The effect of lead anode, rotating cylinder electrode (RCE), amount of 1,2-dihydroxypropane (12-DHP), temperature and rotation on the electrowinning of copper from low concentration acidified copper sulphate solution ...The effect of lead anode, rotating cylinder electrode (RCE), amount of 1,2-dihydroxypropane (12-DHP), temperature and rotation on the electrowinning of copper from low concentration acidified copper sulphate solution has been investigated. Copper powder was electrodeposited onto RCE that made of pure copper. From cyclic voltammetry experiments, an empirical parameter called the departure percent, S, was obtained which may represent the stability of the organic additive in the given medium and under the experimental conditions. The inhibition percentage, P, was 0.00 - 89.91% depending on the experimental variables. P was affected by temperature and mole fraction of 12-DHP, while rotation did not show any influence on it. Values of activation energy of electrodeposition process, Ea, were found to be less than 28 kJ mol-1 indicating diffusion controlled process. The overall mass transfer correlations under the present conditions have been computed using the dimensional analysis method. The data were valid for 90 < Sh < 1098, 737 < Sc < 59284 and 271 < Re < 7046 and the results agreed with the previous studies of mass transfer to rotating cylinders in turbulent flow regimes. The effect of time, content of 12-DHP, temperature and the speed of rotation on the morphological changes of the electrodeposited copper powder as well as deposits composition and crystallite size have been studied. Various crystallite sizes ranged 7.1 nm - 250.6 nm were obtained and characterized by EDS and XRD. Different topographs proved that the rate of copper electrodeposition increased by increasing deposition time, temperature and the speed of rotation. Also, they proved that the deposition rate decreased by adding 12-DHP to the solution. Therefore, the results obtained by SEM supported those achieved by measuring the limiting current density and follow the normal manner when organic solvents were added to the electrodeposition bath.展开更多
A series of sweeping detonation experiments were conducted to study the grain boundary effects during the primary spallation of high-purity copper cylinder.The free surface velocity profile of the shocked samples was ...A series of sweeping detonation experiments were conducted to study the grain boundary effects during the primary spallation of high-purity copper cylinder.The free surface velocity profile of the shocked samples was measured by Doppler pins systems.The soft-recovered samples were characterized by optical and electron backscatter diffraction microscopy,and the effects of microstructures like grain boundaries,and crystal orientation on spall behavior were investigated.The results indicated that the critical stress of deformation twinning in cylindrical copper increased.The nucleation sites of spallation damage were determined by the joint influence of the grain orientation(Taylor factor)and the angle between grain boundaries and radial impact-stress direction.Voids were prone to nucleating at the grain boundaries perpendicular to the radial impact-stress direction.Nevertheless,the number of voids nucleated at boundaries was relatively different from the results obtained from the plate impact experiment and plate sweeping detonation experiment,which is a result of the curvature that existed in the cylindrical copper and the obliquity of the impact-stress direction during sweeping detonation loading.展开更多
介绍了静标铜柱二次预压测压方法及其使用特点，分析了其产生静动差的原因。将二次预压铜柱放入测压器中和电子测压器组成一个测试组在模拟炮上进行了试验，从试验数据的分析看出静动差可高达18％左右。为了减小静动差，以Ф8 mm ×...介绍了静标铜柱二次预压测压方法及其使用特点，分析了其产生静动差的原因。将二次预压铜柱放入测压器中和电子测压器组成一个测试组在模拟炮上进行了试验，从试验数据的分析看出静动差可高达18％左右。为了减小静动差，以Ф8 mm × 13 mm铜柱为例，采用量纲分析和相似理论，建立了二次预压静标铜柱静动态修正公式，并对测量结果进行了修正。结果表明，该修正公式可将静动差减小到3％以内，并可恢复大量的同批次铜柱的测压结果，为各类兵器及弹药的研制提供可信的压力数据。展开更多
文摘The effect of lead anode, rotating cylinder electrode (RCE), amount of 1,2-dihydroxypropane (12-DHP), temperature and rotation on the electrowinning of copper from low concentration acidified copper sulphate solution has been investigated. Copper powder was electrodeposited onto RCE that made of pure copper. From cyclic voltammetry experiments, an empirical parameter called the departure percent, S, was obtained which may represent the stability of the organic additive in the given medium and under the experimental conditions. The inhibition percentage, P, was 0.00 - 89.91% depending on the experimental variables. P was affected by temperature and mole fraction of 12-DHP, while rotation did not show any influence on it. Values of activation energy of electrodeposition process, Ea, were found to be less than 28 kJ mol-1 indicating diffusion controlled process. The overall mass transfer correlations under the present conditions have been computed using the dimensional analysis method. The data were valid for 90 < Sh < 1098, 737 < Sc < 59284 and 271 < Re < 7046 and the results agreed with the previous studies of mass transfer to rotating cylinders in turbulent flow regimes. The effect of time, content of 12-DHP, temperature and the speed of rotation on the morphological changes of the electrodeposited copper powder as well as deposits composition and crystallite size have been studied. Various crystallite sizes ranged 7.1 nm - 250.6 nm were obtained and characterized by EDS and XRD. Different topographs proved that the rate of copper electrodeposition increased by increasing deposition time, temperature and the speed of rotation. Also, they proved that the deposition rate decreased by adding 12-DHP to the solution. Therefore, the results obtained by SEM supported those achieved by measuring the limiting current density and follow the normal manner when organic solvents were added to the electrodeposition bath.
基金Projects(51871243,51574290)supported by the National Natural Science Foundation of ChinaProject(2019JJ40381)supported by the Natural Science Foundation of Hunan Province,ChinaProject supported by the Guangdong-Hong Kong-Macao Joint Laboratory for Neutron Scattering Science and Technology,China。
文摘A series of sweeping detonation experiments were conducted to study the grain boundary effects during the primary spallation of high-purity copper cylinder.The free surface velocity profile of the shocked samples was measured by Doppler pins systems.The soft-recovered samples were characterized by optical and electron backscatter diffraction microscopy,and the effects of microstructures like grain boundaries,and crystal orientation on spall behavior were investigated.The results indicated that the critical stress of deformation twinning in cylindrical copper increased.The nucleation sites of spallation damage were determined by the joint influence of the grain orientation(Taylor factor)and the angle between grain boundaries and radial impact-stress direction.Voids were prone to nucleating at the grain boundaries perpendicular to the radial impact-stress direction.Nevertheless,the number of voids nucleated at boundaries was relatively different from the results obtained from the plate impact experiment and plate sweeping detonation experiment,which is a result of the curvature that existed in the cylindrical copper and the obliquity of the impact-stress direction during sweeping detonation loading.
文摘介绍了静标铜柱二次预压测压方法及其使用特点，分析了其产生静动差的原因。将二次预压铜柱放入测压器中和电子测压器组成一个测试组在模拟炮上进行了试验，从试验数据的分析看出静动差可高达18％左右。为了减小静动差，以Ф8 mm × 13 mm铜柱为例，采用量纲分析和相似理论，建立了二次预压静标铜柱静动态修正公式，并对测量结果进行了修正。结果表明，该修正公式可将静动差减小到3％以内，并可恢复大量的同批次铜柱的测压结果，为各类兵器及弹药的研制提供可信的压力数据。
