BACKGROUND Pain in the back or pelvis or fear of back pain may affect the timing or cocontraction of the core muscles.In both static and dynamic movements,the Sahrmann core stability test provides an assessment of cor...BACKGROUND Pain in the back or pelvis or fear of back pain may affect the timing or cocontraction of the core muscles.In both static and dynamic movements,the Sahrmann core stability test provides an assessment of core muscle activation and a person's ability to stabilize the lumbopelvic complex.Preparatory cues and images can be used to increase the activation of these muscles.To attain optimal movement patterns,it will be necessary to determine what cueing will give the most effective results for core stability.AIM To investigate the effects of external and internal cues on core muscle activation during the Sahrmann five-level core stability test.METHODS Total 68 participants(21.83±3.47 years)were randomly allocated to an external(n=35)or internal cue group(n=33).Participants performed the Sahrmann fivelevel core stability test without a cue as baseline and the five-level stability exercises with an internal or external cue.External cue group received a pressure biofeedback unit(PBU),and the internal cue group received an audio cue.A Delsys Trigno^(TM)surface electromyography unit was used for muscle activation from the rectus abdominis,external oblique,and transverse abdominis/internal oblique muscles.RESULTS Linear mixed effects model analysis showed that cueing had a significant effect on core muscle activation(P=0.001);however,there was no significant difference between cue types(internal or external)(P=0.130).CONCLUSION Both external and internal cueing have significant effects on core muscle activation during the Sahrmann five-level core stability test and the PBU does not create higher muscle activation than internal cueing.展开更多
Natural gas hydrate(NGH)holds great promise as a source of clean energy.It is critical for acquiring the largest possible in situ NGH core for NGH eigen features and resource assessment.However,the existing NGH coring...Natural gas hydrate(NGH)holds great promise as a source of clean energy.It is critical for acquiring the largest possible in situ NGH core for NGH eigen features and resource assessment.However,the existing NGH coring technology has limitations,such as temperature increments,limited coring diameters,low coring rates,and complex coring structures.Therefore,this study designs and proposes an NGH freezing coring(NGHFC)method and verifies the freezing and coring capacities of the NGHFC method in laboratories and experimental wells.Results suggest that NGHFC shows good freezing and heat-retention properties.A freezing core heat transfer model is developed.According to the actual air temperature and operating time,the optimum initial temperature of the cold source can be determined using this model.The average coring rate of NGHFC can reach 77.86%.The research results will provide a new idea of coring gas hydrates.展开更多
The paper presents the design and preliminary test results of a corer used for hard seafloor sediments sampling. Generally the sediment cores are provided by either gravity-type coting or deep-ocean drilling for a ran...The paper presents the design and preliminary test results of a corer used for hard seafloor sediments sampling. Generally the sediment cores are provided by either gravity-type coting or deep-ocean drilling for a range of studies. However, in consideration of the operability and available sample length in collecting hard sediments, these methods exhibit no advantages. In this paper, a new corer which can exploit both hydrostatic energy and gravity energy for hard sediments coting is presented. The hydrostatic energy is provided by pressure differential between ambient seawater pressure and air pressure in an empty cavity. During sampling process, the corer penetrates into the sediment like a gravity corer and then automatically shifts to the percussion mode. The experiments in the laboratory indicate that the corer can complete 40 cycles in the sea with a cycle time of 2.8 seconds in percussion mode and impact the sample tube with the velocity of 0.2 m/s during each cycle. Besides, its adjustable falling velocity can make the corer achieve the maximum efficiency in coring different sediments.展开更多
The lunar surface and its deep layers contain abundant resources and valuable information resources,the exploration and exploitation of which are important for the sustainable development of the human economy and soci...The lunar surface and its deep layers contain abundant resources and valuable information resources,the exploration and exploitation of which are important for the sustainable development of the human economy and society.Technological exploration and research in the field of deep space science,especially lunar-based exploration,is a scientific strategy that has been pursued in China and worldwide.Drilling and sampling are key to accurate exploration of the desirable characteristics of deep lunar resources.In this study,an in-situ condition preserved coring(ICP-Coring)and analysis system,which can be used to test drilling tools and develop effective sampling strategies,was designed.The key features of the system include:(1)capability to replicate the extreme temperature fluctuations of the lunar environment(-185 to 200℃)with intelligent temperature control;(2)ability to maintain a vacuum environment at a scale of 10^(-3) Pa,both under unloaded conditions within Ф580 mm×1000 mm test chamber,and under loaded conditions using Ф400 mm×800 mm lunar rock simulant;(3)application of axial pressures up to 4 MPa and confining pressures up to 3.5 MPa;(4)sample rotation at any angle with a maximum sampling length of 800 mm;and(5)multiple modes of rotary-percussive drilling,controlled by penetration speed and weight on bit(WOB).Experimental studies on the drilling characteristics in the lunar rock simulant-loaded state under different drill bit-percussive-vacuum environment configurations were conducted.The results show that the outgassing rate of the lunar soil simulant is greater than that of the lunar rock simulant and that a low-temperature environment contributes to a reduced vacuum of the lunar-based simulated environment.The rotary-percussive drilling method effectively shortens the sampling time.With increasing sampling depth,the temperature rise of the drilling tools tends to rapidly increase,followed by slow growth or steady fluctuations.The temperature rise energy accumulation of the drill bits under vacuum is more significant than that under atmospheric pressure,approximately 1.47 times higher.The real-time monitored drilling pressure,penetration speed and rotary torque during drilling serve as parameters for discriminating the drilling status.The results of this research can provide a scientific basis for returning samples from lunar rock in extreme lunar-based environments.展开更多
With the increasing depth of coal mining,the requirements for coring devices that maintain pressure are increasing.To adapt to the special environment in deep coal seams and improve the accuracy of testing gas content...With the increasing depth of coal mining,the requirements for coring devices that maintain pressure are increasing.To adapt to the special environment in deep coal seams and improve the accuracy of testing gas content,a low-disturbance pressure-preserving corer was developed.The measurement of gas content using this corer was analyzed.The coring test platform was used to complete a coring function test.A pressurized core with a diameter of 50 mm was obtained.The pressure was 0.15 MPa,which was equal to the pressure of the liquid column of the cored layer,indicating that the corer can be successfully used in a mud environment.Next,a pressure test of the corer was conducted.The results showed that under conditions of low pressure(8 MPa)and high pressure(25 MPa),the internal pressure of the corer remained stable for more than 1 h,indicating that the corer has good ability to maintain pressure.Therefore,the corer can be applied at deep coal mine sites.The results of this research can be used to promote the safe exploitation of deep coal mines and the exploitation of methane resources in coalbeds.展开更多
Material composition and structural design are important factors influencing the electromagnetic wave(EMW)absorption performance of materials.To alleviate the impedance mismatch attributed to the high dielectric const...Material composition and structural design are important factors influencing the electromagnetic wave(EMW)absorption performance of materials.To alleviate the impedance mismatch attributed to the high dielectric constant of Ti_(3)C_(2)T_(x)MXene,we have successfully synthesized core‐shell structured SiO_(2)@MXene@MoS_(2)nanospheres.This architecture,comprising SiO_(2) as the core,MXene as the intermediate layer,and MoS_(2) as the outer shell,is achieved through an electrostatic self‐assembly method combined with a hydrothermal process.This complex core‐shell structure not only provides a variety of loss mechanisms that effectively dissipate electromagnetic energy but also prevents self‐aggregation of MXene and MoS_(2) nanosheets.Notably,the synergistic combination of SiO_(2) and MoS_(2) with highly conductive MXene enables the suitable dielectric constant of the composites,ensuring optimal impedance matching.Therefore,the core‐shell structured SiO_(2)@MXene@MoS_(2) nanospheres exhibit excellent EMW absorption performance,featuring a remarkable minimum reflection loss(RL_(min))of−52.11 dB(2.4 mm).It is noteworthy that these nanospheres achieve an ultra‐wide effective absorption bandwidth(EAB)of 6.72 GHz.This work provides a novel approach for designing and synthesizing high‐performance EMW absorbers characterized by“wide bandwidth and strong reflection loss.”展开更多
Using pressure-preserved coring technique to determine in-situ gas content provides a more precise assessment of gas resource reserves and safeguard of mining safety in coal seams. How coring technique and depth affec...Using pressure-preserved coring technique to determine in-situ gas content provides a more precise assessment of gas resource reserves and safeguard of mining safety in coal seams. How coring technique and depth affect the determination of gas content is unclear due to borehole zoning rupture caused by roadway excavation and drilling disturbance. To this end, a proposed coupling model of stress distribution and gas migration was simulated and validated by FLAC^(3D) and COMSOL Multiphysics considering superposition effects of roadway excavation and drilling disturbance. The findings indicate that the roadway surrounding rock displays distinct zoning features including stress relief zone, stress concentration zone that is composed of plastic zone, elastic zone, and original stress zone;and the broken situations depending on the borehole peeping are consistent with the corresponding simulation results.On this basis, this study proposes a set of drilling coring depth calculation and prediction model for the gas desorption affected area under engineering disturbance. Optimal depth of coring drilling is not only approach to the in-situ coal bulk, but also can get the balance of the drilling workload and cost controlling. According to the typical mine site geological conditions and the numerical simulation results in this study, if the roadway excavation time is ~1 year, it is recommended that the pressure-preserved coring depth should be greater than 17 m.展开更多
Remarkable progress has characterized the field of electrocatalysis in recent decades,driven in part by an enhanced comprehension of catalyst structures and mechanisms at the nanoscale.Atomically precise metal nanoclu...Remarkable progress has characterized the field of electrocatalysis in recent decades,driven in part by an enhanced comprehension of catalyst structures and mechanisms at the nanoscale.Atomically precise metal nanoclusters,serving as exemplary models,significantly expand the range of accessible structures through diverse cores and ligands,creating an exceptional platform for the investigation of catalytic reactions.Notably,ligand‐protected Au nanoclusters(NCs)with precisely defined core numbers offer a distinct advantage in elucidating the correlation between their specific structures and the reaction mechanisms in electrocatalysis.The strategic modulation of the fine microstructures of Au NCs presents crucial opportunities for tailoring their electrocatalytic performance across various reactions.This review delves into the profound structural effects of Au NC cores and ligands in electrocatalysis,elucidating their underlying mechanisms.A detailed exploration of the fundamentals of Au NCs,considering core and ligand structures,follows.Subsequently,the interaction between the core and ligand structures of Au NCs and their impact on electrocatalytic performance in diverse reactions are examined.Concluding the discourse,challenges and personal prospects are presented to guide the rational design of efficient electrocatalysts and advance electrocatalytic reactions.展开更多
A sandwich plate with a corrugation and auxetic honeycomb hybrid core is constructed,and its sound insulation and optimization are investigated.First,the motion governing equation of the sandwich plate is established ...A sandwich plate with a corrugation and auxetic honeycomb hybrid core is constructed,and its sound insulation and optimization are investigated.First,the motion governing equation of the sandwich plate is established by the third-order shear deformation theory(TSDT),and then combined with the fluid-structure coupling conditions,and the sound insulation is solved.The theoretical results are validated by COMSOL simulation results,and the effects of the structural parameter on the sound insulation are analyzed.Finally,the standard genetic algorithm is adopted to optimize the sound insulation of the sandwich plate.展开更多
Identifying deformational mechanisms and associated structures at various scales,ranging from regional-scale structures to microscopic fabric,is crucial for the assessment of tectonic development.Thirty-three samples ...Identifying deformational mechanisms and associated structures at various scales,ranging from regional-scale structures to microscopic fabric,is crucial for the assessment of tectonic development.Thirty-three samples were taken from the Qazzaz metamorphic core complex to estimate the finite strain for felsic and mafic minerals.These samples included gneisses rocks,monzogranite,and metavolcano-sedimentary rocks for both the Thalbah and Bayda groups.Using the Rf/j and Fry methods,the axial ratios(XZ)range about 2.20 to 7.10 and 1.90 to 9.10,respectively.For various rock units,the strain measurements show moderate to highly deformation.Most of the observed samples show shallow WNW dipping along a N to WNW trend of finite strain(X).The short axes(Z)based to be subvertical foliation related with a subhorizontal foliation.The results demonstrate that contacts generated at semi-brittle to ductile deformation and that the strain of magnitude has the same value for different lithologic units.It concluded that nappe generation in orogens results from pure shear deformation.展开更多
Here,a nonhydrostatic alternative scheme(NAS)is proposed for the grey zone where the nonhydrostatic impact on the atmosphere is evident but not large enough to justify the necessity to include an implicit nonhydrostat...Here,a nonhydrostatic alternative scheme(NAS)is proposed for the grey zone where the nonhydrostatic impact on the atmosphere is evident but not large enough to justify the necessity to include an implicit nonhydrostatic solver in an atmospheric dynamical core.The NAS is designed to replace this solver,which can be incorporated into any hydrostatic models so that existing well-developed hydrostatic models can effectively serve for a longer time.Recent advances in machine learning(ML)provide a potential tool for capturing the main complicated nonlinear-nonhydrostatic relationship.In this study,an ML approach called a neural network(NN)was adopted to select leading input features and develop the NAS.The NNs were trained and evaluated with 12-day simulation results of dry baroclinic-wave tests by the Weather Research and Forecasting(WRF)model.The forward time difference of the nonhydrostatic tendency was used as the target variable,and the five selected features were the nonhydrostatic tendency at the last time step,and four hydrostatic variables at the current step including geopotential height,pressure in two different forms,and potential temperature,respectively.Finally,a practical NAS was developed with these features and trained layer by layer at a 20-km horizontal resolution,which can accurately reproduce the temporal variation and vertical distribution of the nonhydrostatic tendency.Corrected by the NN-based NAS,the improved hydrostatic solver at different horizontal resolutions can run stably for at least one month and effectively reduce most of the nonhydrostatic errors in terms of system bias,anomaly root-mean-square error,and the error of the wave spatial pattern,which proves the feasibility and superiority of this scheme.展开更多
Curved shells are increasingly utilized in applied engineering due to their shared characteristics with other sandwich structures,flexibility,and attractive appearance.However,the inability of controlling and regulati...Curved shells are increasingly utilized in applied engineering due to their shared characteristics with other sandwich structures,flexibility,and attractive appearance.However,the inability of controlling and regulating vibrations and destroying them afterward is a challenge to scientists.In this paper,the curve shell equations and a linear quadratic regulator are adopted for the state feedback design to manage the structure vibrations in state space forms.A five-layer sandwich doubly curved micro-composite shell,comprising two piezoelectric layers for the sensor and actuator,is modeled by the fourth-order shear deformation theory.The core(honeycomb,truss,and corrugated)is analyzed for the bearing of transverse shear forces.The results show that the honeycomb core has a greater effect on the vibrations.When the parameters related to the core and the weight percentage of graphene increase,the frequency increases.The uniform distribution of graphene platelets results in the lowest natural frequency while the natural frequency increases.Furthermore,without taking into account the piezoelectric layers,the third-order shear deformation theory(TSDT)and fourth-order shear deformation theory(FOSDT)align closely.However,when the piezoelectric layers are incorporated,these two theories diverge significantly,with the frequencies in the FOSDT being lower than those in the TSDT.展开更多
Many networks exhibit the core/periphery structure.Core/periphery structure is a type of meso-scale structure that consists of densely connected core nodes and sparsely connected peripheral nodes.Core nodes tend to be...Many networks exhibit the core/periphery structure.Core/periphery structure is a type of meso-scale structure that consists of densely connected core nodes and sparsely connected peripheral nodes.Core nodes tend to be well-connected,both among themselves and to peripheral nodes,which tend not to be well-connected to other nodes.In this brief report,we propose a new method to detect the core of a network by the centrality of each node.It is discovered that such nodes with non-negative centralities often consist in the core of the networks.The simulation is carried out on different real networks.The results are checked by the objective function.The checked results may show the effectiveness of the simulation results by the centralities of the nodes on the real networks.Furthermore,we discuss the characters of networks with the single core/periphery structure and point out the scope of the application of our method at the end of this paper.展开更多
Pressure-preserved coring is an effective means to develop deep resources. However, due to the complexity of existing pressure-preserved technology, the average success rate of pressure-preserved coring is low. In res...Pressure-preserved coring is an effective means to develop deep resources. However, due to the complexity of existing pressure-preserved technology, the average success rate of pressure-preserved coring is low. In response, a novel in situ magnetically controlled self-sealing pressure-preserved coring technology for deep reserves has been proposed and validated. This innovative technology distinguishes itself from conventional methods by employing noncontact forces to replace traditional pretensioning mechanisms, thereby enhancing the mechanical design of pressure-preserved coring equipment and significantly boosting the fault tolerance of the technology. Here, we report on the design,theoretical calculations, experimental validation, and industrial testing of this technology. Through theoretical and simulation calculations, the self-sealing composite magnetic field of the pressure controller was optimized. The initial pre-tensioning force of the optimal magnetic field was 13.05 N. The reliability of the magnetically controlled self-sealing pressure-preserved coring technology was verified using a self-developed self-sealing pressure performance testing platform, confirming the accuracy of the composite magnetic field calculation theory. Subsequently, a magnetically controlled self-triggering pressure-preserved coring device was designed. Field pressure-preserved coring was then conducted,preliminarily verifying the technology's effective self-sealing performance in industrial applications.Furthermore, the technology was analyzed and verified to be adaptable to complex reservoir environments with pressures up to 30 MPa, temperatures up to 80℃, and p H values ranging from 1 to 14. These research results provide technical support for multidirectional pressure-preserved coring, thus paving a new technical route for deep energy exploration through coring.展开更多
Manganese-based perovskite is popular for research on ferromagnetic materials,and its spectroscopic studies are essential for understanding its electronic structure,dielectric,electrical,and magnetic properties.In thi...Manganese-based perovskite is popular for research on ferromagnetic materials,and its spectroscopic studies are essential for understanding its electronic structure,dielectric,electrical,and magnetic properties.In this paper,the M-edge spectra of La ions and the M-edge,L-edge,and K-edge spectra of Mn ions in LaMnO3 are calculated by considering both the free-ion multiplet calculation and the crystal field effects.We analyze spectral shapes,identify peak origins,and estimate the oxidation states of La and Mn ions in LaMnO3 theoretically.It is concluded that La ions in LaMnO3 predominantly exist in the trivalent state,while Mn ions exist primarily in the trivalent state with a minor presence of tetravalent ions.Furthermore,the calculated spectra are in better conformity with the experimental spectra when the proportion of Mn3+is 90%and Mn4+is 10%.This article enhances our comprehension of the oxidation states of La and Mn within the crystal and also provides a valuable guidance for spectroscopic investigations of other manganates.展开更多
Curcumin is a natural polyphenol that is used in various traditional medicines.However,its inherent properties,such as its rapid degradation and metabolism,low bioavailability,and short half-life,are serious problems ...Curcumin is a natural polyphenol that is used in various traditional medicines.However,its inherent properties,such as its rapid degradation and metabolism,low bioavailability,and short half-life,are serious problems that must be resolved.To this end,a drug carrier incorporating natural magnetic cores in a zeolite framework was developed and applied to the loading of curcumin in ethanol solutions.In this system,curcumin is encapsulated in a zeolite Na(ZNA)magnetic core–shell structure(Fe@Si/ZNA),which can be easily synthesized using an in situ method.Synthesis of Fe_(3)O_(4) nanoparticles was carried out from natural materials using a co-precipitation method.Analysis of the prepared magnetic core–shell structures and composites was carried out using vibrating-sample magnetometery,Fourier transform infrared spectroscopy,transmission electron microscopy,and x-ray diffraction.The cumulative loading of curcumin in the ZNA composite with 9%nanoparticles was found to reach 90.70%with a relatively long half-life of 32.49 min.Stability tests of curcumin loading in the composite showed that adding magnetic particles to the zeolite framework also increased the stability of the composite structure.Adsorption kinetics and isotherm studies also found that the system follows the pseudo-second-order and Langmuir isotherm models.展开更多
文摘BACKGROUND Pain in the back or pelvis or fear of back pain may affect the timing or cocontraction of the core muscles.In both static and dynamic movements,the Sahrmann core stability test provides an assessment of core muscle activation and a person's ability to stabilize the lumbopelvic complex.Preparatory cues and images can be used to increase the activation of these muscles.To attain optimal movement patterns,it will be necessary to determine what cueing will give the most effective results for core stability.AIM To investigate the effects of external and internal cues on core muscle activation during the Sahrmann five-level core stability test.METHODS Total 68 participants(21.83±3.47 years)were randomly allocated to an external(n=35)or internal cue group(n=33).Participants performed the Sahrmann fivelevel core stability test without a cue as baseline and the five-level stability exercises with an internal or external cue.External cue group received a pressure biofeedback unit(PBU),and the internal cue group received an audio cue.A Delsys Trigno^(TM)surface electromyography unit was used for muscle activation from the rectus abdominis,external oblique,and transverse abdominis/internal oblique muscles.RESULTS Linear mixed effects model analysis showed that cueing had a significant effect on core muscle activation(P=0.001);however,there was no significant difference between cue types(internal or external)(P=0.130).CONCLUSION Both external and internal cueing have significant effects on core muscle activation during the Sahrmann five-level core stability test and the PBU does not create higher muscle activation than internal cueing.
基金supported by the Program for Guangdong Introducing Innovative and Entrepreneurial Teams(No.2019ZT08G315)National Natural Science Foundation of China No.51827901 and U2013603Shenzhen Basic Research Project(JCYJ20190808153416970)
文摘Natural gas hydrate(NGH)holds great promise as a source of clean energy.It is critical for acquiring the largest possible in situ NGH core for NGH eigen features and resource assessment.However,the existing NGH coring technology has limitations,such as temperature increments,limited coring diameters,low coring rates,and complex coring structures.Therefore,this study designs and proposes an NGH freezing coring(NGHFC)method and verifies the freezing and coring capacities of the NGHFC method in laboratories and experimental wells.Results suggest that NGHFC shows good freezing and heat-retention properties.A freezing core heat transfer model is developed.According to the actual air temperature and operating time,the optimum initial temperature of the cold source can be determined using this model.The average coring rate of NGHFC can reach 77.86%.The research results will provide a new idea of coring gas hydrates.
基金supported by the National Natural Science Foundation of China (Grant No. 40806043)
文摘The paper presents the design and preliminary test results of a corer used for hard seafloor sediments sampling. Generally the sediment cores are provided by either gravity-type coting or deep-ocean drilling for a range of studies. However, in consideration of the operability and available sample length in collecting hard sediments, these methods exhibit no advantages. In this paper, a new corer which can exploit both hydrostatic energy and gravity energy for hard sediments coting is presented. The hydrostatic energy is provided by pressure differential between ambient seawater pressure and air pressure in an empty cavity. During sampling process, the corer penetrates into the sediment like a gravity corer and then automatically shifts to the percussion mode. The experiments in the laboratory indicate that the corer can complete 40 cycles in the sea with a cycle time of 2.8 seconds in percussion mode and impact the sample tube with the velocity of 0.2 m/s during each cycle. Besides, its adjustable falling velocity can make the corer achieve the maximum efficiency in coring different sediments.
基金supported by the National Natural Science Foundation of China(Nos.52225403,U2013603,52434004,and 52404365)the Program for Guangdong Introducing Innovative and Entrepreneurial Teams(No.2019ZT08G315)+2 种基金the Shenzhen National Science Fund for Distinguished Young Scholars(No.RCJC20210706091948015)the National Key Research and Development Program of China(2023YFF0615404)the Scientific Instrument Developing Project of Shenzhen University。
文摘The lunar surface and its deep layers contain abundant resources and valuable information resources,the exploration and exploitation of which are important for the sustainable development of the human economy and society.Technological exploration and research in the field of deep space science,especially lunar-based exploration,is a scientific strategy that has been pursued in China and worldwide.Drilling and sampling are key to accurate exploration of the desirable characteristics of deep lunar resources.In this study,an in-situ condition preserved coring(ICP-Coring)and analysis system,which can be used to test drilling tools and develop effective sampling strategies,was designed.The key features of the system include:(1)capability to replicate the extreme temperature fluctuations of the lunar environment(-185 to 200℃)with intelligent temperature control;(2)ability to maintain a vacuum environment at a scale of 10^(-3) Pa,both under unloaded conditions within Ф580 mm×1000 mm test chamber,and under loaded conditions using Ф400 mm×800 mm lunar rock simulant;(3)application of axial pressures up to 4 MPa and confining pressures up to 3.5 MPa;(4)sample rotation at any angle with a maximum sampling length of 800 mm;and(5)multiple modes of rotary-percussive drilling,controlled by penetration speed and weight on bit(WOB).Experimental studies on the drilling characteristics in the lunar rock simulant-loaded state under different drill bit-percussive-vacuum environment configurations were conducted.The results show that the outgassing rate of the lunar soil simulant is greater than that of the lunar rock simulant and that a low-temperature environment contributes to a reduced vacuum of the lunar-based simulated environment.The rotary-percussive drilling method effectively shortens the sampling time.With increasing sampling depth,the temperature rise of the drilling tools tends to rapidly increase,followed by slow growth or steady fluctuations.The temperature rise energy accumulation of the drill bits under vacuum is more significant than that under atmospheric pressure,approximately 1.47 times higher.The real-time monitored drilling pressure,penetration speed and rotary torque during drilling serve as parameters for discriminating the drilling status.The results of this research can provide a scientific basis for returning samples from lunar rock in extreme lunar-based environments.
基金supported by the National Natural Science Foundation of China(No.51827901)the National Natural Science Foundation of China(No.52225403)+1 种基金the Program for Guangdong Introducing Innovative and Entrepreneurial Teams of China(No.2019ZT08G315)the Sichuan Science and Technology Program of China(No.2023NSFSC0780).
文摘With the increasing depth of coal mining,the requirements for coring devices that maintain pressure are increasing.To adapt to the special environment in deep coal seams and improve the accuracy of testing gas content,a low-disturbance pressure-preserving corer was developed.The measurement of gas content using this corer was analyzed.The coring test platform was used to complete a coring function test.A pressurized core with a diameter of 50 mm was obtained.The pressure was 0.15 MPa,which was equal to the pressure of the liquid column of the cored layer,indicating that the corer can be successfully used in a mud environment.Next,a pressure test of the corer was conducted.The results showed that under conditions of low pressure(8 MPa)and high pressure(25 MPa),the internal pressure of the corer remained stable for more than 1 h,indicating that the corer has good ability to maintain pressure.Therefore,the corer can be applied at deep coal mine sites.The results of this research can be used to promote the safe exploitation of deep coal mines and the exploitation of methane resources in coalbeds.
基金Joint Fund of Research and Development Program of Henan Province,Grant/Award Number:222301420002National Natural Science Foundation of China,Grant/Award Number:U21A2064Scientific and Technological Innovation Talents in Colleges and Universities in Henan Province,Grant/Award Number:22HASTIT001。
文摘Material composition and structural design are important factors influencing the electromagnetic wave(EMW)absorption performance of materials.To alleviate the impedance mismatch attributed to the high dielectric constant of Ti_(3)C_(2)T_(x)MXene,we have successfully synthesized core‐shell structured SiO_(2)@MXene@MoS_(2)nanospheres.This architecture,comprising SiO_(2) as the core,MXene as the intermediate layer,and MoS_(2) as the outer shell,is achieved through an electrostatic self‐assembly method combined with a hydrothermal process.This complex core‐shell structure not only provides a variety of loss mechanisms that effectively dissipate electromagnetic energy but also prevents self‐aggregation of MXene and MoS_(2) nanosheets.Notably,the synergistic combination of SiO_(2) and MoS_(2) with highly conductive MXene enables the suitable dielectric constant of the composites,ensuring optimal impedance matching.Therefore,the core‐shell structured SiO_(2)@MXene@MoS_(2) nanospheres exhibit excellent EMW absorption performance,featuring a remarkable minimum reflection loss(RL_(min))of−52.11 dB(2.4 mm).It is noteworthy that these nanospheres achieve an ultra‐wide effective absorption bandwidth(EAB)of 6.72 GHz.This work provides a novel approach for designing and synthesizing high‐performance EMW absorbers characterized by“wide bandwidth and strong reflection loss.”
基金supported by National Natural Science Foundation of China (Nos. 51827901, 52104096)the Shenzhen National Science Fund for Distinguished Young Scholars (No. RCJC20210706091948015)+2 种基金Open Fund of State Key Laboratory of Hydraulics and Mountain River Engineering, Sichuan University (No. SKHL2216)National Key R & D Program of China (No. 2022YFB3706605)Youth Foundation of Sichuan Natural Science Foundation (No. 2023NSFSC0780)。
文摘Using pressure-preserved coring technique to determine in-situ gas content provides a more precise assessment of gas resource reserves and safeguard of mining safety in coal seams. How coring technique and depth affect the determination of gas content is unclear due to borehole zoning rupture caused by roadway excavation and drilling disturbance. To this end, a proposed coupling model of stress distribution and gas migration was simulated and validated by FLAC^(3D) and COMSOL Multiphysics considering superposition effects of roadway excavation and drilling disturbance. The findings indicate that the roadway surrounding rock displays distinct zoning features including stress relief zone, stress concentration zone that is composed of plastic zone, elastic zone, and original stress zone;and the broken situations depending on the borehole peeping are consistent with the corresponding simulation results.On this basis, this study proposes a set of drilling coring depth calculation and prediction model for the gas desorption affected area under engineering disturbance. Optimal depth of coring drilling is not only approach to the in-situ coal bulk, but also can get the balance of the drilling workload and cost controlling. According to the typical mine site geological conditions and the numerical simulation results in this study, if the roadway excavation time is ~1 year, it is recommended that the pressure-preserved coring depth should be greater than 17 m.
基金Guangzhou Key R&D Program/Plan Unveiled Flagship Project,Grant/Award Number:20220602JBGS02Guangzhou Basic and Applied Basic Research Project,Grant/Award Number:202201011449+3 种基金Research Fund Program of Guangdong Provincial Key Laboratory of Fuel Cell Technology,Grant/Award Numbers:FC202220,FC202216Guangdong Basic and Applied Basic Research Foundation,Grant/Award Numbers:2021A1515010167,2022A1515011196National Natural Science Foundation of China,Grant/Award Numbers:21975292,21978331,22068008,52101186Training Program of the Major Research Plan of the National Natural Science Foundation of China,Grant/Award Number:92061124。
文摘Remarkable progress has characterized the field of electrocatalysis in recent decades,driven in part by an enhanced comprehension of catalyst structures and mechanisms at the nanoscale.Atomically precise metal nanoclusters,serving as exemplary models,significantly expand the range of accessible structures through diverse cores and ligands,creating an exceptional platform for the investigation of catalytic reactions.Notably,ligand‐protected Au nanoclusters(NCs)with precisely defined core numbers offer a distinct advantage in elucidating the correlation between their specific structures and the reaction mechanisms in electrocatalysis.The strategic modulation of the fine microstructures of Au NCs presents crucial opportunities for tailoring their electrocatalytic performance across various reactions.This review delves into the profound structural effects of Au NC cores and ligands in electrocatalysis,elucidating their underlying mechanisms.A detailed exploration of the fundamentals of Au NCs,considering core and ligand structures,follows.Subsequently,the interaction between the core and ligand structures of Au NCs and their impact on electrocatalytic performance in diverse reactions are examined.Concluding the discourse,challenges and personal prospects are presented to guide the rational design of efficient electrocatalysts and advance electrocatalytic reactions.
基金Project supported by the National Natural Science Foundation of China (Nos. 12172339 and 11732005)the Beijing Natural Science Foundation of China (No. 1222006)。
文摘A sandwich plate with a corrugation and auxetic honeycomb hybrid core is constructed,and its sound insulation and optimization are investigated.First,the motion governing equation of the sandwich plate is established by the third-order shear deformation theory(TSDT),and then combined with the fluid-structure coupling conditions,and the sound insulation is solved.The theoretical results are validated by COMSOL simulation results,and the effects of the structural parameter on the sound insulation are analyzed.Finally,the standard genetic algorithm is adopted to optimize the sound insulation of the sandwich plate.
基金supported and funded by the Researchers Supporting Project(Project No.RSPD2024R781),King Saud University,Riyadh,Saudi Arabia。
文摘Identifying deformational mechanisms and associated structures at various scales,ranging from regional-scale structures to microscopic fabric,is crucial for the assessment of tectonic development.Thirty-three samples were taken from the Qazzaz metamorphic core complex to estimate the finite strain for felsic and mafic minerals.These samples included gneisses rocks,monzogranite,and metavolcano-sedimentary rocks for both the Thalbah and Bayda groups.Using the Rf/j and Fry methods,the axial ratios(XZ)range about 2.20 to 7.10 and 1.90 to 9.10,respectively.For various rock units,the strain measurements show moderate to highly deformation.Most of the observed samples show shallow WNW dipping along a N to WNW trend of finite strain(X).The short axes(Z)based to be subvertical foliation related with a subhorizontal foliation.The results demonstrate that contacts generated at semi-brittle to ductile deformation and that the strain of magnitude has the same value for different lithologic units.It concluded that nappe generation in orogens results from pure shear deformation.
基金supported by the National Science Foundation of China(Grant No.42230606)。
文摘Here,a nonhydrostatic alternative scheme(NAS)is proposed for the grey zone where the nonhydrostatic impact on the atmosphere is evident but not large enough to justify the necessity to include an implicit nonhydrostatic solver in an atmospheric dynamical core.The NAS is designed to replace this solver,which can be incorporated into any hydrostatic models so that existing well-developed hydrostatic models can effectively serve for a longer time.Recent advances in machine learning(ML)provide a potential tool for capturing the main complicated nonlinear-nonhydrostatic relationship.In this study,an ML approach called a neural network(NN)was adopted to select leading input features and develop the NAS.The NNs were trained and evaluated with 12-day simulation results of dry baroclinic-wave tests by the Weather Research and Forecasting(WRF)model.The forward time difference of the nonhydrostatic tendency was used as the target variable,and the five selected features were the nonhydrostatic tendency at the last time step,and four hydrostatic variables at the current step including geopotential height,pressure in two different forms,and potential temperature,respectively.Finally,a practical NAS was developed with these features and trained layer by layer at a 20-km horizontal resolution,which can accurately reproduce the temporal variation and vertical distribution of the nonhydrostatic tendency.Corrected by the NN-based NAS,the improved hydrostatic solver at different horizontal resolutions can run stably for at least one month and effectively reduce most of the nonhydrostatic errors in terms of system bias,anomaly root-mean-square error,and the error of the wave spatial pattern,which proves the feasibility and superiority of this scheme.
基金the Iranian Nanotechnology Development Committee for their financial supportUniversity of Kashan for supporting this work by Grant No. 1223097/10the micro and nanomechanics laboratory by Grant No. 14022023/5
文摘Curved shells are increasingly utilized in applied engineering due to their shared characteristics with other sandwich structures,flexibility,and attractive appearance.However,the inability of controlling and regulating vibrations and destroying them afterward is a challenge to scientists.In this paper,the curve shell equations and a linear quadratic regulator are adopted for the state feedback design to manage the structure vibrations in state space forms.A five-layer sandwich doubly curved micro-composite shell,comprising two piezoelectric layers for the sensor and actuator,is modeled by the fourth-order shear deformation theory.The core(honeycomb,truss,and corrugated)is analyzed for the bearing of transverse shear forces.The results show that the honeycomb core has a greater effect on the vibrations.When the parameters related to the core and the weight percentage of graphene increase,the frequency increases.The uniform distribution of graphene platelets results in the lowest natural frequency while the natural frequency increases.Furthermore,without taking into account the piezoelectric layers,the third-order shear deformation theory(TSDT)and fourth-order shear deformation theory(FOSDT)align closely.However,when the piezoelectric layers are incorporated,these two theories diverge significantly,with the frequencies in the FOSDT being lower than those in the TSDT.
基金Project supported by the National Natural Science Foundation of China (Gant No.11872323)。
文摘Many networks exhibit the core/periphery structure.Core/periphery structure is a type of meso-scale structure that consists of densely connected core nodes and sparsely connected peripheral nodes.Core nodes tend to be well-connected,both among themselves and to peripheral nodes,which tend not to be well-connected to other nodes.In this brief report,we propose a new method to detect the core of a network by the centrality of each node.It is discovered that such nodes with non-negative centralities often consist in the core of the networks.The simulation is carried out on different real networks.The results are checked by the objective function.The checked results may show the effectiveness of the simulation results by the centralities of the nodes on the real networks.Furthermore,we discuss the characters of networks with the single core/periphery structure and point out the scope of the application of our method at the end of this paper.
基金supported by the National Natural Science Foundation of China (52225403, 52304146)the Sichuan Science and Technology Program (2023NSFSC0919, 2023NSFSC0790)the China Postdoctoral Science Foundation (2023M742460)。
文摘Pressure-preserved coring is an effective means to develop deep resources. However, due to the complexity of existing pressure-preserved technology, the average success rate of pressure-preserved coring is low. In response, a novel in situ magnetically controlled self-sealing pressure-preserved coring technology for deep reserves has been proposed and validated. This innovative technology distinguishes itself from conventional methods by employing noncontact forces to replace traditional pretensioning mechanisms, thereby enhancing the mechanical design of pressure-preserved coring equipment and significantly boosting the fault tolerance of the technology. Here, we report on the design,theoretical calculations, experimental validation, and industrial testing of this technology. Through theoretical and simulation calculations, the self-sealing composite magnetic field of the pressure controller was optimized. The initial pre-tensioning force of the optimal magnetic field was 13.05 N. The reliability of the magnetically controlled self-sealing pressure-preserved coring technology was verified using a self-developed self-sealing pressure performance testing platform, confirming the accuracy of the composite magnetic field calculation theory. Subsequently, a magnetically controlled self-triggering pressure-preserved coring device was designed. Field pressure-preserved coring was then conducted,preliminarily verifying the technology's effective self-sealing performance in industrial applications.Furthermore, the technology was analyzed and verified to be adaptable to complex reservoir environments with pressures up to 30 MPa, temperatures up to 80℃, and p H values ranging from 1 to 14. These research results provide technical support for multidirectional pressure-preserved coring, thus paving a new technical route for deep energy exploration through coring.
基金Project supported by the National Natural Science Foundation of China(Grant No.11974253).
文摘Manganese-based perovskite is popular for research on ferromagnetic materials,and its spectroscopic studies are essential for understanding its electronic structure,dielectric,electrical,and magnetic properties.In this paper,the M-edge spectra of La ions and the M-edge,L-edge,and K-edge spectra of Mn ions in LaMnO3 are calculated by considering both the free-ion multiplet calculation and the crystal field effects.We analyze spectral shapes,identify peak origins,and estimate the oxidation states of La and Mn ions in LaMnO3 theoretically.It is concluded that La ions in LaMnO3 predominantly exist in the trivalent state,while Mn ions exist primarily in the trivalent state with a minor presence of tetravalent ions.Furthermore,the calculated spectra are in better conformity with the experimental spectra when the proportion of Mn3+is 90%and Mn4+is 10%.This article enhances our comprehension of the oxidation states of La and Mn within the crystal and also provides a valuable guidance for spectroscopic investigations of other manganates.
基金funding from the Ministry of Education,Culture,Research,and Technology,Indonesia,through the PDKN Research Grant with Contract No.041/E5/PG.02.00.PL/2023.
文摘Curcumin is a natural polyphenol that is used in various traditional medicines.However,its inherent properties,such as its rapid degradation and metabolism,low bioavailability,and short half-life,are serious problems that must be resolved.To this end,a drug carrier incorporating natural magnetic cores in a zeolite framework was developed and applied to the loading of curcumin in ethanol solutions.In this system,curcumin is encapsulated in a zeolite Na(ZNA)magnetic core–shell structure(Fe@Si/ZNA),which can be easily synthesized using an in situ method.Synthesis of Fe_(3)O_(4) nanoparticles was carried out from natural materials using a co-precipitation method.Analysis of the prepared magnetic core–shell structures and composites was carried out using vibrating-sample magnetometery,Fourier transform infrared spectroscopy,transmission electron microscopy,and x-ray diffraction.The cumulative loading of curcumin in the ZNA composite with 9%nanoparticles was found to reach 90.70%with a relatively long half-life of 32.49 min.Stability tests of curcumin loading in the composite showed that adding magnetic particles to the zeolite framework also increased the stability of the composite structure.Adsorption kinetics and isotherm studies also found that the system follows the pseudo-second-order and Langmuir isotherm models.