A review of interaction mechanisms and microscopic simulation methods for CO_(2)-water-rock system

This work systematically reviews the complex mechanisms of CO_(2)-water-rock interactions,microscopic simulations of reactive transport(dissolution,precipitation and precipitate migration)in porous media,and microscopic simulations of CO_(2)-water-rock system.The work points out the key issues in current research and provides suggestions for future research.After injection of CO_(2) into underground reservoirs,not only conventional pressure-driven flow and mass transfer processes occur,but also special physicochemical phenomena like dissolution,precipitation,and precipitate migration.The coupling of these processes causes complex changes in permeability and porosity parameters of the porous media.Pore-scale microscopic flow simulations can provide detailed information within the three-dimensional pore and throat space and explicitly observe changes in the fluid-solid interfaces of porous media during reactions.At present,the research has limitations in the decoupling of complex mechanisms,characterization of differential multi-mineral reactions,precipitation generation mechanisms and characterization(crystal nucleation and mineral detachment),simulation methods for precipitation-fluid interaction,and coupling mechanisms of multiple physicochemical processes.In future studies,it is essential to innovate experimental methods to decouple“dissolution-precipitation-precipitate migration”processes,improve the accuracy of experimental testing of minerals geochemical reaction-related parameters,build reliable characterization of various precipitation types,establish precipitation-fluid interaction simulation methods,coordinate the boundary conditions of different physicochemical processes,and,finally,achieve coupled flow simulation of“dissolution-precipitation-precipitate migration”within CO_(2)-water-rock systems.

Unexpected Diversity in Ecosystem Nutrient Responses to Experimental Drought in Temperate Grasslands

The responses of ecosystem nitrogen (N) and phosphorus (P) to drought are an important component of globalchange studies. However, previous studies were more often based on site-specific experiments, introducing a significantuncertainty to synthesis and site comparisons. We investigated the responses of vegetation and soil nutrientsto drought using a network experiment of temperate grasslands in Northern China. Drought treatment (66%reduction in growing season precipitation) was imposed by erecting rainout shelters, respectively, at the driest,intermediate, and wettest sites. We found that vegetation nutrient concentrations increased but soil nutrient concentrationsdecreased along the aridity gradient. Differential responses were observed under experimentaldrought among the three grassland sites. Specifically, the experimental drought did not change vegetation andsoil nutrient status at the driest site, while strongly reduced vegetation but increased soil nutrient concentrationsat the site with intermediate precipitation. On the contrary, experimental drought increased vegetation N concentrationsbut did not change vegetation P and soil nutrient concentrations at the wettest site. In general, the differentialeffects of drought on ecosystem nutrients were observed between manipulative and observationalexperiments as well as between sites. Our research findings suggest that conducting large-scale, consistent, andcontrolled network experiments is essential to accurately evaluate the effects of global climate change on terrestrialecosystem bio-geochemistry.

Recognition of Organizational Morphology of Mesoscale Convective Systems Using Himawari-8 Observations

The onset,evolution,and propagation processes of convective cells can be reflected by the organizational morphology of mesoscale convective systems(MCSs),which are key factors in determining the potential for heavy precipitation.This paper proposed a method for objectively classifying and segmenting MCSs using geosynchronous satellite observations.Validation of the product relative to the classification in radar composite reflectivity imagery indicates that the algorithm offers skill for discriminating between convective and stratiform areas and matched 65%of convective area identifications in radar imagery with a false alarm rate of 39%and an accuracy of 94%.A quantitative evaluation of the similarity between the structures of 50 MCSs randomly obtained from satellite and radar observations shows that the similarity was as high as 60%.For further testing,the organizational modes of the MCS that caused the heavy precipitation in Northwest China on August 21,2016(hereinafter known as the“0821”rainstorm)were identified.It was found that the MCS,accompanied by the“0821”rainstorm,successively exhibited modes of the isolated cell,squall line with parallel stratiform(PS)rain,and non-linear system during its life cycle.Among them,the PS mode might have played a key role in causing this flooding.These findings are in line with previous studies.

Ge and Cu recovery from precipitating vitriol supernatant in zinc plant

A novel technology using Fe powder as reducing agent for Ge and Cu recovery from precipitating vitriol supernatant in Zn hydrometallurgical plant was investigated. The results show that reaction time, temperature, agitation speed, initial pH value of solution and the amount of reducing Fe have significant effects on recovering Ge and Cu, and the optimum process operating parameters are established as follows： time 120 min, initial pH value 1.5, the dosage of reducing Fe powder 4 g/L, agitation speed 600 r/min and temperature 80 °C. Under these experimental conditions, the recovery ratios of Ge and Cu from precipitating vitriol supernatant in Zn hydrometallurgical plant can reach 96% and 100%, respectively. The content of Ge in the reduced residue reaches up to 2.06% （mass fraction）, indicating that the separation and enrichment of Ge from the Zn sulfate solution is realized. The grade of Ge and Cu can reach up to 4.88% and 56.75%, respectively, when the reduced residue is further processed.

Artificial Precipitation Enhancement Weather System and the Operation Timing in Shenyang Area

By using the mathematical statistics and classification,the artificial precipitation enhancement cases in Shenyang area were analyzed.The results showed that the precipitation enhancement weather systems mainly included the northeast cold vortex,high-altitude trough,North China low-pressure,high-pressure rear and cold front cloud system.The appropriate height of precipitation enhancement was about 3 000-6 000 m in the middle and upper part of the cloud layer.The timing of precipitation enhancement should be in the radar's monitoring.The systems moved slowly or maintained stably in the developing or mature stages.The aircraft rainfall enhancement should be used in the stable and deep cloud layers.The rocket and antiaircraft gun rainfall enhancement should be used in the unstable move.

Practice and analysis of recycling non-drinking water from air-condition and reverse-osmosis system into rainwater collection system

This paper is based on the rainwater collection project in the retrofit of the Dongyi teaching block in Zhejiang University Xixi Campus.The analysis incorporates the local meteorological data, recycling water utilization, and precipitation adjustment.The rainwater collection system in this program also adds the condensation water from the heating, ventilation and air conditioning （ HVAC） system and the concentration from the reverse-osmosis system used for watering greens and supplying waterscapes.By calculating, the quantity of the HVAC condensation water in summer is 3.48 m3/d, and the quantity of the reverse-osmosis concentrated water is 198 to 396 L/d.This method solves the water shortage caused by high evaporation in summer and low precipitation in winter.Supported by empirical monitoring data, the proposed method significantly increases the economic efficiency of the system during the summer period.

The Research about A Regional Drought Identifying System Based on Dynamic Drought Index

With the data of daily precipitation and daily evaporation,dynamic drought index was calculated and compared with the identification standard of drought grade to qualify the severity of drought.According to the dynamic drought index,a regional drought identifying system was developed for the watershed between the reach of the Yangtze River and Huaihe River in Anhui Province by using VC++ working platform and Access database.This drought identifying system would be very useful to forecast and early warn the happening of drought in this area.

A method for calculation of ion distribution in reaction system forming hydroxide

A formula was proposed to calculate the distribution of metal ions quantitatively in chemical reaction system forming hydroxide where precipitation and complex are formed together. The effects of some factors on formation of precipitation and complex were investigated, and the corresponding precipitation rates of zinc, iron （III）, aluminum, copper and magnesium were calculated. As a result, it shows that the proposed formula is reliable. By the proposed formula, the existence state of metal ions in hydroxides reaction system with any metal ions can be well described and the effects of some factors on the distribution of metal ions were determined.

Influence of flue gas cleaning system on characteristics of PM_(2.5)emission from coal-fired power plants

This study investigated the influence of precipitators and wet flue gas desulfurization equipment on characteristics of PM_(2.5)emission from coal-fired power stations.We measured size distribution and removal efficiencies,including hybrid electrostatic precipitator/bag filters(ESP/BAGs)which have rarely been studied.A bimodal distribution of particle concentrations was observed at the inlet of each precipitator.After the precipitators,particle concentrations were significantly reduced.Although a bimodal distribution was still observed,all peak positions shifted to the smaller end.The removal efficiencies of hybrid ESP/BAGs reached 99%for PM_(2.5),which is considerably higher than those for other types of precipitators.In particular,the influence of hybrid ESP/BAG operating conditions on the performance of dust removal was explored.The efficiency of hybrid ESP/BAGs decreased by 1.9%when the first electrostatic field was shut down.The concentrations and distributions of particulate matter were also measured in three coal-fired power plants before and after desulfurization devices.The results showed diverse removal efficiencies for different desulfurization towers.The reason for the difference requires further research.We estimated the influence of removal technology for particulate matter on total emissions in China.Substituting ESPs with hybrid ESP/BAGs could reduce the total emissions to 104.3 thousand tons,with 47.48 thousand tons of PM_(2.5).

Conserved Quantities and Conformal Mechanico-Electrical Systems

The conformal meehanico-electrical systems are presented by infinitesimal point transformations of time and generalized coordinates. The necessary and suflleient conditions that the eonformal meehanieo-eleetrieal systems possess Lie symmetry are given. The Noether conserved quantities of the eonformal meehanieo-eleetrieal systems are obtained from Lie symmetries.

Evapotranspiration and Its Energy Exchange in Alpine Meadow Ecosystem on the Qinghai-Tibetan Plateau

To understand the water and energy exchange on the Qinghai-Tibetan Plateau, we explored the characteristics of evapotranspiration （ET） and energy fluxes from 2002 to 2005 over a Kobresia meadow ecosystem using the eddy covariance method. The ratio of annual ET to precipitation （P） of meadow ecosystem was about 60%, but varied greatly with the change of season from summer to winter. The annual ET/P in meadow was lower than that in shrub, steppe and wetland ecosystems of this plateau. The incident solar radiation （Rs） received by the meadow was obviously higher than that of lowland in the same latitude; however the ratio of net radiation （Rn） to Rs with average annual value of 0.44 was significantly lower than that in the same latitude. The average annual ET was about 390 mm for 2002-2005, of which more than 80% occurred in growing season from May to September. The energy consumed on the ET was about 44% of net radiation in growing season, which was lower than that of shrub, steppe and wetland on this plateau. This study demonstrates that the Kobresia meadow may prevent the excessive water loss through evapotranspiration from the ecosystem into the atmosphere in comparison to the shrub, steppe and wetland ecosystems of the Qinghai-Tibetan Plateau.

Temperature and Precipitation Suitability Evaluation for the Winter Wheat and Summer Maize Cropping System in the Huang-Huai-Hai Plain of China

The Huang-Huai-Hai Plain is the most important winter wheat and maize production region in China.In response to the increasing population pressure,the Chinese authorities strongly invested in improving the irrigation systems and increasing ground and surface water exploitation within the plain to increase the crop productivity.This resulted in a reduction of water resource availability and in turn indirectly affected the suitability of various agricultural ecosystems in the plain.The main purpose of this study was to review the suitability of temperature and precipitation for the winter wheat and summer maize cropping system in the Huang-Huai-Hai Plain,in order to provide a preliminary irrigation scheme.This analysis provides a first attempt to enhance the water resource management as well as to increase the water use efficiency.For this aim,a GIS-based multicriteria analysis procedure has been developed consisting of（1） definition of objectives（evaluated entities） and database building;（2） definition of evaluation criteria;（3） standardization of the criteria;（4） combination of the criteria;（5） classification of the objectives;and（6） integration of the objectives.The land suitability classification maps were transformed into maps of required irrigation amounts for each growing stage of the winter wheat and summer maize cropping system.The study also exemplified the limitations and proposed future research activities that will improve the detail and accuracy of the evaluation results.

Wigner Functions for Non-Hamiltonian Systems on Noncommutative Space

We propose a modified form of Wigner functions for generic non-Hamiltonian systems on noncommutative space and prove that it satisfies the corresponding ＊-genvalue equation. In addition, as an example, we derive exact energy spectra and Wigner functions for a non-Hamiltonian toy model on the noncommutative space.

A （2＋1）-Dimensional Displacement Shallow Water Wave System

A new （2＋1）-dimensional shallow water wave system, the （2＋1）-dimensional displacement shallow water wave system （2DDSWWS）, is constructed by applying variational principle of the analytic mechanics under the Lagrange coordinates. The general travelling wave solution is expressed as an elliptic integral. A special case is explicitly expressed by the Jacobi elliptic function which is a generalization of the solitary wave solution. Compared with some traditional （2＋1）-dimensional shallow water wave systems such as the Kadomtsev Petviashvili （KP） description under the Euler coordinates, the 2DDSWWS has some its own advantages. In addition, the KP equation can also be derived from the 2DDSWWS under the weak two-dimensional long-wave approximation.

Stable and metastable phase equilibria in binary Mg-Gd system: A comprehensive understanding aided by CALPHAD modeling

In this paper,a comprehensive understanding of stable and metastable phase equilibria in binary Mg-Gd system was conducted with an aid of the CALculation of PHAse Diagram(CALPHAD)modeling.Firstly,thermodynamic descriptions of all the stable phases in the Mg-Gd system were re-assessed by considering all the experimental data in the literature.The discrepancy between the phase equilibria and thermochemical properties existing in the previous assessments was eliminated,and the better agreement with the experimental data was achieved in the present assessment.Secondly,the Gibbs energies for metastable β"-Mg3Gd and β"-Mg7Gd were constructed based on the first-principles and CALPHAD computed results as well as their correlation,and then incorporated into the CALPHAD descriptions.The model-predicted solvuses of(Mg)in equilibrium with the metastable β"-Mg7Gd and β'-Mg7Gd compounds showed very good agreement with the limited experimental data.Finally,the presently obtained thermodynamic descriptions of both stable and metastable phases in the binary Mg-Gd system were further validated by realizing the quantitative Scheil-Gulliver solidification simulations of 5 as-cast Mg-Gd alloys,and the successful prediction of the precipitation sequences in Mg-15Gd and Mg-12Gd alloys during the aging process.

Responses of gross primary productivity to different sizes of precipitation events in a temperate grassland ecosystem in Inner Mongolia, China

Changes in the sizes of precipitation events in the context of global climate change may have profound impacts on ecosystem productivity in arid and semiarid grasslands. However, we still have little knowledge about to what extent grassland productivity will respond to an individual precipitation event. In this study, we quantified the duration, the maximum, and the time-integrated amount of the response of daily gross primary productivity (GPP) to an individual precipitation event and their variations with different sizes of precipitation events in a typical temperate steppe in Inner Mongolia, China. Results showed that the duration of GPP-response (τR) and the maximum absolute GPP-response (GPPmax) increased linearly with the sizes of precipitation events (Pes), driving a corresponding increase in time-integrated amount of the GPP-response (GPPtotal) because variations of GPPtotal were largely explained by τR and GPPmax. The relative contributions of these two parameters to GPPtotal were strongly Pes-dependent. The GPPmax contributed more to the variations of GPPtotal when Pes was relatively small (<20 mm), whereas τR was the main driver to the variations of GPPtotal when Pes was relatively large. In addition, a threshold size of at least 5 mm of precipitation was required to induce a GPP-response for the temperate steppe in this study. Our work has important implications for the modeling community to obtain an advanced understanding of productivity-response of grassland ecosystems to altered precipitation regimes.

A Single Photon Imaging System Based on Wedge and Strip Anodes

A new prototype of single photon imaging system based on wedge and strip anodes is developed. The prototype can directly measure the intensity and position information for an ultra-weak radiant source which takes on the character of single photons. The image of the ultra-weak radiant source can be reconstructed with a wedge and strip anodes detector and an electronic readout subsystem by photon counting and photon position sensitive detecting in a period of time. With proper evaluation, the prototype reveals a spatial resolution superior to 150μm, a 66-kHz maximal counting rate and a dark-count below 0.67 count /cm^2 s.

Last Multiplier of Generalized Hamilton System

We study an application of the Jacobi last multiplier to a generalized Hamilton system. A partial differential equation on the last multiplier of the system is established. The last multiplier can be found by the equation. If the quantity of integrals of the system is sufficient, the solution of the system can be found by the last multiplier.

Simulation of Quasi-Linear Mesoscale Convective Systems in Northern China：Lightning Activities and Storm Structure

Two intense quasi-linear mesoscale convective systems（QLMCSs） in northern China were simulated using the WRF（Weather Research and Forecasting） model and the 3D-Var（three-dimensional variational） analysis system of the ARPS（Advanced Regional Prediction System） model.A new method in which the lightning density is calculated using both the precipitation and non-precipitation ice mass was developed to reveal the relationship between the lightning activities and QLMCS structures.Results indicate that,compared with calculating the results using two previous methods,the lightning density calculated using the new method presented in this study is in better accordance with observations.Based on the calculated lightning densities using the new method,it was found that most lightning activity was initiated on the right side and at the front of the QLMCSs,where the surface wind field converged intensely.The CAPE was much stronger ahead of the southeastward progressing QLMCS than to the back it,and their lightning events mainly occurred in regions with a large gradient of CAPE.Comparisons between lightning and non-lightning regions indicated that lightning regions featured more intense ascending motion than non-lightning regions;the vertical ranges of maximum reflectivity between lightning and non-lightning regions were very different;and the ice mixing ratio featured no significant differences between the lightning and non-lightning regions.

Thermodynamic analysis for separation of vanadium and chromium in V(Ⅳ)-Cr(Ⅲ)-H_2O system

To recycle vanadium and chromium from the V?Cr-bearing reducing slag,the thermodynamics of separating V(IV)and Cr(III)at 298 K was summarized in the form of potential-pH diagram and activity-pH diagram.The potential-pH diagrams of V-Mn-H2O and Cr-Mn-H2O systems show that the electrode potential of MnO2/Mn2+is higher than that of VO2+/VO2+but lower than that of Cr2O7 2-/Cr3+,which proves that it is feasible to selectively oxidize low valent vanadium using MnO2.The activity-pH diagrams of V(V)-H2O and Cr(III)-H2O systems show that the precipitation pH of V(V)is far lower than that of Cr(III),and therefore V(V)and Cr(III)can be separated through precipitation method.Based on the thermodynamic analysis,the flowsheet of recovery of vanadium and chromium from the V-Cr-bearing reducing slag is designed.