Vacancy engineering mediated hollow structured ZnO/ZnS S-scheme heterojunction for highly efficient photocatalytic H_(2) production

Designing a step-scheme(S-scheme)heterojunction photocatalyst with vacancy engineering is a reliable approach to achieve highly efficient photocatalytic H_(2)production activity.Herein,a hollow ZnO/ZnS S-scheme heterojunction with O and Zn vacancies(VO,Zn-ZnO/ZnS)is rationally constructed via ion-exchange and calcination treatments.In such a photocatalytic system,the hollow structure combined with the introduction of dual vacancies endows the adequate light absorption.Moreover,the O and Zn vacancies serve as the trapping sites for photo-induced electrons and holes,respectively,which are beneficial for promoting the photo-induced carrier separation.Meanwhile,the S-scheme charge transfer mechanism can not only improve the separation and transfer efficiencies of photo-induced carrier but also retain the strong redox capacity.As expected,the optimized VO,Zn-ZnO/ZnS heterojunction exhibits a superior photocatalytic H_(2) production rate of 160.91 mmol g^(-1)h^(-1),approximately 643.6 times and 214.5 times with respect to that obtained on pure ZnO and ZnS,respectively.Simultaneously,the experimental results and density functional theory calculations disclose that the photo-induced carrier transfer pathway follows the S-scheme heterojunction mechanism and the introduction of O and Zn vacancies reduces the surface reaction barrier.This work provides an innovative strategy of vacancy engineering in S-scheme heterojunction for solar-to-fuel energy conversion.

Progress and prospects of oil and gas production engineering technology in China

This paper summarizes the important progress in the field of oil and gas production engineering during the"Thirteenth Five-Year Plan"period of China,analyzes the challenges faced by the current oil and gas production engineering in terms of technological adaptability,digital construction,energy-saving and emission reduction,and points out the future development direction.During the"Thirteenth Five-Year Plan"period,series of important progresses have been made in five major technologies,including separated-layer injection,artificial lift,reservoir stimulation,gas well de-watering,and workover,which provide key technical support for continuous potential tapping of mature oilfields and profitable production of new oilfields.Under the current complex international political and economic situation,oil and gas production engineering is facing severe challenges in three aspects:technical difficulty increases in oil and gas production,insignificant improvements in digital transformation,and lack of core technical support for energy-saving and emission reduction.This paper establishes three major strategic directions and implementation paths,including oil stabilization and gas enhancement,digital transformation,and green and low-carbon development.Five key research areas are listed including fine separated-layer injection technology,high efficiency artificial lift technology,fine reservoir stimulation technology,long term gas well de-watering technology and intelligent workover technology,so as to provide engineering technical support for the transformation,upgrading and high-quality development of China’s oil and gas industry.

Achievements and future work of oil and gas production engineering of CNPC

This paper summarizes the latest achievements and technological progress in oil and gas production engineering of China National Petroleum Corporation(CNPC) and discusses the main four challenges faced: developing low quality resource at low oil price; keeping stable production of mature oilfields when well oil production drops year by year; low systematic efficiency, high cost, prominent environmental protection issue and short of technological strategy for high water cut ratio and high oil recovery ratio oilfields; and lacking of high level horizontal well drilling and completion technology to develop unconventional and deep reservoirs. Three technological development directions to address these challenges are put forward: developing fracture controlling stimulation and well factory to produce low quality resource economically, developing re-fracturing technology for old wells in mature oilfields, promoting the fourth generation separate layer water injection technology to stabilize the production of mature oilfields; innovating new technologies of water flooding with nano-material, injecting and producing through one well.

Automated Dimensioning Method of Engineering Drawings for Mechanical Products Based on Curve Chain

An automated method based on the curve chain was proposed for dimensioning of engineering drawings for the mechanical products.According to the internal relation between the features of 3D model feature and elements of 2D drawing,the curve chain was established to reflect the geometric topological structure between the elements.It divides the dimensions into the absolute dimensions within the cure chain and the relative dimensions between the curve chains.The parallel and lengthy relationship between the drawing elements of the constructed X and Y parallel matrix was solved to remove redundant elements in the curve chain and labeled the absolute dimensions of the remaining valid elements.The average minimum weight coefficient was introduced to judge the dependence on the relative dimensions between curve chains.Through the analysis of the overlap between the circular rectangular areas,including all the absolute dimensions of the curve chains,overlapping curve chains were merged,and their dimensions were rearranged to avoid the cross interference between them.The method was seamlessly integrated into the drafting module of product design software NX,and it developed an automated dimensioning system.The examples show that the system has excellent interactivity and robustness in the dimensioning of product engineering drawings.The dimension information is complete,accurate and reliable.

Development of Sustainable Solutions for Zebra Mussel Control Through Chemical Product Engineering

The zebra mussel is an important aquatic pest that causes great damage to freshwater-dependent industries, due to biofouling. The main goal of the project discussed here is to develop improved solutions to control this species. Three approaches have been explored in an attempt to design innovative application strategies for existing biocides： （i） encapsulation of toxins; （ii） combination of toxins; （iii） investigation of the seasonal variation of the species＇ tolerance to toxins. In this paper, the principles behind these approaches and the major results on each topic are presented. The benefits of adopting a chemical product engineering approach in conducting this project are also discussed.

Task Decomposition Technique's Deduction and Application of Product Developing Process in Concurrent Engineering

Task decomposition is a kind of powerful technique increasingly being used within industry as a pathway for achieving product's developing success. In this paper, topology's concept in modern mathematics is used for task decomposition technique's deduction in product developing process. It puts fonvard the views of resolvability, measurability and connectivity of tasks and their practi-cal principles. Combined with an example of developing the typical mechanical product, it ex-plains the implementing method of task decomposition in Concurrent Engineering (CE).

A Domain Engineering Approach to Increase Productivity in the Development of a Service for Changes Notification of the Configuration Management Database

This paper presents a domain engineering approach to build a software product line that supports the change notification service in a Configuration Management Database (CMDB) according to the Information Technology Infrastructure Library (ITIL) best practices. For the development of this product line, the proposed approach makes use of a construction of products methodology by analogy: this is a new notation which reports the variability of the products, obtaining metrics as important as the number of products and uses a language that enables, by means of the flexibilization of a product and the development of some generators, to build the rest of the product line. In addition the paper offers a standard for the analysis and design of the CMDB as well. Finally, the paper presents an economic model for the product line, where the profitability and productivity of the proposed solution are analyzed.

Research on a Product Information Management System Facing Remanufacture Engineering

Remanufacture Engineering is an important characteristic and development trend of a manufacturing system in the 21st Century, and product information management is very important to Remanufacture Engineering. In this paper, we first compared traditional manufacturing and remanufacturing. Then, according to the features of Remanufacture Engineering, we analyzed the request of product information management system facing Remanufacture Engineering, and designed the system module. Finally, we built a kind of system structure of product information management facing Remanufacture Engineering and gave realization methods based on Web.

Development and Application of WebGIS Middleware in Oil Production Engineering

WebGIS is the result of combining the technology of Internet with that of Geographic Information Systems (GIS). This paper aims at some problems in the development of GIS, such as the system of development is instable, and presents the method of adopting component technology to accomplish WebGIS middleware which has been successfully applied to the Oil Production Engineering information visible system. It showed in practice that the WebGIS middleware can be casily embedded in the web pages to accomplish GIS application system in a network environment. On the one hand, its application can reduce complexity of system and speed up the pace of development. On the other hand, it is certain to reduce the development costs and improve the maintainability. Key words WebGIS - middleware - oil production engineering CLC number TP 31 Biography: LIU Quan (1969-), male, Ph. D. candidate, research direction: include automated resoning, WebGIS.

Intercalation Assembly and Chemical Product Engineering of Layered Intercalated Functional Materials Based on Efficient Utilization of Magnesium Resources in Salt Lakes

1 Introduction Magnesium salts are very important by-product of salt lake industry in West China.Nearly 200 million cubic meters of waste brine are released to the environment

A CORBA-Based Integration Platform of Product Development Process Management for Concurrent Engineering

Product development process management plays an important role in concurrent engineering (CE). The integration platform is a useful tool for effectively supporting the software development and integration. Based on the analysis of practical requirements for product development process management for CE, a CORBA-based integration platform of product development process management (IP-PDPM) is designed and developed. The design principles for IP-PDPM are described. The system architecture and functions of the platform are given, the key technologies for the implementation of IP-PDPM are presented, the application integration mechanism and its implementation techniques are also detailed.

Integrated Product and Process Design Using a Reverse Engineering System

Computer-integrated manufacturing (CIM) and revers e engineering (RE) have changed drastically the concept of product re-design, pla nning and manufacture of components. However, the main problems currently facing the developers of reverse engineering system, is the time consuming digitis ation of 3D data and the conversion of large amounts of data into a concise and manageable format and linking it to a CAD/CAM system. Automated 3-D profile gen eration, measurements and inspection of manufactured component represents one of the important functions in reverse engineering and in the improvements in produ ct quality in rapid product developments. The paper presents a novel methodology for the development of a reverse enginee ring technique for use in the rapid product development in a CIM environment . The system developed provides integration, data capture and manipulation, dat a transfer between a CAD, CAM, Computer-aided inspection (CAI) and a 3-D profi le scanning system. An efficient scanning strategy has been developed for scann ing and surfaces data acquisition. The products were scanned using a laser scann ing system with a dedicated scan control card and the associated software packag es. A versatile rig was developed for the ease of data gathering of the profile scanning process. The surface data collected was then used to build a mathematic al surface model, which was then used to develop a virtual 3-D model of the pro duct. The resulting surface model provides the geometrical input to the subseque nt machining operation using either a CNC system or other manufacturing operatio n e.g. dies casting/mould casting etc. The prototypes developed were inspected u sing a state-of-the art CNC-CMM that was integrated to the CAD/CAM system. Si nce the scanning/digitised data captured by laser scanning probes requires no ma nual editing, significant time saving over most non-contact probe systems was a chieved. Since the creation of an accurate CAD model of a redesigned component o r a prototype constitute a major element of the total turnaround time; maximum r eturn can be achieved by increasing the efficiency of the redesigning process. T he paper also outlines with a case study the application of the developed system . The system developed offers the flexibility of using the concept of reverse en gineering of a variety of components with the complimentary facility of integrat ion between CAD/CAM Computer-aided Inspection (CAI) systems and a scanning syst em. The developed reverse engineering application in an integrated manufacturing system can increase the consistency, improve cost-efficiency, reduce produ ct turn around and skill levels required to redesign, reengineer and prototyping components and products.

Development of Simulation Tool Orienting Production Engineering

A simulation tool named BITSIM orienting production engineering is developed in order to improve enterprise＇s productivity and making up the scarcity of computer application. The architecture of BITSIM is presented first. Hierarchical technique, control strategy based on multi-agent and simulation output analysis are depicted in detail then. In the end, an application example is taken out to prove that this system could be used to analyzing different hypothetical situation and configuring the auxiliary manufacturing system before production.

Concurrent Engineering oriented Integrated Product Model Based on STEP

In this paper, the generalized feature concept is put forward according to concurrent engineering. An integrated product model is established based on the generalized feature according to STEP in order to provide enrichment information for product concurrent development process. The integration of the information and function of CAD/CAPP can be realized based on the integrated product model that supports concurrent engineering. IPM has been used successfully in product concurrent development.

Lateral bearing characteristics of subsea wellhead assembly in the hydrate trial production engineering

Conductor and suction anchor are the key equipment providing bearing capacity in the field of deep-water drilling or offshore engineering,which have the advantages of high operation efficiency and short construction period.In order to drill a horizontal well in the shallow hydrate reservoir in the deep water,the suction anchor wellhead assembly is employed to undertake the main vertical bearing capacity in the second round of hydrate trial production project,so as to reduce the conductor running depth and heighten the kick-off point position.However,the deformation law of the deep-water suction anchor wellhead assembly under the moving load of the riser is not clear,and it is necessary to understand the lateral bearing characteristics to guide the design of its structural scheme.Based on 3D solid finite element method,the solid finite element model of the suction anchor wellhead assembly is established.In the model,the seabed soil is divided into seven layers,the contact between the wellhead assembly and the soil is simulated,and the vertical load and bending moment are applied to the wellhead node to simulate the riser movement when working in the deep water.The lateral bearing stability of conventional wellhead assembly and suction anchor wellhead assembly under the influence of wellhead load is discussed.The analysis results show that the bending moment is the main factor affecting the lateral deformation of the wellhead string;the anti-bending performance from increasing the outer conductor diameter is better than that from increasing the conductor wall thickness;for the subsea wellhead,the suction anchor obviously improves the lateral bearing capacity and reduces the lateral deformation.The conduct of the suction anchor wellhead assembly still needs to be lowered to a certain depth that below the maximum disturbed depth to ensure the lateral bearing stability,Thus,a method for the minimum conductor running depth for the suction anchor wellhead assembly is developed.The field implementations show that compared with the first round of hydrate trial production project,the conductor running depth is increased by 9.42 m,and there is no risk of wellhead overturning during the trial production.The method for determining the minimum conductor running depth in this paper is feasible and will still play an important role in the subsequent hydrate exploration and development.

Novel Technology and Products: Fluidized Bed Incineration and Energy Recovery for Waste Disposal——Developed by the Institute for Thermal Power Engineering, Zhejiang University

The waste referred to includes solid waste and sludge. Solid waste is mainly from urban garbage and industrial waste. Sludge is from water treatment factories, paper mills, chemical factories, pharmaceutical factories, rivers and lakes. The waste and sludge are very harmful to water organisms, human health and drinking water, and directly affect the environment. Sludge and waste also occupy large areas of land. There are several methods to treat waste and sludge, such as burial, chemical treatment and incineration. Incineration is more effective than the

State of the Art Manufacturing and Engineering of Nanocellulose: A Review of Available Data and Industrial Applications

This review provides a critical overview of the recent methods and processes developed for the production of cellulose nanoparticles with controlled morphology, structure and properties, and also sums up (1) the processes for the chemical modifications of these particles in order to prevent their re-aggregation during spray-drying procedures and to increase their reactivity, (2) the recent processes involved in the production of nanostructured biomaterials and composites. The structural and physical properties of those nanocelluloses, combined with their biodegradability, make them materials of choice in the very promising area of nanotechnology, likely subject to major commercial successes in the context of green chemistry. With a prospective and pioneering approach to the subject matter, various laboratories involved in this domain have developed bio-products now almost suitable to industrial applications;although some important steps remain to be overcome, those are worth been reviewed and supplemented. At this stage, several pilot units and demonstration plants have been built to improve, optimize and scale-up the processes developed at laboratory scale. Industrial reactors with suitable environment and modern control equipment are to be expected within that context. This review shall bring the suitable processing dimension that may be needed now, given the numerous reviews outlining the product potential attributes. An abundant literature database, close to 250 publications and patents, is provided, consolidating the various research and more practical angles.

FuzEmotion as a Backward Kansei Engineering Tool

Kansei engineering, also known as k, unsei ergonomics or emotional engineering, aims at analysing and incorporating customer＇s feeling and demands into product function and product design. Founded in the late 1970＇s, kansei is now considered as a key consumer-oriented technology for new product development. This paper described a system called FuzEmotion for the purpose of assessing the kansei aspects of a product by considering design attributes of a product. Fuzzy logic is used to represent kansei words and process fuzzy input. The system has been successfully implemented to ascertain gender inclination of a mobile phone. Principal parameters of a mobile phone are considered, i.e., length, width, thickness, and mass. The system can inform gender inclination of a mobile phone with accuracy up to 76 %. This is based on a set of 92 mobile phone samples from the five major mobile phone manufacturers.

Computational chemical engineering–Towards thorough understanding and precise application

The paradigms of chemical engineering discipline are discussed. The first paradigm of Unit Operations and the second paradigm of Transport Phenomena are well recognized among the chemical engineers all over the world, and what the next paradigm is remains still an open question. Several proposals such as Chemical product engineering, Sustainable chemical engineering and Multi-scale methodology are considered as candidates for next paradigm. Might Computational Chemical Engineering be the next one, which is advancing the discipline of chemical engineering toward ultimate mechanism-based understanding of chemical processes? This possibility is comparatively expounded with other proposals, and the scope and depth of computational chemical engineering are shortly listed.

Membrane Engineering for Green Process Engineering

Green process engineering, which is based on the principles of the process intensification strategy, can provide an important contribution toward achieving industrial sustainable development. Green process engineering refers to innovative equipment and process methods that are expected to bring about substan- tial improvements in chemical and any other manufacturing and processing aspects. It includes decreasing production costs, equipment size, energy consumption, and waste generation, and improving remote con- trol, information fluxes, and process flexibility. Membrane-based technology assists in the pursuit of these principles, and the potential of membrane operations has been widely recognized in the last few years. This work starts by presenting an overview of the membrane operations that are utilized in water treatment and in the production of energy and raw materials. Next, it describes the potential advantages of innovative membrane-based integrated systems. A case study on an integrated membrane system （IMS） for seawa- ter desalination coupled with raw materials production is presented. The aim of this work is to show how membrane systems can contribute to the realization of the goals of zero liquid discharge （ZLD）, total raw materials utilization, and low energy consumption.