Synthesis of VIB Group Metals Silicides Dispersed Powders by Electrolysis of Halide-Oxide Melts

Study of electrochemical behavior of chromium （molybdenum, tungsten） and silicon containing melts allowed defining conditions for synthesis of silicides of chromium, molybdenum and tungsten in the form of fine powders by electrolysis of halide-oxide melts. Sequence of stages of electrosynthesis of silicides of molybdenum and tungsten was found as follows： deposition of more electroposifve metal （molybdenum or tungsten）, deposition of the second component （silicon） on the surface of metal deposited previously, and reaction diffusion of silicon into the deep of the metal-salt ＂pear＂ with the formation of silicide phases of different compositions up to the higher silicides. In contrast, during the electrodeposition of chromium silicides, one of the components （chromium） is deposited not in elemental form, but in oxide form, and the other （silicon） acts as a reducing agent for this oxide to form binary compounds. Duration of the synthesis first stage （deposition of refractory metal or of its oxide） depends on the refractory metal compound content in the system and on the cathode current density. Synthesis of silicides is possible due to retention of powders of molybdenum （tungsten） or chromium oxide at the cathode without scaling. Optimal values of concentrations ratio, current density, temperature, and duration of electrosynthesis were found. Phase composition of products were obtained, as well as their chemical and thermal stability, were studied.

Physical modelling of particle transport phenomenon and vibration behavior of converter with bottom powder injection

A cold model of top-bottom blown converter was set up to study the particle transport phenomenon and vibration performance of converter with bottom powder injection.The effect of bottom blowing flow rates,tuyere diameters,arrangements,and powder to gas mass ratios on powder distribution and furnace body vibration was investigated.The results show that the bottom injection parameters and modes have significant effects on the particle transport behavior and furnace vibration.The powder dispersion uniformity and furnace vibration increase with the increase in bottom blowing tuyere diameters.In the lower range of bottom blowing flow rates and powder to gas mass ratios,the powder dispersion uniformity is improved with the increase in them.However,in the higher range,the excessive furnace vibration leads to reduction in uniformity in powder dispersion.When the bottom blowing tuyeres arrange at double arrangement of 0.5R(R refers to the radius of the bottom)distance between tuyere and center of bath bottom,the converter has optimal particle transport behavior and vibration performance.The vibration law of converter with bottom powder injection was revealed by deducing the empirical formulas of furnace vibration maximum amplitude.The vibration intensity is affected by Froude number,powder to gas mass ratio,and tuyere arrangement.

Circulation intensity and axial dispersion of non-cohesive solid particles in a V-blender via DEM simulation

In this study, discrete element method （DEM） was employed to simulate the movement of non-cohesive mono-dispersed particles in a V-blender along with particle-particle and particle-boundary interactions. To validate the model, DEM results were successfully compared to positron emission particle tracking （PEPT） data reported in literature. The validated model was then utilized to explore the effects of rotational speed and fill level on circulation intensity and axial dispersion coefficient of non-cohesive particles in the V-blender. The results showed that the circulation intensity increased with an increase in the rotational speed from 15 to 60 rpm. As the fill level increased from 20% to 46%, the circulation intensity decreased, reached its minimum value at a fill level of 34% for all rotational speeds, and did not change significantly at fill levels greater than 34%. The DEM results also revealed that the axial dispersion coefficient of particles in the V-blender was a linear function of the rotational speed. These trends were in good agreement with the experimentallv determined values reported bv previous researchers.