The influence of process control agents （PCAs） on the mechanical properties of Ni3AI intermetallic compounds by mechanical alloying was investigated in order to develop oxide deposition reinforced intermetallics. Th...The influence of process control agents （PCAs） on the mechanical properties of Ni3AI intermetallic compounds by mechanical alloying was investigated in order to develop oxide deposition reinforced intermetallics. The PCAs in mechanical alloying were pure ligroin, 75 vol.% ligroin ＋ 25 vol.% alcohol, 50 vol.% ligroin ＋ 50 vol.% alcohol, 25 vol.% ligroin ＋ 75 vol.% alcohol, and pure alcohol. The normal composition is Ni-22.9at.%Al-0.5at.%B, the ball-to-powder weight ratio is 10：1, and the milling time is 30 min. Then, the powders were sintered by spark plasma sintering under 40 MPa for 5 min at 1000℃. The results show that a higher bending strength and a higher hardness were obtained when the PCAs were 75% ligroin ＋ 25% alcohol in mechanical alloying. The bending strength is about 2700 MPa and the hardness （HV） is more than 6 GPa.展开更多
The evolutions of microstructure of Fe0.85Ni0.15 products, which were prepared by mechanical alloying (MA) with and without process control agent (PCA), were studied using X-ray diffraction and scanning electron micro...The evolutions of microstructure of Fe0.85Ni0.15 products, which were prepared by mechanical alloying (MA) with and without process control agent (PCA), were studied using X-ray diffraction and scanning electron microscopy respectively. After MA without PCA (dry method) for 30h, Fe0.85Ni0.15 nanocrystalline alloy powders with bcc-Fe(Ni) phase were obtained; however, powders milled with PCA (wet method) from 20 to 90 h, were unalloyed Fe-Ni mixtures with balanced morphology. It seems that dry method works efficiently in nanocrystalline alloying while wet method postpones MA but functionally fines the morphology of materials. Finally, the results were discussed considering the MA kinetics.展开更多
Different amounts of absolute ethanol(0-50 mL)are used as process control agents(PCA)to prepare FeCoNiAlCr0.9 high entropy alloy(HEA)powders via 90 h ball milling.The results show that the increased amount of PCA play...Different amounts of absolute ethanol(0-50 mL)are used as process control agents(PCA)to prepare FeCoNiAlCr0.9 high entropy alloy(HEA)powders via 90 h ball milling.The results show that the increased amount of PCA plays an active role in the crystallinity of powders,and regulate the thickness and size distribution of flake particles.As the volume of PCA increases,the real and imaginary parts(ε′andε″)of complex permittivity get increased by the enhancement of the interface polarization and surface polarization,while the increase in the real and imaginary parts(μ′andμ″)of complex permeability arises from the increased anisotropic energy.The addition of PCA not only promotes the reflection loss but also extends the effective bandwidth(up to 4.28 GHz).Here,the performance adjustment of HEA electromagnetic absorber is realized by forthrightly changing the process parameters of ball milling.展开更多
文摘The influence of process control agents （PCAs） on the mechanical properties of Ni3AI intermetallic compounds by mechanical alloying was investigated in order to develop oxide deposition reinforced intermetallics. The PCAs in mechanical alloying were pure ligroin, 75 vol.% ligroin ＋ 25 vol.% alcohol, 50 vol.% ligroin ＋ 50 vol.% alcohol, 25 vol.% ligroin ＋ 75 vol.% alcohol, and pure alcohol. The normal composition is Ni-22.9at.%Al-0.5at.%B, the ball-to-powder weight ratio is 10：1, and the milling time is 30 min. Then, the powders were sintered by spark plasma sintering under 40 MPa for 5 min at 1000℃. The results show that a higher bending strength and a higher hardness were obtained when the PCAs were 75% ligroin ＋ 25% alcohol in mechanical alloying. The bending strength is about 2700 MPa and the hardness （HV） is more than 6 GPa.
文摘The evolutions of microstructure of Fe0.85Ni0.15 products, which were prepared by mechanical alloying (MA) with and without process control agent (PCA), were studied using X-ray diffraction and scanning electron microscopy respectively. After MA without PCA (dry method) for 30h, Fe0.85Ni0.15 nanocrystalline alloy powders with bcc-Fe(Ni) phase were obtained; however, powders milled with PCA (wet method) from 20 to 90 h, were unalloyed Fe-Ni mixtures with balanced morphology. It seems that dry method works efficiently in nanocrystalline alloying while wet method postpones MA but functionally fines the morphology of materials. Finally, the results were discussed considering the MA kinetics.
基金the National Natural Science Foundation of China(Nos.51577021 and U1704253)the National Key R&D Program of China(No.2017YFB0703103)the Fundamental Research Funds for the Central Universities(No.DUT20GF111)。
文摘Different amounts of absolute ethanol(0-50 mL)are used as process control agents(PCA)to prepare FeCoNiAlCr0.9 high entropy alloy(HEA)powders via 90 h ball milling.The results show that the increased amount of PCA plays an active role in the crystallinity of powders,and regulate the thickness and size distribution of flake particles.As the volume of PCA increases,the real and imaginary parts(ε′andε″)of complex permittivity get increased by the enhancement of the interface polarization and surface polarization,while the increase in the real and imaginary parts(μ′andμ″)of complex permeability arises from the increased anisotropic energy.The addition of PCA not only promotes the reflection loss but also extends the effective bandwidth(up to 4.28 GHz).Here,the performance adjustment of HEA electromagnetic absorber is realized by forthrightly changing the process parameters of ball milling.
