Long‐life lithium batteries enabled by a pseudo‐oversaturated electrolyte

The specific energy of Li metal batteries(LMBs)can be improved by using high‐voltage cathode materials;however,achieving long‐term stable cycling performance in the corresponding system is particularly challenging for the liquid electrolyte.Herein,a novel pseudo‐oversaturated electrolyte(POSE)is prepared by introducing 1,1,2,2‐tetrafluoroethyl‐2,2,3,3‐tetrafluoropropyl ether(TTE)to adjust the coordination structure between diglyme(G2)and lithium bis(trifluoromethanesulfonyl)imide(LiTFSI).Surprisingly,although TTE shows little solubility to LiTFSI,the molar ratio between LiTFSI and G2 in the POSE can be increased to 1:1,which is much higher than that of the saturation state,1:2.8.Simulation and experimental results prove that TTE promotes closer contact of the G2 molecular with Li^(+)in the POSE.Moreover,it also participates in the formation of electrolyte/electrode interphases.The electrolyte shows outstanding compatibility with both the Li metal anode and typical high‐voltage cathodes.Li||Li symmetric cells show a long life of more than 2000 h at 1 mA cm^(−2),1 mAh cm^(−2).In the meantime,Li||LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)cell with the POSE shows a high reversible capacity of 134.8 mAh g^(−1 )after 900 cycles at 4.5 V,1 C rate.The concept of POSE can provide new insight into the Li^(+)solvation structure and in the design of advanced electrolytes for LMBs.

Pseudo channel:time embedding for motor imagery decoding

Motor imagery(MI)based electroencephalogram(EEG)represents a frontier in enabling direct neural control of external devices and advancing neural rehabilitation.This study introduces a novel time embedding technique,termed traveling-wave based time embedding,utilized as a pseudo channel to enhance the decoding accuracy of MI-EEG signals across various neural network architectures.Unlike traditional neural network methods that fail to account for the temporal dynamics in MI-EEG in individual difference,our approach captures time-related changes for different participants based on a priori knowledge.Through extensive experimentation with multiple participants,we demonstrate that this method not only improves classification accuracy but also exhibits greater adaptability to individual differences compared to position encoding used in Transformer architecture.Significantly,our results reveal that traveling-wave based time embedding crucially enhances decoding accuracy,particularly for participants typically considered“EEG-illiteracy”.As a novel direction in EEG research,the traveling-wave based time embedding not only offers fresh insights for neural network decoding strategies but also expands new avenues for research into attention mechanisms in neuroscience and a deeper understanding of EEG signals.

Laboratory Implementation of Direct Torque Controller based Speed Loop Pseudo Derivative Feedforward Controller for PMSM Drive

This paper,evaluate the effectiveness of a proposed speed loop pseudo derivative feedforward(PDFF)controller-based direct torque controller(DTC)for a PMSM drive against the performance of existing PI speed controller-based DTC and hysteresis current controller(HCC).The proposed PDFF-based speed regulator effectively reduces oscillation and overshoot associated with rotor angular speed,electromagnetic torque,and stator current.Two case studies,one using forward-to-reverse motoring operation and the other involving reverse-to-forward braking operation,has been validated to show the effectiveness of the proposed control strategy.The proposed controller's superior performance is demonstrated through experimental verification utilizing an FPGA controller for a 1.5 kW PMSM drive laboratory prototype.

IgG4 Coronary Arteritis Presenting as a Cardiac Pseudo-Tumour

We report on an unusual case presenting with a cardiac pseudo-tumour on echocardiogram, which corresponded to a large soft tissue mural thickening around the mid-right coronary artery. There were similar but not as thick mural lesions around other parts of the coronary arteries. The so-called “pigs-in-a-blanket” sign on computed tomography (CT) scan was pathognomonic of IgG4 coronary arteritis. The IgG4 level was grossly elevated at more than 10 times the upper limit of normal. Positron emission tomography (PET)-CT scans with 18F-fluoro-deoxy-glucose (FDG) and 68Ga-Fibroblast Activation Protein Inhibitor (FAPI) were performed to assess the extent of organ involvement of the IgG4-related disease. The patient was treated with 8 injections of rituximab with good serological response. However, the coronary arteritis findings on CT scan remained unchanged.

Pseudo-Semi-Overlap Functions-Based Fuzzy Rough Sets Applied to Image Edge Extraction

As an extension of overlap functions, pseudo-semi-overlap functions are a crucial class of aggregation functions. Therefore, (I, PSO)-fuzzy rough sets are introduced, utilizing pseudo-semi-overlap functions, and further extended for applications in image edge extraction. Firstly, a new clustering function, the pseudo-semi-overlap function, is introduced by eliminating the symmetry and right continuity present in the overlap function. The relaxed nature of this function enhances its applicability in image edge extraction. Secondly, the definitions of (I, PSO)-fuzzy rough sets are provided, using (I, PSO)-fuzzy rough sets, a pair of new fuzzy mathematical morphological operators (IPSOFMM operators) is proposed. Finally, by combining the fuzzy C-means algorithm and IPSOFMM operators, a novel image edge extraction algorithm (FCM-IPSO algorithm) is proposed and implemented. Compared to existing algorithms, the FCM-IPSO algorithm exhibits more image edges and a 73.81% decrease in the noise introduction rate. The outstanding performance of (I, PSO)-fuzzy rough sets in image edge extraction demonstrates their practical application value.

Acute Colonic Pseudo-Obstruction (ACPO): An Expanding Colon with Unusual Risk Factors

The distention of the colon without mechanical or anatomical obstruction, Acute Colonic Pseudo-obstruction (ACPO), is a common condition occurring in the critically ill. ACPO in the setting of an acute pulmonary embolism and embolic stroke is a rarity. A 76-year-old female with shortness of breath, left hemiparesis and right-sided paresthesias presented with acute pulmonary embolism and acute infarcts of the left caudate nucleus, thalamus and occipital lobe. Her hospitalization was complicated with persistent distention of the large bowel without dilation of the small bowel. Empiric antibiotics were initiated without improvement and laboratory studies including Clostridium difficile were negative. She underwent nasogastric decompression and two decompressive colonoscopies with a resolution of her symptoms. This case illustrates an example of acute abdominal distension, without underlying etiology, in the setting of acute embolism of the pulmonary and cerebral vasculature. Early identification and action with decompressive colonoscopy were key to preventing further bowel damage or rupture.

Sub-Differential Characterizations of Non-Smooth Lower Semi-Continuous Pseudo-Convex Functions on Real Banach Spaces

In this paper, we characterize lower semi-continuous pseudo-convex functions f : X → R ∪ {+ ∞} on convex subset of real Banach spaces K ⊂ X with respect to the pseudo-monotonicity of its Clarke-Rockafellar Sub-differential. We extend the results on the characterizations of non-smooth convex functions f : X → R ∪ {+ ∞} on convex subset of real Banach spaces K ⊂ X with respect to the monotonicity of its sub-differentials to the lower semi-continuous pseudo-convex functions on real Banach spaces.

Does sevoflurane sedation in pediatric patients lead to“pseudo”leptomeningeal enhancement in the brain on 3 Tesla magnetic resonance imaging?

BACKGROUND Prominent leptomeningeal contrast enhancement(LMCE)in the brain is observed in some pediatric patients during sedation for imaging.However,based on clinical history and cerebrospinal fluid analysis,the patients are not acutely ill and do not exhibit meningeal signs.Our study determined whether sevoflurane inhalation in pediatric patients led to this pattern of‘pseudo’LMCE(pLMCE)on 3 Tesla magnetic resonance imaging(MRI).AIM To highlight the significance of pLMCE in pediatric patients undergoing enhanced brain MRI under sedation to avoid misinterpretation in reports.METHODS A retrospective cross-sectional evaluation of pediatric patients between 0-8 years of age was conducted.The patients underwent enhanced brain MRI under inhaled sevoflurane.The LMCE grade was determined by two radiologists,and interobserver variability of the grade was calculated using Cohen’s kappa.The LMCE grade was correlated with duration of sedation,age and weight using the Spearman rho rank correlation.RESULTS A total of 63 patients were included.Fourteen(22.2%)cases showed mild LMCE,48(76.1%)cases showed moderate LMCE,and 1 case(1.6%)showed severe LMCE.We found substantial agreement between the two radiologists in detection of pLMCE on post-contrast T1 imaging(kappa value=0.61;P<0.001).Additionally,we found statistically significant inverse and moderate correlations between patient weight and age.There was no correlation between duration of sedation and pLMCE.CONCLUSION pLMCE is relatively common on post-contrast spin echo T1-weighted MRI of pediatric patients sedated by sevoflurane due to their fragile and immature vasculature.It should not be misinterpreted for meningeal pathology.Knowing pertinent clinical history of the child is an essential prerequisite to avoid radiological overcalling and the subsequent burden of additional investigations.

Acute colonic pseudo-obstruction: A systematic review of aetiology and mechanisms

To critically review the literature addressing the definition, epidemiology, aetiology and pathophysiology of acute colonic pseudo-obstruction (ACPO). METHODSA systematic search was performed to identify articles investigating the aetiology and pathophysiology of ACPO. A narrative synthesis of the evidence was undertaken. RESULTSNo consistent approach to the definition or reporting of ACPO has been developed, which has led to overlapping investigation with other conditions. A vast array of risk factors has been identified, supporting a multifactorial aetiology. The pathophysiological mechanisms remain unclear, but are likely related to altered autonomic regulation of colonic motility, in the setting of other predisposing factors. CONCLUSIONFuture research should aim to establish a clear and consistent definition of ACPO, and elucidate the pathophysiological mechanisms leading to altered colonic function. An improved understanding of the aetiology of ACPO may facilitate the development of targeted strategies for its prevention and treatment.

Rapid, accurate and serotype independent pipeline for in silico epitope mapping of SARS-CoV-2 antigens: a combined machine learning and Chou’s pseudo amino acid composition method

Here,a new integrated machine learning and Chou’s pseudo amino acid composition method has been proposed for in silico epitope mapping of severe acute respiratorysyndrome-like coronavirus antigens.For this,a training dataset including 266 linear B-cell epitopes,1,267 T-cell epitopes and 1,280 non-epitopes were prepared.The epitope sequences were then converted to numerical vectors using Chou’s pseudo amino acid composition method.The vectors were then introduced to the support vector machine,random forest,artificial neural network,and K-nearest neighbor algorithms for the classification process.The algorithm with the highest performance was selected for the epitope mapping procedure.Based on the obtained results,the random forest algorithm was the most accurate classifier with an accuracy of 0.934 followed by K-nearest neighbor,artificial neural network,and support vector machine respectively.Furthermore,the efficacies of predicted epitopes by the trained random forest algorithm were assessed through their antigenicity potential as well as affinity to human B cell receptor and MHC-I/II alleles using the VaxiJen score and molecular docking,respectively.It was also clear that the predicted epitopes especially the B-cell epitopes had high antigenicity potentials and good affinities to the protein targets.According to the results,the suggested method can be considered for developing specific epitope predictor software as well as an accelerator pipeline for designing serotype independent vaccine against the virus.

Boundedness for Multilinear Operators of Pseudo-Differential Operators

In this paper, we establish a sharp function estimate for the multilinear integral operators associated to the pseudo-differential operators. As the application, we obtain the Lp (1 p norm inequalities for the multilinear operators.

Pseudo-Linear Mechanics with Pseudo-Translation Symmetry

In this paper, we will consider the simplest pseudo-addition where pseudo-multiplication and pseudo-division are the same as the ordinary ones and distributivity hold. Using this we consider a special type of the non-uniform discrete times with the pseudo-translation symmetry. Besides, we demand that the displacement should be invariant under the pseudo-translation. From these, we obtain the new definition of the instantaneous velocity which is pseudo-translation symmetry in both time and position and formulate the mechanics which are pseudo-linear and pseudo-translation invariant.

Depression effect of pseudo glycolythiourea acid in flotation separation of copper-molybdenum

Pseudo glycolythiourea acid（PGA） was synthesized and used as depressant for flotation separation of Cu and Mo.The results indicate that a low amount of PGA has strong depression effect on chalcopyrite.Mo grade of 26.17% and recovery of 89.83% were achieved with rougher and scavenger one time and cleaners twice,while the recovery of Mo was deceased by 2% when Na2S was used as depressant.Measurement on adsorption of PGA on the mineral surface indicates that PGA and xanthate were adsorbed on mineral surface by competition,and PGA was adsorbed on chalcopyrite surface much stronger than on molybdenite surface.FTIR results indicate a chemical absorption process for PGA on chalcopyrite surface and a physical adsorption process on molybdenite surface.The frontier orbital calculation shows that the S atom is an active center,and the depression of PGA can be explained with the Fermi level of energy based on the electrochemical mechanism.

基于Pseudo-Zernike不变矩的PNN车牌汉字识别

基于不变矩理论,提出一种应用概率神经网络作为识别器的车牌汉字识别技术。利用Pseudo-Zernike矩特征的旋转不变性和良好的抗噪性能,将其作为车牌汉字识别的特征矢量,结合Pseudo-Zernike矩的快速算法和概率神经网络识别器快速学习和识别的性能,可适应实时环境下所获取的车牌汉字灰度图像的识别,具有较高的准确率,实验结果表明了该方法的有效性。

Reservoir information extraction using a fractional Fourier transform and a smooth pseudo Wigner-Ville distribution

Currently, it is difficult for people to express signal information simultaneously in the time and frequency domains when analyzing acoustic logging signals using a simple-time or frequency-domain method. It is difficult to use a single type of time-frequency analysis method, which affects the feasibility of acoustic logging signal analysis. In order to solve these problems, in this paper, a fractional Fourier transform and smooth pseudo Wigner Ville distribution （SPWD） were combined and used to analyze array acoustic logging signals. The time-frequency distribution of signals with the variation of orders of fractional Fourier transform was obtained, and the characteristics of the time-frequency distribution of different reservoirs under different orders were summarized. Because of the rotational characteristics of the fractional Fourier transform, the rotation speed of the cross terms was faster than those of primary waves, shear waves, Stoneley waves, and pseudo Rayleigh waves. By choosing different orders for different reservoirs according to the actual circumstances, the cross terms were separated from the four kinds of waves. In this manner, we could extract reservoir information by studying the characteristics of partial waves. Actual logging data showed that the method outlined in this paper greatly weakened cross-term interference and enhanced the ability to identify partial wave signals.

一种新的Pseudo-Zernike矩的快速算法

Zernike矩因具有正交性和旋转不变性而广泛应用于模式识别、图像分析等领域.Pseudo-Zernike矩具有与Zernike矩相似的性质,但它较Zernike矩具有更好的抗噪声性.由于pseudo-Zernike矩的复杂性,相关的快速算法的研究尚未得到很好的解决.本文根据pseudo-Zernike矩自身的特点,推导了一种快速有效的计算方法.

单周控制无桥Pseudo-Boost PFC变换器

本文研究了一种新型无桥Pseudo-Boost功率因数校正(Power Factor Correction,PFC)变换器,变换器完全消除了传统Boost PFC变换器的整流桥,无桥Pseudo-Boost PFC变换器存在谐振支路,但却呈现出PWM变换器的性质;分析了无桥Pseudo-Boost PFC变换器的工作原理,在交流输入电压正半周或是负半周内,具有传统Boost PFC变换器的特性,其电压传输比与谐振支路参数无关。为了验证该新型变换器的有效性,采用了单周控制策略的数字控制实现方案,仿真和实验表明,该变换器直流输出电压稳定,交流输入电流与输入电压相位相同,功率因数可达到1,具有PFC变换器的功能。

基于FDK框架的锥形束Pseudo-LT优质重建

目前医用CT已由二维扇形束扫描模式成功演变至三维锥形束扫描模式。本文作者从经典的FDK算法框架出发,结合Noo等人提出的二维扇形束超短扫描重建算法,并在本文作者先前工作的基础上,首次将二维Lambda tomography(LT)算法与FDK型算法结合,提出一种新的锥形束Pseudo-LT算法,新算法在回避了成像公式中有关PI线计算的同时,还将关于投影数据的微分运算进行回避,较基于PI线的LT重建有了较大改进,提高了图像重建速度和重建质量。数值实验进一步验证了本文算法的有效性。

一种二帽pseudo-Keggin结构簇合物[HN(C_2H_5)_3]_3[N(C_2H_5)_3]_2[Mo_8~ⅣMo_4~ⅤV_2~ⅣO_(38)(PO_4)]的水热合成、结构和性质研究

The novel polyoxometalate, 32[Mo8ⅣMo4ⅤV2ⅣO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X ray diffraction. The compoundcrystallizes in triclinic system, space group with a= 1.41999(2)nm, b=1.43467(2)nm, c=1.694610(10)nm, α=95.7250(10)°, β=92.2110(10)°, γ=92.6060(10)°, V=3.42829(7)nm3, Z=2, Dc=2.388g·cm-3, Mr=2465.10g·mol-1, μ=2.489mm-1, F(000)=2388, R1=0.0584, wR2=0.1461, S=1.164. The heteropolyanion is a bi capped pseudo Keggin complex. CCDC: 186645.

基于混沌与Pseudo-Newton法组合优化的直接衰减正弦原子库分解方法在低频振荡分析中的应用

传统原子库分解法在对信号进行分解时，往往先将信号分解为较易离散化的Gabor原子，再转化为衰减正弦原子，由于Gabor原子库并不符合振荡信号的本质特性，加之转化过程为近似转化，使分解存在双重误差。为克服以上不足，提出一种新的低频振荡分析方法，即基于混沌与Pseudo-Newton法组合优化的直接衰减正弦原子库分解方法。为了解决离散困难和六维空间寻优效率低的问题，采用混沌与Pseudo-Newton法组合优化方法，可以同时对6个参数进行寻优，极大的提高方法的速度。通过对自合成信号、仿真信号、华中电网能量管理单元实测信号等3个算例进行分析，并与其他2种辨识方法进行对比，表明该文算法在计算精度、辨识速度、抗噪能力方面都有较大优势。