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Property analysis of bistatic forward-looking SAR with arbitrary geometry 被引量:2
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作者 Ziqiang Meng Yachao Li +1 位作者 Mengdao Xing Zheng Bao 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2016年第1期111-127,共17页
Bistatic forward-looking synthetic aperture radar(SAR) has many advantages and applications owing to its twodimensional imaging capability.There could be various imaging configurations because of the geometric flexi... Bistatic forward-looking synthetic aperture radar(SAR) has many advantages and applications owing to its twodimensional imaging capability.There could be various imaging configurations because of the geometric flexibility of bistatic platforms,resulting in kinds of models built independently among which there could be some similar even the same motion features.Comprehensive research on such systems in a more comprehensive and general point of view is required to address their difference and consistency.Property analysis of bistatic forwardlooking SAR with arbitrary geometry is achieved including stripmap and spotlight modes on airborne platform,missile-borne platform,and hybrid platform of both.Emphasis is placed on azimuth space variance of some key parameters significantly affecting the subsequent imaging processing,based on which the frequency spectra are further described and compared considering respective features of different platforms for frequency imaging algorithm developing.Simulation results confirm the effectiveness and correctness of our analysis. 展开更多
关键词 bistatic forward-looking synthetic aperture radar(SAR) comprehensive research property analysis azimuth space variance.
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Analysis of Mechanical Properties of Injection Molded Short Glass Fibre (SGF)/Calcite/ABS Composites 被引量:2
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《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1997年第5期389-396,共8页
Acrylonitrile-butadiene-Styrene (ABS), with and without calcium carbonate (calcite) particles,was used as the matrix for reinforcement with as-received short-glass fibres (were originallytreated by the manufacturer) a... Acrylonitrile-butadiene-Styrene (ABS), with and without calcium carbonate (calcite) particles,was used as the matrix for reinforcement with as-received short-glass fibres (were originallytreated by the manufacturer) and sized short-glass fibres with two amino-silane coupling agents.The calcite particle content is 0, 11.7 and 23.5 vol. pct for the matrices. The glass fiber contentis 0, 10 and 15 vol. pct. The matrix materials and corresponding composites were compoundedusing a twin screw extruder and dumbbell-shaped tensile bars were prepared with an injectionmolding process. The tensile and flexural properties as well as the unnotched and notchedCharpy impact energies of short glass fibre/calcite/ABS composites were studied in this paper.The effects of fibres, fibre surface treatments and particles on these mechanical properties ofthe composites were discussed in detail. An importarit information was obtained, which is thatthe tensile and flexural strengths of hybrid SGF/calcite/ABS composites are the same as thoseof corresponding fibre composites when the ratio of the interfacial adhesion strength betweenparticles and matrix to that between fibres and matrix is higher than certain value. otherwise theformer are lower than the latter. 展开更多
关键词 ABS Calcite/ABS Composites SGF analysis of Mechanical Properties of Injection Molded Short Glass Fibre
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Mode-based equivalent multi-degree-of-freedom system for one-dimensional viscoelastic response analysis of layered soil deposit 被引量:8
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作者 Li Chong Yuan Juyun +1 位作者 Yu Haitao Yuan Yong 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2018年第1期103-124,共22页
Discrete models such as the lumped parameter model and the finite element model are widely used in the solution of soil amplification of earthquakes. However, neither of the models will accurately estimate the natural... Discrete models such as the lumped parameter model and the finite element model are widely used in the solution of soil amplification of earthquakes. However, neither of the models will accurately estimate the natural frequencies of soil deposit, nor simulate a damping of frequency independence. This research develops a new discrete model for onedimensional viscoelastic response analysis of layered soil deposit based on the mode equivalence method. The new discrete model is a one-dimensional equivalent multi-degree-of-freedom(MDOF) system characterized by a series of concentrated masses, springs and dashpots with a special configuration. The dynamic response of the equivalent MDOF system is analytically derived and the physical parameters are formulated in terms of modal properties. The equivalent MDOF system is verified through a comparison of amplification functions with the available theoretical solutions. The appropriate number of degrees of freedom(DOFs) in the equivalent MDOF system is estimated. A comparative study of the equivalent MDOF system with the existing discrete models is performed. It is shown that the proposed equivalent MDOF system can exactly present the natural frequencies and the hysteretic damping of soil deposits and provide more accurate results with fewer DOFs. 展开更多
关键词 ground response analysis MDOF system mode equivalence modal properties layered soil viscoelastic amplification
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The difference analysis of physical-mechanical properties of sediments in the central South Yellow Sea and Zhe-Min coastal area in China 被引量:1
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作者 XU Yuanqin LI Ping +4 位作者 LI Peiying DU Jun LIU Lejun GAO Wei LIU Jie 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2017年第7期77-85,共9页
The difference analysis of physical-mechanical properties of muddy sediments is made in the central South Yellow Sea and the Zhe-Min(Zhejiang Province to Fujian Province of China) coastal area. The results show that... The difference analysis of physical-mechanical properties of muddy sediments is made in the central South Yellow Sea and the Zhe-Min(Zhejiang Province to Fujian Province of China) coastal area. The results show that sediments in the two regions are both dominated by mud. There are perfect negative power function correlations between the water content and the density, the compression coefficient and the compression modulus; a good positive power function correlation between the liquid limit and the plastic limit, a perfect positive linear correlation between the water content and the void ratio, and a perfect polynomial function correlation between the miniature vane shear strength and the pocket penetration resistance. In general, compared with sediments in the Zhe-Min coastal area, sediments in the central South Yellow Sea possess high water content, high void ratio,low density, high plasticity, high compressibility, low shear strength. The causes of the differences between physical-mechanical properties of sediments are analyzed from the topographic features, material sources,hydrodynamic conditions, deposition rate, and material composition. Compared with the Zhe-Min coastal area,the central South Yellow Sea is far from the Mainland and low-lying; has poor hydrodynamic condition; the materials diffused to the area are less and dominated by fine clay, have the high content of smectite and organic matters. These factors lead to sediments of the central South Yellow Sea has the higher water content, the higher plasticity, the lower density, and the lower strength than sediments in the Zhe-Min coastal area. 展开更多
关键词 sediment Zhe-Min coastal area central South Yellow Sea physical-mechanical properties difference analysis
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Diatom distribution and its relationship to sediment property in the Minjiang Estuary, southeast China 被引量:1
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作者 SHEN Linnan GAO Aiguo +1 位作者 LI Chao CHEN Min 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2017年第10期20-30,共11页
The distribution of diatoms in surface sediments in the Minjiang Estuary, southeast China, was investigated in2009. Total 56 species and other species belonging to 25 genera were identified, among them 11 species were... The distribution of diatoms in surface sediments in the Minjiang Estuary, southeast China, was investigated in2009. Total 56 species and other species belonging to 25 genera were identified, among them 11 species were dominant over 5%. Dominant species included Actinocyclus ehrenbergii, Coscinodiscus curvatulus, C. divisus, C.jonesianus, C. radiatus, C. rothii, C. subtilis, Cyclotella stylorum, Epithemia hyndmanii, Hydrosera whampoensis,and Trachyneis aspera. Diatom abundance varied spatially, with the absolute abundance of diatoms ranging from13 valves/g to 11×104 valves/g, and averaging 2.5×104 valves/g. A canonical correspondence analysis(CCA) was used to explain the relationships between diatom distribution and sediment properties in the Minjiang Estuary.CCA revealed that the major elements(Fe_2O_3, Na_2O, CaO, MgO, TiO_2, SiO_2, Al_2O_3, and K_2O) were closely related to diatom abundance. Four diatom assemblages were distinguished, representing different sediment properties,which may assist late Quaternary palaeoceanographic reconstructions of the Minjiang Estuary. 展开更多
关键词 diatom surface sediment Minjiang Estuary canonical correspondence analysis sediment properties
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Synthesis, Crystal Structure and Electrochemical Properties of a One-dimensional Chain Coordination Polymer [Cu(phen)(2,4,6-TMBA)_2(H_2O)]_n 被引量:10
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作者 LI Wei LI Chang-Hong +1 位作者 YANG Ying-Qun KUANG Yun-Fei 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第2期210-214,共5页
A one-dimensional chain coordination polymer [Cu(phen)(2,4,6-TMBA)2(H2O)]n has been synthesized by reacting 2,4,6-trimethyl-benzoic acid, 1,10-phenanthroline and Cu(Ⅱ) perchlorate and its structure was charac... A one-dimensional chain coordination polymer [Cu(phen)(2,4,6-TMBA)2(H2O)]n has been synthesized by reacting 2,4,6-trimethyl-benzoic acid, 1,10-phenanthroline and Cu(Ⅱ) perchlorate and its structure was characterized. Crystal data for this complex: tetragonal, space group I41, a = 2.0293(3), b = 2.0293(3), c = 1.3758(2) nm, α =β= γ = 90°, V= 5.6657(13) nm3, Dc= 1.379 g/cm3, Z = 8, μ(MoKa) = 0.815 mm-1, Mr = 588.14, F(000) = 2456, S = 1.047, R = 0.0459 and wR = 0.1053. The crystal structure shows that two neighboring Cu(Ⅱ) ions are linked together by one bridging-chelating 2,4,6-trimethyl-benzoic group, forming a one-dimensional chain structure. Each Cu(Ⅱ) ion is coordinated with two nitrogen atoms from one 1,10-phenanthroline molecule, three oxygen atoms from three 2,4,6-trimethyl-benzoic acid molecules and one oxygen atom from one water molecule, giving a six-coordinate distorted octahedral coordination geometry. The cyclic voltammetry behavior of the complex was also investigated. 展开更多
关键词 Cu(Ⅱ) coordination polymer crystal structure electrochemical property analysis
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Study on process and mechanism of superplastic diffusion bonding of dissimilar steels 被引量:2
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作者 王敏 葛利玲 《China Welding》 EI CAS 1999年第2期76-81,共6页
The probability, main effect factors and diffusion theory of structural superplastic diffusion bonding of W6Mo5Cr4V2/45 steel have been observed and analyzed by means of tensile test at the room temperature, scanning ... The probability, main effect factors and diffusion theory of structural superplastic diffusion bonding of W6Mo5Cr4V2/45 steel have been observed and analyzed by means of tensile test at the room temperature, scanning electron microscope and microhardness test. Results show that after fine graining treatment and short time superplastic pressing formation under the conditions of superplastic temperature and strain rate, W6Mo5Cr4V2/45 specimens can achieve solid state diffusion bonding and the property of welded area is the same as the other parts in the specimen. The diffusion path of carbon element is intergranular and of dislocation. 展开更多
关键词 superplastic diffusion bonding welded joint quality property analysis de carbon layer
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Synthesis, Crystal Structure and Electrochemical Properties of a One-dimensional Chain Coordination Polymer [Mn(NAA)_2(4,4’-bipy)(H_2O)_4]_n 被引量:2
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作者 杨颖群 李昶红 +1 位作者 李薇 匡云飞 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第4期404-408,共5页
A novel one-dimensional chain coordination polymer [Mn(NAAh(4,4′-bipy)(H2O)4], has been synthesized with a-naphthaleneacetic acid, 4,4′-bipy and manganese(Ⅱ) sulfate as raw materials. Crystal data for this c... A novel one-dimensional chain coordination polymer [Mn(NAAh(4,4′-bipy)(H2O)4], has been synthesized with a-naphthaleneacetic acid, 4,4′-bipy and manganese(Ⅱ) sulfate as raw materials. Crystal data for this complex: monoclinic, space group P21/c, a = 1.1421(2), b = 1.6337(3), c = 0.94177(19) nm, β = 112.15(3)°, V = 1.6275(6) nm^3, De = 1.407 g/cm^3, Z = 2, μ(MoKa) = 0.467 mm^-1, F(000) = 722, S = 1.007, R= 0.0412 and wR = 0.1022. The crystal structure shows that two neighboring manganese(Ⅱ) ions are linked together by one 4,4′-bipy molecule, and the whole complex molecule forms a one-dimensional chain structure. Each manganese(Ⅱ) ion is coordinated with two oxygen atoms of two a-naphthaleneacetic acid molecules, two nitrogen atoms of two 4,4′-bipy molecules and two oxygen atoms from two water molecules, giving a distorted octahedral coordination geometry. The electrochemical properties were also analyzed. 展开更多
关键词 manganese(Ⅱ) coordination polymer crystal structure electrochemical property analysis
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Do Search and Selection Operators Play Important Roles in Multi-Objective Evolutionary Algorithms:A Case Study 被引量:1
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作者 Yan Zhen-yu, Kang Li-shan, Lin Guang-ming ,He MeiState Key Laboratory of Software Engineering, Wuhan University, Wuhan 430072, Hubei, ChinaSchool of Computer Science, UC, UNSW Australian Defence Force Academy, Northcott Drive, Canberra, ACT 2600 AustraliaCapital Bridge Securities Co. ,Ltd, Floor 42, Jinmao Tower, Shanghai 200030, China 《Wuhan University Journal of Natural Sciences》 CAS 2003年第S1期195-201,共7页
Multi-objective Evolutionary Algorithm (MOEA) is becoming a hot research area and quite a few aspects of MOEAs have been studied and discussed. However there are still few literatures discussing the roles of search an... Multi-objective Evolutionary Algorithm (MOEA) is becoming a hot research area and quite a few aspects of MOEAs have been studied and discussed. However there are still few literatures discussing the roles of search and selection operators in MOEAs. This paper studied their roles by solving a case of discrete Multi-objective Optimization Problem (MOP): Multi-objective TSP with a new MOEA. In the new MOEA, We adopt an efficient search operator, which has the properties of both crossover and mutation, to generate the new individuals and chose two selection operators: Family Competition and Population Competition with probabilities to realize selection. The simulation experiments showed that this new MOEA could get good uniform solutions representing the Pareto Front and outperformed SPEA in almost every simulation run on this problem. Furthermore, we analyzed its convergence property using finite Markov chain and proved that it could converge to Pareto Front with probability 1. We also find that the convergence property of MOEAs has much relationship with search and selection operators. 展开更多
关键词 multi-objective evolutionary algorithm convergence property analysis search operator selection operator Markov chain
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Density Functional Studies on Isonicotinato Lead(II) Complex [Pb(C_5H_4NCOO)_2] 被引量:1
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作者 ZHAO Pu-Su JIAN Fang-Fang +1 位作者 LI Chun-Lei ZHENG Jian 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第6期657-662,共6页
The title compound of isonicotinato lead(Ⅱ) [Pb(C5H4NCOO)2] has been optimized at B3LYP/LANL2DZ level of theory and calculated results show that the lead(Ⅱ) ion adopts 4-coordinate geometry. Atomic charge dist... The title compound of isonicotinato lead(Ⅱ) [Pb(C5H4NCOO)2] has been optimized at B3LYP/LANL2DZ level of theory and calculated results show that the lead(Ⅱ) ion adopts 4-coordinate geometry. Atomic charge distributions indicate that during forming the title compound, each isonicotinic acid ion transfers -0.452 e to lead(Ⅱ) ion. The electronic spectra calculations show that there exist two absorption bands and the electronic transitions are mainly derived from the contribution of intraligand π→π^* transition and ligand-to-metal charge transfer (LMCT) transition. The thermodynamic properties of the title compound at different temperatures have been calculated and corresponding relations between property and temperature have also been obtained. The calculation of the second order optical nonlinearity was carried out, and the molecular hyperpolarizability was 3.62365^*10^-30 esu. 展开更多
关键词 isonicotinato lead(Ⅱ) complex density functional theory electronic spectra thermal property analysis the second order optical nonlinearity
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Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of Complex [Cd(phen)_3]·(ClO_4)_2·(p-MBA)_2·(H_2O)_2 被引量:1
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作者 李薇 李昶红 +1 位作者 杨颖群 匡云飞 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2007年第11期1267-1270,共4页
One new cadmium complex [Cd(phen)3]·(ClO4)2·(p-MBA)2·(H2O)2 has been hydrothermally synthesized by reacting p-methylbenzoic acid (p-MBA), 1,10-phenanthroline (phen) and cadmium perchlorate. ... One new cadmium complex [Cd(phen)3]·(ClO4)2·(p-MBA)2·(H2O)2 has been hydrothermally synthesized by reacting p-methylbenzoic acid (p-MBA), 1,10-phenanthroline (phen) and cadmium perchlorate. It crystallizes in the triclinic system, space group P1, with a = 1.2809(3), b = 1.3431(3), c = 1.3734(3) nm, α = 84.259(4), β = 71.603(3), γ = 74.424(3)°, V= 2.1594(8) nm3, Do = 1.532 g/cm3, Z = 2, F(000) = 1008, μ= 0.697 mm^-1, R = 0.0646 and wR = 0.1648. The crystal structure shows that the cadmium ion is coordinated with six nitrogen atoms from three 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. The result of electrochemical property analysis shows that the electron transfer in the electrode reaction is irreversible. 展开更多
关键词 cadmium(Ⅱ) complex crystal structure electrochemical property analysis
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Synthesis,Crystal Structure and Electrochemical Properties of a Cadmium(Ⅱ) Complex with α-Furoic Acid and 1,10-Phenanthroline 被引量:1
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作者 张少华 李昶红 +1 位作者 李薇 杨颖群 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第10期1261-1264,共4页
A new cadmium complex [Cd(phen)3]·(ClO4)2·(α-FRA)-(H2O)3 was prepared by self-assembly of α-furoic acid, 1,10-phenanthroline (phen), and cadmium perchlorate. It crystallizes in the monoclinic sys... A new cadmium complex [Cd(phen)3]·(ClO4)2·(α-FRA)-(H2O)3 was prepared by self-assembly of α-furoic acid, 1,10-phenanthroline (phen), and cadmium perchlorate. It crystallizes in the monoclinic system, space group P21/n, with a = 1.28130(15), b = 2.5957(3), c = 1.35449(16) nm, β = 109.395(2)°, V = 4.2492(9) nm^3, Dc = 1.491 g/cm^3, Z = 4, F(000) = 1926, GOOF = 1.023, the final R = 0.0729 and wR = 0.2086. The crystal structure analysis indicates that the cadmium ion is coordinated with six nitrogen atoms from six 1,10-phenanthroline molecules, giving a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex was also investigated. 展开更多
关键词 cadmium(Ⅱ) complex crystal structure electrochemical property analysis
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Modeling and targeting an essential metabolic pathway of Plasmodium falciparum in apicoplast using Petri nets
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作者 Sakshi Gupta Gajendra Pratap Singh Sunita Kumawat 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2022年第1期91-110,共20页
Petri net(PN) is one of the promising computational and mathematical formalisms used to represent and study the behavior of complex metabolic networks. The various available analysis techniques of PN could be used to ... Petri net(PN) is one of the promising computational and mathematical formalisms used to represent and study the behavior of complex metabolic networks. The various available analysis techniques of PN could be used to validate and analyze the network in different scenarios. Plasmodium falciparum is one of the threatening parasites which causes malaria, a deadly disease affecting a large number of today’s world population. The development of antimalarial drug resistance is an emerging global threat, highlighting the need to discover novel antimalarial targets. The fatty acid biosynthesis of malarial parasite is one of the essential metabolic pathways required for its growth and is present in apicoplast, a non-photosynthetic plastid. The malarial parasite obtains fatty acids by using type two fatty acid synthase(FAS II) enzyme,which is different from type one enzyme used by human host, making it an ideal drug target.This article proposes and studies the PN model of the parasite’s FAS II pathway to analyze the mechanism of potential drug targets in this pathway. The proposed PN model can serve as a base for further findings in the field of antimalarial drug targets to decrease the malaria mortality rate. 展开更多
关键词 Petri net MALARIA Plasmodium falciparum type II fatty acid biosynthesis drug target property analysis
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Computational studies on magnetism and ferroelectricity
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作者 徐可 冯俊生 向红军 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第9期76-86,共11页
Magnetics,ferroelectrics,and multiferroics have attracted great attentions because they are not only extremely im-portant for investigating fundamental physics,but also have important applications in information techn... Magnetics,ferroelectrics,and multiferroics have attracted great attentions because they are not only extremely im-portant for investigating fundamental physics,but also have important applications in information technology.Here,recent computational studies on magnetism and ferroelectricity are reviewed.We first give a brief introduction to magnets,fer-roelectrics,and multiferroics.Then,theoretical models and corresponding computational methods for investigating these materials are presented.In particular,a new method for computing the linear magnetoelectric coupling tensor without applying an external field in the first principle calculations is proposed for the first time.The functionalities of our home-made Property Analysis and Simulation Package for materials(PASP)and its applications in the field of magnetism and ferroelectricity are discussed.Finally,we summarize this review and give a perspective on possible directions of future computational studies on magnetism and ferroelectricity. 展开更多
关键词 MAGNETS FERROELECTRICS MULTIFERROICS Monte Carlo simulation four-state method DFT calculation property analysis and Simulation Package for materials(PASP)software
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RESEARCH AND DEVELOPMENT OF VIRTUAL PROTOTYPE OF RUNNING GEARS FOR RAILWAY VEHICLE 被引量:6
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作者 ZOU Yisheng DING Guofu +2 位作者 ZHANG Weihua XU Mingheng HE Yong 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2008年第1期36-41,共6页
Virtual prototype is an important idea to resolve design problems of railway vehicle. A different development method, which is based on national product and autonomous development, and would like to reflect the specia... Virtual prototype is an important idea to resolve design problems of railway vehicle. A different development method, which is based on national product and autonomous development, and would like to reflect the specialty of railway vehicle development in China, is presented. According to the developing process of railway vehicle, the research contents and developing method are pointed out. The integration between CAD and performance analysis software on dynamics and strength is mainly considered. In CAD environment, the properties for dynamics computing are extracted directly from the model and exported with model. This method can avoid data losing caused by model rebuilding in CAE software, and increase the direct dependence of product CAD. Then the vehicle model with properties will be used for real-time dynamics and kinematics analysis and simulation. Therefore, the strength of the parts can be analyzed. The results of dynamics and strength analysis will be fed back to optimize the design model. All operations are dispatched by a control platform, and all data are managed according to the principle of PDM. Testing results show this method is correct. 展开更多
关键词 Virtual prototype Railway vehicle property extraction Dynamics analysis Strength analysis
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Synthesis, Crystal Structure and Properties of a Copper Complex with the Bicycle[2.2.1]-2-heptene-5,6-dicarboxylic Acid 被引量:2
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作者 李薇 李昶红 +1 位作者 李衡峰 谭雄文 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2014年第10期1527-1532,共6页
A new copper complex 2{Cu(C10H8N2)[C8H11O2(COO)](H2O)3}·(H2O)5 with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid(H2L) [C7H8(COOH)2], basic copper carbonate and 2,2'-bipyridine has been synthesized i... A new copper complex 2{Cu(C10H8N2)[C8H11O2(COO)](H2O)3}·(H2O)5 with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid(H2L) [C7H8(COOH)2], basic copper carbonate and 2,2'-bipyridine has been synthesized in the mixed solvents of methanol and water. It crystallizes in the triclinic system, space group P1, with a = 7.4626(5), b = 11.9779(8), c = 12.9841(8)A, α = 109.7040(10), β = 98.7550(10), γ = 90.6240(10)°, V = 1077.50(12)A3, Dc = 1.538 g/cm^3, Z = 1, F(000) = 520, GOOF = 1.065, R = 0.0360 and wR = 0.0950. The copper ion is coordinated with four oxygen atoms from one H2 L molecule and three water molecules together with two nitrogen atoms from the 2,2'-bipyridine molecule, forming a distorted octahedral coordination geometry. The thermal stability and electrochemical properties were also studied. 展开更多
关键词 copper(II) complex crystal structure properties analysis
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Influence of TiO_2 on the electrochemical performance of pasted typeβ-nickel hydroxide electrode in alkaline electrolyte 被引量:3
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作者 B.Shruthi B.J.Madhu V.Bheema Raju 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第1期41-48,共8页
Nickel hydroxide was used as the positive electrode material in rechargeable alkaline batteries, which plays a significant role in the field of electric energy storage devices. β-nickel hydroxide(β-Ni(OH)2 ) was... Nickel hydroxide was used as the positive electrode material in rechargeable alkaline batteries, which plays a significant role in the field of electric energy storage devices. β-nickel hydroxide(β-Ni(OH)2 ) was prepared from nickel sulphate solution using potassium hydroxide as a precipitating agent. Pure β-phase of nickel hydroxide was confirmed from XRD and FT-IR studies. The effects of TiO2 additive on the β-Ni(OH)2 electrode performance are examined. The structure and property of the TiO2 added β-Ni(OH)2 were characterized by XRD, TG-DTA and SEM analysis. A pasted–type electrode is prepared using nickel hydroxide powder as the main active material on a nickel sheet as a current collector. Cyclic voltammetry and electrochemical impedance spectroscopy studies were performed to evaluate the electrochemical performance of the β-Ni(OH)2 and TiO2 added β-Ni(OH)2 electrodes in 6 M KOH electrolyte. Anodic(Epa) and cathodic(Epc)peak potentials are found to decrease after the addition of TiO 2 into β-Ni(OH)2 electrode material. Further,addition of TiO2 is found to enhance the reversibility of the electrode reaction and also increase the separation of the oxidation current peak of the active material from the oxygen evolution current. Compared with pure β-Ni(OH)2 lectrode,TiO2 added β-Ni(OH)2 electrode is found to exhibit higher proton diffusion coefficient(D) and lower charge transfer resistance. These findings suggest that the TiO2 added β-Ni(OH)2 electrode possess improved electrochemical properties and thus can be recognized as a promising candidate for the battery electrode applications. 展开更多
关键词 Nickel hydroxide Electrode material Thermogravimetric analysis Electrochemical properties Impedance spectroscopy
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Preparation and characterization of γ-La_2S_3 nanoparticles from thermal decomposition 被引量:2
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作者 Pei-sen Li Huan-yong Li Wan-qi Jie 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2011年第6期748-752,共5页
To synthesize pure γ-La2S3 at lower temperature,lanthanide complex La(Et2S2CN)3·phen,containing La?S bond,was chosen as the precursors to decompose.The obtained samples were characterized by X-ray power diffr... To synthesize pure γ-La2S3 at lower temperature,lanthanide complex La(Et2S2CN)3·phen,containing La?S bond,was chosen as the precursors to decompose.The obtained samples were characterized by X-ray power diffraction (XRD),field-emission scanning electron microscopy (FE-SEM) with an energy dispersive spectrometer and UV-Vis diffuse reflectance spectra.The decomposition mechanism of the lanthanide complex was studied by thermogravimetric analyses (TGA).The results show that the obtained samples are cubic phase particles with sizes among 20-50 nm and the band gap is 2.97 eV,which is bigger than that of its bulk crystal.TG/DTG results indicate that La(Et2S2CN)3·phen decomposed to γ-La2S3 via La4(Et2S2CN)3 as an intermediate product. 展开更多
关键词 chalcogenides nanoparticles thermogravimetric analysis decomposition optical properties
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Influence of tool pin profile and rotational speed on the formation of friction stir welding zone in AZ31 magnesium alloy 被引量:2
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作者 Dr.S.Ugender 《Journal of Magnesium and Alloys》 SCIE EI CAS 2018年第2期205-213,共9页
In this investigation,the effect of friction stir welding(FSW)parameters such as tool pin profiles,rotational speed and welding speed on the mechanical properties of tensile strength,hardness and impact energy of magn... In this investigation,the effect of friction stir welding(FSW)parameters such as tool pin profiles,rotational speed and welding speed on the mechanical properties of tensile strength,hardness and impact energy of magnesium alloy AZ31 was studied.The experiments were carried out as per Taguchi parametric design concepts and an L9 orthogonal array was used to study the influence of various combinations of process parameters.Statistical optimization technique,ANOVA,was used to determine the optimum levels and to find the significance of each process parameter.The results indicate that rotational speed(RS)and transverse speed(TS)are the most significant factors,followed by tool pin profile(PF),in deciding the mechanical properties of friction stir welded magnesium alloy.In addition,mathematical models were developed to establish relationship between different process variables and mechanical properties. 展开更多
关键词 Friction stir welding Tool pin profile Mechanical properties Taguchi orthogonal array analysis of variance(ANOVA)
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Influence of the gassing materials on the dielectric properties of air 被引量:2
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作者 张含天 厉天威 +4 位作者 罗兵 吴翊 杨飞 孙昊 唐力 《Plasma Science and Technology》 SCIE EI CAS CSCD 2017年第5期68-73,共6页
Influence of the gassing materials, such as PA6, PMMA, and POM on the dielectric properties of air are investigated. In this work, the fundamental electron collision cross section data were carefully selected and vali... Influence of the gassing materials, such as PA6, PMMA, and POM on the dielectric properties of air are investigated. In this work, the fundamental electron collision cross section data were carefully selected and validated. Then the species compositions of the air–organic vapor mixtures were calculated based on the Gibbs free energy minimization. Finally, the Townsend ionization coefficient, the Townsend electron attachment coefficient and the critical reduced electric field strength were derived from the calculated electron energy distribution function by solving the Boltzmann transport equation. The calculation results indicated that H;O with large attachment cross sections has a great impact on the critical reduced electric field strength of the air–organic vapor mixtures. On the other hand, the vaporization of gassing materials can help to increase the dielectric properties of air circuit breakers to some degree. 展开更多
关键词 air circuit breaker gassing materials Boltzmann equation analysis dielectric properties EEDF critical reduced electric field strength electron collision cross section
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