Quantitative determination of anti-structured defects applied to alloys of a wide chemical range

Anti-structured defects bridge atom migration among heterogeneous sublattices facilitating diffusion but could also result in the collapse of ordered structure.Component distribution Ni（75）AlxV（25-x） alloys are investigated using a microscopic phase field model to illuminate relations between anti-structured defects and composition,precipitate order,precipitate type,and phase stability.The Ni（75）AlxV（25-x） alloys undergo single Ni3V（stage Ⅰ）,dual Ni3Al and Ni3V（stage Ⅱ with Ni3V prior;and stage Ⅲ with Ni3Al prior）,and single Ni3Al（stage Ⅳ） with enhanced aluminum level.For Ni3V phase,anti-structured defects（V（Ni1）,Niy,except V（Ni2）） and substitution defects（Al（Ni1）,Al（Ni2）,Alv） exhibit a positive correlation to aluminum in stage I,the positive trend becomes to negative correlation or smooth during stage Ⅱ.For Ni3 Al phase,anti-structured defects（Al（Ni）,Ni（Al）） and substitution defects（V（Ni）,V（Al）） have a positive correlation to aluminum in stage Ⅱ,but Ni（Al） goes down since stage Ⅲ and lasts to stage Ⅳ.V（Ni） and V（Al） fluctuate when Ni3Al precipitates prior,but go down drastically in stageⅣ.Precipitate type conversion of single Ni3V/dual（Ni3V＋Ni3Al） affects Ni3V defects,while dual（Ni3V＋Ni3Al）/single Ni3 Al has little effect on Ni3Al defects.Precipitate order swap occurred in the dual phase region affects on Ni3Al defects but not on Ni3V.

TRMM测雨雷达对1998年东亚降水季节性特征的研究(英)

Precipitation radar data derived from the Tropical Rainfall Measuring Mission (TRMM) satellite are used to study precipitation characteristics in 1998 over East Asia (10?38癗, 100C-145癊), especially over mid-latitude land (continental land) and ocean (East China Sea and South China Sea). Results are compared with precipitations in the tropics. Yearly statistics show dominant stratiform rain events over East Asia (about 83.7% by area fraction) contributing to 50% of the total precipitation. Deep convective rains contribute 48% to the total precipitation with a 13.7% area fraction. The statistics also show the unimportance of warm convective rain in East Asia, contributing 1.5% to the total precipitation with a 2.7% area fraction. On a seasonal scale, the results indicate that the rainfall ratio of stratiform rain to deep convective rain is proportional to their rainfall pixel ratio. Seasonal precipitation patterns compare well between Global Precipitation Climatology Project rainfall and TRMM PR measurements except in summer. Studies indicate a clear opposite shift of rainfall amount and events between deep convective and stratiform rains in the meridional in East Asia, which corresponds to the alternative activities of summer monsoon and winter monsoon in the region. The vertical structures of precipitation also exhibit strong seasonal variability in precipitation Contoured Rainrate by Altitude Diagrams (CRADs) and mean profiles in the mid-latitudes of East Asia. However, these structures in the South China Sea are of a tropical type except in winter. The analysis of CRADs reveals a wide range of surface rainfall rates for most deep convective rains, especially in the continental land, and light rain rate for most stratiform rains in East Asia, regardless of over land or ocean.

用TRMM资料研究1998年长江流域暴雨(英文)

TRMM (Tropical Rainfall Measuring Mission) data have been made available to the public users since June 1998. In this paper, some preliminary research is reported for the case study of heavy rainfall over the Yangtze River Basin using TRMM data at 2140 UTC 20 July 1998. TRMM derived precipitation products are also compared with rain gauge observation, ground radar data and numerical model simulation results. It is shown that TRMM data can be easily used to monitor the heavy rainfall and have many applications. Key words Heavy rainfall - TRMM data - Precipitation structure The research was supported by the National Natural Science Foundation of China (Grant No. 49705064), the Ministry of Science and Technology of China (Grant No. G19998040909), the Chinese Meteorological Administration, and the Ministry of Personnel (Outstanding Returned Oversea Scholar Program).

Satellite Observations of Reflectivity Maxima above the Freezing Level Induced by Terrain

Previous studies have recognized reflectivity maxima above the freezing level(RMAF) within stratiform precipitation over mountain slopes, however, quantitative studies are limited due to the lack of adequate identification criteria. Here, we establish an identification method for RMAF precipitation and apply it to the Tropical Rainfall Measuring Mission(TRMM) Precipitation Radar(PR) observations. Using the TRMM 2A25 product from 1998 to 2013, we show that the RMAF structure in reflectivity profiles can be effectively identified. RMAF exists not only in stratiform precipitation but also in convective precipitation. RMAF frequency is positively correlated with elevation, which is thought to be caused by enhanced updrafts in the middle layers of stratiform precipitation, or in the low to middle layers of convective precipitation over mountains. The average RMAF heights in stratiform and convective precipitation were 1.35 and 2.01 km above the freezing level, respectively, which is lower than previous results. In addition, our results indicate that the RMAF structure increased the echo top height and enhanced precipitation processes above the RMAF height, but it suppressed the downward propagation of ice particles and the near-surface rain rate. Future studies of orographic precipitation should take into account the impact of the RMAF structure and its relevant dynamic triggers.

TEM Studies of δ-TiN_(0．5)→δ′-TiN_(0．5) Ordering Transformation

The nucleation and growth processes of the stoichiometric δ'-TiN_0.5 long-range ordered precipitates duringδ-TiN0.5 →δ'-TiN_0.5 ordering transformation were investigated by transmission electron inicroscopy (TEM).The nucleation of the new δ'-TiN_0.5 phase is homogeneous in the matrix. In general, the nucleation andgrowth of the new δ'-TiN_0.5 phase proceed preferentially on the { 110)M lattice planes of parent δ-TiN_0. s. Theδ'-TiN_0.5 precipitates are always of lamellar features formed by combination of the three equivalent orientationdomains with their habit planes parallel to {11 0 }M planes.

Observed Vertical Structure of Precipitation over the Southeastern Tibetan Plateau in Summer 2021

Mêdog County,with its mountains and valleys,is located in the southeastern Tibetan Plateau(TP)and at the lower reaches of the Yarlung Zangbo River.This area has the highest annual rainfall amount over the TP,and in situ measurements are very scarce due to frequent debris flows and transportation difficulties.A monitoring campaign focused on cloud and precipitation observations was established in Mêdog in 2019 as a part of the Second Tibetan Plateau Scientific Expedition and Research Program.This paper evaluates the accuracy of micro rain radar(MRR)measurements and investigates the variations in precipitation vertical structure in Mêdog using observations collected from the MRR,disdrometer,and rain gauges in summer 2021.The measurements from the three instruments show a strong consistency,with correlation coefficients exceeding 0.93.Although the profiles of integral rain parameters for different rain rate categories in Mêdog are similar to those in other regions,the vertical evolution of raindrop size distributions shows significant differences.For lightest rain,the evaporation of small raindrops and breakup of large raindrops are clear during their descent.For the rainfall rate category of 0.2–2.0 mm h−1(2.0–20.0 mm h−1),concentrations of small and medium(large)drops show almost uniform vertical structures,while the large(medium)drop number displays a positive(negative)gradient.A disturbance at height of 1.5–2.0 km above ground level(AGL)is observed in the heavy rainfall due to strong updrafts.In general,the MRR measurements in Mêdog are robust.The raindrop breakup process is more apparent in Mêdog than in other regions,resulting in high concentration of sizelimited raindrops.In addition,it is found that the interaction between steep terrain and Mêdog convective rain causes the strong updrafts between 1.5 and 2.0 km AGL.

Variations of Precipitation Structure and Microwave Tbs During the Evolution of a Hailstorm from TRMM Observations

In this paper, a hailstorm occurring on 9 May 1999 in Huanghuai region was studied by using the combined data from the precipitation radar （PR）, microwave image （TMI）, and visible infrared scanner （VIRS） on the Tropical Rainfall Measuring Mission （TRMM） satellite. According to the 3-orbit observations of 5- h duration from the TRMM satellite, the variation characteristics of the precipitation structures as well as cloud top temperature and microwave signals of the precipitating cloud were comprehensively analyzed during the evolution of hailstorm. The results show that the precipitation is obviously converted from early hail cloud with strong convection into the later storm cloud with weak convection. For hail cloud, there exists some strong convective cells, and the heavy solid precipitation is shown at the middle-top levels so that the contribution of rainfall amount above the freezing-layer to the column precipitation amount is rather larger than that within the melting-layer. However, for storm cloud, the convective cells are surrounded by the large area of stratiform precipitation, and the precipitation thickness gradually decreases, and the rainfall above the freezing-layer obviously reduces and the contribution of rainfall amount within the melting-layer rapidly increases. Therefore, the larger ratio of rainfall amount above the freezing layer to column precipitation amount is, the more convective the cloud is; reversely, the larger proportion of rainfall below the melting layer is, the more stable the stratiform cloud is. The different changing trends of microwave signals at different precipitation stages show that it is better to consider the structures and stages of precipitating cloud to choose the optimal microwave channels to retrieve surface rainfall.

Effect of solidification rate on dendrite segregation and mechanical properties of Cu-15Ni-8Sn alloy prepared by directional solidification

The microstructures and mechanical properties of the directionally solidified Cu-15Ni-8Sn alloy were investigated at solidification rates ranging from 100 to 3000μm/s.The results showed that the solidification rate significantly affects the phase distribution of the as-cast Cu-15Ni-8Sn alloy.The primary and secondary dendritic spacing reduces and eventually becomes stable as the solidification rate increases.Meanwhile,the size of the primary phase decreases,and its distribution becomes more uniform.The most severe segregation problem of this alloy has been greatly improved.Upon solidification at 100μm/s,the as-cast Cu-15Ni-8Sn alloy consists of the α-Cu matrix,γ-CuNi_(2)Sn phase,discontinuous precipitation structure,modulated structure,and DO_(22) ordered phases.However,as the solidification rate increases,the discontinuous precipitation structure,modulated structures,and DO_(22) ordered phases decrease and even disappear,reducing hardness.As the solidification rate increases,after homogenization treatment,the composition and microhardness distributions of Cu-15Ni-8Sn alloy become more uniform.The time for homogenization is also shortened.It reduces production energy usage and facilitates further mechanical processing.

Climatological Characteristics of Summer Precipitation over East Asia Measured by TRMM PR:A Review

Precipitation is an important indicator of climate change and a critical process in the hydrological cycle, on both the global and regional scales. Methods of precipitation observation and associated analyses are of strategic importance in global climate change research. As the first space-based radar, the Tropical Rainfall Measuring Mission （TRMM） Precipitation Radar （PR） has been in operation for almost 17 years and has acquired a huge amount of cloud and pre- cipitation data that provide a distinctive view to help expose the nature of cloud and precipitation in the tropics and subtropics. In this paper we review recent advances in summer East Asian precipitation climatology studies based on long-term TRMM PR measurements in the following three aspects： （1） the three-dimensional structure of precipita- tion, （2） the diurnal variation of precipitation, and （3） the recent precipitation trend. Additionally, some importantprospects regarding satellite remote sensing of precipitation and its application in the near future are discussed.

Structural Characteristics of Atmospheric Temperature and Humidity inside Clouds of Convective and Stratiform Precipitation in the Rainy Season over East Asia

In this study, a merged dataset constructed from Tropical Rainfall Measuring Mission precipitation radar rain products and Integrated Global Radiosonde Archive data is used to investigate the thermal structural characteristics of convective and stratiform precipitation in the rainy season （May-August） of 1998-2012 over East Asia. The res- ults show that the storm tops for convective precipitation are higher than those for stratiform precipitation, because of the more unstable atmospheric motions for convective precipitation. Moreover, the storm tops are higher at 1200 UTC than at 0000 UTC over land regions for both convective and stratiform precipitation, and vice versa for ocean region. Additionally, temperature anomaly patterns inside convective and stratiform precipitating clouds show a neg- ative anomaly of about 0-2 K, which results in cooling effects in the lower troposphere. This cooling is more obvi- ous at 1200 UTC for stratiform precipitation. The positive anomaly that appears in the middle troposphere is more than 2 K, with the strongest warming at 300 hPa. Relative humidity anomaly patterns show a positive anomaly in the middle troposphere （700-500 hPa） prior to the occurrence of the two types of precipitation, and the increase in mois- ture is evident for stratiform precipitation.

Influence of size and distribution of W phase on strength and ductility of high strength Mg-5.1Zn-3.2Y-0.4Zr-0.4Ca alloy processed by indirect extrusion

A high strength Mg-5.1Zn-3.2Y-0.4Zr-0.4Ca （wt%） alloy containing W phase （Mg3Y2Zn3） prepared by permanent mold direct-chill casting is indirectly extruded at 350 ℃ and 400 ℃, respectively. The extruded alloys show bimodal grain structure consisting of fine dynamic recrystallized （DRXed） grains and unre- crystallized coarse regions containing fine W phase and β2′ precipitates. The fragmented W phase particles induced by extrusion stimulate nucleation of DRXed grains, leading to the formation of fine DRXed grains, which are mainly distributed near the W particle bands along the extrusion direction. The alloy extruded at 350 ℃ exhibits yield strength of 373 MPa, ultimate tensile strength of 403 MPa and elongation to failure of 5.1%. While the alloy extruded at 400 ℃ shows lower yield strength of 332 MPa, ultimate tensile strength of 352 MPa and higher elongation to failure of 12%. The mechanical properties of the as-extruded alloys vary with the distribution and size of W phase. A higher fraction of DRXed grains is obtained due to the homogeneous distribution of micron-scale broken W phase particles in the alloy extruded at 400 ℃, which can lead to higher ductility. In addition, the nano-scale dynamic W phase precipitates distributed in the unDRXed regions are refined at lower extrusion temperature. The smaller size of nano-scale W phase precipitates leads to a higher fraction of unDRXed regions which contributes to higher strength of the alloy extruded at 350 ℃.

Fabrication of magnetic nanosized γ-FeNi-coated ceramic core-shell microspheres by heterogeneous precipitation and thermal reduction

Precursors with NiCO3-2Ni（OH）2.2H2O- and Fe203.nH20-coated alumina, graphite and cenosphere were synthesized by precipitation using ferrous sulfate, nickel sulfate, ammonium bicarbonate, alumina, graphite and cenosphere as the main starting materials. Magnetic γ-FeNi-coated alumina, graphite and cenosphere core-shell structural microspheres were subsequently prepared by thermal reduction of the as-prepared precursors at 600℃ for 2 h. Precipitation parameters, e.g. concentration of ceramic micropowders （lOg/L）, sulfate solution （0.2mol/L）, rate of adding reactants （3 mL/min） and pH value were optimized by a trial-and-error method. Powders of the precursors and the resulting coating of γ-FeNi with grain size below 40 nm on alumina, graphite and cenosphere microspheres were characterized by scanning electron microscopy （SEM）, energy dispersive spectroscopy （EDS） and X-ray diffraction （XRD）. The magnetic properties of the nanosize γ-FeNi-coated alumina, graphite and cenosphere microspheres were measured by vibrating sample magnetometer （VSM）. The results show that the core-shell structural γ-FeNi-coated ceramic microspheres exhibited higher coercivity than pure γ-FeNi powders, indicating that these materials can be used for high-Derformance functional materials and devices.