed and visual effects and resolution can be enhanced by the method. The other method is based on the modified Radon transform and gradient calculation and is used to detect and enhance linear features in gravity and magnetic images. The method facilites the detection of line segments in the transform domain. Tests with synthetic images and real data show the methods to be effective in feature enhancement.展开更多
基金supported by the National Natural Science Foundation of China(no.22372154,21972131).
文摘Despite substantial efforts in developing high-performance catalysts for the oxygen reduction reaction(ORR),the persistent challenge lies in the high onset overpotential of the ORR,and the effect of the elec-trolyte solution cannot be ignored.Consequently,we have systematically investigated the impact of adsorbate species and concentration,as well as solution pH,on the ORR activity on Pt(111)and Pt(poly)electrodes.The results all tend to establish a linear quantitative relationship between the onset potential for ORR and the adsorption equilibrium potential of the adsorbate.This finding indicates the decisive role of adsorbates in the onset potential for ORR,suggesting that the adsorption potential of adsorbates can serve as an intuitive criterion for ORR activity.Additional support for this conclusion is derived from experimental results obtained from the oxygen evolution reaction on Pt(poly)with different adsorbate species and from the hydrogen evolution reaction on Pt(111)with iodine adsorption.We further propose both an empirical equation for the onset potential for ORR and the concept of a potential-regulated adsor-bate shielding effect to elucidate the influence of adsorbates on ORR activity.This study provides new insights into the high onset overpotential of the ORR and offers potential strategies for predicting and enhancingORRactivity inthefuture.
文摘A PT-symmetric Hamiltonian associated with a trigonometric Razhavi potential is analyzed. Along the same lines of the general quasi-exactly solvable analytic method considered in the [1] [2] [3], three necessary and sufficient algebraic conditions for this Hamiltonian to have a finite-dimensional invariant vector space are established. This PT-symmetric 2 x 2 -matrix Hamiltonian is called quasi-exactly solvable (QES).
基金This work is supported by the research project (grant No. G20000467) of the Institute of Geology and Geophysics, CAS and bythe China Postdoctoral Science Foundation (No. 2004036083).
文摘In this paper the application of image enhancement techniques to potential field data is briefly described and two improved enhancement methods are introduced. One method is derived from the histogram equalization technique and automatically determines the color spectra of geophysical maps. Colors can be properly distributed and visual effects and resolution can be enhanced by the method. The other method is based on the modified Radon transform and gradient calculation and is used to detect and enhance linear features in gravity and magnetic images. The method facilites the detection of line segments in the transform domain. Tests with synthetic images and real data show the methods to be effective in feature enhancement.
