We demonstrated a facile method to prepare photoluminescent graphene quantum dots using commercial polyacrylonitrile(PAN) based carbon fibers(CFs) as the raw material by facile chemical oxidation and exfoliation m...We demonstrated a facile method to prepare photoluminescent graphene quantum dots using commercial polyacrylonitrile(PAN) based carbon fibers(CFs) as the raw material by facile chemical oxidation and exfoliation method. The as-prepared GQDs with uniform size exhibit an excitation-independent photoluminescence behavior, which is similar to other semiconductor quantum dots. Moreover, when acting as catalyst the uniform GQDs have better activity for electrochemical oxidation of dopamine(DA) than graphene oxides(GOs). The square wave voltammogram(SWV) peak values of GQDs are in good correspondence with DA concentrations and can act as a sensor of DA.展开更多
A novel quantum dots (QDs) optical fiber amplifier was proposed and demonstrated. It was fabricated by dipcoating the PbSe QDs doped sol onto the taper region of fiber coupler. The PbSe QDs was synthesized according...A novel quantum dots (QDs) optical fiber amplifier was proposed and demonstrated. It was fabricated by dipcoating the PbSe QDs doped sol onto the taper region of fiber coupler. The PbSe QDs was synthesized according to a colloidal method. A lower refractive index sol was also synthesized as the host of PbSe QDs. A standard single mode fiber was used to make the fusion tapered fiber coupler which had double input and output ports. With the simple structure, a signal and a pump can be injected into the amplifier and excite the PbSe QDs through evanescent wave. The experimental results indicated that the amplified light wave was observed at 1 550 nm wavelength with 980 nm .wavelength laser diode as pump.展开更多
基金Funded by the National Natural Science Foundation of China(21676070)the Hebei Training Program for Talent Project(A2015007)+1 种基金the Beijing National Laboratory for Molecular Sciences(20140120)the Special Project for Synthesis and Application of Graphene in Hebei University of Science and Technology(2015PT65)
文摘We demonstrated a facile method to prepare photoluminescent graphene quantum dots using commercial polyacrylonitrile(PAN) based carbon fibers(CFs) as the raw material by facile chemical oxidation and exfoliation method. The as-prepared GQDs with uniform size exhibit an excitation-independent photoluminescence behavior, which is similar to other semiconductor quantum dots. Moreover, when acting as catalyst the uniform GQDs have better activity for electrochemical oxidation of dopamine(DA) than graphene oxides(GOs). The square wave voltammogram(SWV) peak values of GQDs are in good correspondence with DA concentrations and can act as a sensor of DA.
基金Project supported by the Innovation Program of Shanghai Municipal Education Commission (Grant No.10YZ12)the Science and Technology of Commission of Shanghai Municipality (Grant No.0952nm06800)the Shanghai Leading Academic Discipline Project (Grant No.S30108)
文摘A novel quantum dots (QDs) optical fiber amplifier was proposed and demonstrated. It was fabricated by dipcoating the PbSe QDs doped sol onto the taper region of fiber coupler. The PbSe QDs was synthesized according to a colloidal method. A lower refractive index sol was also synthesized as the host of PbSe QDs. A standard single mode fiber was used to make the fusion tapered fiber coupler which had double input and output ports. With the simple structure, a signal and a pump can be injected into the amplifier and excite the PbSe QDs through evanescent wave. The experimental results indicated that the amplified light wave was observed at 1 550 nm wavelength with 980 nm .wavelength laser diode as pump.