The difference analysis of physical-mechanical properties of muddy sediments is made in the central South Yellow Sea and the Zhe-Min(Zhejiang Province to Fujian Province of China) coastal area. The results show that...The difference analysis of physical-mechanical properties of muddy sediments is made in the central South Yellow Sea and the Zhe-Min(Zhejiang Province to Fujian Province of China) coastal area. The results show that sediments in the two regions are both dominated by mud. There are perfect negative power function correlations between the water content and the density, the compression coefficient and the compression modulus; a good positive power function correlation between the liquid limit and the plastic limit, a perfect positive linear correlation between the water content and the void ratio, and a perfect polynomial function correlation between the miniature vane shear strength and the pocket penetration resistance. In general, compared with sediments in the Zhe-Min coastal area, sediments in the central South Yellow Sea possess high water content, high void ratio,low density, high plasticity, high compressibility, low shear strength. The causes of the differences between physical-mechanical properties of sediments are analyzed from the topographic features, material sources,hydrodynamic conditions, deposition rate, and material composition. Compared with the Zhe-Min coastal area,the central South Yellow Sea is far from the Mainland and low-lying; has poor hydrodynamic condition; the materials diffused to the area are less and dominated by fine clay, have the high content of smectite and organic matters. These factors lead to sediments of the central South Yellow Sea has the higher water content, the higher plasticity, the lower density, and the lower strength than sediments in the Zhe-Min coastal area.展开更多
The previously unknown different chemical properties of carbon isotopes in natural processes of synthesis-formation of different carbon-containing compounds,in particular of the more difficult(13C)carbon isotope in th...The previously unknown different chemical properties of carbon isotopes in natural processes of synthesis-formation of different carbon-containing compounds,in particular of the more difficult(13C)carbon isotope in the processes of synthesis of solid carbon-containing compounds:carbonates,diamonds and,respectively,lighter(12C)synthetic isotopes,including methane have been established.展开更多
Titanium dioxide (TiO2) nanosheet, nanorod and nanotubes are synthesized using chemical vapor deposition (CVD) and anodizing processes. TiO2 nanosheets are grown on Ti foil which is coated with Au catalyst in CVD,...Titanium dioxide (TiO2) nanosheet, nanorod and nanotubes are synthesized using chemical vapor deposition (CVD) and anodizing processes. TiO2 nanosheets are grown on Ti foil which is coated with Au catalyst in CVD, TiO2 nanorods are synthesized on treated Ti foil with HCl by CVD, and TiO2 nanotubes are prepared by the three-step anodization method. Scanning electron microscopy shows the final TiO2 structures prepared using three processes with three different morphologies of nanosheet, nanorod and nanotube. X-ray diffraction verifies the presence of TiO2. TiO2 sheets and rods are crystalized in rutile phase, and TiO2 tubes after annealing turn into the anatase crystal phase. The optical investigations carried out by diffuse reflection spectroscopy reveal that the morphology of TiO2 nanostructures influencing their optical response and band gap energy of TiO2 is changed for different TiO2 nanostructures.展开更多
This work focuses on the relationship between flexibility of molecular chains and thermal properties of polyurethane elastomer(PUE), which laid the foundation of further research about how to improve thermal propert...This work focuses on the relationship between flexibility of molecular chains and thermal properties of polyurethane elastomer(PUE), which laid the foundation of further research about how to improve thermal properties of PUE. A series of PUE samples with different flexibility of molecular chains was prepared by using 1,4-butanediol(1,4-BDO)/bisphenol-a(BPA) blends with different mole ratios including9/1, 8/2, 7/3, 6/4 and 5/5. As comparison, PUE extended with pure 1,4-BDO and BPA was also synthesized.These samples were characterized by differential scanning calorimetry(DSC), thermogravimetric analysis(TGA), dynamic mechanical analysis(DMA), etc. The results showed that with the decrease in flexibility of molecular chains the glass transition temperature(Tg) increased and low-temperature properties became worse. Besides, all samples had a certain degree of microphase separation, and soft segments in some samples were crystallized, i.e. the decreasing flexibility of molecular chains led to the impossibility of chains tightly packing and crystalline domains forming so that the degree of microphase separation decreased and the thermal properties became worse.展开更多
We continue our investigations on pointwise multipliers for Besov spaces of dominating mixed smoothness. This time we study the algebra property of the classes S_(p,q)~rB(R^d) with respect to pointwise multiplication....We continue our investigations on pointwise multipliers for Besov spaces of dominating mixed smoothness. This time we study the algebra property of the classes S_(p,q)~rB(R^d) with respect to pointwise multiplication. In addition, if p≤q, we are able to describe the space of all pointwise multipliers for S_(p,q)~rB(R^d).展开更多
The effects of various cooling paths on uniformity of through-thickness microstructure and mechanical properties of X80 pipeline steel of 22.0 mm in thickness were studied. The finite difference method was employed to...The effects of various cooling paths on uniformity of through-thickness microstructure and mechanical properties of X80 pipeline steel of 22.0 mm in thickness were studied. The finite difference method was employed to calculate the temperature field during cooling. It was confirmed by the experimental result and temperature field calculation that the optimizing process was achieved by the ultra-fast cooling with medium cooling capacity(cooling rate of *23 K/s)followed by ultimate cooling capacity(cooling rate of *50 K/s). After optimization, the experimental steel displayed much uniform microstructure and the deviation of through-thickness hardness was controlled within 20 HV. In addition,the yield strength, tensile strength and elongation of the experimental steel were 621, 728 MPa and 21.5%, respectively,meeting the requirements of the API standard for X80 pipeline steels.展开更多
基金The NSFC-Shandong Joint Fund for Marine Science Research Centers under contract No.U150640007the Natural Science Foundation of Shandong Province of China under contract No.BS2015HZ009the National Natural Science Foundation of China under contract No.41506071
文摘The difference analysis of physical-mechanical properties of muddy sediments is made in the central South Yellow Sea and the Zhe-Min(Zhejiang Province to Fujian Province of China) coastal area. The results show that sediments in the two regions are both dominated by mud. There are perfect negative power function correlations between the water content and the density, the compression coefficient and the compression modulus; a good positive power function correlation between the liquid limit and the plastic limit, a perfect positive linear correlation between the water content and the void ratio, and a perfect polynomial function correlation between the miniature vane shear strength and the pocket penetration resistance. In general, compared with sediments in the Zhe-Min coastal area, sediments in the central South Yellow Sea possess high water content, high void ratio,low density, high plasticity, high compressibility, low shear strength. The causes of the differences between physical-mechanical properties of sediments are analyzed from the topographic features, material sources,hydrodynamic conditions, deposition rate, and material composition. Compared with the Zhe-Min coastal area,the central South Yellow Sea is far from the Mainland and low-lying; has poor hydrodynamic condition; the materials diffused to the area are less and dominated by fine clay, have the high content of smectite and organic matters. These factors lead to sediments of the central South Yellow Sea has the higher water content, the higher plasticity, the lower density, and the lower strength than sediments in the Zhe-Min coastal area.
文摘The previously unknown different chemical properties of carbon isotopes in natural processes of synthesis-formation of different carbon-containing compounds,in particular of the more difficult(13C)carbon isotope in the processes of synthesis of solid carbon-containing compounds:carbonates,diamonds and,respectively,lighter(12C)synthetic isotopes,including methane have been established.
文摘Titanium dioxide (TiO2) nanosheet, nanorod and nanotubes are synthesized using chemical vapor deposition (CVD) and anodizing processes. TiO2 nanosheets are grown on Ti foil which is coated with Au catalyst in CVD, TiO2 nanorods are synthesized on treated Ti foil with HCl by CVD, and TiO2 nanotubes are prepared by the three-step anodization method. Scanning electron microscopy shows the final TiO2 structures prepared using three processes with three different morphologies of nanosheet, nanorod and nanotube. X-ray diffraction verifies the presence of TiO2. TiO2 sheets and rods are crystalized in rutile phase, and TiO2 tubes after annealing turn into the anatase crystal phase. The optical investigations carried out by diffuse reflection spectroscopy reveal that the morphology of TiO2 nanostructures influencing their optical response and band gap energy of TiO2 is changed for different TiO2 nanostructures.
基金supported financially by the National Natural Science Foundation of China (Grant No. 51372200)Program for New Century Excellent Talents in University of Ministry of Education of China (Grant No. NCET-12-1045)+2 种基金Special Program for local serving from Education Department of Shaanxi Provincial Government (Grant No. 2013JC19)Program for Innovation Team in Xi’an University of Technology (Grant No. 108-25605T401)Ph.D. Innovation Fund Projects of Xi’an University of Technology (Fund No. 310-252071501)
文摘This work focuses on the relationship between flexibility of molecular chains and thermal properties of polyurethane elastomer(PUE), which laid the foundation of further research about how to improve thermal properties of PUE. A series of PUE samples with different flexibility of molecular chains was prepared by using 1,4-butanediol(1,4-BDO)/bisphenol-a(BPA) blends with different mole ratios including9/1, 8/2, 7/3, 6/4 and 5/5. As comparison, PUE extended with pure 1,4-BDO and BPA was also synthesized.These samples were characterized by differential scanning calorimetry(DSC), thermogravimetric analysis(TGA), dynamic mechanical analysis(DMA), etc. The results showed that with the decrease in flexibility of molecular chains the glass transition temperature(Tg) increased and low-temperature properties became worse. Besides, all samples had a certain degree of microphase separation, and soft segments in some samples were crystallized, i.e. the decreasing flexibility of molecular chains led to the impossibility of chains tightly packing and crystalline domains forming so that the degree of microphase separation decreased and the thermal properties became worse.
文摘We continue our investigations on pointwise multipliers for Besov spaces of dominating mixed smoothness. This time we study the algebra property of the classes S_(p,q)~rB(R^d) with respect to pointwise multiplication. In addition, if p≤q, we are able to describe the space of all pointwise multipliers for S_(p,q)~rB(R^d).
基金supported by the National Natural Science Foundation of China(No.51234002)the Fundamental Research Funds for the Central Universities(N130407001)
文摘The effects of various cooling paths on uniformity of through-thickness microstructure and mechanical properties of X80 pipeline steel of 22.0 mm in thickness were studied. The finite difference method was employed to calculate the temperature field during cooling. It was confirmed by the experimental result and temperature field calculation that the optimizing process was achieved by the ultra-fast cooling with medium cooling capacity(cooling rate of *23 K/s)followed by ultimate cooling capacity(cooling rate of *50 K/s). After optimization, the experimental steel displayed much uniform microstructure and the deviation of through-thickness hardness was controlled within 20 HV. In addition,the yield strength, tensile strength and elongation of the experimental steel were 621, 728 MPa and 21.5%, respectively,meeting the requirements of the API standard for X80 pipeline steels.