Effect of supports on the redox performance of pyrite cinder in chemical looping combustion

Chemical looping combustion(CLC)is a clean and efficient flame-free combustion technology,which combust the fuels by lattice oxygen from a solid oxygen carrier with inherent CO_(2)capture.The development of oxygen carriers with low cost and high redox performance is crucial to the whole efficiency of CLC process.As the solid by-product from the sulfuric acid production,pyrite cinder presented excellent redox performance as an oxygen carrier in CLC process.The main components in pyrite cinder are Fe_(2)O_(3),CaSO_(4),Al_(2)O_(3)and SiO_(2)in which Fe_(2)O_(3)is the active component to provide lattice oxygen.In order to systematic investigate the functions of supports(CaSO_4,Al_(2)O_(3)and SiO_(2))in pyrite cinder,three oxygen carriers(Fe_(2)O_(3)-CaSO_(4),Fe_(2)O_(3)-Al_(2)O_(3)and Fe_(2)O_(3)-SiO_(2))were prepared and evaluated in this study.The results showed that Fe_(2)O_(3)-CaSO_(4) displayed high redox activity and cycling stability in the multiple redox cycles.However,both Fe_(2)O_(3)-Al_(2)O_(3)and Fe_(2)O_(3)-SiO_(2)experienced serious deactivation during redox reactions.It indicated that the inert Fe-Si solid solution(Fe_(2)SiO_(4))was formed in the spent Fe_(2)O_(3)-SiO_(2)sample,which decreased the oxygen carrying capacity of this sample.The XPS results showed that the oxygen species on the surface of Fe_(2)O_(3)-CaSO_(4) could be fully recovered after the 20 redox cycles.It can be concluded that CaSO_(4) is the key to the high redox activity and cycling stability of pyrite cinder.

Investigation of the redox performance of pyrite cinder calcined at different temperature in chemical looping combustion

As an industrial solid waste,pyrite cinder exhibited excellent reactivity and cycle stability in chemical looping combustion.Prior to the experiment,oxygen carriers often experienced a high temperature calcination process to stabilize the physico-chemical properties,which presented significant influence on the redox performance of oxygen carriers.However,the effect of calcination temperature on the cyclic reaction performance of pyrite cinder has not been studied in detail.In this work,the effect of calcination temperature on the redox activity and attrition characteristic of pyrite cinder were studied in a fluidizedbed reactor using CH_(4) as fuel.A series of pyrite cinder samples were prepared by controlling the calcination temperature.The redox activity and attrition rate of the obtained pyrite cinder samples were investigated deeply.The results showed that calcination temperature displayed significant impact on the redox performance of pyrite cinder.Considering CH_(4) conversion(80%–85%)and attrition resistance,the pyrite cinder calcined at 1050℃ presented excellent redox properties.In the whole experiment process,the CO_(2) selectivity of the pyrite cinder samples were not affected by the calcination temperature and were still close to 100%.The results can provide reference for optimizing the calcination temperature of pyrite cinder during chemical looping process.

Process Optimization and Reaction Mechanism of Removing Copper From an Fe-Rich Pyrite Cinder Using Chlorination Roasting

The aim is to remove copper from a pyrite cinder by optimizing the chlorination roasting process using re-sponse surface methodology （RSM） and the reaction mechanism of chlorination roasting based on thermodynamic calculation was discussed. A quadratic model was suggested by RSM to correlate the key parameters, namely, dos-age of chlorinating agent, roasting temperature and roasting time to the copper volatilization ratio. The results indi- cate that the model is well consistent with the experimental data at a correlation coefficient （R2） of 0.95, and the dosage of chlorinating agent and roasting temperature both have significant effects on the copper volatilization ratio. However, a roasting temperature exceeding 1170 ~C decreases the volatilization ratio. The optimum conditions for removing copper from the cinder were identified as chlorinating agent dosage at 5%, roasting temperature at i155.10 ℃ and roasting time of 10 min; under Such a conditiom a copper volatilization ratid of 95.16% Was a- chieved from the cinder. Thermodynamic calculation shows that SiO2 in the pellet plays a key role in the chlorine re-lease from calcium chloride, and the chlorine release reactions cannot occur without it.

Reduction of Pyrite Cinder Pellets Mixed with Coal Powder

Direct reduction of pyrite cinder in a rotary hearth furnace （RHF） was studied under the condition of labo ratory simulation. Effects of reduction temperature, reduction time, molar ratio of carbon to oxygen, .and CaO addition on metallization rate as well as compressive strength of the pellets after reduction were discussed. The results showed that the metallization rate and compressive strength were 93.9% and 2 160 N per pellet respectively under the conditions of the reduction temperature of 1 200 ℃, the reduction time of 16 min, and the molar ratio of carbon to oxygen （xc/xo） of 1. 0; adding 2.5% CaO was beneficial to sulfur enrichment in slag phase of pellet, and metal- lization rate increased slightly while compressive strength decreased.

Effect of Biochar as Reductant on Magnetizing-roasting Behavior of Pyrite Cinder

The effect of biochar substituted for anthracite as reductant on magnetizing-roasting pyrite cinder was in- vestigated. The key of magnetizing-roasting is the gasification reaction between reductants and CO2. Since biochar could react with CO2 more rapidly at lower temperature, the reactivity of biochar is better than that of anthracite. The gasification of biochar could produce reducing condition of φco/（φco--φco2 ） about 10 %- 20 % between 700-- 800 ℃, which is in accord with the atmosphere and temperature of Fe2 O3 reduction. So it is beneficial to the reduc- tion of iron mineral of pyrite cinder. Compared with anthracite, bioehar could decrease the roasting temperature from 825 to 750 ℃ and roasting time from 20 to 15 min, which shows that a better effect of magnetization could be ob- tained in the condition of lower temperature and shorter time. Using biochar as reductant, iron concentrate extracted from pyrite cinder as about 64% iron grade could be produced, and the recovery is over 90% under the condition of above 90% grinding particle less than 0. 045 mm and magnetic intensity of 0. 124--0. 194 T.

Utilization of High Sulfur Raw Materials in Iron Ore Pellets

Pyrite cinder and high sulfur magnetite were used as raw materials to produce iron ore pellets. Good quali ties of green balls and fired pellets were obtained from the feed comprising 50G pyrite cinder and 50% high sulfur magnetite concentrate at a small scale. Small scale tests were proven by pilot-scale tests. The high grade fired pel lets, assaying 63. 22% Fe, were analyzed, and the compressive strength of fired pellets was over 2 500 N/pellet. The fired pellets possessed excellent metallurgical performances, such as reducibility index higher than 67%, reduction swelling index lower than 15% and low temperature reduction degradation index （＋ 3.15 mm） higher than 1%, which can be used as the hurden for blast furnace.