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COPOLYMERIZATION OF PROPYLENE WITH HINDERED PIPERIDINE MONOMER OVER A HIGH ACTIVITY SUPPORTED ZIEGLER-NATTA CATALYST 被引量:2
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作者 杨汉飚 吕起镐 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1997年第2期146-153,共8页
Copolymerization of propylene and hindered piperidine monomers was carried out over a high activity supported Ziegler-Natta catalyst, using Al(C2H5)(3) as cocatalyst. Factors which affect the copolymerization were stu... Copolymerization of propylene and hindered piperidine monomers was carried out over a high activity supported Ziegler-Natta catalyst, using Al(C2H5)(3) as cocatalyst. Factors which affect the copolymerization were studied, The copolymers exhibited high light stability without adding extra light stabilizers. A self-stabilized polypropylene was prepared. 展开更多
关键词 ziegler-natta catalyst propylene copolymerization hindered piperidine chemically bound stabilizer self-stabilized polypropylene
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钛系Ziegler-Natta催化剂下的丙烯/α-烯烃的共聚合 被引量:4
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作者 陈辉 王建国 +2 位作者 张学全 庞德仁 黄葆同 《应用化学》 CAS CSCD 北大核心 1994年第5期5-9,共5页
研究了TiCl_4/MgCl_2-三乙基铝(TEA)高效载体催化体系下的丙烯/癸烯-1共聚及δ-TiCl_3--氯二乙基铝(DEAC)催化体系下的丙烯/辛烯-1共聚合的基本反应规律,考察了铝钛比、温度、共聚单体浓度等... 研究了TiCl_4/MgCl_2-三乙基铝(TEA)高效载体催化体系下的丙烯/癸烯-1共聚及δ-TiCl_3--氯二乙基铝(DEAC)催化体系下的丙烯/辛烯-1共聚合的基本反应规律,考察了铝钛比、温度、共聚单体浓度等对共聚合的影响;对比了两种催化体系的不同,利用非均相Ziegler-Natta催化体系下共聚合的非稳态扩散动力学的观点,解释了观察到的共聚合催化效率增加,共聚物粒子增大等实验现象. 展开更多
关键词 钛系催化剂 丙烯 烯烃 共聚合
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