Effects of diamond particle size on microstructure and properties of diamond/Al-12Si composites prepared by vacuum-assisted pressure infiltration

Diamond/aluminium composites have attracted attention in the field of thermal management of electronic packaging for their excellent properties.In order to solve the interfacial problem between diamond and aluminium,a novel process combining pressure infiltration with vacuum-assisted technology was proposed to prepare diamond/aluminum composites.The effect of diamond particle size on the microstructure and properties of the diamond/Al-12Si composites was investigated.The results show that the diamond/Al-12Si composites exhibit high relative density and a uniform microstructure.Both thermal conductivity and coefficient of thermal expansion increase with increasing particle size,while the bending strength exhibits the opposite trend.When the average diamond particle size increases from 45μm to 425μm,the thermal conductivity of the composites increases from 455 W·m^(-1)·K^(-1)to 713 W·m^(-1)·K^(-1)and the coefficient of thermal expansion increases from 4.97×10^(-6)K^(-1)to 6.72×10^(-6)K^(-1),while the bending strength decreases from 353 MPa to 246 MPa.This research demonstrates that high-quality composites can be prepared by the vacuum-assisted pressure infiltration process and the thermal conductivity of the composites can be effectively improved by increasing the diamond particle size.

Effect of specific pressure on fabrication of 2D-C_f/Al composite by vacuum and pressure infiltration

Carbon fiber reinforced aluminum matrix （Cf/Al） composite has many excellent properties, and it has received more and more attention. Two-dimensional （2D） Cf/Al composites were fabricated by vacuum and pressure infiltration, which was an integrated technique and could provide high vacuum and high infiltration pressure. The effect of specific pressure on the infiltration quality of the obtained composites was comparatively evaluated through microstructure observation. The experimental results show that satisfied Cf/Al composites could be fabricated at the specific pressure of 75 MPa. In this case, the preform was infiltrated much more completely by aluminum alloy liquid, and the residual porosity was seldom found. It is found that the ultimate tensile strength of the obtained Cf/Al composite reached maximum at the specific pressure of 75 MPa, which was improved by 138.9% compared with that of matrix alloy.

Effects of boron on the microstructure and thermal properties of Cu/diamond composites prepared by pressure infiltration

Diamond reinforced copper（Cu/diamond） composites were prepared by pressure infiltration for their application in thermal management where both high thermal conductivity and low coefficient of thermal expansion（CTE） are important.They were characterized by the microstructure and thermal properties as a function of boron content,which is used for matrix-alloying to increase the interfacial bonding between the diamond and copper.The obtained composites show high thermal conductivity（660 W/（m·K）） and low CET（7.4×10-6 K-1） due to the formation of the B13C2 layer at the diamond-copper interface,which greatly strengthens the interfacial bonding.Thermal property measurements indicate that in the Cu-B/diamond composites,the thermal conductivity and the CTE show a different variation trend as a function of boron content,which is attributed to the thickness and distribution of the interfacial carbide layer.The CTE behavior of the present composites can be well described by Kerner＇s model,especially for the composites with 0.5wt% B.

Microstructure,mechanical properties and wear resistance of SiC_(p)/AZ91 composite prepared by vacuum pressure infiltration

SiC_(p)/AZ91 composites were prepared by vacuum pressure infiltration.The microstructure,mechanical properties and wear resistance of composite were studied.Results indicated that SiC particles were uniformly distributed in the metal matrix and had a good interface bonding with the metal matrix.Mg_(17)Al_(12) preferably precipitated near the SiC particles,and high-density dislocations were induced by the mismatch of the coefficient of thermal expansion(CTE)between the SiC particle and the AZ91 matrix,thereby accelerating the aging precipitation of the matrix.Compared with AZ91 alloy,the addition of SiC particles improves the hardness and compressive strength of the composite,which is mainly due to the load transfer strengthening and grain refinement strengthening mechanisms.Furthermore,a stable support surface-protecting matrix formed during the wear process because of the excellent wear resistance of SiC.

Thermal conductivity of diamond/copper composites with a bimodal distribution of diamond particle sizes prepared by pressure infiltration method

The thermal conductivity of diamond/copper composites with bimodal particle sizes was studied. The composites were prepared through pressure infiltration of liquid copper into diamond preforms with a mixture of 40 and 100 pm-size diamonds. The permeability of the preforms with different coarse-to-fine volume ratios of diamonds was investigated. The thermal conductivity of the diamond/copper composites with bimodal size distribution was compared to the theoretical value derived from an analytical model developed by Chu. It is predicted that the diamond/copper composites could reach a higher thermal conductivity and their surface roughness could be improved by applying bimodal diamond particle sizes.

Effect of graphite powder as a forming filler on the mechanical properties of SiCp/Al composites by pressure infiltration

（38vo1% SiCp ＋ 2vo1% A1203f）/2024 A1 composites were fabricated by pressure infiltration. Graphite powder was introduced as a forming filler in preform preparation, and the effects of the powder size on the microstructures and mechanical properties of the final com- posites were investigated. The results showed that the composite with 15 μm graphite powder as a forming filler had the maximum tensile strength of 506 MPa, maximum yield strength of 489 MPa, and maximum elongation of 1.2%, which decreased to 490 MPa, 430 MPa, and 0.4%, respectively, on increasing the graphite powder size from 15 to 60 μm. The composite with 60 μm graphite powder showed the highest elastic modulus, and the value decreased from 129 to 113 GPa on decreasing the graphite powder size from 60 to 15 μm. The differences between these properties are related to the different microstructures of the corresponding composites, which determine their failure modes.

Low-temperature heat conduction characteristics of diamond/Cu composite by pressure infiltration method

In this paper,diamond/CuCr and diamond/CuB composites were prepared using the pressure infiltration method.The physical property measurement system(PPMS)was adopted to evaluate the thermal conductivity of diamond/Cu and MoCu composites within the range of100–350 K,and a scanning electron microscope(SEM)was utilized to analyze the microstructure and fracture appearance of the materials.The research indicates that the thermal conductivity of diamond/Cu composite within the range of100–350 K is 2.5–3.0 times that of the existing MoCu material,and the low-temperature thermal conductivity of diamond/Cu composite presents an exponential relationship with the temperature.If B element was added to a Cu matrix and a low-temperature binder was used for prefabricated elements,favorable interfacial adhesion,relatively high interfacial thermal conductivity,and favorable low-temperature heat conduction characteristics would be apparent.

Co_(47.5)Fe_(28.·5)Ni_(19)Si_(3.3)Al_(1.7)High-entropy Skeletons Fabricated by Selective Laser Melting and Properties tuned by pressure infiltration of Al

High saturation magnetization and low coercivity are required for soft magnetic materials.This study investigated the Co_(47.5)Fe_(28.5)Ni_(19)Si_(3.3)Al_(1.7)high-entropy soft magnetic skeleton was prepared by selective laser melting.Then Al wpressure infiltrated into skeletons to obtain a dense composite material.The high-entropy composite materials possessed favorable compressive ductility and moderate soft magnetic properties.The high-entropy composite materials were obtained with Ms being 97.1 emu/g,79.8 emu/g,33 emu/g and possessing 19 Oe,15.8Oe and 17Oe of Hc,respectively.However,the magnetostriction coefficient remains low level,about 5ppm.These reported properties are attributed to the special structure of the material studied in present experiment.Nevertheless,a novel strategy of structural designing was proposed in this paper.

Mechanical Properties of C_f/Mg Composites Fabricated by Pressure Infiltration Method

The carbon fibers and the woven reinforced magnesium matrix composites were fabricated by pressure infiltration method.Effects of fiber species,fiber arrangement,hybrid particles and environment temperature on microstructures and properties of the composite were studied.Results showed that the mechanical properties at ambient temperature were affected by interfacial reaction.The magnesium matrix composites reinforced with graphite fibers showed higher strength and elastic modulus due to less interfacial reaction.During loading,the fibers were pulled out and the load was transferred through the interfaces,then the fiber bundles were fractured,finally the whole specimen failed.The introduction of hybrid SiC particles during fabrication can improve the mechanical properties of the magnesium matrix composites.Moreover,taking orthogonal carbon fiber woven as reinforcement can modify the anisotropy and reliability of materials.

Thermal properties of diamond/Al composites by pressure infiltration:comparison between methods of coating Ti onto diamond surfaces and adding Si into Al matrix

This study was pertained to the effects of Ti coating on diamond surfaces and Si addition into Al matrix on the thermal conductivity（TC） and the coefficient of thermal expansion（CTE） of diamond/Al composites by pressure infiltration.The fracture surfaces,interface microstructures by metal electro-etching and interfacial thermal conductance of the composites prepared by two methods were compared.The results reveal that Ti coating on diamond surfaces and only12.2 wt% Si addition into Al matrix could both improve the interfacial bonding and increase the TCs of the composites.But the Ti coating layer introduces more interfacial thermal barrier at the diamond/Al interface compared to adding 12.2 wt% Si into Al matrix.The diamond/Al composite with 12.2 wt% Si addition exhibits maximum TC of 534 W·m^-1·K^-1and a very low CTE of 8.9×10^-6K^-1,while the coating Ti-diamond/Al composite has a TC of 514 W·m^-1·K^-1 and a CTE of 11.0×10^-6K^-1.

Fabrication and anodic polarization behavior of lead-based porous anodes in zinc electrowinning

A new type of lead-based porous anode in zinc electrowinning was prepared by negative pressure infiltration. The anodic polarization potential and corrosion rate were studied and compared with those of traditional fiat anodes （Pb-0.8%Ag） used in industry. The anode corrosion rate was determined by anode actual current density and microstructure. The results show that the anodic oxygen evolution potential decreases first and then increases with the decrease of pore diameter. The anodic potential decreases to the lowest value of 1.729 V at the pore diameter of 1.25-1.60 mm. The porous anode can decrease its actual current density and thus decrease the anodic corrosion rate. When the pore diameter is 1.60-2.00 mm, the anodic relative corrosion rate reaches the lowest value of 52.1%.

Microstructural examination and mechanical properties of replicated aluminium composite foams

Open-cell aluminium foams can be produced with the structural replication of dimensional accuracy from polymeric foam patterns through a pressure infiltration casting process.The strength of open-cell foam is much less than that of the closed-cell counterpart,and thereby subjects to mainly functional applications.An improvement in mechanical properties of the foams can be implemented with the addition of ceramic particles.In the present study,the composite foams were produced using AC3A alloy added with varying contents of SiC particles.The resultant foams have ceramic particles embedded in the alloy matrix and on the strut surface.Higher volume fraction of ceramic particles resulted in an increase in the compressive strength,energy absorption and microhardness of the foams.The improvement of these properties is due to the modification of the microstructure of the foams and the increased strength in the node and struts at which the ceramic particles reside.