Synergistic effect of Zr and Mo on precipitation and high-temperature properties of Al-Si-Cu-Mg alloys

This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,to be used in automobile engines at high temperatures,was prepared by adding Zr and Mo into Al-Si-Cu-Mg alloy.The synergistic effects of Zr and Mo on the microstructure evolution and high-temperature mechanical properties were studied.Results show that the addition of Zr and Mo generates a series of intermetallic phases dispersed in the alloy.They can improve the strength of the alloy by hindering dislocation movement and crack propagation.In addition,some nano-strengthened phases show coherent interfaces with the matrix and improve grain refinement.The addition of Mo greatly improves the heat resistance of the alloy.The extremely low diffusivity of Mo enables it to improve the thermal stability of the intermetallic phases,inhibit precipitation during aging,reduce the size of the precipitates,and improve the heat resistance of the alloy.

Microstructure and mechanical properties of a cast TRIP-assisted multiphase stainless steel

Stainless steels are used in a wide range of complex environments due to their excellent corrosion resistance.Multiphase stainless steels can offer an excellent combination of strength,toughness and corrosion resistance due to the coexistence of different microstructures.The microstructure and mechanical properties of a novel cast multiphase stainless steel,composed of martensite,ferrite,and austenite,were investigated following appropriate heat treatment processes:solution treatment at 1,050℃ for 0.5 h followed by water quenching to room temperature,and aging treatment at 500℃ for 4 h followed by water quenching to room temperature.Results show reversed austenite is formed by diffusion of Ni element during aging process,and the enrichment of Ni atoms directly determines the mechanical stability of austenite.The austenite with a lower Ni content undergoes a martensitic transformation during plastic deformation.The tensile strength of the specimen exceeds 1,100 MPa and the elongation exceeds 24%after solid solution,and further increases to 1,247 MPa and 25%after aging treatment.This enhancement is due to the TRIP effect of austenite and the precipitation of the nanoscale G-phase pinning dislocations in ferrite and martensite.

Transformation of long-period stacking ordered structures in Mg-Gd-Y-Zn alloys upon synergistic characterization of first-principles calculation and experiment and its effects on mechanical properties

Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process of long-period stacking ordered(LPSO)structure during solidification and heat treatment and its effect on the mechanical properties of experimental alloys are discussed.Results reveal that the stacking faults and 18R LPSO phases appear in the as-cast Mg-10Gd-4Y-1Zn-0.6Zr and Mg-10Gd-4Y-2Zn-0.6Zr alloys,respectively.After solution treatment,the stacking faults and 18R LPSO phase transform into 14H LPSO phase.The Enthalpies of formation and reaction energy of 14H and 18R LPSO are calculated based on first-principles.Results show that the alloying ability of 18R is stronger than that of 14H.The reaction energies show that the 14H LPSO phase is more stable than the 18R LPSO.The elastic properties of the 14H and 18R LPSO phases are also evaluated by first-principles calculations,and the results are in good agreement with the experimental results.The precipitation of LPSO phase improves the tensile strength,yield strength and elongation of the alloy.After solution treatment,the Mg-10Gd-4Y-2Zn-0.6Zr alloy has the best mechanical properties,and its ultimate tensile strength and yield strength are 278.7 MPa and 196.4 MPa,respectively.The elongation of Mg-10Gd-4Y-2Zn-0.6Zr reaches 15.1,which is higher than that of Mg-10Gd-4Y0.6Zr alloy.The improving mechanism of elastic modulus by the LPSO phases and the influence on the alloy mechanical properties are also analyzed.

Effect of sodium starch octenyl succinate-based Pickering emulsion on the physicochemical properties of hairtail myofibrillar protein gel subjected to multiple freeze-thaw cycles

A Pickering emulsion based on sodium starch octenyl succinate(SSOS)was prepared and its effects on the physicochemical properties of hairtail myofibrillar protein gels(MPGs)subjected to multiple freeze-thaw(F-T)cycles were investigated.The whiteness,water-holding capacity,storage modulus(G')and texture properties of the MPGs were significantly improved by adding 1%-2%Pickering emulsion(P<0.05).Meanwhile,Raman spectral analysis demonstrated that Pickering emulsion promoted the transformation of secondary structure,enhanced hydrogen bonds and hydrophobic interactions,and promoted the transition of disulfide bond conformation from g-g-g to g-g-t and t-g-t.At an emulsion concentration of 2%,theα-helix content decreased by 10.37%,while theβ-sheet content increased by 7.94%,compared to the control.After F-T cycles,the structure of the MPGs was destroyed,with an increase in hardness and a decrease in whiteness and water-holding capacity,however,the quality degradation of MPGs was reduced with 1%-2%Pickering emulsion.These findings demonstrated that SSOS-Pickering emulsions,as potential fat substitutes,can enhance the gel properties and the F-T stability of MPGs.

Near-Surface Soil Chemical Properties as Affected by Cover Crops Over Time in the Lower Mississippi River Valley

Typical row-crop agricultural practices can potentially be harmful to soil health and future sustainability. The use of cover crops (CC) as a mechanism to improve soil health on a wide scale remains underutilized. Soil health remains a major concern for the sustainability of agricultural productivity, therefore, research into CC implementation as a mean to preserve or improve soil health is warranted. The objective of this study was to evaluate the effects of CC on the soils in the eastern Arkansas portion of the Lower Mississippi River Valley (LMRV) over time for various chemical soil parameters, including pH, soil organic matter (SOM), soil elemental contents (i.e., P, K, Ca, Mg, S, Na, Fe, Mn, Zn, Cu, and B), soil respiration, and a generalized soil health score index. Soil pH decreased over time under both CC and no-cover-crop (NCC) treatments, by −0.3 and −0.2, respectively. Soil OM decreased over time under NCC by −0.1%, but did not differ between CC treatments. Soil N availability decreased over time under NCC (−22.6 kg·ha−1), but did not change over time under CC. Soil respiration decreased over time under both CC and NCC, by −76.1 mg·L−1 and −77.3 mg·L−1, respectively, though there was no effect of CC treatment. The Haney soil health score index decreased under CC (−7.0) and NCC (−6.8) without an effect from CC treatment. Results of the study place emphasis on the temporal nature of soil health as influenced by cover crops and their potential to improve soil health.

Mechanical Properties and Electronic Structures of M(M=Ti,V,Cr,Mn and Fe)Dopedβ-Si_(3)N_(4) from First-Principle

The structures,mechanical properties and electronic structures of M metals(M=Ti,V,Cr,Mn and Fe)dopedβ-Si_(3)N_(4) were investigated by First-principles calculations within CASTEP.The calculated lattice parameters ofβ-Si_(3)N_(4) were consistent with previous date.The cohesive energy and formation enthalpy show that initialβ-Si_(3)N_(4) has the highest structural stability.The calculated elastic constant and the Voigt-Reuss-Hill approximation indicate that elastic moduli ofβ-Si_(3)N_(4) are slightly reduced by M doping.Based on Poisson’s and Pugh’s ratio,β-Si_(3)N_(4) is a ductile material and the toughness ofβ-Si_(3)N_(4) increases with M doping,and Fe doping exhibited the best toughness.The results of density of states,charge distributions and overlapping populations indicate thatβ-Si_(3)N_(4) has the strong covalent and ionic bond strength between N and Si.

Synthesis,crystal structure and photo-physical properties of tris(4-methyl-2,5-diphenylpyridine)iridium for OLED

Organic light-emitting diodes(OLEDs)have important applications in the field of next-generation displays and lighting,and phosphorescent iridium complexes are an important class of electroluminescent phosphorescent materials.In this paper,Ir(bmppy)_(3),tris(4-methyl-2,5-diphenylpyridine)iridium,was synthesized and elvaluted for photo-physical characteristics.Single crystals suitale for X-ray diffraction(XRD)were grown from a mixture solvent of dichloromethane and absolute ethanol.The composition and structur of Ir(bmppy)_(3)were determined by element analysis,NMR spectra and XRD.The complex crystallizes in the monoclinic symmetry with the space group P21/c with a slightly distorted octahedral configuration.As measured by UV-Visible and photoluminescence spectra,Ir(bmppy)_(3) displays a maximum emission at at 527 nm at ambient temperature,a typical green-emitting profile.The complex has potential for application in the OLED industry.

The Effect of External Pressure on Mechanical Properties of Aquamarine Gemstone Using First Principles Studies

Aquamarine gemstones are popular jewelry in the gemstone trade and are currently one of the important products in the world market because of their economic value. Aquamarine is a Beryllium Aluminium Silicate with the chemical formula Be3Al2Si6O18 and crystallizes in the hexagonal system with space group P6/mcc (192), and Tanzania has wide deposits of aquamarine gemstones. The quality of gemstone depends on its characteristic properties, including electronic, optical, and mechanical properties. In the present study, the effect of external pressure on mechanical properties including independent elastic constants and other related parameters such as Bulk modulus, Shear modulus, Young modulus, Poisson’s ratio, and Compressibility were studied. Density Function Theory in the forcite module of the material studies software on the external pressure within the range of 0 - 200 GPa on the optimized structure at electrostatic, Van der Waals and Ewald terms were used in this study. The results reveal that the independent elastic constants are mechanically unstable at 50 - 120 Gpa and are stable at 0 - 40 GPa and above 120 GPa, with the average bulk modulus, shear modulus, young modulus, Poisson’s ratio of 2319.9447, 652.3058, 1789.2236, and 0.26 respectively with the compressibility of 0.059921/TPa, this indicates that aquamarine gemstones are stable against strain and strongly against shear stress but opposing shear deformation. These values are within other crystalline materials found in the literature. This provides technological backing for the comprehensive valuation of mechanical properties, quality, and stability of gemstones available in Tanzania.

Composite Panels from the Combination of Rice Husk and Wood Chips with a Natural Resin Based on Tannins Reinforced with Sugar Cane Molasses Intended for Building Insulation: Physico-Mechanical and Thermal Properties

The objective of this work is to develop new biosourced insulating composites from rice husks and wood chips that can be used in the building sector. It appears from the properties of the precursors that rice chips and husks are materials which can have good thermal conductivity and therefore the combination of these precursors could make it possible to obtain panels with good insulating properties. With regard to environmental and climatic constraints, the composite panels formulated at various rates were tested and the physico-mechanical and thermal properties showed that it was essential to add a crosslinker in order to increase certain solicitation. an incorporation rate of 12% to 30% made it possible to obtain panels with low thermal conductivity, a low surface water absorption capacity and which gives the composite good thermal insulation and will find many applications in the construction and real estate sector. Finally, new solutions to improve the fire reaction of the insulation panels are tested which allows to identify suitable solutions for the developed composites. In view of the flame tests, the panels obtained are good and can effectively combat fire safety in public buildings.

First-Principle Study on the Electronic Structure and Optical Property of New Diluted Magnetic Semiconductor(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO

The band structure,DOSs,and optical properties of(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO,including dielectric function,absorption function,reflection function,and energy loss spectrum were studied by using the first-principles calculation.The calculation results indicate that(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO is a direct bandgap semiconductor with a bandgap of 1.1 eV.The Fermi surface is asymmetric and exhibits spin splitting phenomenon.The new type of dilute magnetic semiconductor(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO exhibits significant light loss around 70 eV,with light reflection gradually increasing after 30 eV,and light absorption mainly occurring around 8-30 eV.These results also provide a basis for the discovery of more types of 1111 phase new dilute magnetic semiconductors in the future.

IP属地化政策对舆情评论的影响研究——基于微博用户属地公开的准自然实验

[目的/意义]实证评估公开属地政策能否以及如何对舆情评论产生影响,为网络舆情研究、平台优化和治理提供启示。[研究设计/方法]基于自我监控理论和隐私计算理论构建研究模型和假设,以微博“IP属地”功能的推出为准自然实验,运用双重差分法和断点回归模型探究IP属地化政策对舆情评论的影响。[结论/发现]政策引发用户自我监控效应和风险感知效应,不仅整体改善了评论情感倾向、评论可读性和共情性,也能够显著抑制评论情感极性,该结论在一系列稳健性检验后仍然成立。政策影响在不同用户群体之间存在显著差异,相较处于事件热点中心的用户,属地公开更能促使处于非热点中心的用户做出改变。政策同时加剧评论中的地域歧视现象。[创新/价值]揭示了IP属地化政策对在线评论行为的作用,为清朗网络环境提供新视角,丰富了IP属地化与舆情评论行为影响因素的相关研究。

基于移情设计理念下的秦岭生态旅游IP形象设计研究

为了促进秦岭生态文化保护及旅游业的发展,针对目前文创产品的发展现状及不足之处,以移情理念为视角,提出有效设计策略,为秦岭生态文化的传承与发展提供新的思路。根据调研和受众问题反馈,将移情设计理念引入文创IP设计,归纳设计流程为“观察-互动-感知”3个阶段,从视觉、交互、情感等层面系统性梳理秦岭文创产品移情输出设计流程。提取秦岭生态地域形态、色彩与文化语义等设计要素,明晰设计要点,以秦岭四宝IP文创及衍生设计为例,进行秦岭四宝文创IP的视觉形象设计。通过移情设计对秦岭生态元素分析与整理,能够有效契合受众的情感需求,将优秀的文化元素及情感映射到IP设计本身,为受众赋予秦岭生态文化旅游设计形态与色彩,提升文化价值促进秦岭生态文化的发展与保护。

数字时代传统文化经典再IP化的趋势特征与多元动力

传统文化经典在数字时代的传承与创新,呈现出再IP化的趋势。传统文化经典再IP化,是传统经典依托数字技术的再创造,它以知识产权为核心支撑,并且在介质、感知、功能和运营等维度呈现出跨界融合的趋势特性。传统文化经典再IP化受到多重力量的共同驱动,具体体现为宏观层面的文化安全、文化本体层面的传承需求、科技创新层面的“双向赋能”,以及受众群体层面的代际转换等。但是,传统文化经典再IP化不是简单地将经典的场景予以数字化呈现,而具有一套以观念旨向、业态创新和场景饱和为要素构成的“三位一体”结构体系。

基于身份认证的BACnet/IP分析与改进

为了解决BACnet/IP身份认证存在多种可攻击漏洞和密钥泄露带来的安全问题,提出了一种安全增强的BACnet/IP-SA协议认证方案。研究协议身份认证消息流模型,基于着色Petri网理论和CPNTools对身份认证消息流建模,采用Dolev-Yao攻击者模型和形式化分析方法对BACnet/IP进行安全性分析,发现协议漏洞并提出改进方案。BACnet/IP-SA协议使用设备的伪身份来保护真实身份信息,使用PUF响应进行认证,通过多信息集合的验证值来验证端身份的真实性并生成会话密钥。结合BAN逻辑和非形式化方法,对协议的安全性进行了证明。实验结果表明,所提方案能有效抵抗多类攻击和密钥泄露带来的安全威胁,在减少计算开销的同时增强了协议身份认证的安全性。

椅旁IPS e.max CAD高嵌体修复后牙缺损的临床效果探析

目的为评价CEREC椅旁CAD/CAM系统制作的IPS e.max CAD玻璃陶瓷高嵌体应用于根管治疗后牙缺损病例的临床效果。方法选择42例根管治疗后牙,应用高嵌体的牙体预备方式,采用CEREC椅旁CAD/CAM修复系统和IPS e.max CAD玻璃陶瓷,即刻完成修复体并粘接;修复1年后复查,参照改良修正后的美国公众健康服务标准(US Public Health Service Criteria,USPHS),在修复体边缘染色、边缘继发龋、修复体边缘适合性、修复体崩瓷折裂或脱落、修复体颜色、牙龈健康状况、修复体邻接关系、患者满意度8个方面进行评价。结果修复体边缘染色C级病例1例,成功率97.6%;边缘继发龋C级病例1例,成功率97.6%;修复体邻接关系欠佳C级病例1例,成功率97.6%;在边缘适合性、修复体崩瓷折裂或脱落、修复体颜色、牙龈健康状况、患者满意方面表现优秀,成功率均为100%。结论椅旁CAD/CAM系统制作的IPS e.maxCAD高嵌体修复体在短期内可取得良好的修复效果。

数智化背景下IP出版的创新发展与实践路径

IP具有品牌性、开放性与广泛的受众基础,能够将文化资源转化为品牌价值。数智化转型背景下,出版业价值转向知识服务,用户导向与技术融合形成出版新趋势。借势数智技术,IP出版能够实现创新发展:产品形态创新主要呈现从产品到服务、从实体到虚拟趋势的转变;叙事方式创新能够实现沉浸式体验与个性化设计;传播方式创新能够实现价值共创,塑造文化认同。IP出版应平衡经济价值与文化价值,推动本土文化走出去,激活传统文化价值,扩大流行文化影响力,发挥凝结人类文明成果、传播知识的重要作用,承担起文化传承与现代化发展的时代重任。

基于品牌内涵传达的湖北省博物馆IP文创日用产品开发策略研究

就湖北省博物馆IP文创日用产品开发,对博物馆品牌内涵的传达现状和问题点展开分析,提出明确色彩体系规划、提升产品体验趣味性以及多途径实现品牌价值来强化品牌内涵传达效果的策略和方案,为省博IP文创日用产品开发提供参考。

浅析手游IP计中的应用研究

本文从手游IP在新式茶饮联名设计中的现状入手,分析手游IP在新式茶饮联名设计中的应用基础,对手游IP在新式茶饮联名设计中的应用规则进行细致的阐述,旨在更好地了解手游IP在新式茶饮联名设计中的未来发展趋势,认清IP联名的现状,归纳与总结IP联名的缺憾,实现跨圈双赢。

“粤字号”农产品品牌IP形象设计与叙事策略研究

目的本文以叙事理论为指导,针对“粤字号”农业品牌IP形象设计研究,旨在探索新时代下叙事策略在农业品牌IP形象设计中的方法,为我国农业品牌建设提供新的思路。方法首先,概述了叙事理论的基本概念,分析了“粤字号”农业品牌的发展现状和存在的问题;其次,通过品牌叙事的逻辑,探讨了叙事理论在品牌IP形象设计中的应用方法;最后,通过西关香香IP形象元素的设计实践,总结了“粤字号”农业品牌IP形象的叙事策略。结果通过叙事逻辑的分析,在“粤字号”农业品牌的实践中找到了叙事的核心价值,并通过叙事表达和叙事传播完成了叙事的心理认知。结论品牌叙事从品牌文化、品牌形象和品牌传播等方面形成品牌认知的逻辑关系,为“粤字号”农业品牌IP形象设计提供了系统的方法论,对农业品牌IP形象设计的故事进行挖掘,提升消费者对品牌IP形象的体验感和认知度,提高“粤字号”农产品品牌的市场价值,为农业品牌IP设计提供了有价值的参考。

文本与IP:改编活动的当代认知

本文系统探讨了影视创作中IP改编从古典美学认知到现代美学认知的转换,强调古典改编理论主要关注原始文本在特定艺术门类中的不同演绎和跨艺术门类的内容转化,而现代改编理论则强调尊重不同艺术形式的主体性和开放性。通过对具体案例的分析,文章展示了从原始文本到现代IP建设的转化路径,体现了IP改编在数字时代的独特价值。最终得出结论,认为IP改编不仅是对原著的忠实再现,更是一种具备现代美学态度的扩展性再创造。随着数字时代的发展,改编活动将在新的文化语境中获得更大的学术关注和实践意义。