Simulation of pre-precipitation in Ni_(75)Al_(14)Mo_(11) alloy by microscopic phase-field model

The early precipitation process of Ni（75）Al（14）Mo（11） alloy was simulated by microscopic phase-field model at different temperatures.The microstructure of the alloy,the precipitation time of Llo structure and occupation probability of the three kinds of atoms were investigated.It is indicated that the non-stoichiometric Ll0（Ⅰ/Ⅱ） phases are found in the precipitation process.With the temperature increasing,the appearance time of Ll0 is brought forward.The Ll0（Ⅱ） structure always precipitates earlier than the Ll0（Ⅰ） structure.Compared with lower temperature,higher temperature brings the formation time of Ll0 phase forward and makes Ll0 phase have a higher order degree.But lower temperature shortens the process time of the Ll0 phase to the Ll2 phase.Al and Mo atoms tend to occupy γ site,Ni atom tends to occupy a and β sites.At the same temperature,Al atom has stronger occupation ability than Mo atom in the same site.Ni,Al and Mo collectively form the composited Ll2 structure.

Phenomena of Periodic Precipitaion in Rare Earth-Cholate Diffusion Systems

The precipitate patterns were studied in rare earthcholate diffusion systems. The corresponding precipitates were characterized by Forie Transformed Infrared(FTIR) and Extended XRay Absorption Fine Structure(EXAFS) spectroscopy. The experimental results indicate that rare earth ions tend to produce periodic precipitation, and the pattern precipitates are just the corresponding rare earth cholate complexes.

Study on the Variation Characteristics of Precipitation Concentration Degree in Guangxi under the Background of Global Climate Becoming Warm

Based on the daily precipitation data of 87 meteorological observation stations in Guangxi during 1961-2008,the variation characteristics of precipitation concentration degree(PCD) in Guangxi were counted and analyzed by using Monte Carlo test method.The results showed that the climate warming in most areas of Guangxi was very obvious,and the annual precipitation concentration degree increased gradually from the northeast to the southwest in Guangxi.The precipitation concentration period was from the middle of April to the end of August and delayed from the northeast to the southwest in Guangxi.In the background which the global climate became warm,the annual precipitation in most areas of Guangxi had the trend which the precipitation concentrated strengthening.It was said that the probability of flood disaster had the increase trend.The precipitation concentration period had the earlier trend,which was more obvious in the north than in the south of Guangxi.The rainstorm concentration degree in the northwest of Guangxi and few parts had the decrease trend and had the increase trend in other areas.It was said that the probabilities of flood and mud-rock flow disasters increased.The rainstorm concentration periods in most areas had the later trend.

Analysis of Intra-annual Heterogeneous Characteristics of Precipitation in Shaoguan City

Based on the daily precipitation data between 1965 and 2009 from 8 rainfall stations in Shaoguan City,the indexes of precipitation concentration degree（ PCD） and precipitation concentration period（ PCP） were calculated. And then inverse distance weighted（ IDW） interpolation method was used to analyze the heterogeneous distribution characteristics of inter-annual precipitation by introducing the spatial distribution of annual mean values,variable coefficients,correlation coefficients with annual precipitation,change trends and composite analysis. The results showed that PCD was mainly decreasing from southeast to northwest in spatial distribution,long-term average annual values of PCP were distributed in the first ten days of June at most region. Annual precipitation increased as PCD increased in southern region,but the change trend was the opposite in northern region. Annual precipitation increased as PCP lagged in most region. PCD and PCP mainly appeared upward trend. Composite analysis of PCD in more-precipitation years was similar to less-precipitation years in spatial distribution,but the PCD in less-precipitation years was higher.Seen from the mean in the whole region,PCP in more-precipitation years lagged about 20 days behind those in less-precipitation years. The research can provide basis for the production of agriculture and industry as well as disaster prevention and reduction.

CHARACTERISTICS OF RAINFALL VARIATION OVER EAST CHINA FOR THE LAST 50 YEARS AND THEIR RELATIONSHIP WITH DROUGHTS AND FLOODS

With the precipitation data of 113 stations in East China during the last 50 years,the characteristics of the precipitation,including Precipitation Concentration Degree (PCD) and Precipitation Concentration Period (PCP) and their tendencies,are analyzed.The results show that the PCD in the northern part of the region is markedly higher than that in the southern part,but the PCP in the south is much earlier than that in the north by about one and a half months,which displays significant regional differences in precipitation.With the global warming,precipitation over East China shows an increasing tendency,but PCD displays a trend that is neither increasing nor decreasing.At the same time,the PCP is later than before,which can be mainly found in Jiangxi and southern Henan provinces.As a result,there are strong associations between the precipitation,PCD and PCP,which can be shown in the years with more precipitation,stronger PCD and later-than-usual PCP.In a word,the abnormal distribution of precipitation,PCP,and PCD over East China results in more extreme events of precipitation and more droughts and floods.

Analysis on Change Characteristics of PCD and PCP in Beijiang River Basin

Based on the daily precipitation data between 1965 and 2009 from 18 rainfall stations in Guangdong Beijiang River basin and the definitions of Precipitation Concentration Degree(PCD) and Precipitation Concentration Period(PCP),the inhomogeneous distribution characteristics of interannual precipitation were analyzed by introducing the spatial distribution of annual mean values,variable coefficients,correlation coefficients between annual precipitation,change trends and composite analysis. The results showed that(1) PCD mainly decreased from south to north in spatial distribution; PCP was earlier in most of north-central basin,but relatively later in southern basin.(2) Annual precipitation would increase if PCD decreased in most of river basin,and annual precipitation would decrease as PCP lagged in southern basin,but the change trend was the opposite in northern basin.(3) PCD and PCP mainly showed insignificant upward trend in the entire basin by Mann-Kendall test.

Rhythmic precipitate patterns and fractal structure

Liesegang patterns of parallel precipitate bands are obtained when solutions containing co-precipitate ions interdiffuse in a 1D gel matrix.The sparingly soluble salt formed,displays a beautiful stratification of discs of precipitate perpendicular to the 1D tube axis.The Liesegang structures are analyzed from the viewpoint of their fractal nature.Geometric Liesegang patterns are constructed in conformity with the well-known empirical laws such as the time,band spacing and band width laws.The dependence of the band spacing on the initial concentrations of diffusing（outer）and immobile（inner）electrolytes（A0 and B0,respectively）is taken to follow the Matalon-Packter law.Both mathematical fractal dimensions and box-count dimensions are calculated.The fractal dimension is found to increase with increasing A0 and decreasing B0.We also analyze mosaic patterns with random distribution of crystallites,grown under different conditions than the classical Liesegang gel method,and report on their fractal properties.Finally,complex Liesegang patterns wherein the bands are grouped in multiplets are studied,and it is shown that the fractal nature increases with the multiplicity.

Precipitation recycling ratio and water vapor sources on the Tibetan Plateau

Precipitation recycling ratio(i.e.,evaporation-precipitation feedback strength)and water vapor sources are two key aspects of regional water cycle,and their quantification is essential for understanding water cycle processes and their changes.The results of existing studies on the precipitation recycling ratio and water vapor sources for the Tibetan Plateau were highly controversial.This article clarifies different frameworks for understanding the water cycle.It points out that(1)the ratio of evaporation to precipitation depends mainly on climate regimes,while the precipitation recycling ratio is closely related to both the climate regimes and the scale of the region of interest,and(2)the water vapor sources depend on the traced period(precipitating or non-precipitating period)and the degree of tracing.Within the same theoretical framework,there is no fundamental conflict among the results of different studies on the water cycle in the Tibetan Plateau.

Progress in the study on the composition and formation mechanism of gallstone

Our serial studies from {dy1970}s on chemical composition, structure determination and formation mechanism of gallstones were reviewed. The chemical component investigation of brown-pigment gallstone demonstrated that it consists of macromolecules such as proteins, glycoproteins, polysaccharides, bilirubin polymers and pigment polymers, and biomolecules such as cholesterol, bile salts, calcium salts of carbonate, phosphate, fatty acids and bilirubinate as well as various metal ions. The binding of metal ions with bile salts and bilirubin plays important roles in gallstone formation, i.e., calcium bilirubinate complex is the major constitute of brown-pigment gallstones, and copper bilirubinate complex is critical in the black color appearance of black-pigment gallstone. The cross section of many gallstones exhibits a concentric ring structure composed of various small particles with a fractal character. This is nonlinear phenomenon in gallstone formation. Atypical model system of metal ions-deoxycholate (or cholate)-gel was chosen to mimic an in vitro pattern formation system. The experimental results suggested that a nonlinear scientific concept should be considered in understanding gallstone formation. Minor changes in the chemical composition and/or the microenvironment may lead to very different precipitate patterns with a variety of shapes, colors, appearances, and structures. A new model was suggested that periodical templets of periodical and fractal patterns were formed in the initial stage, then the spatio-temporal patterns grew gradually on it. Furthermore, the interaction between divalent metal ions and bile saltsin vitro was investigated, and the results indicated that non-stoichiometric M(DC)2-NaDC mixed complexes with mixed micelles structure can be formed in physiological condition.