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A method to model the effect of pre-existing cracks on P-wave velocity in rocks 被引量:6
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作者 Haimeng Shen Xiaying Li +1 位作者 Qi Li Haibin Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2020年第3期493-506,共14页
Crack closure is one of the reasons inducing changes of P-wave velocity of rocks under compression.In this context,a method is proposed to investigate the relationships among P-wave velocity,pre-existing cracks,and co... Crack closure is one of the reasons inducing changes of P-wave velocity of rocks under compression.In this context,a method is proposed to investigate the relationships among P-wave velocity,pre-existing cracks,and confining pressure based on the discrete element method(DEM).Pre-existing open cracks inside the rocks are generated by the initial gap of the flat-joint model.The validity of the method is evaluated by comparing the P-wave velocity tested on a sandstone specimen with numerical result.As the crack size is determined by the diameter of particles,the effects of three factors,i.e.number,aspect ratio,and orientation of cracks on the P-wave velocity are discussed.The results show that P-wave velocity is controlled by the(i.e.number) of open micro-cracks,while the closure pressure is determined by the aspect ratio of crack.The reason accounting for the anisotropy of P-wave velocity is the difference in crack number in measurement paths.Both of the number and aspect ratio of cracks can affect the responses of P-wave velocity to the applied confining pressure.Under confining pressure,the number of open cracks inside rocks will dominate the lowest P-wave velocity,and the P-wave velocity of the rock containing narrower cracks is more sensitive to the confining pressure.In this sense,crack density is difficult to be back-calculated merely by P-wave velocity.The proposed method offers a means to analyze the effect of pre-existing cracks on P-wave velocity. 展开更多
关键词 pre-existing cracks P-wave velocity Discrete element method(DEM) Anisotropic rock
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Effects of pre-existing cracks and infillings on strength of natural rocks--Cases of sandstone, argillite and basalt 被引量:4
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作者 Chen Cui Ivan Gratchev 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2020年第6期1333-1338,共6页
This study aims to examine the influence of pre-existing discontinuities on the strengths of four natural rocks of different origins.A series of unconfined compression tests was performed on specimens of two types of ... This study aims to examine the influence of pre-existing discontinuities on the strengths of four natural rocks of different origins.A series of unconfined compression tests was performed on specimens of two types of sandstones,argillite and basalt that contain open and filled cracks.It was found that the presence of cracks tends to decrease the overall strength for all studied rocks;however,the magnitude of strength reduction is related to the property of rock.The larger strength decrease was observed for the relatively harder argillite and basalt,compared to the softer sandstone.It was also found that the infill material could increase the strength of rock specimens,while the obtained strength depended on the characteristics of the fill material. 展开更多
关键词 pre-existing crack Rock strength Infill material Laboratory test
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Damage and failure characteristics of rock similar materials with pre-existing cracks 被引量:5
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作者 Xiaoyu Cheng 《International Journal of Coal Science & Technology》 EI 2019年第4期505-517,共13页
In order to further study the damage and failure mechanism for rock similar materials,this study investigated the mechanical properties and failure characteristics,law of damage space development,and damage evolution ... In order to further study the damage and failure mechanism for rock similar materials,this study investigated the mechanical properties and failure characteristics,law of damage space development,and damage evolution characteristics for rock similar materials with pre-existing cracks of varying length under uniaxial compression load.The equipment used in this study is the self-developed YYW-Ⅱ strain controlled unconfined compression apparatus and the PCIE-8 acoustic emission monitoring system.Results show that,as the length of pre-existing crack increases:(1) the peak and residual strength reduces,and the peak axial strain and the strain during the initial compression phase increases;(2) the major failure mode is changed from shear failure to tensile failure along a vertical plane that passes the middle of the pre-existing crack;(3) The damage increases during the stable and accelerated development stage,and the effect of the pre-existing cracks is more during the accelerated development stage than the stable development stage. 展开更多
关键词 pre-existing cracks ROCK similar materials Mechanical properties ACOUSTIC EMISSION LOCALIZATION DAMAGE EVOLUTION
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Plastic deformation mechanism transition of Ti/Ni nanolaminate with pre-existing crack:Molecular dynamics study 被引量:1
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作者 宿梦嘉 邓琼 +1 位作者 安敏荣 刘兰亭 《Chinese Physics B》 SCIE EI CAS CSCD 2020年第11期427-438,共12页
Tensile behaviors of Ti/Ni nanolaminate with model-I crack are investigated by molecular dynamics simulations.The Ti/Ni nanolaminates with center crack either in Ti layer or in Ni layer under different loading directi... Tensile behaviors of Ti/Ni nanolaminate with model-I crack are investigated by molecular dynamics simulations.The Ti/Ni nanolaminates with center crack either in Ti layer or in Ni layer under different loading directions are utilized to systematically study the mechanical performance of the cracked material.The results indicate that pre-existing crack dramatically changes the plastic deformation mechanism of the Ti/Ni nanolaminate.Unlike the initial plastic deformation originating from the interface or weak Ti layer of the crack-free samples,the plastic behavior of cracked Ti/Ni nanolaminate first occurs at the crack tip due to the local stress concentration.Subsequent plastic deformation is dominated by the interaction between the crack and interface.The Ti/Ni interface not only impedes the movement of the initial plastic deformation carriers(dislocation,slip band,and deformation twinning)from the crack tip,but also promotes the movement of interfacial dislocations in the tension process.Microstructure evolution analysis further confirms that the plastic deformation mechanism transition is ascribed to the orientation-dependent tensile behavior at the crack tip,which is intrinsically attributed to the anisotropy of the certain crystal structure and loading direction of the cracked Ti/Ni nanolaminate.In addition,by analyzing the effects of different plastic deformation carriers on crack propagation in specific crystal,it can be discovered that the interfacial dislocations moving towards the crack tip can further promote the crack growth. 展开更多
关键词 molecular dynamics Ti/Ni nanolaminate plastic deformation mechanisms crack propagation
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Stress tensor determination by modified hydraulic tests on pre-existing fractures:Method and stress constraints
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作者 Guiyun Gao Chenghu Wang Ke Gao 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第5期1637-1648,共12页
The hydraulic testing of pre-existing fractures(HTPF)is one of the most promising in situ stress measurement methods,particularly for three-dimensional stress tensor determination.However,the stress tensor determinati... The hydraulic testing of pre-existing fractures(HTPF)is one of the most promising in situ stress measurement methods,particularly for three-dimensional stress tensor determination.However,the stress tensor determination based on the HTPF method requires at least six tests or a minimum of 14-15 tests(under different conditions)for reliable results.In this study,we modified the HTPF method by considering the shear stress on each pre-existing fracture,which increased the number of equations for the stress tensor determination and decreased the number of tests required.Different shear stresses were attributed to different fractures by random sampling;therefore,the stress tensors were obtained by searching for the optimal solution using the least squares criterion based on the Monte Carlo method.Thereafter,we constrained the stress tensor based on the tensile strength criterion,compressive strength criterion,and vertical stress constraints.The inverted stress tensors were presented and analyzed based on the tensorial nature of the stress using the Euclidean mean stress tensor.Two stress-measurement campaigns in Weifang(Shandong Province,China)and Mercantour road tunnel(France)were implemented to highlight the validity and efficiency of the modified HTPF(M-HTPF)method.The results showed that the M-HTPF method can be applied for stress tensor inversion using only three to four tests on pre-existing fractures,neglecting the stress gradient.The inversion results were confined to relatively small distribution dispersions and were significantly reliable and stable due to the shear stresses on the fractures and the stress constraints employed.The M-HTPF method is highly feasible and efficient for complete stress tensor determination in a single borehole. 展开更多
关键词 Stress tensor Hydraulic tests on pre-existing fractures Mean stress Stress constraint Hydraulic fracturing
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Recent research progress in the mechanism and suppression of fusion welding-induced liquation cracking of nickel based superalloys 被引量:1
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作者 Zongli Yi Jiguo Shan +2 位作者 Yue Zhao Zhenlin Zhang Aiping Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期1072-1088,共17页
Nickel-based superalloys are extensively used in the crucial hot-section components of industrial gas turbines,aeronautics,and astronautics because of their excellent mechanical properties and corrosion resistance at ... Nickel-based superalloys are extensively used in the crucial hot-section components of industrial gas turbines,aeronautics,and astronautics because of their excellent mechanical properties and corrosion resistance at high temperatures.Fusion welding serves as an effective means for joining and repairing these alloys;however,fusion welding-induced liquation cracking has been a challenging issue.This paper comprehensively reviewed recent liquation cracking,discussing the formation mechanisms,cracking criteria,and remedies.In recent investigations,regulating material composition,changing the preweld heat treatment of the base metal,optimizing the welding process parameters,and applying auxiliary control methods are effective strategies for mitigating cracks.To promote the application of nickel-based superalloys,further research on the combination impact of multiple elements on cracking prevention and specific quantitative criteria for liquation cracking is necessary. 展开更多
关键词 nickel-based superalloy fusion welding liquation cracking cracking mechanism cracking suppression
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Cracks coalescence mechanism and cracks propagation paths in rock-like specimens containing pre-existing random cracks under compression 被引量:16
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作者 Hadi Haeri Kourosh Shahriar +1 位作者 Mohammad Fatehi Marji Parviz Moarefvand 《Journal of Central South University》 SCIE EI CAS 2014年第6期2404-2414,共11页
The mechanism of cracks propagation and cracks coalescence due to compressive loading of the brittle substances containing pre-existing cracks(flaws)was modeled experimentally using specially made rock-like specimens ... The mechanism of cracks propagation and cracks coalescence due to compressive loading of the brittle substances containing pre-existing cracks(flaws)was modeled experimentally using specially made rock-like specimens from Portland Pozzolana Cement(PPC).The breakage process of the specimens was studied by inserting single and double flaws with different inclination angles at the center and applying uniaxial compressive stress at both ends of the specimen.The first crack was oriented at 50° from the horizontal direction and kept constant throughout the analysis while the orientation of the second crack was changed.It is experimentally observed that the wing cracks are produced at the first stage of loading and start their propagation toward the direction of uniaxial compressive loading.The secondary cracks may also be produced in form of quasi-coplanar and/or oblique cracks in a stable manner.The secondary cracks may eventually continue their propagation in the direction of maximum principle stress.These experimental works were also simulated numerically by a modified higher order displacement discontinuity method and the cracks propagation and cracks coalescence were studied based on Mode I and Mode II stress intensity factors(SIFs).It is concluded that the wing cracks initiation stresses for the specimens change from 11.3 to 14.1 MPa in the case of numerical simulations and from 7.3 to 13.8 MPa in the case of experimental works.It is observed that cracks coalescence stresses change from 21.8 to 25.3 MPa and from 19.5 to 21.8 MPa in the numerical and experimental analyses,respectively.Comparing some of the numerical and experimental results with those recently cited in the literature validates the results obtained by the proposed study.Finally,a numerical simulation was accomplished to study the effect of confining pressure on the crack propagation process,showing that the SIFs increase and the crack initiation angles change in this case. 展开更多
关键词 裂纹扩展 传播路径 压缩载荷 机制 标本 聚结 数值模拟 岩样
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Characterization of alpine meadow surface crack and its correlation with root-soil properties
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作者 WU Yuechen ZHU Haili +5 位作者 ZHANG Yu ZHANG Hailong LIU Guosong LIU Yabin LI Guorong HU Xiasong 《Journal of Arid Land》 SCIE CSCD 2024年第6期834-851,共18页
Quantifying surface cracks in alpine meadows is a prerequisite and a key aspect in the study of grassland crack development.Crack characterization indices are crucial for the quantitative characterization of complex c... Quantifying surface cracks in alpine meadows is a prerequisite and a key aspect in the study of grassland crack development.Crack characterization indices are crucial for the quantitative characterization of complex cracks,serving as vital factors in assessing the degree of cracking and the development morphology.So far,research on evaluating the degree of grassland degradation through crack characterization indices is rare,especially the quantitative analysis of the development of surface cracks in alpine meadows is relatively scarce.Therefore,based on the phenomenon of surface cracking during the degradation of alpine meadows in some regions of the Qinghai-Tibet Plateau,we selected the alpine meadow in the Huangcheng Mongolian Township,Menyuan Hui Autonomous County,Qinghai Province,China as the study area,used unmanned aerial vehicle(UAV)sensing technology to acquire low-altitude images of alpine meadow surface cracks at different degrees of degradation(light,medium,and heavy degradation),and analyzed the representative metrics characterizing the degree of crack development by interpreting the crack length,length density,branch angle,and burrow(rat hole)distribution density and combining them with in situ crack width and depth measurements.Finally,the correlations between the crack characterization indices and the soil and root parameters of sample plots at different degrees of degradation in the study area were analyzed using the grey relation analysis.The results revealed that with the increase of degradation,the physical and chemical properties of soil and the mechanical properties of root-soil composite changed significantly,the vegetation coverage reduced,and the root system aggregated in the surface layer of alpine meadow.As the degree of degradation increased,the fracture morphology developed from"linear"to"dendritic",and eventually to a complex and irregular"polygonal"pattern.The crack length,width,depth,and length density were identified as the crack characterization indices via analysis of variance.The results of grey relation analysis also revealed that the crack length,width,depth,and length density were all highly correlated with root length density,and as the degradation of alpine meadows intensified,the underground biomass increased dramatically,forming a dense layer of grass felt,which has a significant impact on the formation and expansion of cracks. 展开更多
关键词 alpine meadow grassland degradation grassland cracks crack characterization index crack morphology root length density grey relation analysis
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Particle Discontinuous Deformation Analysis of Static and Dynamic Crack Propagation in Brittle Material
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作者 Zediao Chen Feng Liu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第5期2215-2236,共22页
Crack propagation in brittle material is not only crucial for structural safety evaluation,but also has a wideranging impact on material design,damage assessment,resource extraction,and scientific research.A thorough ... Crack propagation in brittle material is not only crucial for structural safety evaluation,but also has a wideranging impact on material design,damage assessment,resource extraction,and scientific research.A thorough investigation into the behavior of crack propagation contributes to a better understanding and control of the properties of brittle materials,thereby enhancing the reliability and safety of both materials and structures.As an implicit discrete elementmethod,the Discontinuous Deformation Analysis(DDA)has gained significant attention for its developments and applications in recent years.Among these developments,the particle DDA equipped with the bonded particle model is a powerful tool for predicting the whole process of material from continuity to failure.The primary objective of this research is to develop and utilize the particle DDAtomodel and understand the complex behavior of cracks in brittle materials under both static and dynamic loadings.The particle DDA is applied to several classical crack propagation problems,including the crack branching,compact tensile test,Kalthoff impact experiment,and tensile test of a rectangular plate with a hole.The evolutions of cracks under various stress or geometrical conditions are carefully investigated.The simulated results are compared with the experiments and other numerical results.It is found that the crack propagation patterns,including crack branching and the formation of secondary cracks,can be well reproduced.The results show that the particle DDA is a qualified method for crack propagation problems,providing valuable insights into the fracture mechanism of brittle materials. 展开更多
关键词 Discontinuous deformation analysis particle DDA crack propagation crack branching brittle materials
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Analytical solution for the effective elastic properties of rocks with the tilted penny-shaped cracks in the transversely isotropic background
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作者 Zheng-Qian Ma Xing-Yao Yin +2 位作者 Zhao-Yun Zong Yuan-Yuan Tan Ya-Ming Yang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期221-243,共23页
Seismic prediction of cracks is of great significance in many disciplines,for which the rock physics model is indispensable.However,up to now,multitudinous analytical models focus primarily on the cracked rock with th... Seismic prediction of cracks is of great significance in many disciplines,for which the rock physics model is indispensable.However,up to now,multitudinous analytical models focus primarily on the cracked rock with the isotropic background,while the explicit model for the cracked rock with the anisotropic background is rarely investigated in spite of such case being often encountered in the earth.Hence,we first studied dependences of the crack opening displacement tensors on the crack dip angle in the coordinate systems formed by symmetry planes of the crack and the background anisotropy,respectively,by forty groups of numerical experiments.Based on the conclusion from the experiments,the analytical solution was derived for the effective elastic properties of the rock with the inclined penny-shaped cracks in the transversely isotropic background.Further,we comprehensively analyzed,according to the developed model,effects of the crack dip angle,background anisotropy,filling fluid and crack density on the effective elastic properties of the cracked rock.The analysis results indicate that the dip angle and background anisotropy can significantly either enhance or weaken the anisotropy degrees of the P-and SH-wave velocities,whereas they have relatively small effects on the SV-wave velocity anisotropy.Moreover,the filling fluid can increase the stiffness coefficients related to the compressional modulus by reducing crack compliance parameters,while its effects on shear coefficients depend on the crack dip angle.The increasing crack density reduces velocities of the dry rock,and decreasing rates of the velocities are affected by the crack dip angle.By comparing with exact numerical results and experimental data,it was demonstrated that the proposed model can achieve high-precision estimations of stiffness coefficients.Moreover,the assumption of the weakly anisotropic background results in the consistency between the proposed model and Hudson's published theory for the orthorhombic rock. 展开更多
关键词 Effective elastic property Tilted crack Transverse isotropy Analytical solution crack opening displacement
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Effect of carbon material and surfactant on ink property and resulting surface cracks of fuel-cell microporous layers
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作者 Zhekun Chen Weitong Pan +2 位作者 Longfei Tang Xueli Chen Fuchen Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期1-12,共12页
Ensuring the consistency of electrode structure in proton-exchange-membrane fuel cells is highly desired yet challenging because of wide-existing and unguided cracks in the microporous layer(MPL). The first thing is t... Ensuring the consistency of electrode structure in proton-exchange-membrane fuel cells is highly desired yet challenging because of wide-existing and unguided cracks in the microporous layer(MPL). The first thing is to evaluate the homogeneity of MPL with cracks quantitatively. This paper proposes the homogeneity index of a full-scale MPL with an area of 50 cm~2, which is yet to be reported in the literature to our knowledge. Besides, the effects of the carbon material and surfactant on the ink and resulting MPL structure have been studied. The ink with a high network development degree produces an MPL with low crack density, but the ink with high PDI produces an MPL with low crack homogeneity. The polarity of the surfactant and the non-polarity of polytetrafluoroethylene(PTFE) are not mutually soluble,resulting in the heterogeneous PTFE distribution. The findings of this study provide guidelines for MPL fabrication. 展开更多
关键词 Proton-exchange-membrane fuel cell Microporous layer crack density crack homogeneity Polytetrafluoroethylene distribution SURFACTANT
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Solid-state NMR reveals that oxygen tri-clusters make glass highly crackresistant
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作者 Zhiwu Yu 《Magnetic Resonance Letters》 2024年第2期77-78,共2页
In a recent paper,advanced solid-state nuclear magnetic resonance(SSNMR)technology was employed to reveal the underlying mechanism contributing to the high hardness and exceptional resistance to fragmentation observed... In a recent paper,advanced solid-state nuclear magnetic resonance(SSNMR)technology was employed to reveal the underlying mechanism contributing to the high hardness and exceptional resistance to fragmentation observed in certain special glasses[1].This study utilized SSNMR to analyze the atomic-scale internal structure of glass,enabling the quantification of the fraction of three-coordinated oxygen([^((3))O]).The research findings demonstrate a quantitative relationship between[^((3))O]and the resistance of glass to crack initiation. 展开更多
关键词 crack resistance GLASS
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Automatic Road Tunnel Crack Inspection Based on Crack Area Sensing and Multiscale Semantic Segmentation
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作者 Dingping Chen Zhiheng Zhu +1 位作者 Jinyang Fu Jilin He 《Computers, Materials & Continua》 SCIE EI 2024年第4期1679-1703,共25页
The detection of crack defects on the walls of road tunnels is a crucial step in the process of ensuring travel safetyand performing routine tunnel maintenance. The automatic and accurate detection of cracks on the su... The detection of crack defects on the walls of road tunnels is a crucial step in the process of ensuring travel safetyand performing routine tunnel maintenance. The automatic and accurate detection of cracks on the surface of roadtunnels is the key to improving the maintenance efficiency of road tunnels. Machine vision technology combinedwith a deep neural network model is an effective means to realize the localization and identification of crackdefects on the surface of road tunnels.We propose a complete set of automatic inspection methods for identifyingcracks on the walls of road tunnels as a solution to the problem of difficulty in identifying cracks during manualmaintenance. First, a set of equipment applied to the real-time acquisition of high-definition images of walls inroad tunnels is designed. Images of walls in road tunnels are acquired based on the designed equipment, whereimages containing crack defects are manually identified and selected. Subsequently, the training and validationsets used to construct the crack inspection model are obtained based on the acquired images, whereas the regionscontaining cracks and the pixels of the cracks are finely labeled. After that, a crack area sensing module is designedbased on the proposed you only look once version 7 model combined with coordinate attention mechanism (CAYOLOV7) network to locate the crack regions in the road tunnel surface images. Only subimages containingcracks are acquired and sent to the multiscale semantic segmentation module for extraction of the pixels to whichthe cracks belong based on the DeepLab V3+ network. The precision and recall of the crack region localizationon the surface of a road tunnel based on our proposed method are 82.4% and 93.8%, respectively. Moreover, themean intersection over union (MIoU) and pixel accuracy (PA) values for achieving pixel-level detection accuracyare 76.84% and 78.29%, respectively. The experimental results on the dataset show that our proposed two-stagedetection method outperforms other state-of-the-art models in crack region localization and detection. Based onour proposedmethod, the images captured on the surface of a road tunnel can complete crack detection at a speed often frames/second, and the detection accuracy can reach 0.25 mm, which meets the requirements for maintenanceof an actual project. The designed CA-YOLO V7 network enables precise localization of the area to which a crackbelongs in images acquired under different environmental and lighting conditions in road tunnels. The improvedDeepLab V3+ network based on lightweighting is able to extract crack morphology in a given region more quicklywhile maintaining segmentation accuracy. The established model combines defect localization and segmentationmodels for the first time, realizing pixel-level defect localization and extraction on the surface of road tunnelsin complex environments, and is capable of determining the actual size of cracks based on the physical coordinatesystemafter camera calibration. The trainedmodelhas highaccuracy andcanbe extendedandapplied to embeddedcomputing devices for the assessment and repair of damaged areas in different types of road tunnels. 展开更多
关键词 Road tunnel crack inspection crack area sensing multiscale semantic segmentation CA-YOLO V7 DeepLab V3+
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Effects of orientation on the fatigue crack growth behaviors of the ZK60 magnesium alloy in air and PBS
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作者 Jiaqi Hu Zheng Liu +1 位作者 Zuoliang Ning Hong Gao 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第1期281-294,共14页
Strong anisotropic corrosion and mechanical properties caused by specimen orientations greatly limit the applications of wrought magnesium alloys.To investigate the influences of specimen orientation,the corrosion tes... Strong anisotropic corrosion and mechanical properties caused by specimen orientations greatly limit the applications of wrought magnesium alloys.To investigate the influences of specimen orientation,the corrosion tests and(corrosion)fatigue crack growth tests were conducted.The rolled and transverse surfaces of the materials show distinct corrosion rate differences in the stable corrosion stage,but the truth is the opposite for the initial stage of corrosion.In air,specimen orientations have a significant influence on the plastic deformation mechanisms near the crack tip,which results in different fatigue fracture surfaces and cracking paths.Compared with R-T specimens,N-T specimens show a slower fatigue crack growth(FCG)rate in air,which can be attributed to crack closure effects and deformation twinning near the crack tip.The corrosion environment will not significantly change the main plastic deformation mechanisms for the same type of specimen.However,the FCG rate in phosphate buffer saline(PBS)is one order of magnitude higher than that in air,which is caused by the combined effects of hydrogen-induced cracking and anodic dissolution.Owing to the similar corrosion rates at crack tips,the specimens with different orientations display close FCG rates in PBS. 展开更多
关键词 Magnesium alloy ORIENTATION CORROSION Fatigue crack growth
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Development and Catalytic Cracking Performance of Ultrastable Y Zeolite Rich in Secondary Pores
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作者 Li Jiaxing Wang Shengji +3 位作者 Sha Hao Wang Juan Zhou Lingping Wang Lixia 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第2期13-21,共9页
A novel ultra-stable zeolite, NSZ, rich in secondary pores was developed through the combination of gas-phase andmild hydrothermal methods. This zeolite was successfully tested in an industrial setting for the first t... A novel ultra-stable zeolite, NSZ, rich in secondary pores was developed through the combination of gas-phase andmild hydrothermal methods. This zeolite was successfully tested in an industrial setting for the first time in the world. The porestructure characteristics of the NSZ zeolite prepared for industrial use were analyzed and characterized using BET. The resultsindicate a significant increase in the secondary pore volume of NSZ zeolite compared to the existing ultra-stable zeolite HSZ-5, which is produced through a conventional gas-phase method. The average secondary pore volume to total pore volume ratioin NSZ zeolite was found to be 58.96% higher. The catalytic cracking performance of NSZ zeolite was evaluated. The resultsshowed that the NSC-LTA catalyst, with NSZ as the active component, outperformed the HSC-LTA catalyst with HSZ-5 zeolitein terms of obtaining more high-value products (gasoline and liquefied petroleum gas) during the hydrogenated light cycle oilprocessing. Additionally, the NSC-LTA catalyst showed a significant improvement in coke selectivity. 展开更多
关键词 GAS-PHASE ultra-stable ZEOLITE CATALYST catalytic cracking
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Unraveling engineering disturbance effects on deformation in red-bed mudstone railway cuttings:incorporating crack-facilitated moisture diffusion
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作者 HUANG Kang DAI Zhangjun +3 位作者 YAN Chengzeng YAO Junkai CHI Zecheng CHEN Shanxiong 《Journal of Mountain Science》 SCIE CSCD 2024年第5期1663-1682,共20页
Red-bed mudstone, prevalent in southwest China, poses a formidable challenge due to its hydrophilic clay minerals, resulting in expansion, deformation, and cracking upon exposure to moisture. This study addresses upli... Red-bed mudstone, prevalent in southwest China, poses a formidable challenge due to its hydrophilic clay minerals, resulting in expansion, deformation, and cracking upon exposure to moisture. This study addresses uplift deformation disasters in high-speed railways by employing a moisture diffusion-deformation-fracture coupling model based on the finite-discrete element method(FDEM). The model integrates the influence of cracks on moisture diffusion. The investigation into various excavation depths reveals a direct correlation between depth and the formation of tensile cracks at the bottom of the railway cutting. These cracks expedite moisture migration, significantly impacting the temporal and spatial evolution of the moisture field. Additionally, crack expansion dominates hygroscopic deformation, with the lateral coordinate of the crack zone determining peak vertical displacement. Furthermore, key factors influencing deformation in railway cuttings, including the swelling factor and initial moisture content at the bottom of the cutting, are explored. The number of tensile and shear cracks increases with greater excavation depth, particularly concerning shear cracks. Higher swelling factors and initial moisture contents result in an increased total number of cracks, predominantly shear cracks. Numerical calculations provide valuable insights, offering a scientific foundation and directional guidance for the precise prevention, control, prediction, and comprehensive treatment of mudstone-related issues in high-speed railways. 展开更多
关键词 Red-bed mudstone Railway cutting FDEM Moisture diffusion DEFORMATION crack
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HZSM-5 zeolites undergoing the high-temperature process for boosting the bimolecular reaction in n-heptane catalytic cracking
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作者 Chenggong Song Zhenzhou Ma +6 位作者 Xu Hou Hao Zhou Huimin Qiao Changchang Tian Li Yin Baitang Jin Enxian Yuan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期136-144,共9页
High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,... High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,N2physisorption,27Al magic angle spinning nuclear magnetic resonance(MAS NMR),and temperature-programmed desorption of ammonia results indicated that the hightemperature treatment at 650℃ hardly affected the inherent crystal and texture of HZSM-5zeolites but facilitated the conversion of framework Al to extra-framework Al,reducing the acid site and enhancing the acid strength.Moreover,the high-temperature treatment improved the performance of HZSM-5 zeolites in n-heptane catalytic cracking,promoting the conversion and light olefins yield while inhibiting coke formation.Based on the kinetic and mechanism analysis,the improvement of HZSM-5 performance caused by high-temperature treatment has been attributed to the formation of extra-framework Al,which enhanced the acid strength,facilitated the bimolecular reaction,and promoted the entropy change to overcome a higher energy barrier in n-heptane catalytic cracking. 展开更多
关键词 HZSM-5 N-HEPTANE Catalytic cracking High-temperature treatment Extra-framework Al
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Evolution model and failure mechanisms of rainfall-induced cracked red clay slopes:insights from Xinshao County,China
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作者 JIAO Weizhi ZHANG Ming +4 位作者 LI Peng XIE Junjin PANG Haisong LIU Fuxing YANG Long 《Journal of Mountain Science》 SCIE CSCD 2024年第3期867-881,共15页
Red clay landslides are widely distributed worldwide,resulting in severe loss of life and property.Although rainfall-induced red clay slopes have received extensive attention,the role of cracks in the evolutionary pro... Red clay landslides are widely distributed worldwide,resulting in severe loss of life and property.Although rainfall-induced red clay slopes have received extensive attention,the role of cracks in the evolutionary process of red clay slopes and their connection to failure mechanisms is still poorly understood.A comprehensive approach integrating field investigation,laboratory tests,and numerical simulations was conducted to study the 168 red clay landslides in Xinshao County,China.The results show that red clay is prone to forming cracks at high moisture content due to its low swelling and high shrinkage properties.The failure mode of red clay slopes can be summarized in three stages:crack generation,slope excavation,and slope failure.Furthermore,the retrospective analysis and numerical simulations of the typical landslide in Guanchong indicated that intense rainfall primarily impacts the shallow layer of soil within approximately 0.5 m on the intact slope.However,cracks change the pattern of rainfall infiltration in the slope.Rainwater infiltrates rapidly through the preferential channels induced by the cracks rather than uniformly and slowly from the slope surface.This results in a significant increase in both the depth of infiltration and the saturated zone area of the cracked slope,reaching 3.8 m and 36.2 m^(2),respectively.Consequently,the factor of safety of the slope decreases by 13.4%compared to the intact slope,ultimately triggering landslides.This study can provide valuable insights into understanding the failure mechanisms of red clay slopes in China and other regions with similar geological settings. 展开更多
关键词 Red clay slopes cracks Preferential flow Failure mechanism
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Effect of icosahedral phase formation on the stress corrosion cracking(SCC)behaviors of the as-cast Mg-8%Li(in wt.%)based alloys
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作者 Shuo Wang Daokui Xu +2 位作者 Dongliang Wang Zhiqiang Zhang Baojie Wang 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第1期225-236,共12页
Through exploring the stress corrosion cracking(SCC)behaviors of the as-cast Mg-8%Li and Mg-8%Li-6%Zn-1.2%Y alloys in a 0.1 M NaCl solution,it revealed that the SCC susceptibility index(I_(SCC))of the Mg-8%Li alloy wa... Through exploring the stress corrosion cracking(SCC)behaviors of the as-cast Mg-8%Li and Mg-8%Li-6%Zn-1.2%Y alloys in a 0.1 M NaCl solution,it revealed that the SCC susceptibility index(I_(SCC))of the Mg-8%Li alloy was 47%,whilst the I_(SCC)of the Mg-8%Li-6%Zn-1.2%Y alloy was 68%.Surface,cross-sectional and fractography observations indicated that for the Mg-8%Li alloy,theα-Mg/β-Li interfaces acted as the preferential crack initiation sites and propagation paths during the SCC process.With regard to the Mg-8%Li-6%Zn-1.2%Y alloy,the crack initiation sites included the I-phase and the interfaces of I-phase/β-Li andα-Mg/β-Li,and the preferential propagation paths were the I-phase/β-Li andα-Mg/β-Li interfaces.Moreover,the SCC of the two alloys was concerned with hydrogen embrittlement(HE)mechanism. 展开更多
关键词 Magnesium-lithium alloy Stress corrosion cracking I-phase Fracture analysis
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A phase-field model for simulating the propagation behavior of mixed-mode cracks during the hydraulic fracturing process in fractured reservoirs
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作者 Dan ZHANG Liangping YI +4 位作者 Zhaozhong YANG Jingqiang ZHANG Gang CHEN Ruoyu YANG Xiaogang LI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第5期911-930,共20页
A novel phase-field model for the propagation of mixed-mode hydraulic fractures,characterized by the formation of mixed-mode fractures due to the interactions between fluids and solids,is proposed.In this model,the dr... A novel phase-field model for the propagation of mixed-mode hydraulic fractures,characterized by the formation of mixed-mode fractures due to the interactions between fluids and solids,is proposed.In this model,the driving force for the phase field consists of both tensile and shear components,with the fluid contribution primarily manifesting in the tension driving force.The displacement and pressure are solved simultaneously by an implicit method.The numerical solution's iterative format is established by the finite element discretization and Newton-Raphson(NR)iterative methods.The correctness of the model is verified through the uniaxial compression physical experiments on fluid-pressurized rocks,and the limitations of the hydraulic fracture expansion phase-field model,which only considers mode I fractures,are revealed.In addition,the influence of matrix mode II fracture toughness value,natural fracture mode II toughness value,and fracturing fluid injection rate on the hydraulic fracture propagation in porous media with natural fractures is studied. 展开更多
关键词 mixed-mode crack hydraulic fracturing poro-elasticity phase-field method(PFM)
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