Hydrothermal Synthesis,Crystal Structure,Spectrum Properties and Quantum Chemical Calculation of a Trinuclear Copper(Ⅱ) Complex with 3-(Pyridin-2-yl)-1,2,4-triazole

A three-dimensional framework copper（Ⅱ） coordination polymer with copper carbonate basic and 3-（pyridin-2-yl）-1,2,4-triazole （Hpt） has been hydrothemally synthesized.The complex （2,C14 H10 CuN8 ·3H2 O） crystallizes in tetragonal,space group P4 2 /n,a=2.08581（12）,b=2.08581（12）,c=0.72331（4） nm,M r=761.73,V=3.1468（3） nm 3,Dc=1.608 g/cm 3,Z=4,F（000）=1552,GOOF=1.07,R=0.0515 and wR=0.1689.Every asymmetric unit molecular structure of the complex is composed with one copper ion,one and half water molecules and two Hpt molecules.Each copper ion is coordinated with five nitrogen atoms from four Hpt molecules,forming a distorted square pyramidal geometry.The fluorescence spectrum analysis shows that the title complex at room temperature exhibits intense photoluminescence with maximum emission at 450 nm.The quantum chemistry calculation study on the complex has been performed.The stability,some frontier molecular orbital energies and composition characteristics of some frontier molecular orbitals of the complex have been investigated.

Quantum properties near the instability boundary in optomechanical system

The properties of the system near the instability boundary are very sensitive to external disturbances, which is important for amplifying some physical effects or improving the sensing accuracy. In this paper, the quantum properties near the instability boundary in a simple optomechanical system have been studied by numerical simulation. Calculations show that the transitional region connecting the Gaussian states and the ring states when crossing the boundary is sometimes different from the region centered on the boundary line, but it is more essential. The change of the mechanical Wigner function in the transitional region directly reflects its bifurcation behavior in classical dynamics. Besides, quantum properties, such as mechanical second-order coherence function and optomechanical entanglement, can be used to judge the corresponding bifurcation types and estimate the parameter width and position of the transitional region. The non-Gaussian transitional states exhibit strong entanglement robustness, and the transitional region as a boundary ribbon can be expected to replace the original classical instability boundary line in future applications.

Effect of Green Quantum Well Number on Properties of Green GaN-Based Light-Emitting Diodes

In GaN-based green light-emitting diodes（LEDs） with different green quantum well numbers grown on Si（111）substrates by metal organic chemical vapor deposition are investigated. It is observed that V-shaped pits appear in the AFM images with the green quantum well number increasing from 5 to 9, and results in larger reverse-bias leakage current. Meanwhile, in the case of the sample with the number from 5 to 7 then to 9, the external quantum efficiency increases firstly, and then decreases. These phenomena may be related to the size of V-shaped pits in the active area and the distribution of electrons and holes in the active area caused by V-shaped pits. The optimal number of green quantum wells is determined to be 7.

Lorentz-Invariant System with Quantum Mechanical Properties

In this work, we study potential fluids, within which eddies exist and have quantum mechanical properties because according to Helmholtz, they are made up of an integer number of lines and their displacement in a potential medium is a function of a frequency. However, this system is Lorentz-invariant since Maxwell’s equations can be obtained from it, and this is what we demonstrate here. The considered hypothesis is that the electric charge arises naturally as the intensity of the eddy in the potential fluid, that is, the circulation of the velocity vector of the elements that constitute it, along that potential (it is not another parameter, whose experimental value must be added, as proposed by the standard model of elementary particles). Hence, the electric field appears as the rotational of the velocity field, at each point of the potential medium, and the magnetic field appears as the variation with respect to the velocity field of the potential medium, which is equivalent to the Biot and Savart law. From these considerations, Maxwell’s equations are reached, in particular his second equation which is the non-existence of magnetic monopoles, and the fourth equation which is Ampere’s law, both of which to date are obtained empirically demonstrated theoretically. The electromagnetic field propagation equation also arrives, thus this can be considered a demonstration that a potential medium in which eddies exists constitutes a Lorentz-invariant with quantum mechanical properties.

First-Principles Calculation on Geometric,Electronic and Optical Properties of Fully Fluorinated Stanene:a Large-Gap Quantum Spin Hall Insulator

The searches for large-gap quantum spin Hall insulators are important for both practical and fundamental inter- ests. In this work, we present a theoretical observation of the two-dimensional fully fluorinated stanene （SnF） by means of density functional theory. Remarkably, a significant spin-orbit coupling is observed for the SnF monolayer in the valence band at the F point, with a considerable indirect band gap of 278 meV. The direct gap of the SnF monolayer is at the F point, which is slightly larger by as much as 381 meV. In addition, the elastic modulus of the SnF monolayer is about 20J/m^2, which is comparable with the in-plane stiffness of black phos- phorus monolayer along the x-direction （~28.94 J/m^2）. Finally, the optical properties of stanene, SnF monolayer and stanene/SnF bilayer are calculated, in which the stanene/SnF bilayer is supposed to be an attractive sunlight absorber.

Spin-filter effect and spin-polarized optoelectronic properties in annulene-based molecular spintronic devices

Using Fe, Co or Ni chains as electrodes, we designed several annulene-based molecular spintronic devices and investigated the quantum transport properties based on density functional theory and non-equilibrium Green＇s function method.Our results show that these devices have outstanding spin-filter capabilities and exhibit giant magnetoresistance effect,and that with Ni chains as electrodes, the device has the best transport properties. Furthermore, we investigated the spinpolarized optoelectronic properties of the device with Ni electrodes and found that the spin-polarized photocurrents can be directly generated by irradiating the device with infrared, visible or ultraviolet light. More importantly, if the magnetization directions of the two electrodes are antiparallel, the photocurrents with different spins are spatially separated, appearing at different electrodes. This phenomenon provides a new way to simultaneously generate two spin currents.

The effects of the Dzyaloshinskii-Moriya interaction on the ground-state properties of the XY chain in a transverse field

The effects of the Dzyaloshinski-Moriya （DM） interaction on the ground-state properties of the anisotropic XY chain in a transverse field have been studied by means of correlation functions and entanglement. Different from the case without the DM interaction, the excitation spectra ek of this model are not symmetrical in the momentum space and are not always positive. As a result, besides the ferromagnetic （FM） and the paramagnetic （PM） phases, a gapless chiral phase is induced. In the chiral phase, the von Neumann entropy is proportional to log2 L （L is the length of a subchain） with the coefficient A ~ 1/3, which is the same as that of the XY chain in a transverse field without the DM interaction for 7 = 0 and 0 〈 h 〈 1. And in the vicinity of the critical point between the chiral phase and the FM （or PM） phase, the behaviors of the nearest- neighbor concurrence and its derivative are like those for the anisotropy transition.

Tunable thermoelectric properties in bended graphene nanoribbons

The ballistic thermoelectric properties in bended graphene nanoribbons（GNRs） are systematically investigated by using atomistic simulation of electron and phonon transport. We find that the electron resonant tunneling effect occurs in the metallic–semiconducting linked ZZ-GNRs（the bended GNRs with zigzag edge leads）. The electron-wave quantum interference effect occurs in the metallic–metallic linked AA-GNRs（the bended GNRs with armchair edge leads）.These different physical mechanisms lead to the large Seebeck coefficient S and high electron conductance in bended ZZGNRs/AA-GNRs. Combined with the reduced lattice thermal conduction, the significant enhancement of the figure of merit ZT is predicted. Moreover, we find that the ZTmax（the maximum peak of ZT） is sensitive to the structural parameters. It can be conveniently tuned by changing the interbend length of bended GNRs. The magnitude of ZT ranges from the 0.15 to 0.72. Geometry-controlled ballistic thermoelectric effect offers an effective way to design thermoelectric devices such as thermocouples based on graphene.

Structural Characterization of Thin Epitaxial GaN Films on Polymer Polyimides Substrates by Ion Beam Assisted Deposition

The Epitaxial GaN thin films have been fabricated by Ion Beam Assisted Deposition (IBAD) process using nitrogen ions with hyperthermal energies on the polyimides polymer substrates. By applying with the Reflection of High-Energy Electron Diffraction (RHEED), Scanning Electron Microscopy (SEM) and Quantum Design Physical Properties Measurement System, the behaviour of hexagonal GaN thin films is investigated. The result showed that the high quality of the deposited GaN layers kept appearing for many parameters depending on the temperature greatly. The behaviour of high quality of epitaxial GaN coating on the polyimide polymer substrates is a promising material for optoelectronic devices and semiconductor devices application.

Nonlinear properties of quantum dot semiconductor optical amplifiers at 1.3 μm:errata

The authors regret that one of the coauthors was inadvertently omitted in the previous paper. E. Varene was a member of the Institut fur Festk6rperphysik at the Technische Universitat Berlin and contributed to the results on cross-phase modulation.

Exact investigation of the electronic structure and the linear and nonlinear optical properties of conical quantum dots

Intersubband linear and third-order nonlinear optical properties of conical quantum dots with infinite barrier potential are studied. The electronic structure of conical quantum dots through effective mass approximation is determined analytically. Linear, nonlinear, and total absorption coefficients, as well as the refractive indices of GaAs conical dots, are calculated. The effects of the size of the dots and of the incident electromagnetic field are investigated. Results show that the total absorption coefficient and the refractive index of the dots largely depend on the size of the dots and on the intensity and polarization of the incident electromaenetic field.

A novel coupled quantum well structure and its excellent electro-optical properties

A novel InGaAs/InAlAs coupled quantum well structure is proposed for large field-induced refractive index change with low absorption loss. In the case of low applied electric field of 15 kV/cm and low absorption loss （α≤100 cm^-1）, a large field-induced refractive index change （for transverse electric （TE） mode, △n= 0.012; for transverse magnetic （TM） mode, △n = 0.0126） is obtained in the structure at the operation wavelength of 1.55 μm. The value is larger by over one order of magnitude than that in a rectangular quantum well. The result is very attractive for semiconductor optical switching devices.

Photon higher-order squeezing effects of the q analogue of a single-mode field interacting with a -type three-level atom

The nonlinear theory of interaction between the q analogue of a single-mode field and a Ξ-type threelevel atom has been established. And the formal solution of the Schrodinger equation in the representation and its average number are obtained. Then, the photon squeezing effects are studied through numerical calculation. The results show that the q deformation nonlinear action has a lot of influence on the quantum coherence and quantum properties. When q approaches 1, the theory reduces to the common linear theory.