A new single-molecule magnet [Mn11Fe1O12 （CH3COO）16（H2O）4]·2CH3COOH·4H2O （Mn11Fe1） has been synthesized. The structure has been studied by the single crystal x-ray diffraction. The difference of Jahn-T...A new single-molecule magnet [Mn11Fe1O12 （CH3COO）16（H2O）4]·2CH3COOH·4H2O （Mn11Fe1） has been synthesized. The structure has been studied by the single crystal x-ray diffraction. The difference of Jahn-Teller distortion between Fe^3＋ and Mn^3＋ ion reveals that Fe^3＋ ion substitutes for Mn^3＋ ion on the Mn（3） sites in the Mn12 skeleton. The temperature dependence of the magnetization gives a blocking temperature TB=1.9K for Mn11Fe1. Based on the magnetization process analysis of the crystal at T=2K, we suggest that Mn11Fe1 has the ground state with a total spin S=11/2.展开更多
基金Project supported by the National Natural Science Foundation of China （Grant No 10375088）.
文摘A new single-molecule magnet [Mn11Fe1O12 （CH3COO）16（H2O）4]·2CH3COOH·4H2O （Mn11Fe1） has been synthesized. The structure has been studied by the single crystal x-ray diffraction. The difference of Jahn-Teller distortion between Fe^3＋ and Mn^3＋ ion reveals that Fe^3＋ ion substitutes for Mn^3＋ ion on the Mn（3） sites in the Mn12 skeleton. The temperature dependence of the magnetization gives a blocking temperature TB=1.9K for Mn11Fe1. Based on the magnetization process analysis of the crystal at T=2K, we suggest that Mn11Fe1 has the ground state with a total spin S=11/2.
