Because there is neither waste rock nor mill tailings in the gypsum mine, and the buildings on the goaf of gypsum mine are needed to be protected, the research proposed the scheme of the clay filling technology. Gypsu...Because there is neither waste rock nor mill tailings in the gypsum mine, and the buildings on the goaf of gypsum mine are needed to be protected, the research proposed the scheme of the clay filling technology. Gypsum, cement, lime and water glass were used as adhesive, and the strength of different material ratios were investigated in this study. The influence factors of clay strength were obtained in the order of cement, gypsum, water glass and lime. The results show that the cement content is the determinant influence factor, and gypsum has positive effects, while the water glass can enhance both clay strength and the fluidity of the filing slurry. Furthermore, combining chaotic optimization method with neural network, the optimal ratio of composite cementing agent was obtained. The results show that the optimal ratio of water glass, cement, lime and clay (in quality) is 1.17:6.74:4.17:87.92 in the process of bottom self-flow filling, while the optimal ratio is 1.78:9.58:4.71:83.93 for roof-contacted filling. A novel filling process to fill in gypsum mine goaf with clay is established. The engineering practice shows that the filling cost is low, thus, notable economic benefit is achieved.展开更多
Modeling for nitritation process was discussed and analyzed quantitatively for the factors that influence nitrite accumulation. The results indicated that pH, inorganic carbon source and Hydraulic Retention Time(HRT) ...Modeling for nitritation process was discussed and analyzed quantitatively for the factors that influence nitrite accumulation. The results indicated that pH, inorganic carbon source and Hydraulic Retention Time(HRT) as well as biomass concentration are the main factors that influenced the conversion ratio of ammonium to nitrite. A constant high pH can lead to a high nitritation rate and results in high conversion ratio on condition that free ammonia inhibition do not happen. In a CSTR system, without pH control, this conversion ratio can be monitored by pH variation in the reactor. The pH goes down far from the inlet level means a strongly nitrite accumulation. High concentration of alkalinity can promoted the conversion ratio by means of accelerating the nitritation rate through providing sufficient inorganic carbon source(carbon dioxide). When inorganic carbon source was depleted, the nitritation process stopped. HRT adjustment could be an efficient way to make the nitritation system run more flexible, which to some extent can meet the requirements of the fluctuant of inlet parameters such as ammonium concentration, pH, and temperature and so on. Biomass concentration is the key point, especially for a CSTR system in steady state, which was normally circumscribed by the characteristics of bacteria and may also affected by aeration mode and can be increased by prolonging the HRT on the condition of no nitrate accumulation when no recirculation available. The higher the biomass concentration is, the better the nitrite accumulation can be obtained.展开更多
The QDB-5 sulfur tolerant CO shift catalyst, with anti-methanation property by supported compositing alkali promoters, has been proved to effectively reduce the outlet methane content in the condition of a low water g...The QDB-5 sulfur tolerant CO shift catalyst, with anti-methanation property by supported compositing alkali promoters, has been proved to effectively reduce the outlet methane content in the condition of a low water gas ratio. Thus, a new technology based on a lower water/gas ratio than before has been developed with the new catalyst. The CO conversion at lower temperatures and catalyst stability were confirmed by long term industrial application. The high temperature catalyst performance also showed a better result than the conventional commercial catalyst, with higher CO conversion and well controlled methane outlet. Our research and the industrial application of catalyst have shown the importance of alkali metals as core promoters for such kind of catalysts.展开更多
Early Production Facilities are makeshift process deployment that ensures that marginal oilfield operators make revenues from their new discoveries with little cash outlay and limited investment risks. Authors have in...Early Production Facilities are makeshift process deployment that ensures that marginal oilfield operators make revenues from their new discoveries with little cash outlay and limited investment risks. Authors have in past simulated a gas process facility using Hysys without particularly developing mathematical models for the key equipment. There also has been modeling of phase separation dynamics and process simulation but still without models for equipment. We basically developed models for the critical process equipment for early production, sized the equipment with data from a marginal field in the Niger delta region of Nigeria and then ran a dynamic simulation with the sized equipment. The important elements of the deployment are two-phase process vessel, 3-phase process vessel;knock-out drum, produced water treatment unit. Mathematical models were developed and adapted with Mathlab for the equipment sizing whilst ASPEN PLUS was used for simulating the process. Process data retrieved from a marginal field in Nigeria was used as input to quantify the equipment models. Sized equipment was deployed in Hysys V8.8 for a steady and dynamic state. The system simulation was comprised of a two-phase process vessel followed by a 3-phase process vessel [1]. The unwanted gas was sent to knock out drum for removal of entrained liquid droplets before flaring (this was because the volume of gas processed is deemed uneconomical) and produced water to treatment unit for removing droplets of oil before disposal. Gas, oil and water were fed into the first stage separator (2-phase) at 132918.34 Ibmole/hr, 7622.95 Ibmole/hr and 1082.74 Ibmole/hr respectively. The operating pressures of the first and second vessels were at 850 psi and 150 psi respectively. The 2-phase vessel flashed off 96.7% of the gas and increased the liquid recovery by 3.3%. At the end of the second stage separation, oil yield increased by 270 Ibmole/hr, the gas increased by 110.15 Ibmole/hr whilst water reduced by 379 Ibmole/hr. This result confirmed that the vessels were sized to optimize recovery of hydrocarbons entrained in the various phases into the most required oil phase.展开更多
基金supported by the National Basic Research and Development Program of China (No. 2010CB732004)the joint funding of the National Natural Science Foundation and Shanghai Baosteel Group Corporation of China (No. 51074177)
文摘Because there is neither waste rock nor mill tailings in the gypsum mine, and the buildings on the goaf of gypsum mine are needed to be protected, the research proposed the scheme of the clay filling technology. Gypsum, cement, lime and water glass were used as adhesive, and the strength of different material ratios were investigated in this study. The influence factors of clay strength were obtained in the order of cement, gypsum, water glass and lime. The results show that the cement content is the determinant influence factor, and gypsum has positive effects, while the water glass can enhance both clay strength and the fluidity of the filing slurry. Furthermore, combining chaotic optimization method with neural network, the optimal ratio of composite cementing agent was obtained. The results show that the optimal ratio of water glass, cement, lime and clay (in quality) is 1.17:6.74:4.17:87.92 in the process of bottom self-flow filling, while the optimal ratio is 1.78:9.58:4.71:83.93 for roof-contacted filling. A novel filling process to fill in gypsum mine goaf with clay is established. The engineering practice shows that the filling cost is low, thus, notable economic benefit is achieved.
文摘Modeling for nitritation process was discussed and analyzed quantitatively for the factors that influence nitrite accumulation. The results indicated that pH, inorganic carbon source and Hydraulic Retention Time(HRT) as well as biomass concentration are the main factors that influenced the conversion ratio of ammonium to nitrite. A constant high pH can lead to a high nitritation rate and results in high conversion ratio on condition that free ammonia inhibition do not happen. In a CSTR system, without pH control, this conversion ratio can be monitored by pH variation in the reactor. The pH goes down far from the inlet level means a strongly nitrite accumulation. High concentration of alkalinity can promoted the conversion ratio by means of accelerating the nitritation rate through providing sufficient inorganic carbon source(carbon dioxide). When inorganic carbon source was depleted, the nitritation process stopped. HRT adjustment could be an efficient way to make the nitritation system run more flexible, which to some extent can meet the requirements of the fluctuant of inlet parameters such as ammonium concentration, pH, and temperature and so on. Biomass concentration is the key point, especially for a CSTR system in steady state, which was normally circumscribed by the characteristics of bacteria and may also affected by aeration mode and can be increased by prolonging the HRT on the condition of no nitrate accumulation when no recirculation available. The higher the biomass concentration is, the better the nitrite accumulation can be obtained.
文摘The QDB-5 sulfur tolerant CO shift catalyst, with anti-methanation property by supported compositing alkali promoters, has been proved to effectively reduce the outlet methane content in the condition of a low water gas ratio. Thus, a new technology based on a lower water/gas ratio than before has been developed with the new catalyst. The CO conversion at lower temperatures and catalyst stability were confirmed by long term industrial application. The high temperature catalyst performance also showed a better result than the conventional commercial catalyst, with higher CO conversion and well controlled methane outlet. Our research and the industrial application of catalyst have shown the importance of alkali metals as core promoters for such kind of catalysts.
文摘Early Production Facilities are makeshift process deployment that ensures that marginal oilfield operators make revenues from their new discoveries with little cash outlay and limited investment risks. Authors have in past simulated a gas process facility using Hysys without particularly developing mathematical models for the key equipment. There also has been modeling of phase separation dynamics and process simulation but still without models for equipment. We basically developed models for the critical process equipment for early production, sized the equipment with data from a marginal field in the Niger delta region of Nigeria and then ran a dynamic simulation with the sized equipment. The important elements of the deployment are two-phase process vessel, 3-phase process vessel;knock-out drum, produced water treatment unit. Mathematical models were developed and adapted with Mathlab for the equipment sizing whilst ASPEN PLUS was used for simulating the process. Process data retrieved from a marginal field in Nigeria was used as input to quantify the equipment models. Sized equipment was deployed in Hysys V8.8 for a steady and dynamic state. The system simulation was comprised of a two-phase process vessel followed by a 3-phase process vessel [1]. The unwanted gas was sent to knock out drum for removal of entrained liquid droplets before flaring (this was because the volume of gas processed is deemed uneconomical) and produced water to treatment unit for removing droplets of oil before disposal. Gas, oil and water were fed into the first stage separator (2-phase) at 132918.34 Ibmole/hr, 7622.95 Ibmole/hr and 1082.74 Ibmole/hr respectively. The operating pressures of the first and second vessels were at 850 psi and 150 psi respectively. The 2-phase vessel flashed off 96.7% of the gas and increased the liquid recovery by 3.3%. At the end of the second stage separation, oil yield increased by 270 Ibmole/hr, the gas increased by 110.15 Ibmole/hr whilst water reduced by 379 Ibmole/hr. This result confirmed that the vessels were sized to optimize recovery of hydrocarbons entrained in the various phases into the most required oil phase.
文摘碳纤维混杂增强复合材料由于具有重量轻、可设计性强等诸多优点,广泛用于汽车、海洋、航空航天等行业.根据固化剂与环氧树脂的配比化学原理,计算出石墨烯-碳纤维混杂增强树脂基(GO-CF/EP)复合材料的最佳配比为1∶5,并采用真空浸渗热压成型工艺(VIHPS)制备1∶2~1∶7共六个配比的试样,结合形状记忆性能测试及微观形貌的观察,得到固化剂与环氧树脂实际最佳配比.实验结果表明,GO-CF/EP复合材料性能主要取决于体系中交联度的大小,交联度越大,复合材料的形状记忆性能越好,微观组织形貌也较理想.当基体配比为1∶5时,GO-CF/EP复合材料体系中交联度最大,微观形貌呈现均匀致密的状态,形状固定率最大,为95.90%;形状回复率最大,为95.40%;形状回复时间最短,为80.30 s;形状回复力最大,为9.48 N.当基体配比为1∶2或1∶7时,固化剂过量或不足,交联度较小,微观组织形貌中有大量的基体聚集区,其形状记忆性能下降,形状固定率及回复率也相应减小,分别为82.99%,81.66%,81.91%,78.75%;形状回复力分别只有5.20 N和5.50 N.
