期刊文献+
共找到3,509篇文章
< 1 2 176 >
每页显示 20 50 100
Lagrangian coherent structure analysis on transport of Acetes chinensis along coast of Lianyungang,China 被引量:1
1
作者 Kexin WANG Xueqing ZHANG +2 位作者 Qi LOU Xusheng XIANG Ying XIONG 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第1期345-359,共15页
Spatial heterogeneity or“patchiness”of plankton distributions in the ocean has always been an attractive and challenging scientific issue to oceanographers.We focused on the accumulation and dynamic mechanism of the... Spatial heterogeneity or“patchiness”of plankton distributions in the ocean has always been an attractive and challenging scientific issue to oceanographers.We focused on the accumulation and dynamic mechanism of the Acetes chinensis in the Lianyungang nearshore licensed fishing area.The Lagrangian frame approaches including the Lagrangian coherent structures theory,Lagrangian residual current,and Lagrangian particle-tracking model were applied to find the transport pathways and aggregation characteristics of Acetes chinensis.There exist some material transport pathways for Acetes chinensis passing through the licensed fishing area,and Acetes chinensis is easy to accumulate in the licensed fishing area.The main mechanism forming this distribution pattern is the local circulation induced by the nonlinear interaction of topography and tidal flow.Both the Lagrangian coherent structure analysis and the particle trajectory tracking indicate that Acetes chinensis in the licensed fishing area come from the nearshore estuary.This work contributed to the adjustment of licensed fishing area and the efficient utilization of fishery resources. 展开更多
关键词 plankton accumulation hydrodynamic model lagrangian particle-tracking model lagrangian analysis
下载PDF
对抗条件下基于SAC-Lagrangian的UAV智能规划
2
作者 岳龙飞 杨任农 +4 位作者 闫孟达 赵小茹 左家亮 刘会亮 张明元 《电光与控制》 CSCD 北大核心 2024年第8期1-7,共7页
无人机因其低成本、可消耗、分布部署、敏捷灵活的优势,在多个民用领域大放异彩。但受其智能化程度限制,如何在复杂对抗条件下自主安全完成任务仍存在巨大挑战。针对目前无人机任务规划存在的智能性和安全性问题,提出一种基于安全强化... 无人机因其低成本、可消耗、分布部署、敏捷灵活的优势,在多个民用领域大放异彩。但受其智能化程度限制,如何在复杂对抗条件下自主安全完成任务仍存在巨大挑战。针对目前无人机任务规划存在的智能性和安全性问题,提出一种基于安全强化学习算法的无人机智能规划方法(SAC-Lagrangian)。考虑了雷达威胁、禁飞区安全约束和地导对抗条件,将任务规划问题建模为约束马尔可夫决策过程(CMDP),通过拉格朗日乘子法变为对偶问题,采用最大熵柔性行动者-评论家(SAC)算法近似求解最优策略,保证了智能体在遵守安全约束条件下最大化期望回报。仿真结果表明,与其他基线算法相比,所提方法能在保证任务性能的同时确保安全性,适应动态变化的场景,任务完成率达到96%,因此,具有高效、鲁棒和安全的优势。 展开更多
关键词 无人机 安全强化学习 SAC-lagrangian 智能任务规划 鲁棒性
下载PDF
Dynamic Modeling of Robotic Manipulator via an Augmented Deep Lagrangian Network
3
作者 Shuangshuang Wu Zhiming Li +1 位作者 Wenbai Chen Fuchun Sun 《Tsinghua Science and Technology》 SCIE EI CAS CSCD 2024年第5期1604-1614,共11页
Learning the accurate dynamics of robotic systems directly from the trajectory data is currently a prominent research focus.Recent physics-enforced networks,exemplified by Hamiltonian neural networks and Lagrangian ne... Learning the accurate dynamics of robotic systems directly from the trajectory data is currently a prominent research focus.Recent physics-enforced networks,exemplified by Hamiltonian neural networks and Lagrangian neural networks,demonstrate proficiency in modeling ideal physical systems,but face limitations when applied to systems with uncertain non-conservative dynamics due to the inherent constraints of the conservation laws foundation.In this paper,we present a novel augmented deep Lagrangian network,which seamlessly integrates a deep Lagrangian network with a standard deep network.This fusion aims to effectively model uncertainties that surpass the limitations of conventional Lagrangian mechanics.The proposed network is applied to learn inverse dynamics model of two multi-degree manipulators including a 6-dof UR-5 robot and a 7-dof SARCOS manipulator under uncertainties.The experimental results clearly demonstrate that our approach exhibits superior modeling precision and enhanced physical credibility. 展开更多
关键词 deep lagrangian network nonconservative dynamics multi-degree manipulator inverse dynamic modeling
原文传递
An Updated Lagrangian Particle Hydrodynamics (ULPH)-NOSBPD Coupling Approach forModeling Fluid-Structure Interaction Problem
4
作者 Zhen Wang Junsong Xiong +3 位作者 Shaofan Li Xin Lai Xiang Liu Lisheng Liu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第10期491-523,共33页
A fluid-structure interaction approach is proposed in this paper based onNon-Ordinary State-Based Peridynamics(NOSB-PD)and Updated Lagrangian Particle Hydrodynamics(ULPH)to simulate the fluid-structure interaction pro... A fluid-structure interaction approach is proposed in this paper based onNon-Ordinary State-Based Peridynamics(NOSB-PD)and Updated Lagrangian Particle Hydrodynamics(ULPH)to simulate the fluid-structure interaction problem with large geometric deformation and material failure and solve the fluid-structure interaction problem of Newtonian fluid.In the coupled framework,the NOSB-PD theory describes the deformation and fracture of the solid material structure.ULPH is applied to describe the flow of Newtonian fluids due to its advantages in computational accuracy.The framework utilizes the advantages of NOSB-PD theory for solving discontinuous problems and ULPH theory for solving fluid problems,with good computational stability and robustness.A fluidstructure coupling algorithm using pressure as the transmission medium is established to deal with the fluidstructure interface.The dynamic model of solid structure and the PD-ULPH fluid-structure interaction model involving large deformation are verified by numerical simulations.The results agree with the analytical solution,the available experimental data,and other numerical results.Thus,the accuracy and effectiveness of the proposed method in solving the fluid-structure interaction problem are demonstrated.The fluid-structure interactionmodel based on ULPH and NOSB-PD established in this paper provides a new idea for the numerical solution of fluidstructure interaction and a promising approach for engineering design and experimental prediction. 展开更多
关键词 Fluid-structure interaction(FSI) updated lagrangian particle hydrodynamics PERIDYNAMICS meshfree method
下载PDF
Updated Lagrangian Particle Hydrodynamics (ULPH)Modeling of Natural Convection Problems
5
作者 Junsong Xiong Zhen Wang +3 位作者 Shaofan Li Xin Lai Lisheng Liu Xiang Liu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第10期151-169,共19页
Natural convection is a heat transfer mechanism driven by temperature or density differences,leading to fluid motion without external influence.It occurs in various natural and engineering phenomena,influencing heat t... Natural convection is a heat transfer mechanism driven by temperature or density differences,leading to fluid motion without external influence.It occurs in various natural and engineering phenomena,influencing heat transfer,climate,and fluid mixing in industrial processes.This work aims to use the Updated Lagrangian Particle Hydrodynamics(ULPH)theory to address natural convection problems.The Navier-Stokes equation is discretized using second-order nonlocal differential operators,allowing a direct solution of the Laplace operator for temperature in the energy equation.Various numerical simulations,including cases such as natural convection in square cavities and two concentric cylinders,were conducted to validate the reliability of the model.The results demonstrate that the proposed model exhibits excellent accuracy and performance,providing a promising and effective numerical approach for natural convection problems. 展开更多
关键词 Updated lagrangian particle hydrodynamics(ULPH) natural convection meshless methods higher order Laplacian model
下载PDF
An Unconventional Divergence Preserving Finite-Volume Discretization of Lagrangian Ideal MHD
6
作者 Walter Boscheri Raphael Loubere Pierre-Henri Maire 《Communications on Applied Mathematics and Computation》 EI 2024年第3期1665-1719,共55页
We construct an unconventional divergence preserving discretization of updated Lagrangian ideal magnetohydrodynamics(MHD)over simplicial grids.The cell-centered finite-volume(FV)method employed to discretize the conse... We construct an unconventional divergence preserving discretization of updated Lagrangian ideal magnetohydrodynamics(MHD)over simplicial grids.The cell-centered finite-volume(FV)method employed to discretize the conservation laws of volume,momentum,and total energy is rigorously the same as the one developed to simulate hyperelasticity equations.By construction this moving mesh method ensures the compatibility between the mesh displacement and the approximation of the volume flux by means of the nodal velocity and the attached unit corner normal vector which is nothing but the partial derivative of the cell volume with respect to the node coordinate under consideration.This is precisely the definition of the compatibility with the Geometrical Conservation Law which is the cornerstone of any proper multi-dimensional moving mesh FV discretization.The momentum and the total energy fluxes are approximated utilizing the partition of cell faces into sub-faces and the concept of sub-face force which is the traction force attached to each sub-face impinging at a node.We observe that the time evolution of the magnetic field might be simply expressed in terms of the deformation gradient which characterizes the Lagrange-to-Euler mapping.In this framework,the divergence of the magnetic field is conserved with respect to time thanks to the Piola formula.Therefore,we solve the fully compatible updated Lagrangian discretization of the deformation gradient tensor for updating in a simple manner the cell-centered value of the magnetic field.Finally,the sub-face traction force is expressed in terms of the nodal velocity to ensure a semi-discrete entropy inequality within each cell.The conservation of momentum and total energy is recovered prescribing the balance of all the sub-face forces attached to the sub-faces impinging at a given node.This balance corresponds to a vectorial system satisfied by the nodal velocity.It always admits a unique solution which provides the nodal velocity.The robustness and the accuracy of this unconventional FV scheme have been demonstrated by employing various representative test cases.Finally,it is worth emphasizing that once you have an updated Lagrangian code for solving hyperelasticity you also get an almost free updated Lagrangian code for solving ideal MHD ensuring exactly the compatibility with the involution constraint for the magnetic field at the discrete level. 展开更多
关键词 Cell-centered lagrangian finite-volume(FV)schemes Hyper-elasticity Ideal magnetohydrodynamics(MHD)equations Moving unstructured meshes A posteriori MOOD limiting
下载PDF
Noether symmetry and conserved quantity for dynamical system with non-standard Lagrangians on time scales 被引量:11
7
作者 宋静 张毅 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第8期201-209,共9页
This paper focuses on studying the Noether symmetry and the conserved quantity with non-standard Lagrangians, namely exponential Lagrangians and power-law Lagrangians on time scales. Firstly, for each case, the Hamilt... This paper focuses on studying the Noether symmetry and the conserved quantity with non-standard Lagrangians, namely exponential Lagrangians and power-law Lagrangians on time scales. Firstly, for each case, the Hamilton prin- ciple based on the action with non-standard Lagrangians on time scales is established, with which the corresponding Euler-Lagrange equation is given. Secondly, according to the invariance of the Hamilton action under the infinitesimal transformation, the Noether theorem for the dynamical system with non-standard Lagrangians on time scales is established. The proof of the theorem consists of two steps. First, it is proved under the infinitesimal transformations of a special one-parameter group without transforming time. Second, utilizing the technique of time-re-parameterization, the Noether theorem in a general form is obtained. The Noether-type conserved quantities with non-standard Lagrangians in both clas- sical and discrete cases are given. Finally, an example in Friedmann-Robertson-Walker spacetime and an example about second order Duffing equation are given to illustrate the application of the results. 展开更多
关键词 time scale non-standard lagrangian Noether symmetry conserved quantity
下载PDF
Symmetry of Lagrangians of holonomic systems in terms of quasi-coordinates 被引量:7
8
作者 吴惠彬 梅凤翔 《Chinese Physics B》 SCIE EI CAS CSCD 2009年第8期3145-3149,共5页
This paper discusses the symmetry of Lagrangians of holonomic systems in terms of quasi-coordinates. Firstly, the definition and the criterion of the symmetry are given. Secondly, the condition under which there exist... This paper discusses the symmetry of Lagrangians of holonomic systems in terms of quasi-coordinates. Firstly, the definition and the criterion of the symmetry are given. Secondly, the condition under which there exists a conserved quantity and the form of the conserved quantity are obtained. Finally, an example is shown to illustrate the application of the results. 展开更多
关键词 quasi-coordinate holonomic system symmetry of lagrangians conserved quantity
下载PDF
Symmetry of Lagrangians of nonholonomic systems of non-Chetaev's type 被引量:9
9
作者 吴惠彬 梅凤翔 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第3期27-30,共4页
This paper studies the symmetry of Lagrangians of nonholonomic systems of non-Chetaev's type. First, the definition and the criterion of the symmetry of the system are given. Secondly, it obtains the condition under ... This paper studies the symmetry of Lagrangians of nonholonomic systems of non-Chetaev's type. First, the definition and the criterion of the symmetry of the system are given. Secondly, it obtains the condition under which there exists a conserved quantity and the form of the conserved quantity. Finally, an example is shown to illustrate the application of the result. 展开更多
关键词 nonholonomic system non-Chetaev's type constraint symmetry of lagrangians con-served quantity
下载PDF
Further study on a class of augmented Lagrangians of Di Pillo and Grippo in nonlinear programming 被引量:2
10
作者 杜学武 梁玉梅 张连生 《Journal of Shanghai University(English Edition)》 CAS 2006年第4期293-298,共6页
In this paper, a class of augmented Lagrangiaus of Di Pillo and Grippo (DGALs) was considered, for solving equality-constrained problems via unconstrained minimization techniques. The relationship was further discus... In this paper, a class of augmented Lagrangiaus of Di Pillo and Grippo (DGALs) was considered, for solving equality-constrained problems via unconstrained minimization techniques. The relationship was further discussed between the uneonstrained minimizers of DGALs on the product space of problem variables and multipliers, and the solutions of the eonstrained problem and the corresponding values of the Lagrange multipliers. The resulting properties indicate more precisely that this class of DGALs is exact multiplier penalty functions. Therefore, a solution of the equslity-constralned problem and the corresponding values of the Lagrange multipliers can be found by performing a single unconstrained minimization of a DGAL on the product space of problem variables and multipliers. 展开更多
关键词 nonlinear programming constrained optimization augmented lagrangians augmented lagrangians of Di Pillo and Grippo.
下载PDF
Symmetry of Lagrangians of a holonomic variable mass system 被引量:1
11
作者 吴惠彬 梅凤翔 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第6期335-338,共4页
The symmetry of Lagrangians of a holonomic variable mass system is studied. Firstly, the differential equations of motion of the system are established. Secondly, the definition and the criterion of the symmetry of th... The symmetry of Lagrangians of a holonomic variable mass system is studied. Firstly, the differential equations of motion of the system are established. Secondly, the definition and the criterion of the symmetry of the system are presented. Thirdly, the conditions under which there exists a conserved quantity deduced by the symmetry are obtained. The form of the conserved quantity is the same as that of the constant mass Lagrange system. Finally, an example is shown to illustrate the application of the result. 展开更多
关键词 Holonomic system variable mass system symmetry of lagrangians conserved quantity
下载PDF
Perturbation to Noether Symmetry and Adiabatic Invariants for Dynamical Systems with Nonstandard Lagrangians 被引量:3
12
作者 WANG Xueping ZHANG Yi 《Journal of Donghua University(English Edition)》 EI CAS 2018年第1期24-27,共4页
The perturbation to Noether symmetry and adiabatic invariants for dynamical systems with nonstandard Lagrangians are studied.Based on two kinds of nonstandard Lagrangians(i.e.exponential Lagrangians and power-law Lagr... The perturbation to Noether symmetry and adiabatic invariants for dynamical systems with nonstandard Lagrangians are studied.Based on two kinds of nonstandard Lagrangians(i.e.exponential Lagrangians and power-law Lagrangians),the exact invariants of Noether type are given.Based on the definition of highorder adiabatic invariants,the relationship between the perturbation of Noether symmetry and the adiabatic invariants of the system under a small disturbance is studied,and then the corresponding theorems of adiabatic invariants are established.Finally,two examples are given to illustrate the methods and results appear in this paper. 展开更多
关键词 nonstandard lagrangians Noether symmetry PERTURBATION adiabatic invariants
下载PDF
Approximate Noether-Type Symmetries and Conservation Laws via Partial Lagrangians for Nonlinear Wave Equation with Damping 被引量:2
13
作者 苏敬蕊 张顺利 李吉娜 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第1期37-42,共6页
In terms of our new exact definition of partial Lagrangian and approximate Euler-Lagrange-type equation, we investigate the nonlinear wave equation with damping via approximate Noether-type symmetry operators associat... In terms of our new exact definition of partial Lagrangian and approximate Euler-Lagrange-type equation, we investigate the nonlinear wave equation with damping via approximate Noether-type symmetry operators associated with partial Lagrangians and construct its approximate conservation laws in general form. 展开更多
关键词 approximate Noether-type symmetry partial lagrangian approximate conservation law
下载PDF
复辛空间■^(2),■^(4)中的完全Lagrangian子空间的分类
14
作者 苏雅其其格 姚斯琴 《内蒙古大学学报(自然科学版)》 CAS 北大核心 2023年第6期581-592,共12页
讨论复辛空间■^(2),■^(4)中的完全Lagrangian子空间的标准型。通过参数化的方法研究复辛空间■^(2),■^(4)中的完全Lagrangian子空间的表示与分类。
关键词 复辛空间 完全lagrangian子空间 分类
下载PDF
Symmetry of the Lagrangians of holonomic nonconservative system in event space
15
作者 张斌 方建会 张伟伟 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第7期61-65,共5页
This paper analyzes the symmetry of Lagrangians and the conserved quantity for the holonomic non-conservative system in the event space. The criterion and the definition of the symmetry are proposed first, then a quan... This paper analyzes the symmetry of Lagrangians and the conserved quantity for the holonomic non-conservative system in the event space. The criterion and the definition of the symmetry are proposed first, then a quantity caused by the symmetry and its existence condition are given. An example is shown to illustrate the application of the result at the end. 展开更多
关键词 symmetry of lagrangians event space holonomic nonconservative system conservedquantity
下载PDF
Electromagnetic Gauges and Maxwell Lagrangians Applied to the Determination of Curvature in the Space-Time and their Applications
16
作者 Francisco Bulnes 《Journal of Electromagnetic Analysis and Applications》 2012年第6期252-266,共15页
If we consider the finite actions of electromagnetic fields in Hamiltonian regime and use vector bundles of geodesic in movement of the charges with a shape operator (connection) that measures the curvature of a geome... If we consider the finite actions of electromagnetic fields in Hamiltonian regime and use vector bundles of geodesic in movement of the charges with a shape operator (connection) that measures the curvature of a geometrical space on these geodesic (using the light caused from these points (charges) acting with the infinite null of gravitational field (background)) we can establish a model of the curvature through gauges inside the electromagnetic context. In partular this point of view is useful when it is about to go on in a quantized version from the curvature where the space is distorted by the interactions between particles. This demonstrates that curvature and torsion effect in the space-time are caused in the quantum dimension as back-reaction effects in photon propagation. Also this permits the observational verification and encodes of the gravity through of light fields deformations. The much theoretical information obtained using the observable effects like distortions is used to establish inside this Lagrangian context a classification of useful spaces of electro-dynamic configuration for the description of different interactions of field in the Universe related with gravity. We propose and design one detector of curvature using a cosmic censor of the space-time developed through distortional 3-dimensional sphere. Some technological applications of the used methods are exhibited. 展开更多
关键词 BACK-REACTION Effects Electromagnetic BUNDLES Form Operator Electro-Gravitational Detectors Maxwell’s lagrangian Quantum CURVATURE
下载PDF
A drift-kinetic perturbed Lagrangian for low-frequency nonideal MHD applications
17
作者 徐国盛 伍兴权 胡友俊 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第7期35-41,共7页
We find that the perturbed Lagrangian derived from the drift-kinetic equation in[Porcelli F et al 1994 Phys.Plasmas 1470]is inconsistent with the ordering for the low-frequency large-scale magnetohydrodynamic(MHD).Her... We find that the perturbed Lagrangian derived from the drift-kinetic equation in[Porcelli F et al 1994 Phys.Plasmas 1470]is inconsistent with the ordering for the low-frequency large-scale magnetohydrodynamic(MHD).Here,we rederive the expression for the perturbed Lagrangian within the framework of nonideal MHD using the ordering system for the low-frequency largescale MHD in a low-beta plasma.The obtained perturbed Lagrangian is consistent with Chen's gyrokinetic theory[Chen L and Zonca F 2016 Rev.Mod.Phys.88015008],where the terms related to the field curvature and gradient are small quantities of higher order and thus negligible.As the perturbed Lagrangian has been widely used in the literature to calculate the plasma nonadiabatic response in low-frequency MHD applications,this finding may have a significant impact on the understanding of the kinetic driving and dissipative mechanisms of MHD instabilities and the plasma response to electromagnetic perturbations in fusion plasmas. 展开更多
关键词 perturbed lagrangian drift kinetic low-frequency nonideal MHD fusion plasma
下载PDF
Path Integral Quantization of Non-Natural Lagrangian
18
作者 Ola A. Jarab’ah 《Journal of Applied Mathematics and Physics》 2023年第10期2932-2937,共6页
Path integral technique is discussed using Hamilton Jacobi method. The Hamilton Jacobi function of non-natural Lagrangian is obtained using separation of variables method. This function makes an important role in path... Path integral technique is discussed using Hamilton Jacobi method. The Hamilton Jacobi function of non-natural Lagrangian is obtained using separation of variables method. This function makes an important role in path integral quantization. The path integral is obtained as integration over the canonical phase space coordinates, which contains the generalized coordinate q and the generalized momentum p. One illustrative example is considered to explain the application of our formalism. 展开更多
关键词 Path Integral Quantization Hamilton Jacobi Equation Non-Natural lagrangian Hamilton Jacobi Function
下载PDF
Nonlinear perturbation of a high-order exceptional point:Skin discrete breathers and the hierarchical power-law scaling
19
作者 江慧 成恩宏 +1 位作者 周子榆 郎利君 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第8期319-326,共8页
We study the nonlinear perturbation of a high-order exceptional point(EP)of the order equal to the system site number L in a Hatano-Nelson model with unidirectional hopping and Kerr nonlinearity.Notably,we find a clas... We study the nonlinear perturbation of a high-order exceptional point(EP)of the order equal to the system site number L in a Hatano-Nelson model with unidirectional hopping and Kerr nonlinearity.Notably,we find a class of discrete breathers that aggregate to one boundary,here named as skin discrete breathers(SDBs).The nonlinear spectrum of these SDBs shows a hierarchical power-law scaling near the EP.Specifically,the response of nonlinear energy to the perturbation is given by E_(m)∝Γ~(α_(m)),whereα_(m)=3^(m-1)is the power with m=1,...,L labeling the nonlinear energy bands.This is in sharp contrast to the L-th root of a linear perturbation in general.These SDBs decay in a double-exponential manner,unlike the edge states or skin modes in linear systems,which decay exponentially.Furthermore,these SDBs can survive over the full range of nonlinearity strength and are continuously connected to the self-trapped states in the limit of large nonlinearity.They are also stable,as confirmed by a defined nonlinear fidelity of an adiabatic evolution from the stability analysis.As nonreciprocal nonlinear models may be experimentally realized in various platforms,such as the classical platform of optical waveguides,where Kerr nonlinearity is naturally present,and the quantum platform of optical lattices with Bose-Einstein condensates,our analytical results may inspire further exploration of the interplay between nonlinearity and non-Hermiticity,particularly on high-order EPs,and benchmark the relevant simulations. 展开更多
关键词 skin discrete breather hierarchical power-law scaling double-exponential decay non-Hermitian skin effect high-order exceptional point Kerr nonlinearity
下载PDF
Microwave-Assisted Transition Metal Nanostructure Synthesis: Power-Law Signature Verification
20
作者 Victor J. Law Denis P. Dowling 《American Journal of Analytical Chemistry》 2023年第8期326-349,共24页
A power-law (y = cx<sup>n</sup>) signature between process energy budget (kJ) and process energy density (kJ·ml<sup>-1</sup>) of microwave-assisted synthesis of silver and gold nanostructu... A power-law (y = cx<sup>n</sup>) signature between process energy budget (kJ) and process energy density (kJ·ml<sup>-1</sup>) of microwave-assisted synthesis of silver and gold nanostructures has been recently described [Law and Denis. AJAC, 14(4), 149-174, (2023)]. This study explores this relation further for palladium, platinum, and zinc oxide nanostructures. Parametric cluster analysis and statistical analysis is used to test the power-law signature of over four orders of magnitude as a function of six microwave applicator-types metal precursor, non-Green Chemistry synthesis and claimed Green Chemistry. It is found that for the claimed Green Chemistry, process energy budget ranges from 0.291 to 900 kJ, with a residual error ranging between −33 to +25.9 kJ·ml<sup>-1</sup>. The non-Green Chemistry synthesis has a higher process energy budget range from 3.2 kJ to 3.3 MJ, with a residual error of −33.3 to +245.3 kJ·ml<sup>-1</sup>. It is also found that the energy profile over time produced by software controlled digestion applicators is poorly reported which leads to residual error problematic outliers that produce possible phase-transition in the power-law signature. The original Au and Ag database and new Pd, Pt and ZnO database (with and without problematic outliers) yield a global microwave-assisted synthesis power-law signature constants of c = 0.7172 ± 0.3214 kJ·ml<sup>-1</sup> at x-axes = 0.001 kJ, and the exponent, n = 0.791 ± 0.055. The information in this study is aimed to understand variations in historical microwave-assisted synthesis processes, and develop new scale-out synthesis through process intensification. 展开更多
关键词 Microwave-Assisted Synthesis PD Ag Pt AU ZnO power-law Residual Error Statistical Analysis Parametric Cluster Analysis
下载PDF
上一页 1 2 176 下一页 到第
使用帮助 返回顶部