The Potential step measurements are carried out on single beads of nickel hydroxide and the results are interpreted with a dual structure model featuring fast and slow diffusing components. The intrinsic diffusion coe...The Potential step measurements are carried out on single beads of nickel hydroxide and the results are interpreted with a dual structure model featuring fast and slow diffusing components. The intrinsic diffusion coefficients for the two components are found to be in the order of magnitude 10-7 and 10-13~10-14 cm2s-1, respectively, with an apparent value for the slow component in the order of 10-10cm2s-1.展开更多
Engineering characterization of water has produced huge varieties of materials with special properties to meet human needs. Equilibrium properties of water-based liquids are well understood via localized atomic and mo...Engineering characterization of water has produced huge varieties of materials with special properties to meet human needs. Equilibrium properties of water-based liquids are well understood via localized atomic and molecular orbital theories. However, the mechanism of electrical conductivity of pure water has proven elusive. We show here it is trapping limited drift of positive and negative quasi-protons （or protons and proton-vacancies） on the extended water lattice, which is accounted for by the long-range correlation inherent in the Fermion （electrons and protons） and Boson （phonons） energy band theory of quasi-particles in solids, with vigorous adherence to equilibrium and nonequilibrium states.展开更多
More than 80 years of theories and experiments on water suggested to us, described in our first water-physics report, that pure water＇s ＂abnormally＂ high electrical conductivity is due to transport of positive and ...More than 80 years of theories and experiments on water suggested to us, described in our first water-physics report, that pure water＇s ＂abnormally＂ high electrical conductivity is due to transport of positive and negative quasi-protons, p＋ and p-, between the neutral proton traps V （H20） in the extended water, [（H20）N]＋, converting it respectively to positively and negatively charged proton traps, V＋ = （H30）1＋ and V- = （HO）1-. In this second report, we present the theoretical charge control capacitances of pure and impure water as a function of the DC electric potential applied to water.展开更多
基金This work was supported by the National Natural Science Foundation of China(No.20073223)the State Key Laboratory for Physical Chemistry of Solid surfaces at Xiamen University(project No.200206)
文摘The Potential step measurements are carried out on single beads of nickel hydroxide and the results are interpreted with a dual structure model featuring fast and slow diffusing components. The intrinsic diffusion coefficients for the two components are found to be in the order of magnitude 10-7 and 10-13~10-14 cm2s-1, respectively, with an apparent value for the slow component in the order of 10-10cm2s-1.
文摘Engineering characterization of water has produced huge varieties of materials with special properties to meet human needs. Equilibrium properties of water-based liquids are well understood via localized atomic and molecular orbital theories. However, the mechanism of electrical conductivity of pure water has proven elusive. We show here it is trapping limited drift of positive and negative quasi-protons （or protons and proton-vacancies） on the extended water lattice, which is accounted for by the long-range correlation inherent in the Fermion （electrons and protons） and Boson （phonons） energy band theory of quasi-particles in solids, with vigorous adherence to equilibrium and nonequilibrium states.
基金supported by the Xiamen Universitysupported by the CTSAH Associates which was founded by the late Linda Su-nan Chang Sa
文摘More than 80 years of theories and experiments on water suggested to us, described in our first water-physics report, that pure water＇s ＂abnormally＂ high electrical conductivity is due to transport of positive and negative quasi-protons, p＋ and p-, between the neutral proton traps V （H20） in the extended water, [（H20）N]＋, converting it respectively to positively and negatively charged proton traps, V＋ = （H30）1＋ and V- = （HO）1-. In this second report, we present the theoretical charge control capacitances of pure and impure water as a function of the DC electric potential applied to water.
