A Cu（I） generated in situ from CuSO4.5H2O/sodium ascorbate catalyzed cross-coupling reaction of aryl halides with aqueous ammonia for the synthesis of primary aromatic amines has been developed. Key to the success i...A Cu（I） generated in situ from CuSO4.5H2O/sodium ascorbate catalyzed cross-coupling reaction of aryl halides with aqueous ammonia for the synthesis of primary aromatic amines has been developed. Key to the success in- cluded the application of aqueous ammonia under a homogeneous condition.展开更多
基金We are thankful for the financial support from the National Natural Science Foundation of China （Nos. 20902073 and 21062017）, and the Scientific and Tech- nological Innovation Engineering Program of Northwest Normal University （Nos. nwnukjcxgc-03-64, nwnulkqn- 10-15）.
文摘A Cu（I） generated in situ from CuSO4.5H2O/sodium ascorbate catalyzed cross-coupling reaction of aryl halides with aqueous ammonia for the synthesis of primary aromatic amines has been developed. Key to the success in- cluded the application of aqueous ammonia under a homogeneous condition.
