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高电位下PEMFC阴极催化层Pt对碳腐蚀的影响
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作者 刘明俊 周芬 +3 位作者 朱振 黄鹏涛 姚志鹏 潘牧 《电源技术》 CAS 北大核心 2024年第6期1003-1010,共8页
结合非色散红外光谱(NDIR)和电化学表征的方法研究了质子交换膜燃料电池阴极催化层在0.8 V恒电位下,碳腐蚀的变化规律及其对Pt氧化过程的依赖性。研究发现0.8 V恒电位下,Pt会导致碳载体的腐蚀更加剧烈。运行100 h后,Pt/C电极的碳损失质... 结合非色散红外光谱(NDIR)和电化学表征的方法研究了质子交换膜燃料电池阴极催化层在0.8 V恒电位下,碳腐蚀的变化规律及其对Pt氧化过程的依赖性。研究发现0.8 V恒电位下,Pt会导致碳载体的腐蚀更加剧烈。运行100 h后,Pt/C电极的碳损失质量达到8.7%,是纯碳电极的3.5倍。Pt/C电极的碳腐蚀规律可以分为三个阶段,第一阶段呈对数增长,第三阶段呈线性增长,中间存在混合增长区。而Pt氧化物累积量分析表明Pt的氧化呈现出两段对数关系,且中间存在一个过渡区,这解释了碳腐蚀的三段规律。活跃的Pt-OH催化碳腐蚀,并快速转化成PtO_(x)等惰性氧化物,大幅降低对碳腐蚀的促进作用,当Pt-OH含量稳定后,碳腐蚀速率达到稳态。电位阶跃工况下,Pt氧化物增长速度明显降低,碳载体质量损失达到了15.55%,几乎是恒电位工况的2倍,表明控制Pt氧化物累积速度会加速碳载体的腐蚀。 展开更多
关键词 碳载体腐蚀 0.8 V恒电位 pt催化剂 pt氧化物
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A-E equation of potential field transformations in the wavenumber domain and its application 被引量:7
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作者 Chai Yupu 《Applied Geophysics》 SCIE CSCD 2009年第3期205-216,299,共13页
A shift sampling theory established by author (1997a) is a generalization of Fourier transform computation theory. Based on this theory, I develop an Algorithm-Error (A-E) equation of potential field transformatio... A shift sampling theory established by author (1997a) is a generalization of Fourier transform computation theory. Based on this theory, I develop an Algorithm-Error (A-E) equation of potential field transformations in the wavenumber domain, which not only gives a more flexible algorithm of potential field transformations, but also reveals the law of error of potential field transformations in the wavenumber domain. The DFT0η η(0.5, 0.5) reduction-to-pole (RTP) technique derived from the A-E equation significantly improves the resolution and accuracy of RTP anomalies at low magnetic latitudes, including the magnetic equator. The law (origin, form mechanism, and essential properties) of the edge oscillation revealed by the A-E equation points out theoretically a way of improving the effect of existing padding methods in high-pass transformations in the wavenumber domain. 展开更多
关键词 potential field transformation Fourier transform shift sampling theory A-E equation DFT0η η(0.5 0.5) algorithm
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Laplace Transformation and Ergodic Potential Kernel for q-Process in Random Environment 被引量:2
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作者 LU Ping HU Dihe 《Wuhan University Journal of Natural Sciences》 CAS 2007年第2期218-224,共7页
This paper introduces some concepts such as q- process in random environment, Laplace transformation, ergodic potential kernel, error function and some basic lemmas.We study the continuity and Laplace transformation o... This paper introduces some concepts such as q- process in random environment, Laplace transformation, ergodic potential kernel, error function and some basic lemmas.We study the continuity and Laplace transformation of random transition function. Finally, we give the sufficient condition for the existence of ergodic potential kernel for homogeneous q- processes in random environments. 展开更多
关键词 random transition function transition density func-tion in random environment q-process in random environment Laplace transformation ergodic potential kernel
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双组分玻色-爱因斯坦凝聚体中PT对称势下的异步量子Kármán涡街
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作者 邵凯花 席忠红 +5 位作者 席保龙 涂朴 王青青 马金萍 赵茜 石玉仁 《物理学报》 SCIE EI CAS CSCD 北大核心 2024年第11期37-45,共9页
数值研究了相混合态双组分玻色-爱因斯坦凝聚体(Bose-Einstein condensate,BEC)中PT (parity-time)对称势下的动力学.在障碍势不同的宽度和速度下发现了异步量子Kármán涡街、斜向漂移涡旋偶极子、V字形涡旋对、无规则量子湍... 数值研究了相混合态双组分玻色-爱因斯坦凝聚体(Bose-Einstein condensate,BEC)中PT (parity-time)对称势下的动力学.在障碍势不同的宽度和速度下发现了异步量子Kármán涡街、斜向漂移涡旋偶极子、V字形涡旋对、无规则量子湍流以及各种尾迹的组合模式.研究了作用在移动障碍势上的拖拽力,分析了涡旋对产生的力学机理.在不同障碍势宽度和速度下,系统地模拟了异步量子Kármán涡街和其他尾迹模式的参数区域.同样分析了PT对称势中具有增益-损耗强度的虚部对异步量子Kármán涡街稳定性的影响.最后,提供了一个实现异步量子Kármán涡街的实验方案. 展开更多
关键词 玻色-爱因斯坦凝聚体 Kármán涡街 pt对称势
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Quantum Mechanical Hilbert Transformation for Normally Ordering Coulomb Potential-Type Operators 被引量:1
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作者 FAN Hong-Yi FU Liang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2006年第2X期213-216,共4页
We show that the technique of integration within an ordered product of operators can be extended to Hilbert transform. In so doing we derive normally ordered expansion of Coulomb potential-type operators directly by u... We show that the technique of integration within an ordered product of operators can be extended to Hilbert transform. In so doing we derive normally ordered expansion of Coulomb potential-type operators directly by using the mathematical Hilbert transform formula. 展开更多
关键词 quantum Hilbert transform normally ordering Coulomb potential
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PT对称势下自旋轨道耦合玻色-爱因斯坦凝聚体的能带结构
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作者 邵凯花 马金萍 +2 位作者 王青青 席保龙 石玉仁 《西北师范大学学报(自然科学版)》 CAS 2024年第3期42-47,共6页
数值研究PT对称势下具有自旋轨道耦合玻色-爱因斯坦凝聚体的能带结构.用傅立叶配置法求解布洛赫能带,分析PT对称晶格势的深度、虚部相对大小、自旋轨道耦合强度和拉比耦合强度对能带结构的影响.结果表明,第一、二能带的上下边沿随晶格... 数值研究PT对称势下具有自旋轨道耦合玻色-爱因斯坦凝聚体的能带结构.用傅立叶配置法求解布洛赫能带,分析PT对称晶格势的深度、虚部相对大小、自旋轨道耦合强度和拉比耦合强度对能带结构的影响.结果表明,第一、二能带的上下边沿随晶格深度的增加而上升,但能带宽度变窄;当PT对称晶格势的虚部大于临界值时,第一和第二能带发生重叠;随着自旋轨道耦合强度的增大,第一和第二能带的上下边界均减小;拉比耦合强度对能带结构也具有重要影响. 展开更多
关键词 玻色-爱因斯坦凝聚 pt对称势 自旋轨道耦合 能带结构
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10 kV配网电压互感器PT铁磁谐振异常仿真模型研究 被引量:1
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作者 卢晓宇 高岳达 赵哲 《粘接》 CAS 2024年第1期185-188,共4页
为了研究PT铁磁谐振所带来的影响,分析其影响因素,以10 kV低压配电网形成PT铁磁谐振过电压的基本原理为基础,利用EMTP-ATP计算机软件,构建中性点不接地系统仿真模型。以电压互感器的励磁特性、三相参数不平衡2大因素对铁磁谐振影响为例... 为了研究PT铁磁谐振所带来的影响,分析其影响因素,以10 kV低压配电网形成PT铁磁谐振过电压的基本原理为基础,利用EMTP-ATP计算机软件,构建中性点不接地系统仿真模型。以电压互感器的励磁特性、三相参数不平衡2大因素对铁磁谐振影响为例,进行仿真计算分析。仿真结果表明:PT铁磁特性较佳,可以减少谐振发生的概率,不过不能完全消除;此外,PT铁磁谐振产生较多的几率,受三相参数不平衡,或者对地电容大小不平衡等因素影响较大。基于仿真结果开展对各影响因素范围进行比较,进而为10 kV配网电压互感器PT铁磁谐振防治措施提供相关参考数据。 展开更多
关键词 10 kV配电网电压 互感器 pt铁磁谐振 电压仿真
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Deciphering the linear relationship in the activity of the oxygen reduction reaction on Pt electrodes:A decisive role of adsorbates
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作者 Haowen Cui Yan-Xia Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期70-77,共8页
Despite substantial efforts in developing high-performance catalysts for the oxygen reduction reaction(ORR),the persistent challenge lies in the high onset overpotential of the ORR,and the effect of the elec-trolyte s... Despite substantial efforts in developing high-performance catalysts for the oxygen reduction reaction(ORR),the persistent challenge lies in the high onset overpotential of the ORR,and the effect of the elec-trolyte solution cannot be ignored.Consequently,we have systematically investigated the impact of adsorbate species and concentration,as well as solution pH,on the ORR activity on Pt(111)and Pt(poly)electrodes.The results all tend to establish a linear quantitative relationship between the onset potential for ORR and the adsorption equilibrium potential of the adsorbate.This finding indicates the decisive role of adsorbates in the onset potential for ORR,suggesting that the adsorption potential of adsorbates can serve as an intuitive criterion for ORR activity.Additional support for this conclusion is derived from experimental results obtained from the oxygen evolution reaction on Pt(poly)with different adsorbate species and from the hydrogen evolution reaction on Pt(111)with iodine adsorption.We further propose both an empirical equation for the onset potential for ORR and the concept of a potential-regulated adsor-bate shielding effect to elucidate the influence of adsorbates on ORR activity.This study provides new insights into the high onset overpotential of the ORR and offers potential strategies for predicting and enhancingORRactivity inthefuture. 展开更多
关键词 Oxygen reduction reaction ACTIVITY ADSORBATE Equilibrium potential pt(111)
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Recursion-transform method and potential formulae of the m×n cobweb and fan networks 被引量:11
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作者 谭志中 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第9期82-90,共9页
In this paper, we made a new breakthrough, which proposes a new recursion–transform(RT) method with potential parameters to evaluate the nodal potential in arbitrary resistor networks. For the first time, we found ... In this paper, we made a new breakthrough, which proposes a new recursion–transform(RT) method with potential parameters to evaluate the nodal potential in arbitrary resistor networks. For the first time, we found the exact potential formulae of arbitrary m × n cobweb and fan networks by the RT method, and the potential formulae of infinite and semi-infinite networks are derived. As applications, a series of interesting corollaries of potential formulae are given by using the general formula, the equivalent resistance formula is deduced by using the potential formula, and we find a new trigonometric identity by comparing two equivalence results with different forms. 展开更多
关键词 recursion-transform method network model potential formula exact solution
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Identification of Sources of Potential Fields with Directional Wavelet Transform:Application to Mineral Exploration
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作者 Dianhua Cao,Anjian Wang Institute of Mineral Resources,Chinese Academy of Geological Sciences,Beijing 100037,China. 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期146-146,共1页
For the sustainable supply of mineral resources, blind deposits are becoming the emphasis of exploration after long-period exploitation of exposed deposits.The collection and analysis of gravity or magnetic data repre... For the sustainable supply of mineral resources, blind deposits are becoming the emphasis of exploration after long-period exploitation of exposed deposits.The collection and analysis of gravity or magnetic data represents one of the cheapest forms of large-scale geophysical exploration.With the identification of potential fields,we can get the map of worms or skeletonizations showing the three-dimension structure of shallow crust,and find the 展开更多
关键词 potential field directional WAVELET transform multidirectional and multiscale EDGES detection MINERAL EXPLORATION
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Identification of Potential Mineral Fields with Directional Wavelet Transform:Application to Mineral Exploration
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作者 Dianhua Cao,Anjian Wang Institute of Mineral Resources,Chinese Academy of Geological Sciences,Beijing 100037,China. 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期171-172,共2页
For the sustainable supply of mineral resources, blind deposits are becoming the emphasis of exploration after long-period exploitation of exposed deposits.The collection and analysis of gravity or magnetic data repre... For the sustainable supply of mineral resources, blind deposits are becoming the emphasis of exploration after long-period exploitation of exposed deposits.The collection and analysis of gravity or magnetic data represents one of the cheapest ways of large-scale geophysical exploration.With the identification of potential mineral fields,we can get the map of worms or skeletonizations showing 展开更多
关键词 potential field directional WAVELET transform multidirectional and multiscale EDGES detection MINERAL exploration
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Relativistic effect of pseudospin symmetry and tensor coupling on the Mie-type potential via Laplace transformation method
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作者 M.Eshghi S.M.Ikhdair 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第12期44-49,共6页
A relativistic Mie-type potential for spin-1/2 particles is studied. The Dirac Hamiltonian contains a scalar S(r) and a vector V(r) Mie-type potential in the radial coordinates, as well as a tensor potential U(r... A relativistic Mie-type potential for spin-1/2 particles is studied. The Dirac Hamiltonian contains a scalar S(r) and a vector V(r) Mie-type potential in the radial coordinates, as well as a tensor potential U(r) in the form of Coulomb potential. In the pseudospin(p-spin) symmetry setting Σ = Cps and Δ = V(r), an analytical solution for exact bound states of the corresponding Dirac equation is found. The eigenenergies and normalized wave functions are presented and particular cases are discussed with any arbitrary spin–orbit coupling number κ. Special attention is devoted to the caseΣ = 0 for which p-spin symmetry is exact. The Laplace transform approach(LTA) is used in our calculations. Some numerical results are obtained and compared with those of other methods. 展开更多
关键词 Dirac equation Mie-type potential Laplace transform approach tensor interaction p-spin symmetry
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生成式AI技术助推人力资源管理的转型前景和潜在风险——基于ChatGPT技术的应用场景视角
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作者 隋皓辰 李雨朦 +1 位作者 崔乃鹏 潘丽平 《职业技术》 2024年第1期99-108,共10页
以ChatGPT为代表的生成式AI的崛起是人工智能领域的一次重大变革,伴随着类ChatGPT技术强势介入人力资源生态圈,如何利用好这把“双刃剑”来有效助推人力资源管理变革需要全面冷静的思考。研究以ChatGPT等生成式AI为主要研究对象,基于其... 以ChatGPT为代表的生成式AI的崛起是人工智能领域的一次重大变革,伴随着类ChatGPT技术强势介入人力资源生态圈,如何利用好这把“双刃剑”来有效助推人力资源管理变革需要全面冷静的思考。研究以ChatGPT等生成式AI为主要研究对象,基于其核心特征,探讨在人才招聘选拔、员工培训与发展、员工体验提升、人才画像分析、赋能绩效管理和雇主品牌建设等方面的应用前景。在此基础上,本研究进一步探讨了ChatGPT在人力资源管理中的应用可能引发的风险,即工作替代与岗位流失、用户隐私泄露风险、信息滥用与虚假操纵、决策误导与生成偏差,以及数据安全与网络风险。面对ChatGPT可能引发人力资源的深刻变革,人力资源领域应主动吸纳ChatGPT带来的创新动能,建立科学的生成式AI规范框架和管理体系。 展开更多
关键词 生成式AI 转型前景 潜在风险 AI监管措施
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Pt-W/Al_(2)O_(3)催化甲酸铵转移氢化变压器油的应用研究
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作者 石羽煣 付高节 +1 位作者 谢晨艳 沈彬 《化工时刊》 CAS 2024年第3期9-14,共6页
通过浸渍法制备Pt-W/Al_(2)O_(3)催化剂,以甲酸铵为氢供体、乙醇为溶剂对老化变压器油进行转移加氢以实现变压器油的回收再利用。得益于Pt-W/Al_(2)O_(3)中丰富的酸性位点,与Pd/C、Pd/Al_(2)O_(3)、Pt/Al_(2)O_(3)等单效催化剂相比,本... 通过浸渍法制备Pt-W/Al_(2)O_(3)催化剂,以甲酸铵为氢供体、乙醇为溶剂对老化变压器油进行转移加氢以实现变压器油的回收再利用。得益于Pt-W/Al_(2)O_(3)中丰富的酸性位点,与Pd/C、Pd/Al_(2)O_(3)、Pt/Al_(2)O_(3)等单效催化剂相比,本研究所制备的催化剂性能更优。采用响应面法对工艺条件进行优化并作回归分析,结果表明最优工艺条件为甲酸铵用量39%,催化剂用量2.35%,温度69℃,经验证该模型置信度良好。在此条件下的氢化变压器油脱色率和脱酸率分别达到98.1%和97.4%,主要电气性能恢复至国标新油水平。 展开更多
关键词 转移氢化 变压器油再生 响应面法 pt-W/Al_(2)O_(3)
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Osteogenic Potential of Cultured Bone Marrow Stromal Cells Transfected with Transforming Growth Factor β_1 Gene in vitro
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作者 易诚青 郑启新 +1 位作者 郭晓东 刘勇 《Journal of Huazhong University of Science and Technology(Medical Sciences)》 SCIE CAS 2001年第2期130-133,共4页
To study the osteogenic potential of cultured bone marrow stromal cells transfected with transforming growth factor β 1 gene in vitro , cultured BMSCs were transfected with the complexes of pcDNA 3 TGF β ... To study the osteogenic potential of cultured bone marrow stromal cells transfected with transforming growth factor β 1 gene in vitro , cultured BMSCs were transfected with the complexes of pcDNA 3 TGF β 1 and Lipofectamine Reagent in vitro . The cell proliferation was detected by MTT method and the morphological features of transfected BMSCs was observed. ALP stains and PNP method were used to measure ALP activity. In addition, the collagen type Ⅰ propeptides and mineralized matrixes were examined by immunohistochemical staining and tetracycline fluorescence labeling respectively. The morphological and biological characters of the transfected BMSCs were similar to those of osteoblasts and the cell proliferation was promoted. The cell layer displayed strong positive reaction for ALP stains and immunohistochemical staining. ALP activity and collagen type Ⅰ expression increased remarkably after transfection. Mineralized matrixes formed earlier and more in transfected BMSCs as compared with control group. It is concluded that transfecting with TGF β 1 gene could promote the osteogenic potential of cultured BMSCs. 展开更多
关键词 transforming growth factor β 1 gene transfection bone marrow stromal cells osteogenic potential
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Theoretical Analysis of Lattice Parameter Effect on Order-Disorder Transformation Based on Pair Potential
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作者 TimotheeNsongo XiaodongNi 《Journal of University of Science and Technology Beijing》 CSCD 2002年第1期53-58,共6页
Based on pair potential, the Bragg Williams (B-W) model is modified to takeinto account the effect of the lattice parameter on theoretical order-disorder transformationanalysis. The main purpose of this work is to und... Based on pair potential, the Bragg Williams (B-W) model is modified to takeinto account the effect of the lattice parameter on theoretical order-disorder transformationanalysis. The main purpose of this work is to understand the basic aspects of this effect andrelated reasonable model on order-disorder transformation. In the present approach, theconfiguration free energy is chosen as function of the lattice parameter and the long-range order.This energy is calculated through Taylor's expansion, starting from the disordered state. It wasfound that the configuration free energy has been strongly modified when the lattice parameter istaken into account. It was also found only one type of order-disorder transformation exists in ABalloy and three kinds of order-disorder transformations for non-equiatomic alloy system such as A_3Balloy. This result is in agreement with experiments. 展开更多
关键词 order-disorder transformation computer simulation pair potential PHASEtransformATION
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Gradient Transformation of Momentum and Single-Valued Vector Potential in Nonrelativistic Dynamics
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作者 Illia Dubrovskyi 《Journal of Physical Science and Application》 2014年第5期328-332,共5页
A vector potential of a magnetic field in Lagrangian is defined as the necessary partial solution of a inhomogeneous differential equation. The "gradient transformation" is an addition of arbitrary general solution ... A vector potential of a magnetic field in Lagrangian is defined as the necessary partial solution of a inhomogeneous differential equation. The "gradient transformation" is an addition of arbitrary general solution of the corresponding homogeneous equation that does not change the Lagrange equations. When dynamics is described by momenta and coordinates, this transformation is not the vector potential modification, which does not change expressions for other physical quantities, but a canonical transformation of momentum, which changes expressions for all fimctions of momentum, not changing the Poisson brackets, and, hence, the integrals of motion. The generating function of this transformation must reverse sign under the time-charge reversal. In quantum mechanics the unitary transformation corresponds to this canonical transformation. It also does not change the commutation relations. The phase of this unitary operator also must reverse sign under the time-charge reversal. Examples of necessary vector potentials for some magnetic fields are presented. 展开更多
关键词 Magnetic field vector potential MOMENTUM gradient transformation canonical transformation unitary transformation.
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Observation about the Classical Electromagnetic Gauge Transformation and Its Quantum Correspondence
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作者 Gustavo V. López Jorge A. Lizarraga 《Journal of Modern Physics》 2024年第4期474-479,共6页
Using the Landau and symmetric gauges for the vector potential of a constant magnetic field and the quantum problem of a charged particle moving on a flat surface, we show the classical electromagnetic gauge transform... Using the Landau and symmetric gauges for the vector potential of a constant magnetic field and the quantum problem of a charged particle moving on a flat surface, we show the classical electromagnetic gauge transformation does not correspond to a one-dimensional unitary group transformation U(1) of the wave function for the quantum case. In addition, with the re-examination of the relation between the magnetic field B and its vector potential  A, we found that, in order to have a consistent formulation of the dynamics of the charged particle with both expressions, we must have that B=∇×A if and only if B≠0. 展开更多
关键词 Gauge transformation Harmonic Oscillator Quantum Hall Effect Electromagnetic potentials
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Bcklund Transformations and Explicit Solutions of (2+1)-Dimensional Barotropic and Quasi-Geostrophic Potential Vorticity Equation
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作者 胡晓瑞 陈勇 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第5期803-808,共6页
By the Backlund transformation method, an important (2+1)-dimensional nonlinear barotropie and quasigeostrophic potential vorticity (BQGPV) equation is investigated. Some simple special Backlund transformation th... By the Backlund transformation method, an important (2+1)-dimensional nonlinear barotropie and quasigeostrophic potential vorticity (BQGPV) equation is investigated. Some simple special Backlund transformation theorems are proposed and used to get explicit solutions of the BQGPV equation. Furthermore, all solutions of a second order linear ordinary differential equation including an arbitrary function can be used to construct explicit solutions of the (2+1)-dimensional BQGPV equation. Some figures are also given out to describe these solutions. 展开更多
关键词 Backlund transformation (2+ 1)-dimensional nonlinear barotropic and quasi-geostrophic potential vorticity equation explicit solution
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傅里叶变换求解一维PT对称delta势阱中的束缚态
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作者 贾春玉 梁兆新 《大学物理》 2024年第7期3-5,15,共4页
具有PT对称性的系统是量子力学研究前沿热点.一维PT对称delta势阱中束缚态问题是PT系统最简化模型,对其精确求解是具有科研价值的教学问题.本文通过求解一维PT对称delta势的定态薛定谔方程研究了PT对称性对系统束缚态以及本征能量的影响... 具有PT对称性的系统是量子力学研究前沿热点.一维PT对称delta势阱中束缚态问题是PT系统最简化模型,对其精确求解是具有科研价值的教学问题.本文通过求解一维PT对称delta势的定态薛定谔方程研究了PT对称性对系统束缚态以及本征能量的影响.首先,采用傅里叶变换对一维PT对称delta势的定态薛定谔方程进行了求解并讨论.其次,通过数值手段确定了一维PT对称delta势阱中束缚态的轮廓以及系统的本征能量.最后,分析和探讨了PT对称势强度与本征能量的关系.本文把量子力学教学中传统的厄米delta势阱本征值问题扩展到非厄米delta势阱问题,是对量子力学教学必做习题的有益且及时地扩展. 展开更多
关键词 pt对称 delta函数势 傅里叶变换 非厄米量子力学
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