Light olefins is the incredibly important materials in chemical industry.Methanol to olefins(MTO),which provides a non-oil route for light olefins production,received considerable attention in the past decades.However...Light olefins is the incredibly important materials in chemical industry.Methanol to olefins(MTO),which provides a non-oil route for light olefins production,received considerable attention in the past decades.However,the catalyst deactivation is an inevitable feature in MTO processes,and regeneration,therefore,is one of the key steps in industrial MTO processes.Traditionally the MTO catalyst is regenerated by removing the deposited coke via air combustion,which unavoidably transforms coke into carbon dioxide and reduces the carbon utilization efficiency.Recent study shows that the coke species over MTO catalyst can be regenerated via steam,which can promote the light olefins yield as the deactivated coke species can be essentially transferred to industrially useful synthesis gas,is a promising pathway for further MTO processes development.In this work,we modelled and analyzed these two MTO regeneration methods in terms of carbon utilization efficiency and technology economics.As shown,the steam regeneration could achieve a carbon utilization efficiency of 84.31%,compared to 74.74%for air combustion regeneration.The MTO processes using steam regeneration can essentially achieve the near-zero carbon emission.In addition,light olefins production of the MTO processes using steam regeneration is 12.81%higher than that using air combustion regeneration.In this regard,steam regeneration could be considered as a potential yet promising regeneration method for further MTO processes,showing not only great environmental benefits but also competitive economic performance.展开更多
In this paper we address the dynamics of compensation cutting process from both Laplace s frequency domain and the time domain of the first time, using the two computer aided analyzing softwares: MATLAB and SIMULI...In this paper we address the dynamics of compensation cutting process from both Laplace s frequency domain and the time domain of the first time, using the two computer aided analyzing softwares: MATLAB and SIMULINK. Theoretical analysis and simulation experiments firstly show that not only the systematical stiffness of workpiece, spindle and tools, but also the regenerated coefficient affects the compensation displacement effect. The results show that the SREC is practicable in reality to decease the spindle induced errors in many engineering applications such as hard boring through simulation and the preliminary experiment results.展开更多
Recovering waste heat from industrial processes is bene ficial in order to reduce the primary energy demands and heat pumps can be used to this purpose.Absorption heat pumps are energy-saving and environment-friendly ...Recovering waste heat from industrial processes is bene ficial in order to reduce the primary energy demands and heat pumps can be used to this purpose.Absorption heat pumps are energy-saving and environment-friendly because use working fluids that do not cause ozone depletion and can reduce the global warming emissions.The hybrid heat pump processes combine the conventional vapor-compression and the absorption heat pump cycles.Studies about the simulations and modeling of hybrid heat pumps are few in literature.In this research a mathematical model for single effect absorption and hybrid heat pump is carried out with Chem Cad? 6.0.1.LiBr–H_2O is used as working fluid while electrolytic NRTL and electrolytes latent heat are used as thermodynamic model due to the better results.Binary parameters of activity coef ficients are regressed from experimental vapor pressure data while default constants are used for the solubility expressions.A design of heat pumps is developed and a new modeling of generator is analyzed.The coef ficient of performance of absorption heat pump and hybrid heat pump is equal to 0.7 and 0.83 respectively.For absorption heat pump a sensitivity analysis is carried out to evaluate the effect of temperature and pressure generator,the concentration of Li–Br solution on coef ficient of performance,cooling capacity and working fluid temperature.For hybrid heat pump,the different coef ficients of performance,the primary energy ratio,the generator heat,and the compressor power are analyzed for different values of compressor proportion.Results show that comparing the two systems the hybrid pump allows to save more primary energy,costs and carbon dioxide emissions with respect to absorption heat pump with the increasing of compressor proportion parameter.Future researches should focus on the construction of this heat pumps integrated in chemical processes as a biogas plant or trigeneration systems.展开更多
The catalyst regeneration process running under the partial oxidation mode in traditional fluid catalytic cracking(FCC)units needs a carbon monoxide(CO)boiler to burn the flue gas,resulting in a large volume of CO_(2)...The catalyst regeneration process running under the partial oxidation mode in traditional fluid catalytic cracking(FCC)units needs a carbon monoxide(CO)boiler to burn the flue gas,resulting in a large volume of CO_(2) emissions.In this study,the performance of a set of industrial serial-type FCC regenerators and the changes in flue gas composition were analyzed by establishing a model of the regenerators and the flue gas energy recovery section.Considering the value of utilizing CO,based on the simulation,this paper proposes two schemes for maximizing CO content in the flue gas of regenerators.The two sets of optimal process operating parameters were obtained using a genetic algorithm.Compared with the original process,the CO contents of flue gas in the two optimized processes increased to 6.6%and 12.5%,CO_(2) emissions were reduced by 48.4%and 96.7%,and the costs of CO production were 0.57$/m^(3) and 0.84$/m^(3),respectively.展开更多
基金the financial support from the Strategic Priority Research Program of Chinese Academy of Sciences(XDA21010100)。
文摘Light olefins is the incredibly important materials in chemical industry.Methanol to olefins(MTO),which provides a non-oil route for light olefins production,received considerable attention in the past decades.However,the catalyst deactivation is an inevitable feature in MTO processes,and regeneration,therefore,is one of the key steps in industrial MTO processes.Traditionally the MTO catalyst is regenerated by removing the deposited coke via air combustion,which unavoidably transforms coke into carbon dioxide and reduces the carbon utilization efficiency.Recent study shows that the coke species over MTO catalyst can be regenerated via steam,which can promote the light olefins yield as the deactivated coke species can be essentially transferred to industrially useful synthesis gas,is a promising pathway for further MTO processes development.In this work,we modelled and analyzed these two MTO regeneration methods in terms of carbon utilization efficiency and technology economics.As shown,the steam regeneration could achieve a carbon utilization efficiency of 84.31%,compared to 74.74%for air combustion regeneration.The MTO processes using steam regeneration can essentially achieve the near-zero carbon emission.In addition,light olefins production of the MTO processes using steam regeneration is 12.81%higher than that using air combustion regeneration.In this regard,steam regeneration could be considered as a potential yet promising regeneration method for further MTO processes,showing not only great environmental benefits but also competitive economic performance.
文摘In this paper we address the dynamics of compensation cutting process from both Laplace s frequency domain and the time domain of the first time, using the two computer aided analyzing softwares: MATLAB and SIMULINK. Theoretical analysis and simulation experiments firstly show that not only the systematical stiffness of workpiece, spindle and tools, but also the regenerated coefficient affects the compensation displacement effect. The results show that the SREC is practicable in reality to decease the spindle induced errors in many engineering applications such as hard boring through simulation and the preliminary experiment results.
文摘Recovering waste heat from industrial processes is bene ficial in order to reduce the primary energy demands and heat pumps can be used to this purpose.Absorption heat pumps are energy-saving and environment-friendly because use working fluids that do not cause ozone depletion and can reduce the global warming emissions.The hybrid heat pump processes combine the conventional vapor-compression and the absorption heat pump cycles.Studies about the simulations and modeling of hybrid heat pumps are few in literature.In this research a mathematical model for single effect absorption and hybrid heat pump is carried out with Chem Cad? 6.0.1.LiBr–H_2O is used as working fluid while electrolytic NRTL and electrolytes latent heat are used as thermodynamic model due to the better results.Binary parameters of activity coef ficients are regressed from experimental vapor pressure data while default constants are used for the solubility expressions.A design of heat pumps is developed and a new modeling of generator is analyzed.The coef ficient of performance of absorption heat pump and hybrid heat pump is equal to 0.7 and 0.83 respectively.For absorption heat pump a sensitivity analysis is carried out to evaluate the effect of temperature and pressure generator,the concentration of Li–Br solution on coef ficient of performance,cooling capacity and working fluid temperature.For hybrid heat pump,the different coef ficients of performance,the primary energy ratio,the generator heat,and the compressor power are analyzed for different values of compressor proportion.Results show that comparing the two systems the hybrid pump allows to save more primary energy,costs and carbon dioxide emissions with respect to absorption heat pump with the increasing of compressor proportion parameter.Future researches should focus on the construction of this heat pumps integrated in chemical processes as a biogas plant or trigeneration systems.
文摘The catalyst regeneration process running under the partial oxidation mode in traditional fluid catalytic cracking(FCC)units needs a carbon monoxide(CO)boiler to burn the flue gas,resulting in a large volume of CO_(2) emissions.In this study,the performance of a set of industrial serial-type FCC regenerators and the changes in flue gas composition were analyzed by establishing a model of the regenerators and the flue gas energy recovery section.Considering the value of utilizing CO,based on the simulation,this paper proposes two schemes for maximizing CO content in the flue gas of regenerators.The two sets of optimal process operating parameters were obtained using a genetic algorithm.Compared with the original process,the CO contents of flue gas in the two optimized processes increased to 6.6%and 12.5%,CO_(2) emissions were reduced by 48.4%and 96.7%,and the costs of CO production were 0.57$/m^(3) and 0.84$/m^(3),respectively.
