Pixelated non-volatile programmable photonic integrated circuits with 20-level intermediate states

Multi-level programmable photonic integrated circuits(PICs)and optical metasurfaces have gained widespread attention in many fields,such as neuromorphic photonics,opticalcommunications,and quantum information.In this paper,we propose pixelated programmable Si_(3)N_(4)PICs with record-high 20-level intermediate states at 785 nm wavelength.Such flexibility in phase or amplitude modulation is achieved by a programmable Sb_(2)S_(3)matrix,the footprint of whose elements can be as small as 1.2μm,limited only by the optical diffraction limit of anin-house developed pulsed laser writing system.We believe our work lays the foundation for laser-writing ultra-high-level(20 levels and even more)programmable photonic systems and metasurfaces based on phase change materials,which could catalyze diverse applications such as programmable neuromorphic photonics,biosensing,optical computing,photonic quantum computing,and reconfigurable metasurfaces.

Self-assembly of perovskite nanocrystals:From driving forces to applications

Self-assembly of metal halide perovskite nanocrystals(NCs)into superlattices can exhibit unique collective properties,which have significant application values in the display,detector,and solar cell field.This review discusses the driving forces behind the self-assembly process of perovskite NCs,and the commonly used self-assembly methods and different self-assembly structures are detailed.Subsequently,we summarize the collective optoelectronic properties and application areas of perovskite superlattice structures.Finally,we conclude with an outlook on the potential issues and future challenges in developing perovskite NCs.

Alcohol solvent effect on the self-assembly behaviors of lignin oligomers

The interactions between lignin oligomers and solvents determine the behaviors of lignin oligomers self-assembling into uniform lignin nanoparticles(LNPs).Herein,several alcohol solvents,which readily interact with the lignin oligomers,were adopted to study their effects during solvent shifting process for LNPs’production.The lignin oligomers with widely distributed molecular weight and abundant guaiacyl units were extracted from wood waste(mainly consists of pine wood),exerting outstanding self-assembly capability.Uniform and spherical LNPs were generated in H_(2)O-n-propanol cosolvent,whereas irregular LNPs were obtained in H_(2)O-methanol cosolvent.The unsatisfactory self-assembly performance of the lignin oligomers in H_(2)O-methanol cosolvent could be attributed to two aspects.On one hand,for the initial dissolution state,the distinguishing Hansen solubility parameter and polarity between methanol solvent and lignin oligomers resulted in the poor dispersion of the lignin oligomers.On the other hand,strong hydrogen bonds between methanol solvent and lignin oligomers during solvent shifting process,hindered the interactions among the lignin oligomers for self-assembly.

Reconfigurable mechanism-based metamaterials for ternary-coded elastic wave polarizers and programmable refraction control

Elastic metamaterials with unusual elastic properties offer unprecedented ways to modulate the polarization and propagation of elastic waves.However,most of them rely on the resonant structural components,and thus are frequency-dependent and unchangeable.Here,we present a reconfigurable 2D mechanism-based metamaterial which possesses transformable and frequency-independent elastic properties.Based on the proposed mechanism-based metamaterial,interesting functionalities,such as ternarycoded elastic wave polarizer and programmable refraction,are demonstrated.Particularly,unique ternary-coded polarizers,with 1-trit polarization filtering and 2-trit polarization separating of longitudinal and transverse waves,are first achieved.Then,the strong anisotropy of the proposed metamaterial is harnessed to realize positive-negative bi-refraction,only-positive refraction,and only-negative refraction.Finally,the wave functions with detailed microstructures are numerically verified.

A novel one-time-programmable memory unit based on Schottky-type p-GaN diode

In this work,a novel one-time-programmable memory unit based on a Schottky-type p-GaN diode is proposed.During the programming process,the junction switches from a high-resistance state to a low-resistance state through Schottky junction breakdown,and the state is permanently preserved.The memory unit features a current ratio of more than 10^(3),a read voltage window of 6 V,a programming time of less than 10^(−4)s,a stability of more than 108 read cycles,and a lifetime of far more than 10 years.Besides,the fabrication of the device is fully compatible with commercial Si-based GaN process platforms,which is of great significance for the realization of low-cost read-only memory in all-GaN integration.

Chitosan/Sodium Alginate Multilayer pH-Sensitive Films Based on Layer-by-Layer Self-Assembly for Intelligent Packaging

The abuse of plastic food packaging has brought about severe white pollution issues around the world.Developing green and sustainable biomass packaging is an effective way to solve this problem.Hence,a chitosan/sodium alginate-based multilayer film is fabricated via a layer-by-layer(LBL)self-assembly method.With the help of superior interaction between the layers,the multilayer film possesses excellent mechanical properties(with a tensile strength of 50 MPa).Besides,the film displays outstanding water retention property(blocking moisture of 97.56%)and ultraviolet blocking property.Anthocyanin is introduced into the film to detect the food quality since it is one natural plant polyphenol that is sensitive to the pH changes ranging from 1 to 13 in food when spoilage occurs.It is noted that the film is also bacteriostatic which is desired for food packaging.This study describes a simple technique for the development of advanced multifunctional and fully biodegradable food packaging film and it is a sustainable alternative to plastic packaging.

Hollow tubes constructed by carbon nanotubes self-assembly for CO_(2) capture

Carbon nanotubes(CNTs)have garnered significant attention in the fields of science,engineering,and medicine due to their numerous advantages.The initial step towards harnessing the potential of CNTs involves their macroscopic assembly.The present study employed a gentle and direct self-assembly technique,wherein controlled growth of CNT sheaths occurred on the metal wire’s surface,followed by etching of the remaining metal to obtain the hollow tubes composed of CNTs.By controlling the growth time and temperature,it is possible to alter the thickness of the CNTs sheath.After immersing in a solution containing 1 g/L of CNTs at 60℃ for 24 h,the resulting CNTs layer achieved a thickness of up to 60μm.These hollow CNTs tubes with varying inner diameters were prepared through surface reinforcement using polymers and sacrificing metal wires,thereby exhibiting exceptional attributes such as robustness,flexibility,air tightness,and high adsorption capacity that effectively capture CO_(2) from the gas mixture.

A Non-parametric Gradient-Based Shape Optimization Approach for Solving Inverse Problems in Directed Self-Assemblyof Block Copolymers

We consider the inverse problem of finding guiding pattern shapes that result in desired self-assembly morphologies of block copolymer melts.Specifically,we model polymer selfassembly using the self-consistent field theory and derive,in a non-parametric setting,the sensitivity of the dissimilarity between the desired and the actual morphologies to arbitrary perturbations in the guiding pattern shape.The sensitivity is then used for the optimization of the confining pattern shapes such that the dissimilarity between the desired and the actual morphologies is minimized.The efficiency and robustness of the proposed gradient-based algorithm are demonstrated in a number of examples related to templating vertical interconnect accesses(VIA).

Confined cobalt single-atom catalysts with strong electronic metal-support interactions based on a biomimetic self-assembly strategy

Designing high-performance and low-cost electrocatalysts for oxygen evolu-tion reaction(OER)is critical for the conversion and storage of sustainable energy technologies.Inspired by the biomineralization process,we utilized the phosphorylation sites of collagen molecules to combine with cobalt-based mononuclear precursors at the molecular level and built a three-dimensional(3D)porous hierarchical material through a bottom-up biomimetic self-assembly strategy to obtain single-atom catalysts confined on carbonized biomimetic self-assembled carriers(Co SACs/cBSC)after subsequent high-temperature annealing.In this strategy,the biomolecule improved the anchoring efficiency of the metal precursor through precise functional groups;meanwhile,the binding-then-assembling strategy also effectively suppressed the nonspecific adsorption of metal ions,ultimately preventing atomic agglomeration and achieving strong electronic metal-support interactions(EMSIs).Experimental characterizations confirm that binding forms between cobalt metal and carbonized self-assembled substrate(Co–O_(4)–P).Theoretical calculations disclose that the local environment changes significantly tailored the Co d-band center,and optimized the binding energy of oxygenated intermediates and the energy barrier of oxygen release.As a result,the obtained Co SACs/cBSC catalyst can achieve remarkable OER activity and 24 h durability in 1 M KOH(η10 at 288 mV;Tafel slope of 44 mV dec-1),better than other transition metal-based catalysts and commercial IrO_(2).Overall,we presented a self-assembly strategy to prepare transition metal SACs with strong EMSIs,providing a new avenue for the preparation of efficient catalysts with fine atomic structures.

Layer by Layer Self-assembly Fiber-based Flexible Electrochemical Transistor

Poly(3,4-ethylenedioxyethiophene)-polystyrene sulfonic acid(PEDOT:PSS)/polyallyl dimethyl ammonium chloride modified reduced graphene oxide(PDDA-rGO)was layer by layer self-assembled on the cotton fiber.The surface morphology and electric property was investigated.The results confirmed the dense membrane of PEDOT:PSS and the lamellar structure of PDDA-rGO on the fibers.It has excellent electrical conductivity and mechanical properties.The fiber based electrochemical transistor(FECTs)prepared by the composite conductive fiber has a maximum output current of 8.7 mA,a transconductance peak of 10 mS,an on time of 1.37 s,an off time of 1.6 s and excellent switching stability.Most importantly,the devices by layer by layer self-assembly technology opens a path for the true integration of organic electronics with traditional textile technologies and materials,laying the foundation for their later widespread application.

Teaching Reform and Exploration of Practical Courses Based on Programmable Control

As the country continues to promote the development of intelligent manufacturing,all industries are carrying out enterprise automation upgrading,the Pearl River Delta Intelligent Manufacturing Conference held in March 2024 provides a direction guide for each enterprise on how to integrate the intelligent manufacturing technology into each link and provide direction guidance for enterprises to create new models and new business formats.College teachers,in focusing on the teaching process,should closely match the enterprise and social needs and cultivate excellent students.As the core controller of automation control,the application of programmable controllers in teaching is particularly important.In practical classes,by setting progressive difficulty,project guidance,team collaboration,and other links,students can master the automation equipment design of programmable control in repeated practice.

一款基于新型Field Programmable Gate Array芯片的投影仪梯形校正系统研究与实现

投影设备配备的梯形校正普遍存在校正范围小,画面的一些线条和字符边缘会出现毛刺和不平滑现象,矫正效果不理想.如果采用通用的图像处理芯片和复杂的算法,可以解决上述问题,但又会导致成本急剧上升.为了解决上述矛盾,提出一种基于FPGA(Field Programmable Gate Array)芯片的新型梯形校正实现方案,解决了校正范围与锯齿失真的矛盾问题,并为进一步成为芯片级产品铺平了道路.图像处理采用kaiser窗函数和sinc函数相结合的方法进行插值,这样的滤波器改善了旁瓣抑制,具有较好的通带性能.介绍了梯形失真的产生和校正原理,提出了利用FPGA芯片XC3S400作为核心图像处理单元的梯形校正系统的硬件和软件实现,说明了该芯片结构、功能及特性,最后提供了校正的效果图.

A Programmable 2.4GHz CMOS Multi-Modulus Frequency Divider

A programmable multi-modulus frequency divider is designed and implemented in a 0. 35μm CMOS process. The multi-modulus frequency divider is a single chip with two dividers in series,which are divided by 4 or 5 prescaler and by 128-255 multi-modulus frequency divider. In the circuit design, power and speed trade-offs are analyzed for the prescaler, and power optimization techniques are used according to the input frequency of each divider cell for the 128-255 multimodulus frequency divider. The chip is designed with ESD protected I/O PAD. The dividers chain can work as high as 2.4GHz with a single ended input signal and beyond 2.6GHz with differential input signals. The dual-modulus prescaler consumes 11mA of current while the 128-255 multi-modulus frequency divider consumes 17mA of current with a 3.3V power supply. The core area of the die without PAD is 0.65mm × 0.3mm. This programmable multi-modulus frequency divider can be used for 2.4GHz ISM band PLL-based frequency synthesizers. To our knowledge, this is the first reported multi-modulus frequency divider with this structure in China.

0.18μm CMOS programmable frequency divider design for DVB-T

The implementation of a programmable frequency divider, which is one of the components of the phase-locked loop （PLL） frequency synthesizer for digital video broadcastingterrestrial （DVB-T） and other modem communication systems, is presented. By cooperating with a dual-modulus prescaler, this divider can realize an integer frequency division from 926 to 1 387. Besides the traditional standard cell design flow, such as logic synthesis, placement and routing, the interactions between front-end and back-end are also considered to optimize the design flow under deep submicron technology. By back-annotating the back-end information to front-end design, a custom wire-load model is created which is more practical compared with the default model. This divider has been fabricated in TSMC 0. 18μm CMOS technology using Artisan standard cell library. The chip area is 675 μm × 475 μm and the power consumption is about 2 mW under a 1.8 V power supply. Measurement results show that it works correctly and can realize a frequency division with high precision.

IC Implementation of a Programmable CMOS Voltage Reference

A new approach for the design and implementation of a programmable voltage reference based on an improved current mode bandgap voltage reference is presented. The circuit is simulated and fabricated with Chartered 0. 35μm mixed-signal technology. Measurements demonstrate that the temperature coefficient is ± 36. 3ppm/℃ from 0 to 100℃ when the VID inputs are 11110.As the supply voltage is varied from 2.7 to 5V, the voltage reference varies by about 5mV. The maximum glitch of the transient response is about 20mV at 125kHz. Depending on the state of the five VID inputs,an output voltage between 1.1 and 1.85V is programmed in increments of 25mV.

Self-assembly and UV-curing Property of Polymerized Lyotropic Liquid Crystal Monomer of Sodium 3,4,5-tris（ll-acryloxyundecyloxy）benzoate

A polymerized lyotropic liquid crystal monomer of sodium 3,4,5-tris（11-acryloxyundecyloxy）- benzoate was synthesized by a convenient route starting from 3,4,5-trihydroxybenzoic acid via esterification followed by etherification, acylation and finally neutralization. The chemi- cal structure was confirmed by Fourier transform infrared （FT-IR） and 1H nuclear magnetic resonance spectral analysis. The self-organization behavior of the monomer with deionized water in methanol at room temperature was also demonstrated. The assemblies were char- acterized by polarized optical microscope and X-ray diffraction. The results show that a solution containing 80：20 of the monomer to water was found to be able to self-organize into Lamellar （La） phase and 92：8 with inverted hexagonal （H]I） phase, which was in ac- cordance with the theoretical calculation of critical packing parameter. It suggests that the concentration of the monomer was the key factor to influence assembly structure. Addi- tionally, the acrylate conversion with different photoinitiators and nanostructure retention after polymerization were investigated. The research shows that the acrylate conversion of the monomer with Darocur2959 could reach up to 78% when irradiated by 30 mW/cm2 UV light of 365 nm for 30 min characterized by Real-time FT-IR as well as the sol-gel method. Meanwhile, the La and HII phase nanostructures were both retained after polymerization.

Tailoring the Self-assembly of Melamine on Au（111） via Doping with Cu Atoms

The doping effect of Cu on the self-assembly film of melamine on an Au（111） surface has been investigated with scanning tunneling microscopy （STM）. The evaporated Cu adatoms occupy the positions underneath the amino groups and change the hydrogen bonding pat- tern between the melamine molecules. Accordingly, the self-assembly structure has changed stepwise from a well-defined honeycomb into a track-like and then a triangular structure depending on the amount of Cu adatoms. The interaction between Cu adatom and melamine is moderate thus the Cu adatoms can be released upon mild heating to around 100 ℃. These findings are different from previous observations of either the coordination assembly or the physically trapped metal adatoms.

A signal-summing programmable gain amplifier employing binary-weighted switching and constant-g--_m bias

A novel programmable gain amplifier（ PGA） based on a signal-summing topology is proposed. Different from conventional signal-summing variable gain amplifiers（ VGA）,a binary-weighted switching technique is employed to vary the current-steering transistors＇ aspect ratio to change their transconductance, and hence, an accurate gain step size of 6dB is achieved. The constant-g_m biasing technique and the matching of the transistors and resistors ensures that the gain of the proposed topology is independent of the variation of process, voltage and temperature（ PVT）. P-well NMOS（ Nmetal oxide semiconductor） transistors are utilized to eliminate the influence of back-gate effect which will induce gain error.The source-degeneration technique ensures good linearity performance at a low gain. The proposed PGA is fabricated in a0.18 μm CMOS（ complementary metal oxide semiconductor）process. The measurement results show a variable gain ranging from 0 to24 dB with a step size of 6 dB and a maximum gain error of 0. 3dB. A constant 3dB bandwidth of 210 MHz is achieved at different gain settings. The measured output 3rd intercept point（OIP3） and minimum noise figure（ NF） are20. 9 dBm and 11.1 dB, respectively. The whole PGA has a compact layout of 0.068 mm^2. The total power consumption is4. 8 mW under a 1. 8 V supply voltage.

FPGA-Based Efficient Programmable Polyphase FIR Filter

The modelling, design and implementation of a high-speed programmable polyphase finite impulse response (FIR) filter with field programmable gate array (FPGA) technology are described. This FIR filter can run automatically according to the programmable configuration word including symmetry/asymmetry, odd/even taps, from 32 taps up to 256 taps. The filter with 12 bit signal and 12 bit coefficient word-length has been realized on a Xilinx VirtexⅡ-v1500 device and operates at the maximum sampling frequency of (160 MHz.)

Self-assembly of Binary Particles with Electrostatic and van der Waals Interactions

Nanoparticles with competitive interactions in solution can aggregate into complex structures. In this work, the synergistic self-assembles of binary particles with electrostatic and van der Waals interactions are studied with the particle Langevin dynamics simulation using a simple coarse-grained particle model. Various aggregations such as spherical, stacking-disk and tube structures are observed by varying the particles size and the interaction strength. The aggregation structures are explained with the packing theories of amphiphilic molecules in solution and dibolck copolymers in bulk. When the opposite ions are introduced into solution, the distribution of structures in the phase diagram appears an obvious offset. The simulation result is helpful to deeply understand the formation mechanism of complex nanostructures of multicomponent particles in solution.