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Characterization of CuInS_2 thin films prepared by sulfurization of Cu-In precursor 被引量:1
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作者 阎有花 刘迎春 +5 位作者 方玲 朱景森 赵海花 李德仁 卢志超 周少雄 《中国有色金属学会会刊:英文版》 EI CSCD 2008年第5期1083-1088,共6页
CuInS2 thin films were prepared by sulfurization of Cu-In precursors.The influences of the deposition sequence of Cu and In layers,such as Cu/In,Cu/In/In,and In/Cu/In,on structure,topography,and optical properties of ... CuInS2 thin films were prepared by sulfurization of Cu-In precursors.The influences of the deposition sequence of Cu and In layers,such as Cu/In,Cu/In/In,and In/Cu/In,on structure,topography,and optical properties of CuInS2 thin films were investigated.X-ray diffraction results show that the deposition sequence of Cu and In layers affects the crystalline quality of CuInS2 films.Atomic force microstructure images reveal that the grain size and surface roughness are related to the deposition sequence used.When the deposition sequence of precursor is In/Cu/In,the CuInS2 thin films show a single-phase chalcopyrite structure with (112) preferred orientation.The surface morphology of CIS films is uniform and compacted.The absorption coefficient is larger than 104 cm-1 with optical band gap Eg close to 1.4 eV. 展开更多
关键词 铜铟薄膜 前体 沉积层序 金属学
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Effects of precursor solution concentration on the properties and morphology of YBCO films deposited by TFA-MOD method 被引量:2
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作者 CUI Xumei TAO Bowan +3 位作者 LI Yanrong LIU Xingzhao CHEN Jiajun XIONG Jie 《Rare Metals》 SCIE EI CAS CSCD 2005年第3期272-276,共5页
Epitaxial YBCO films were deposited on (100) LaAlO3 single-crystal substrates by metalorganic deposition of metal trifluoroacetate precursors with different concentrations. All the YBCO films have Tc around 91 K and... Epitaxial YBCO films were deposited on (100) LaAlO3 single-crystal substrates by metalorganic deposition of metal trifluoroacetate precursors with different concentrations. All the YBCO films have Tc around 91 K and Jc excess 2 MA/cm^2 at 77 K in zero field. XRD θ-2θscans show all the films have c-axis normal orientation. The FWHM (full width at half-maximum intensity) values of X-ray ω-scans of (005) reflection are 0.379°, 0.283°, and 0.543° for the YBCO thin films deposited with precursor solution concentrations of 1.52, 1.0, and 0.75 mol/L, respectively. With the concentration of the precursors decreasing, the thickness of the films decreases linearly. SEM micrographs show that porosities in the films become bigger with the precursor solution concentration decreasing. The big porosities in the film with the lowest concentration precursor deteriorate the superconducting property and make it have a wider superconducting transition and a lower Jc. 展开更多
关键词 inorganic ceramic material YBCO film TFA-MOD precursor solution concentration PROPERTY MORPHOLOGY
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Local segregation in Cu-In precursors and its effects on microstructures of selenized CuInSe_2 thin films
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作者 方玲 张弓 +2 位作者 庄大明 赵明 吴敏生 《Journal of Central South University of Technology》 2005年第1期13-16,共4页
Local segregation in Cu-In precursors and its effects on the element distribution and microstructures of selenized CuInSe2 thin films were investigated. Cu-In precursors with an ideal total mole ratio of Cu to In of 0... Local segregation in Cu-In precursors and its effects on the element distribution and microstructures of selenized CuInSe2 thin films were investigated. Cu-In precursors with an ideal total mole ratio of Cu to In of 0.92 were prepared by middle frequency alternating current magnetron sputtering with Cu-In alloy target, then CuInSe2 absorbers for solar cells were formed by selenization process in selenium atmosphere. Scanning electron microscope and energy dispersive X-ray spectroscope were used respectively to observe the surface morphologies and determine the compositions of both Cu-In precursors and CuInSe2 thin films. Their microstructures were characterized by X-ray diffractometry and Raman spectroscope. The results show that Cu-In precursors are mainly composed of (Cu11In9) phase with In-rich solid solution. Stoichiometric CuInSe2 thin films with a homogeneous element distribution and single chalcopyrite phase can be synthesized from a segregated Cu-In precursor film with an ideal total mole ratio of Cu to In of 0.92. CuInSe2 thin film shows P-type conductivity and its resistivity reaches 1.2×103Ω·cm. 展开更多
关键词 太阳能电池 CuInSe2薄膜 磁控管溅射 显微结构
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Ceramic Films via Organometallic Complex as Single Source Precursor
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作者 Shyu Shin-Guang Wu Chi-Chin 《合成化学》 CAS CSCD 2004年第z1期122-122,共1页
关键词 MOCVD FES film SINGLE SOURCE precursor.
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Characterisation of Zinc Oxynitride Thin Films Prepared Using Zinc(II) Complex of Hexamethylenetetramine as the Precursor
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作者 Olumide Oluwole Akinwunmi Oluwaseun Philip Adelabu +4 位作者 Adetokunbo Temitope Famojuro Olakunle A. Akinwumi Priscilla Oluwatumilara Olaopa Kehinde Folorunso Olafisan Ezekiel Oladele Bolarinwa Ajayi 《Materials Sciences and Applications》 CAS 2022年第8期479-489,共11页
A Zinc(II) complex of hexamethylenetetramine was prepared as a single source precursor and used to deposit zinc oxynitride thin films. The thin films were deposited on soda-lime glass substrates using the Metal Organi... A Zinc(II) complex of hexamethylenetetramine was prepared as a single source precursor and used to deposit zinc oxynitride thin films. The thin films were deposited on soda-lime glass substrates using the Metal Organic Chemical Vapour Deposition (MOCVD) technique at the deposition temperature of 370°C and 390°C, respectively. The Fourier Transform Infrared Spectroscopy (FTIR) was used to determine the functional groups in the precursor, with stretching frequency for O-H, N-H, and C-H observed. The deposited films were characterized using UV-Visible Spectroscopy, Scanning Electron Microscopy (SEM), Elemental diffraction X-ray (EDX), and X-ray Diffractometer (XRD). A direct bandgap of 3.15 eV and 3.18 eV was obtained from the film deposited at 370°C and 390°C, respectively, using the Envelope Method. In comparison, a bandgap of 3.19 eV and 3.21 eV was obtained using the absorption spectrum fitting (ASF) method. The SEM revealed that the film is homogeneous, dense, and compact, composed of cluster grains. The EDX confirmed the presence of Zinc, Nitrogen and Oxygen. The X-ray Diffraction indicated the polycrystalline nature of the film. 展开更多
关键词 Zinc Oxynitride Metal Organic Chemical Vapour Deposition (MOCVD) precursor Characterisation Thin film
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MOCVD of Molybdenum Sulphide Thin Film Via Single Solid Source Precursor Bis-(Morpholinodithioato-s,s’)-Mo 被引量:2
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作者 Bolutife Olofinjana Gabriel Egharevba +2 位作者 Bidini Taleatu Olumide Akinwunmi Ezekiel Oladele Ajayi 《Journal of Modern Physics》 2011年第5期341-349,共9页
A single solid source precursor bis-(morpholinodithioato-s,s’)-Mo was prepared and molybdenum sulphide thin film was deposited on sodalime glass using Metal Organic Chemical Vapour Deposition (MOCVD) technique at dep... A single solid source precursor bis-(morpholinodithioato-s,s’)-Mo was prepared and molybdenum sulphide thin film was deposited on sodalime glass using Metal Organic Chemical Vapour Deposition (MOCVD) technique at deposition temperature of 420?C. The film was characterized using Rutherford Backscattering Spectroscopy (RBS), Ultraviolet-Visible Spectroscopy, Four point probe technique, Scanning Electron Mi-croscopy (SEM), X-ray Diffractometry (XRD) and Atomic Force Microscopy (AFM). A direct optical band gap of 1.77 eV was obtained from the analysis of the absorption spectrum. The sheet resistance was found to be of the order of 10P–5P ΩP–1P?cmP–1P. SEM micrographs of the films showed the layered structure of the film with an estimated grain size that is less than 2 μm while XRD indicates parallel orientation of the basal plane to the substrate surface. 展开更多
关键词 MOLYBDENUM SULPHIDE precursor Metal Organic Chemical VAPOUR Deposition (MOCVD) Thin film Characterization
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Mass Transport of β-Diketonate Precursors for MOCVD of YBa_2Cu_3O_(7-δ) High T_c Superconducting Thin Films
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作者 MENG Guang-yao YUAN Zhi-hao YANG Ping-hua and PENG Ding-kun (Department of Materials Science &. Engineering,University of Science & Technology of China, Hefei, 230026) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1996年第1期92-101,共10页
Mass transport of Y(dpm)2 Ba(dpm)5· OH· 2Ho and Cu (dpm)2 by a carrier gas(argon) was theoretically considered and experimentally studied as a function of the system with operating parameters including tempe... Mass transport of Y(dpm)2 Ba(dpm)5· OH· 2Ho and Cu (dpm)2 by a carrier gas(argon) was theoretically considered and experimentally studied as a function of the system with operating parameters including temperature, carrier gas flow rate and system pressure. The experimental results are in a good agreement with the theoretical prediction. The mechanism of mass transport of these organometallic precursors and their use for YBCO film stoichiometry control and reproducibility are discussed. 展开更多
关键词 MOCVD High T_c thin films β-Diketonate precursor Vaporization rate Mass transport
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Deposition and Characterisation of Nitrogen-Doped Zinc Oxide Thin Films by MOCVD Using Zinc Acetate—Ammonium Acetate Precursor
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作者 U. S. Mbamara O.O. Akinwumi +2 位作者 E.I. Obiajunwa I.A.O. Ojo E.O.B. Ajayi 《Journal of Modern Physics》 2012年第8期652-659,共8页
The synthesis and comprehensive analysis of nitrogen-doped zinc oxide thin films grown from a compound precursor of zinc acetate and ammonium acetate has been reported. The precursor was processed in different ratios ... The synthesis and comprehensive analysis of nitrogen-doped zinc oxide thin films grown from a compound precursor of zinc acetate and ammonium acetate has been reported. The precursor was processed in different ratios of the zinc acetate-ammonium acetate additives, and each combination was used to deposit a thin film using metalorganic chemical vapour deposition (MOCVD) method. The produced thin films were characterised using Rutherford backscattering (RBS) spectroscopy, uv-visible spectrometry, x-ray diffractometry, four point probe measurements and optical microscopy. The deposited thin films showed a fairly consistent zinc:oxygen:nitrogen ratio of 4.4:3.7:1, the film structures were quasicrystalline and the sheet resistivities were high, while other familiar characteristics like optical transmittance, bandgap, thermal stability, etc. were maintained in the grown films. Applications in device fabrication and active sensor devices were hence envisaged as the emergent potentials of the thin films. 展开更多
关键词 Zinc Oxide THIN films N-DOPING precursor Characterisation
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Effect of thermal pretreatment of metal precursor on the properties of Cu_2ZnSnS_4 films
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作者 王威 沈鸿烈 +2 位作者 金佳乐 李金泽 马跃 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第5期479-483,共5页
Zn/Sn/Cu (CZT) stacks were prepared by RF magnetron sputtering. The stacks were pretreated at different tem- peratures (200℃, 300 ℃, 350 ℃, and 400 ℃) for 0.5 h and then followed by sulfurization at 500℃ for ... Zn/Sn/Cu (CZT) stacks were prepared by RF magnetron sputtering. The stacks were pretreated at different tem- peratures (200℃, 300 ℃, 350 ℃, and 400 ℃) for 0.5 h and then followed by sulfurization at 500℃ for 2 h. Then, the structures, morphologies, and optical properties of the as-obtained Cu2ZnSnS4 (CZTS) films were studied by x-ray diffraction (XRD), Raman spectroscopy, UV-Vis-NIR, scanning electron microscope (SEM), and energy-dispersive x-ray spectroscopy (EDX). The XRD and Raman spectroscopy results indicated that the sample pretreated at 350℃ had no secondary phase and good crystallization. At the same time, SEM confirmed that it had large and dense grains. According to the UV-Vis-NIR spectrum, the sample had an absorption coefficient larger than 10^4 cm-1 in the visible light range and a band gap close to 1.5 eV. 展开更多
关键词 Cu2ZnSnS4 (CZTS) films radio-frequency magnetron sputtering metal precursor pretreatment
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Plasma-enhanced atomic layer deposition of Co using Co(MeCp)_2 precursor 被引量:3
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作者 Jusang Park Han-Bo-Ram Lee +5 位作者 Doyoung Kim Jaehong Yoon Clement Lansalot Julien Gatineau Henri Chevrel Hyungjun Kim 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2013年第3期403-407,共5页
Cobalt (Co) thermal or plasma enhanced atomic layer deposition (PE-ALD) was investigated using a novel metal organic precursor, Co(MeCp)2, and NH3 or H2 or their plasma as a reactant. The growth characteristics,... Cobalt (Co) thermal or plasma enhanced atomic layer deposition (PE-ALD) was investigated using a novel metal organic precursor, Co(MeCp)2, and NH3 or H2 or their plasma as a reactant. The growth characteristics, electrical and microstructural properties were investigated. Especially, PE-ALD produced Co thin films at low growth temperature down to 100℃. Interestingly, the low temperature growth of Co films showed the formation of columnar structure at substrate temperature below 300℃. The growth characteristics and films properties of PE-ALD Co using bis(η-methylcyclopentadienyl) Co(II) (Co(MeCp)2) was compared with those of PE-ALD Co using other Cp based metal organic precursors, bis-cyclopentadienyl cobalt (II) (CoCp2) and cyclopentadienyl isopropyl acetamidinato-cobalt (Co(CpAMD)). 展开更多
关键词 PE-ALD Th-ALD cobalt metal thin films metal organic precursors
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Metal Organic Chemical Vapour Deposited Thin Films of Cobalt Oxide Prepared via Cobalt Acetylacetonate
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作者 C.U. Mordi M.A. Eleruja +6 位作者 B.A. Taleatu G.O. Egharevba A.V. Adedeji O.O. Akinwunmi B. Olofinjana C. Jeynes E.O.B. Ajayi 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2009年第1期85-89,共5页
The single solid source precursor, cobalt (Ⅱ) acetylacetonate was prepared and characterized by infrared spectroscopy. Thin films of cobalt oxide were deposited on soda lime glass substrates through the pyrolysis ... The single solid source precursor, cobalt (Ⅱ) acetylacetonate was prepared and characterized by infrared spectroscopy. Thin films of cobalt oxide were deposited on soda lime glass substrates through the pyrolysis (metal organic chemical vapour deposition (MOCVD)) of single solid source precursor, cobalt acetylacetonate, Co[C5H7O2]2 at a temperature of 420℃. The compositional characterization carried out by rutherford backscattering spectroscopy and X-ray diffraction (XRD), showed that the films have a stoichiometry of Co2O3 and an average thickness of 227±0.2 nm. A direct energy gap of 2,15±0.01 eV was calculated by the data obtained by optical absorption spectroscopy. The morphology of the films obtained by scanning electron microscopy, showed that the grains were continuous and uniformly distributed at various magnifications, while the average grain size was less than i micron for the deposited thin films of cobalt oxide. 展开更多
关键词 precursor Thin film Oxide Metal organic chemical vapour deposition (MOCVD) Rutherford backscattering spectroscopy (RBS)
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Some Properties of Manganese Oxide (Mn-O) and Lithium Manganese Oxide (Li-Mn-O) Thin Films Prepared via Metal Organic Chemical Vapor Deposition (MOCVD) Technique
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作者 Kabir O. Oyedotun Marcus Adebola Eleruja +7 位作者 Bolutife Olofinjana Olumide Oluwole Akinwunmi Olusoji O.Ilori Ezekiel Omotoso Emmanuel. Ajenifuja Adetokunbo T. Famojuro Eusebius I. Obianjuwa Ezekiel Oladele Bolarlnwa Ajay 《材料科学与工程(中英文B版)》 2015年第5期231-242,共12页
关键词 金属有机化学气相沉积 锂锰氧化物 薄膜沉积 MOCVD 制备 技术 性质 紫外可见光谱
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生物质纳米碳膜的制备及其电化学性能
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作者 何锡凤 宋伟明 +1 位作者 荆涛 左春玲 《化学研究与应用》 CAS 北大核心 2023年第3期572-578,共7页
将衰老叶片用H_(2)SO_(4)进行水热氧化得到氧化水合碳前驱体,前驱体经烘干研磨在KOH存在下进行碳化得到生物质纳米碳膜(LS-OCM),通过FT-IR,XRD、TEM、SEM、AFM、XPS及N_(2)吸附-脱附等测试手段对其材料组成和微观形貌进行表征。TEM、SEM... 将衰老叶片用H_(2)SO_(4)进行水热氧化得到氧化水合碳前驱体,前驱体经烘干研磨在KOH存在下进行碳化得到生物质纳米碳膜(LS-OCM),通过FT-IR,XRD、TEM、SEM、AFM、XPS及N_(2)吸附-脱附等测试手段对其材料组成和微观形貌进行表征。TEM、SEM及N_(2)吸附-脱附分析显示,制得生物质纳米碳膜材料(LS-OCM)既保留叶片原有的叶脉结构又形成丰富多级的孔道结构,比表面积约为450.7 m^(2)/g,孔径分布较窄,平均孔径为3.8 nm;AFM分析显示,LS-OCM类似二维纳米膜,片层平均厚度在1.6 nm左右;XPS及XRD分析表明,该材料中C主要以C=C形似存在,为类石墨烯碳膜。电化学性能分析表明,在电流密度为0.25 A/g下,LS-OCM比电容为262.58 F/g,循环100圈,比电容仍然可达150.8 F/g,表明材料具有良好的稳定性。 展开更多
关键词 叶片 水热氧化 前驱体 生物质 纳米碳膜 比电容
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Lattice Constant α Calculation of PZT Films Prepared by a New Modified Sol-Gel Method
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作者 陈祝 曾勇 杨邦朝 《Journal of Electronic Science and Technology of China》 2005年第2期168-171,共4页
PZT(Zr/Ti=52/48) ferroelectric films are prepared by a new modified Sol-Gel method from three stable-separated Pb2+, Zr4+, Ti4+ precursor–monomers. This method needs no distillation and has the advantage of easy chan... PZT(Zr/Ti=52/48) ferroelectric films are prepared by a new modified Sol-Gel method from three stable-separated Pb2+, Zr4+, Ti4+ precursor–monomers. This method needs no distillation and has the advantage of easy change of the Pb2+/Zr4+/Ti4+ stoichiometric. In the paper we also investigate PT seeds influence on ferroelectric properties, crystallographic structures and surface morphologies, and find the bottom/up PT seeds structure prompte PZT crystallization and have superior ferroeletric properties. The paper introduce a method to deduce and calculate lattice constant α by ‘least square method’, then the more accurate lattice constant a0 can be got from X-ray diffractometer (XRD) analysis data. We also discover that grain sizes of PZT film calculated from XRD data are much closed to those of AFM, and the film a0 is relatively small due to crushing stress. 展开更多
关键词 PZT precursor-monomers lattice constant α ferroelectric films
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Morphological and Electrochemical Characterization of Ti/MxTiySnzO2 (M = Ir or Ru) Electrodes Prepared by the Polymeric Precursor Method
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作者 Jussara F. Carneiro Jéssica R. Silva +2 位作者 Robson S. Rocha Josimar Ribeiro Marcos R. V. Lanza 《Advances in Chemical Engineering and Science》 2016年第4期364-378,共15页
This paper describes the effect of the composition of the oxide films on the properties of electrodes Ti/M<sub>x</sub>Ti<sub>y</sub>Sn<sub>z</sub>O<sub>2</sub> (M = Ir o... This paper describes the effect of the composition of the oxide films on the properties of electrodes Ti/M<sub>x</sub>Ti<sub>y</sub>Sn<sub>z</sub>O<sub>2</sub> (M = Ir or Ru) prepared by the polymeric precursor method. XRD studies showed that the anodes are formed by solid solutions. The electrodes containing IrO<sub>2</sub> exhibit lower activity for the oxygen evolution reaction. The doping of the electrode surface with SnO<sub>2</sub> improves the catalytic properties of the anodes. However, it should be held in appropriate compositions, because the change in the atomic ratio of this element shows a marked effect on the stability of the oxides. Electrode Ti/Ir<sub>0.2</sub>Ti<sub>0.3</sub>Sn<sub>0.5</sub>O<sub>2</sub> has lower lifetime, i.e. 6 hours. The 20% decrease in the stoichiometric amount of SnO<sub>2</sub> increases the time to a value above 70 hours, as observed for Ti/Ir<sub>0.3</sub>Ti<sub>0.4</sub>Sn<sub>0.3</sub>O<sub>2</sub>. Electrode Ti/Ru<sub>0.3</sub>Ti<sub>0.4</sub>Sn<sub>0.3</sub>O<sub>2</sub> shows lifetime of 11 hours;therefore IrO<sub>2</sub> is more stable than RuO<sub>2</sub> under the conditions investigated. These results suggest that electrode Ti/Ir<sub>0.3</sub>Ti<sub>0.4</sub>Sn<sub>0.3</sub>O<sub>2</sub> is promising for different applications, such as water electrolysis, capacitors and organic electrosynthesis. 展开更多
关键词 Dimensionally Stable Anodes (DSA) Oxide films Electrochemical Properties Polymeric precursor Method
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高质量二维WTe2薄膜的可控制备及电输运性能研究
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作者 赵新 卢志红 +3 位作者 张振华 肖杨 冯金地 甘凌霄 《武汉科技大学学报》 CAS 北大核心 2023年第6期418-423,共6页
以WCl_(6)为前驱体,采用化学气相沉积法制备二维WTe_(2)薄膜材料。借助X射线衍射仪、拉曼光谱、原子力显微镜、综合物性测量系统等探究了前驱体用量对二维WTe_(2)薄膜质量的影响并对薄膜的电输运性能进行表征。结果表明,在500℃下,仅需1... 以WCl_(6)为前驱体,采用化学气相沉积法制备二维WTe_(2)薄膜材料。借助X射线衍射仪、拉曼光谱、原子力显微镜、综合物性测量系统等探究了前驱体用量对二维WTe_(2)薄膜质量的影响并对薄膜的电输运性能进行表征。结果表明,在500℃下,仅需10 min的生长时间就可以获得大面积的WTe_(2)薄膜,且薄膜厚度随前驱体用量的减少而减薄。WCl_(6)前驱体为0.6 g时所制多层二维WTe_(2)薄膜在温度为10 K、磁场强度为50000 Oe下的磁电阻率为1.54%,该磁电阻率仍未达到饱和。样品平面霍尔电阻随电场和磁场夹角变化而周期性变化,表明所制WTe_(2)薄膜具有和块体WTe_(2)相似的电输运特性。 展开更多
关键词 二维材料 WTe_(2)薄膜 WCl_(6) 前驱体 磁电阻率 平面霍尔电阻 电输运性能
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乙酰丙酮基1,2-双(二苯基膦)乙烷镍的合成、热性质及其作为化学气相沉积前驱体的应用研究
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作者 张羽翔 李雪仃 +8 位作者 王恒 阴文玉 张慧 徐莉佳 张雅鑫 王潚君 秦娜 郭鑫 瞿轩轩 《广东化工》 CAS 2023年第1期7-9,共3页
本文以乙酰丙酮镍和1,2-双(二苯基膦)乙烷为原料合成了乙酰丙酮基1,2-双(二苯基膦)乙烷镍配合物,通过元素分析、熔点以及热重分析仪对所合成配合物的化学成分、挥发性、热稳定性以及运输行为进行了测定分析。此外,以该化合物为前驱体,... 本文以乙酰丙酮镍和1,2-双(二苯基膦)乙烷为原料合成了乙酰丙酮基1,2-双(二苯基膦)乙烷镍配合物,通过元素分析、熔点以及热重分析仪对所合成配合物的化学成分、挥发性、热稳定性以及运输行为进行了测定分析。此外,以该化合物为前驱体,通过薄膜沉积实验对其作为CVD前驱体的应用性进行了评价,并对所沉积薄膜的形貌、化学组成及晶型结构进行了研究。研究结果表明所制备的薄膜成分为NiO,成膜连续均匀,具有较高的纯度,说明其具有作为CVD前驱体应用于制备镍基薄膜的可行性。 展开更多
关键词 合成 热性质 化学气相沉积 前驱体 镍基薄膜
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混合配体配合物胍基脒基镧的合成及性能
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作者 谢乾 丁玉强 《合成化学》 CAS 2023年第11期855-863,共9页
La_(2)O_(3)薄膜材料应用广泛,而制备La_(2)O_(3)薄膜的前驱体合成面临着挑战,多数现有前驱体热稳定性差、合成路线复杂或者成本高等问题。因此,本文报道了混配型和均配型的胍基、脒基镧配合物二(N,N′-二异丙基-甲胺基胍基)一(N,N′-... La_(2)O_(3)薄膜材料应用广泛,而制备La_(2)O_(3)薄膜的前驱体合成面临着挑战,多数现有前驱体热稳定性差、合成路线复杂或者成本高等问题。因此,本文报道了混配型和均配型的胍基、脒基镧配合物二(N,N′-二异丙基-甲胺基胍基)一(N,N′-二异丙基戊基脒基)合镧(配合物1)和三(N,N′-二异丙基-甲胺基胍基)合镧(配合物2),通过1H NMR,13C NMR表征结构;通过热重分析(TGA)研究所有配合物的热稳定性和挥发性。结果表明:配合物1在加热至170.0℃时,其蒸气压会急剧上升;在202.0℃能产生1.0 Torr的蒸气压;在260.0℃以下该配合物有良好的热稳定性。以上数据说明:该配合物比较好地满足CVD工艺条件,是一种潜在的化学气相沉积前驱体;通过CVD技术,在源加热温度210℃、沉积温度为260.0℃、沉积时间为10.0 min的条件下得到约11.9 nm薄膜,SEM和XPS分析了薄膜的形貌和成分,实验结果表明沉积的纳米薄膜为高纯的La_(2)O_(3)薄膜。 展开更多
关键词 胍基 脒基 前驱体 La_(2)O_(3) 化学气相沉积 薄膜材料
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动态湿润与动态接触角的实验 被引量:8
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作者 王晓东 彭晓峰 王补宣 《航空动力学报》 EI CAS CSCD 北大核心 2005年第2期214-218,共5页
利用精密步进电机、高速CCD图像采集系统、立体显微镜,采用液槽法测试硅酮油在玻璃、铝、不锈钢表面上的动态湿润行为。实验结果与前驱膜模型对比表明,无量纲参数λ在玻璃、铝和不锈钢表面上分别取值0.07,0.16和0.35时,二者吻合较好,表... 利用精密步进电机、高速CCD图像采集系统、立体显微镜,采用液槽法测试硅酮油在玻璃、铝、不锈钢表面上的动态湿润行为。实验结果与前驱膜模型对比表明,无量纲参数λ在玻璃、铝和不锈钢表面上分别取值0.07,0.16和0.35时,二者吻合较好,表明动态接触角不仅是静接触角和毛细数的函数,也和固体表面性质有关。实验同时发现,对于低毛细数下成立的Hoffman-Voinov-Tanner定律(Cazabat推荐适用于Ca 1或θD<10°),直到动态接触角达到70°依然成立,用前驱膜模型可给出合理解释。 展开更多
关键词 航空、航天推进系统 湿润 动态接触角 前驱膜
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粗糙表面上的移动接触线和动态接触角 被引量:11
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作者 王晓东 彭晓峰 李笃中 《磁流体发电情报》 EI CAS 2004年第3期402-407,共6页
提出一个粗糙表面上移动接触线和动态接触角的数理模型 :毛细数较低时表观接触线前缘存在极薄的前驱膜 ,表观接触线在“湿”固体表面上移动 ,不同于传统模型中认为表观接触线在“干”固体表面上移动 .在Moffatt角区内部流动解的基础上 ... 提出一个粗糙表面上移动接触线和动态接触角的数理模型 :毛细数较低时表观接触线前缘存在极薄的前驱膜 ,表观接触线在“湿”固体表面上移动 ,不同于传统模型中认为表观接触线在“干”固体表面上移动 .在Moffatt角区内部流动解的基础上 ,通过引入接触线特征参数表征表观接触线在前驱膜上的滑移程度 ,导出动态接触角的速度关系 .与不同研究者实验数据对比发现量纲 1特征参数反映固体材料特性和表面特性对动态湿润过程的影响 ,与液相的性质无关 .结合前期提出的滞后张力模型 ,对动态法和静态法测量静接触角产生的差异给出合理解释 . 展开更多
关键词 粗糙表面 移动接触线 动态接触角 数理模型 流体力学
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