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Computing large deviation prefactors of stochastic dynamical systems based on machine learning
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作者 李扬 袁胜兰 +1 位作者 陆凌宏志 刘先斌 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期364-373,共10页
We present a large deviation theory that characterizes the exponential estimate for rare events in stochastic dynamical systems in the limit of weak noise.We aim to consider a next-to-leading-order approximation for m... We present a large deviation theory that characterizes the exponential estimate for rare events in stochastic dynamical systems in the limit of weak noise.We aim to consider a next-to-leading-order approximation for more accurate calculation of the mean exit time by computing large deviation prefactors with the aid of machine learning.More specifically,we design a neural network framework to compute quasipotential,most probable paths and prefactors based on the orthogonal decomposition of a vector field.We corroborate the higher effectiveness and accuracy of our algorithm with two toy models.Numerical experiments demonstrate its powerful functionality in exploring the internal mechanism of rare events triggered by weak random fluctuations. 展开更多
关键词 machine learning large deviation prefactors stochastic dynamical systems rare events
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Aerodynamic Noise Propagation Simulation using Immersed Boundary Method and Finite Volume Optimized Prefactored Compact Scheme 被引量:3
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作者 Min LIU Keqi WU 《Journal of Thermal Science》 SCIE EI CAS CSCD 2008年第4期361-367,共7页
Based on the immersed boundary method (IBM) and the finite volume optimized pre-factored compact (FVOPC) scheme, a numerical simulation of noise propagation inside and outside the casing of a cross flow fan is est... Based on the immersed boundary method (IBM) and the finite volume optimized pre-factored compact (FVOPC) scheme, a numerical simulation of noise propagation inside and outside the casing of a cross flow fan is estab- lished. The unsteady linearized Euler equations are solved to directly simulate the aero-acoustic field. In order to validate the FVOPC scheme, a simulation case: one dimensional linear wave propagation problem is carried out using FVOPC scheme, DRP scheme and HOC scheme. The result of FVOPC is in good agreement with the ana- lytic solution and it is better than the results of DRP and HOC schemes, the FVOPC is less dispersion and dissi- pation than DRP and HOC schemes. Then, numerical simulation of noise propagation problems is performed. The noise field of 36 compact rotating noise sources is obtained with the rotating velocity of 1000r/min. The PML absorbing boundary condition is applied to the sound far field boundary condition for depressing the numerical reflection. Wall boundary condition is applied to the casing. The results show that there are reflections on the casing wall and sound wave interference in the field. The FVOPC with the IBM is suitable for noise propagation problems under the complex geometries for depressing the dispersion and dissipation, and also keeping the high order precision. 展开更多
关键词 immersed boundary method finite volume optimized prefactored compact scheme noise
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高分散态铀氧化物对硝酸钾热分解的催化作用
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作者 刘璐 马雅婷 +1 位作者 郁格格 赵玉宝 《南华大学学报(自然科学版)》 2024年第3期90-96,共7页
以SBA-15为载体,通过水热法制得高分散态的铀氧化物,而后引入KNO_(3)。基于程序升温分解-质谱(temperature programmed decomposition-mass spectrometry,TPDE-MS)联用技术,研究了KNO_(3)的热分解行为。利用KAS(Kissinger-Akahira-Suno... 以SBA-15为载体,通过水热法制得高分散态的铀氧化物,而后引入KNO_(3)。基于程序升温分解-质谱(temperature programmed decomposition-mass spectrometry,TPDE-MS)联用技术,研究了KNO_(3)的热分解行为。利用KAS(Kissinger-Akahira-Sunose)方法和F_(1/3)方法分析了KNO_(3)热分解数据,得出相应的动力学参数。结果表明:纯KNO_(3)在600℃左右开始发生分解,分解率位于0.5~0.8时,其分解反应符合F_(1/3)方法模型函数,反应活化能为285 kJ/mol;高分散态铀氧化物上,KNO_(3)分解温度降低至200℃,分解活化能在205.4~207.3 kJ/mol之间。铀氧化物对KNO_(3)具有良好的催化活性,采用KAS和F_(1/3)方法得到KNO_(3)热分解的平均活化能分别降低了30和74 kJ/mol。 展开更多
关键词 硝酸钾 铀氧化物 动力学参数 活化能 指前因子
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分形结构对随机取向烟尘团簇粒子光散射特性的影响 被引量:4
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作者 类成新 冯东太 吴振森 《原子与分子物理学报》 CAS CSCD 北大核心 2012年第1期141-146,共6页
利用蒙特卡罗方法对不同分形维数和分形前向因子的随机取向烟尘团簇粒子的分形结构进行了仿真,采用离散偶极子近似(DDA)方法对随机取向烟尘团簇粒子的缪勒矩阵元进行了数值计算,并与球形粒子模型进行了比较,深入探讨了烟尘团簇粒子的分... 利用蒙特卡罗方法对不同分形维数和分形前向因子的随机取向烟尘团簇粒子的分形结构进行了仿真,采用离散偶极子近似(DDA)方法对随机取向烟尘团簇粒子的缪勒矩阵元进行了数值计算,并与球形粒子模型进行了比较,深入探讨了烟尘团簇粒子的分形维数和分形前因子对其散射特性的影响.研究表明,等效球形粒子的光散射特性与随机取向烟尘团簇粒子的光散射特性存在很大差别,并且此差别随着团簇粒子的分形维数以及分形前向因子的增大而减小;分形维数对表征团簇粒子散射特性的缪勒矩阵元的影响在一定散射角范围内均比较明显,分形前向因子对团簇粒子的缪勒矩阵元角分布的影响与分形维数的影响类似,不过其影响相对分形维数较弱. 展开更多
关键词 光散射特性 离散偶极子近似方法 烟尘团簇粒子 分形维数 分形前向因子
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燃气管用PE100级混配料的热分解动力学和机理 被引量:1
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作者 黄国家 李露水 +1 位作者 徐青永 辛明亮 《中国塑料》 CAS CSCD 北大核心 2020年第10期51-55,共5页
采用热重分析法测定了在氮气气氛中2、5、10、20℃/min 4种不同升温速率下的燃气用PE100级混配料热分解过程。采用Kissinger法、Flynn-Wall-Ozawa方法和Coats-Redfern法考察了燃气用PE100级混配料热分解动力学和机理。运用Toop法对PE10... 采用热重分析法测定了在氮气气氛中2、5、10、20℃/min 4种不同升温速率下的燃气用PE100级混配料热分解过程。采用Kissinger法、Flynn-Wall-Ozawa方法和Coats-Redfern法考察了燃气用PE100级混配料热分解动力学和机理。运用Toop法对PE100级混配料在不同温度下的寿命进行了评估。结果表明,PE100级混配料的热失重为一步分解反应;Kissinger法求得热分解平均活化能(E)为327.8 kJ/mol,Flynn-Wall-Ozawa法求得的E为304.6 kJ/mol,表观指前因子(lnA)值为53.9 min^-1;在12种常见热分解模型中,R2即圆柱对称的收缩机制最适合描述PE100级混配料热分解反应过程;50℃下,Kissinger法和Flynn-Wall-Ozawa法求得的PE100级混配料寿命分别为7.4×10^8年和7.9×10^7年,随着温度的升高,寿命急速降低。 展开更多
关键词 PE100 热分解动力学 活化能 表观指前因子
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