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Etching of quartz crystals in liquid phase environment:A review
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作者 Yide Dong Yike Zhou +5 位作者 Haizhou Huang Bosong Zhang Xihan Li Kaiwen Chen Litao Sun Guangbin Dou 《Nanotechnology and Precision Engineering》 EI CAS CSCD 2024年第2期87-109,共23页
Quartz crystals are the most widely used material in resonant sensors,owing to their excellent piezoelectric and mechanical properties.With the development of portable and wearable devices,higher processing efficiency ... Quartz crystals are the most widely used material in resonant sensors,owing to their excellent piezoelectric and mechanical properties.With the development of portable and wearable devices,higher processing efficiency and geometrical precision are required.Wet etching has been proven to be the most efficient etching method for large-scale production of quartz devices,and many wet etching approaches have been developed over the years.However,until now,there has been no systematic review of quartz crystal etching in liquid phase environments.Therefore,this article provides a comprehensive review of the development of wet etching processes and the achievements of the latest research in thisfield,covering conventional wet etching,additive etching,laser-induced backside wet etching,electrochemical etching,and electrochemical discharge machining.For each technique,a brief overview of its characteristics is provided,associated problems are described,and possible solutions are discussed.This review should provide an essential reference and guidance for the future development of processing strategies for the manufacture of quartz crystal devices. 展开更多
关键词 quartz crystal Materials processing Wet etching MICROFABRICATION quartz MEMS
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Diffusion and reaction mechanism of limestone and quartz in fluxed iron ore pellet roasting process
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作者 Yufeng Guo Jinlai Zhang +5 位作者 Shuai Wang Jianjun Fan Haokun Li Feng Chen Kuo Liu Lingzhi Yang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期485-497,共13页
The increase to the proportion of fluxed pellets in the blast furnace burden is a useful way to reduce the carbon emissions in the ironmaking process.In this study,the interaction between calcium carbonate and iron or... The increase to the proportion of fluxed pellets in the blast furnace burden is a useful way to reduce the carbon emissions in the ironmaking process.In this study,the interaction between calcium carbonate and iron ore powder and the mineralization mechanism of fluxed iron ore pellet in the roasting process were investigated through diffusion couple experiments.Scanning electron microscopy with energy dispersive spectroscopy was used to study the elements’diffusion and phase transformation during the roasting process.The results indicated that limestone decomposed into calcium oxide,and magnetite was oxidized to hematite at the early stage of preheating.With the increase in roasting temperature,the diffusion rate of Fe and Ca was obviously accelerated,while the diffusion rate of Si was relatively slow.The order of magnitude of interdiffusion coefficient of Fe_(2)O_(3)-CaO diffusion couple was 10^(−10) m^(2)·s^(−1) at a roasting temperature of 1200℃for 9 h.Ca_(2)Fe_(2)O_(5) was the initial product in the Fe_(2)O_(3)-CaO-SiO_(2) diffusion interface,and then Ca_(2)Fe_(2)O_(5) continued to react with Fe_(2)O_(3) to form CaFe_(2)O_(4).With the expansion of the diffusion region,the sillico-ferrite of calcium liquid phase was produced due to the melting of SiO_(2) into CaFe_(2)O_(4),which can strengthen the consolidation of fluxed pellets.Furthermore,andradite would be formed around a small part of quartz particles,which is also conducive to the consolidation of fluxed pellets.In addition,the principle diagram of limestone and quartz diffusion reaction in the process of fluxed pellet roasting was discussed. 展开更多
关键词 fluxed iron ore pellet LIMESTONE HEMATITE quartz diffusion reaction
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Trace elements in magmatic and hydrothermal quartz:Implications on the genesis of the Xingluokeng Tungsten Deposit,South China
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作者 Qing-Qing Zhang You-Wei Chen Jian-Feng Gao 《Acta Geochimica》 EI CAS CSCD 2024年第3期441-458,共18页
The Xingluokeng deposit is the largest gran-ite-related tungsten deposit within the Wuyi metallogenic belt in South China.The Xingluokeng intrusion primarily consists of porphyritic biotite granite,biotite granite,and... The Xingluokeng deposit is the largest gran-ite-related tungsten deposit within the Wuyi metallogenic belt in South China.The Xingluokeng intrusion primarily consists of porphyritic biotite granite,biotite granite,andfine-grained granite.The deposit is represented by veinlet-disseminated mineralization with K-feldspathization and biotitization,alongside quartz-vein mineralization with gre-isenization and sericitization.This study investigates in-situ analyses of quartz compositions from both the intrusion and hydrothermal veinlets and veins.Trace element correlations indicate that trivalent Al^(3+)and Fe^(3+)replace Si^(4+)within the quartz lattice,with monovalent cations(such as Li^(+),Na^(+),and K^(+))primarily serving as charge compensators.Low Ge/Al ratios(<0.013)of quartz from granites suggest a mag-matic origin.The low Al/Ti and Ge/Ti ratios,accompanied by high Ti contents in quartz,suggest that the porphyritic biotite granite and biotite granite are characterized by rela-tively low levels of differentiation and high crystallization temperatures.In contrast,thefine-grained granite exhibits a higher degree of fractionation,lower crystallization tem-peratures,and a closer association with tungsten miner-alization.Ti contents in quartz from quartz veins indicate Qz-Ⅰformed at temperatures above 400°C,while Qz-Ⅱto Qz-Ⅴformed at temperatures below 350°C.Variations in different generations of quartz,as indicated by Al content and(Al+Fe)/(Li+Na+K)ratio,suggest that Qz-Ⅰprecipi-tated from a less acidicfluid with a stable pH,whereas Qz-Ⅱto Qz-Ⅴoriginated from a more acidicfluid with notable pH variations.Consequently,alkaline alteration and acidic alteration supplied the essential Ca and Fe for the precipita-tion of scheelite and wolframite,respectively,highlighting a critical mechanism in tungsten mineralization at the Xin-gluokeng deposit. 展开更多
关键词 quartz Xingluokeng Tungsten deposit Trace elements South China
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A highly sensitive LITES sensor based on a multi-pass cell with dense spot pattern and a novel quartz tuning fork with low frequency
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作者 Yahui Liu Shunda Qiao +4 位作者 Chao Fang Ying He Haiyue Sun Jian Liu Yufei Ma 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2024年第3期26-34,共9页
A highly sensitive light-induced thermoelectric spectroscopy(LITES)sensor based on a multi-pass cell(MPC)with dense spot pattern and a novel quartz tuning fork(QTF)with low resonance frequency is reported in this manu... A highly sensitive light-induced thermoelectric spectroscopy(LITES)sensor based on a multi-pass cell(MPC)with dense spot pattern and a novel quartz tuning fork(QTF)with low resonance frequency is reported in this manuscript.An erbi-um-doped fiber amplifier(EDFA)was employed to amplify the output optical power so that the signal level was further enhanced.The optical path length(OPL)and the ratio of optical path length to volume(RLV)of the MPC is 37.7 m and 13.8 cm^(-2),respectively.A commercial QTF and a self-designed trapezoidal-tip QTF with low frequency of 9461.83 Hz were used as the detectors of the sensor,respectively.The target gas selected to test the performance of the system was acetylene(C2H2).When the optical power was constant at 1000 mW,the minimum detection limit(MDL)of the C2H2-LITES sensor can be achieved 48.3 ppb when using the commercial QTF and 24.6 ppb when using the trapezoid-al-tip QTF.An improvement of the detection performance by a factor of 1.96 was achieved after replacing the commer-cial QTF with the trapezoidal-tip QTF. 展开更多
关键词 light-induced thermoelectric spectroscopy quartz tuning fork multi-pass cell gas sensing
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Novel polyhydroxy cationic collector N-(2,3-propanediol)-Ndodecylamine: Synthesis and flotation performance to hematite and quartz 被引量:1
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作者 Wenbao Liu Xiangyu Peng +5 位作者 Wengang Liu Kelin Tong Yanbai Shen Qiang Zhao Sikai Zhao Wenhan Sun 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第1期115-122,共8页
To enhance the performance of traditional cationic collector,a novel polyhydroxy amine collector N-(2,3-Propanediol)-N-dodecylamine(PDDA)was designed by introducing one propylene glycol group into dodecylamine(DDA).It... To enhance the performance of traditional cationic collector,a novel polyhydroxy amine collector N-(2,3-Propanediol)-N-dodecylamine(PDDA)was designed by introducing one propylene glycol group into dodecylamine(DDA).It was prepared by a nucleophilic substitution reaction,which showed better solubility and hydrophobicity than DDA and was firstly employed as the collector for the separation of hematite and quartz.Flotation tests showed that PDDA had an excellent flotation performance and significantly better selectivity than DDA.In addition,the flotation performance and adsorption mechanism of PDDA on hematite and quartz surfaces were studied using Fourier transform infrared spectroscopy(FTIR),zeta potential and X-ray photoelectron spectroscopy(XPS)tests.These results demonstrated that the interaction between PDDA and the minerals’surfaces was mainly electrostatic adsorption and hydrogen bond,while PDDA tended to adsorb on the surfaces of quartz more than that of hematite.Performance optimization of amine collectors by introducing hydroxyl was also verified,which was of great meaning to the design,development,and application of the polyhydroxy cationic collector.In conclusion,PDDA could be used as a potential collector in the flotation separation of quartz and hematite. 展开更多
关键词 Polyhydroxy collector quartz HEMATITE Interaction mechanism Hydrogen bonding
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Geochronology,Geochemistry and Petrogenesis of the Bangbule Quartz Porphyry:Implications for Metallogenesis 被引量:1
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作者 HE Chuankai WANG Yong +5 位作者 WANG Haiyong TANG Juxing YAN Penggang WANG Yongqiang FU Xuelian FENG Yipeng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第3期744-758,共15页
The Bangbule skarn lead-zinc(Pb-Zn)deposit(>1 Mt Zn+Pb)is located in the western Nyainqentanglha polymetallic metallogenetic belt,central Tibet.Lenticular orebodies are all hosted in skarn and developed in the cont... The Bangbule skarn lead-zinc(Pb-Zn)deposit(>1 Mt Zn+Pb)is located in the western Nyainqentanglha polymetallic metallogenetic belt,central Tibet.Lenticular orebodies are all hosted in skarn and developed in the contact zone between the quartz porphyry and carbonate strata of the mid Paleozoic Middle to Upper Chaguoluoma Formation as well as in carbonate and sandstone beds of the Upper Paleozoic Laga Formation.As a newly discovered skarn deposit,the geological background and metallogenesis of this deposit remain poorly understood.Detailed petrological,geochemical and geochronological data of the ore-related quartz porphyry,helps constrain the mineralization age and contributes to discussion on the ore genesis of the Bangbule deposit.Both endoskarn and exoskarn are identified in the Bangbule deposit.From quartz porphyry to carbonate formation,the exoskarn is zoned from proximal garnet skarn to distal pyroxene skarn.Zircon U-Pb dating results show that the quartz porphyry formed at 73.9±0.8 Ma.Geochemical analysis results show that the quartz porphyry has high contents of SiO_(2)(71.40–74.94 wt%)and K_(2)O+Na_(2)O(3.76–8.46 wt%)with A/CNK values of 0.69 to 1.06.Besides,the quartz porphyry is enriched in large ion lithophile elements(LILEs)and light rare earth elements(LREEs)and have lowεNd(t)(from-8.25 to-8.19)and high initial(^(87)Sr/^(86)Sr)i values(0.713611–0.714478).Major,trace elements and whole-rock F concentration analysis results from the endoskarn samples show higher TFe_(2)O_(3),MgO,CaO,Pb+Zn,W,Sn,Mo and F etc.,and lower alkalis(K_(2)O,Na_(2)O,Sr and Ba)than those of fresh quartz porphyry,indicating that the early ore-forming fluids were an Ca-Fe-F-enriched fluid.Massive ore in the proximal skarn might be related to the high F content in the magma,which lowered the solidus temperature of the quartz porphyry magma and caused a lower temperature of the ore-forming fluids,as well as facilitating the precipitation of sphalerite and galena.Based on the geochemical characteristics presented in this study,we propose that the ore-related quartz porphyry was formed by partial melting of crust materials with some juvenile crustal component input.The partial melting of the middle-upper crust after the initial enrichment of lead and zinc elements are important for the formation of Pb-Zn deposits.The case study of the Bangbule deposit has proven that there is still a crust-derived magmatic source region in the western segment of the central Lhasa terrane.Therefore,there is still great potential for Pb-Zn mineralization and Pb-Zn exploration. 展开更多
关键词 PETROGENESIS quartz porphyry METALLOGENESIS Bangbule skarn deposit TIBET
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Hematization of Quartz Grains: Study of the Surface of Quartz Grains (M.E.B) and Semi-Quantitative Mineralization
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作者 Chia Marie Reine Kokoa Touvalé Marcel Kesse +2 位作者 Fory Yao Paul Assale Sougo Aoua Coulibaly Kouadio Affian 《Journal of Geoscience and Environment Protection》 2023年第11期82-90,共9页
Interest in the Côte d’Ivoire sedimentary basin has led to numerous investigations. All these investigations are aimed at understanding the functioning of the basin and a paleogeographic approach including sedim... Interest in the Côte d’Ivoire sedimentary basin has led to numerous investigations. All these investigations are aimed at understanding the functioning of the basin and a paleogeographic approach including sediment transport dynamics. However, the use of exoscopy and semi-quantitative mineralogy has been little developed. This study was carried out to compensate for this lack of interest in these methods. Its aim is to understand the transformation of quartz into hematite using exoscopy and semi-quantitative mineralogy in the Adiaké locality, in the eastern onshore basin of Côte d’Ivoire. Two methods were applied to 250 μm-diameter quartz grains from the 40 m coasts. Exoscopy provides information on microscopic texture, surface and corrosion, as well as determining the transport mechanism and deposition phases of quartz grains. Semi-quantitative mineralogy provides an estimate of the weight percentages of major element oxides and the ultrastructure of quartz grains. Exoscopy showed that these grains had been subjected to torrential fluvial transport. They were marked by mechanical and chemical traces during this transport and evolved in different environments. Semi-quantitative mineralogy shows the existence of negative and positive correlations between oxides. Negative correlations indicate a substitution, in order of importance, of silicon by iron, phosphorus and aluminum in these quartz. Positive correlations show that there is no substitution between the oxides concerned in these quartz grains. Divo’s quartz grains have recorded several mechanical and chemical microstructures of their sedimentary episodes, with the appearance of iron nodules in the ports left by silica. 展开更多
关键词 quartz Exoscopy Semi-Quantitative Mineralogy Adiaké Ivory Coast
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Compensation of Parasitic Capacitance of Quartz Tuning Fork in AFM
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作者 Yidai Liu 《Journal of Applied Mathematics and Physics》 2023年第5期1404-1413,共10页
We have built an atomic force microscope using a quartz tuning fork as sensor. The excitation method we adopted, the electrical excitation, introduces stray capacitance into the signal-processing circuit. In this repo... We have built an atomic force microscope using a quartz tuning fork as sensor. The excitation method we adopted, the electrical excitation, introduces stray capacitance into the signal-processing circuit. In this report, we demonstrated a simple but effective method to compensate for this parasitic capacitance by adding a compensator circuit consisting of an inverting amplifier and a capacitor. The capacitor is connected in series with the inverting amplifier and the compensator is connected in parallel with the quartz tuning fork. The resonance curve of the system measured after adding the homemade compensator resembles that of a pure RLC circuit, meaning that the stray capacitance is successfully eliminated. Furthermore, we tried to use our equipment to measure PDMS sample and got clean data. This system can be further combined with confocal microscope and diamond with NV defect to build scanning NV magnetometry. 展开更多
关键词 Atomic Force Microscope quartz Tuning Fork Stray Capacitance Compensator Circuit PDMS Sample
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Influence of vacuoles with gas–liquid inclusions on the thermobaric destruction conditions of natural quartz under dynamic heating in an RF-TICP torch system
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作者 苗龙 聂明卿 +7 位作者 Yuri Mihailovich GRISHIN 王晓宇 朱政羲 宋家辉 梁福文 何梓豪 田丰 王宁飞 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第4期138-147,共10页
In the present work,the turbulent mixing process of a polydisperse quartz particle flow with a plasma stream generated by a radio-frequency(RF)inductively coupled plasma torch was numerically studied.The thermobaric s... In the present work,the turbulent mixing process of a polydisperse quartz particle flow with a plasma stream generated by a radio-frequency(RF)inductively coupled plasma torch was numerically studied.The thermobaric stress in the quartz particles under dynamic heating in a heterogeneous plasma flow was determined by a two-stage approximation approach.The effect of the presence of vacuoles in natural quartz on the particle thermobaric destruction conditions was studied.It was found that the equivalent thermal and baric stresses in quartz particles may significantly increase in the presence of vacuoles within a small gas volume fraction.The influence of the regime and energetic working conditions of an RF inductively coupled plasma torch system on the particle thermobaric destruction conditions was examined,and a recommendation was given to promote the degree of thermobaric destruction of quartz particles,which is of substantial importance for improving the overall enrichment efficiency of quartz concentrates. 展开更多
关键词 high purity quartz dynamic heating vacuole with gas–liquid inclusions thermobaric destruction radio-frequency inductively coupled plasma torch
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关于高纯石英原料矿石地质学评价方法的探讨 被引量:1
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作者 张亮 刘磊 +2 位作者 朱黎宽 王红杰 原垭斌 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第4期1311-1326,共16页
高纯石英资源是一种重要的战略性资源。本文结合高纯石英成矿地质特征及其对后期选矿提纯、材料加工等的影响,系统总结了高纯石英原料中杂质的赋存状态、形成机理以及评价方法等,得出:(1)可以作为高纯石英原料的潜在岩石类型有花岗伟晶... 高纯石英资源是一种重要的战略性资源。本文结合高纯石英成矿地质特征及其对后期选矿提纯、材料加工等的影响,系统总结了高纯石英原料中杂质的赋存状态、形成机理以及评价方法等,得出:(1)可以作为高纯石英原料的潜在岩石类型有花岗伟晶岩(包括不含暗色矿物的伟晶状花岗岩)、脉石英以及水晶,岩浆演化晚期的伟晶状花岗岩-伟晶岩早期阶段的NYF型花岗伟晶岩结晶形成的石英纯度更高,后期适当的变形变质作用更有利于高纯石英矿床的形成。高纯石英原料矿石中石英矿物呈现无色透明至半透明,矿物构造裂隙少,伟晶岩型矿石矿物组成通常为石英、钠长石、条纹长石、白云母等,黑云母等暗色矿物含量极少,基本不见锂辉石、独居石等稀有金属矿物和电气石、萤石等含挥发分矿物。(2)影响高纯石英的主要地质因素包括脉石矿物及晶界杂质、包裹体、晶格杂质等。其中包裹体类型、数量和尺寸是包裹体评价的关键指标,天然石英矿物中的气液两相包裹体、矿物包裹体和<10μm包裹体应尽量少;Al和Ti是晶格杂质元素评价标志性元素,通常要求天然石英矿物中Al<50×10-6和Ti<10×10-6。(3)建议按照手标本特征-石英矿物特征-石英中包裹体特征-晶格元素赋存状态及含量的顺序,从宏观到微观,综合借助光学显微镜、扫描电子显微镜(SEM)、阴极荧光光谱分析系统(SEM-CL)、激光剥蚀电感耦合等离子质谱仪(LA-ICP-MS)等开展地质学评价和研究工作。 展开更多
关键词 高纯石英 矿石特征 包裹体 晶格杂质元素 评价方法
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基于Quartz.NET的任务调度系统在医院信息化中的应用研究
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作者 黄昌可 《电脑知识与技术》 2023年第13期63-66,共4页
文章探讨了Quartz.NET任务调度系统在医院信息化中的应用。通过对任务调度系统的介绍和Quartz.NET的特点分析,文章提出了基于Quartz.NET的任务调度系统在医院信息化中的应用方案,主要包括任务调度系统的设计和实现、任务执行监控和报警... 文章探讨了Quartz.NET任务调度系统在医院信息化中的应用。通过对任务调度系统的介绍和Quartz.NET的特点分析,文章提出了基于Quartz.NET的任务调度系统在医院信息化中的应用方案,主要包括任务调度系统的设计和实现、任务执行监控和报警机制的建立等方面。该方案在实际应用中,有效提高了医院信息化系统的运行效率和管理水平,减轻人工负担,提高医院服务水平,具有较高的实用价值和推广意义。 展开更多
关键词 quartz.NET 任务调度 医院信息化
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我国石英资源的开发利用特点及应用进展
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作者 李作敏 谭秀民 +6 位作者 张亮 李建国 郭敏 刘航涛 刘磊 吕振福 曹飞 《矿产保护与利用》 2024年第2期115-123,共9页
石英资源是重要的基础性非金属矿产资源,广泛用于玻璃、机械铸造、电子电工、冶金、耐火材料、化工、陶瓷等领域,不同行业对石英砂的技术要求和用量各不相同,宏观了解石英资源的开发利用特点和市场应用对石英资源的高效合理利用意义重... 石英资源是重要的基础性非金属矿产资源,广泛用于玻璃、机械铸造、电子电工、冶金、耐火材料、化工、陶瓷等领域,不同行业对石英砂的技术要求和用量各不相同,宏观了解石英资源的开发利用特点和市场应用对石英资源的高效合理利用意义重大。介绍了我国各类石英资源的资源现状、不同类型矿石的开发利用特点及主要应用方向,详细总结了玻璃、高纯石英、机械、电子电工、冶金、耐火材料、化工、陶瓷、石油、板材等不同领域对石英原料的标准技术要求和产品特点;从石英资源开发利用全领域角度出发,系统梳理了不同领域石英资源的用量及产值,详细分析了高纯石英市场现状及供需发展趋势。结合石英资源开发利用现状,提出了在石英资源的开发利用过程中应分类评价、分级利用等对策建议,以期进一步提高我国石英资源开发利用水平和保障能力。 展开更多
关键词 石英资源 石英砂 技术特点 市场现状 高纯石英
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鄂尔多斯盆地太原组砂岩缝合线特征及成因
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作者 齐荣 林畅松 +2 位作者 黄国家 杨香华 张曼莉 《西南石油大学学报(自然科学版)》 CAS CSCD 北大核心 2024年第2期53-64,共12页
鄂尔多斯盆地北缘太原组砂岩中广泛发育缝合线构造,缝合线成因机理复杂,且会对砂岩储层的物性产生重要影响。基于岩芯观察,并通过能谱、扫描电镜、X衍射及铸体薄片等综合分析,揭示了太原组砂岩缝合线的几何形态、矿物组成及其成因机理... 鄂尔多斯盆地北缘太原组砂岩中广泛发育缝合线构造,缝合线成因机理复杂,且会对砂岩储层的物性产生重要影响。基于岩芯观察,并通过能谱、扫描电镜、X衍射及铸体薄片等综合分析,揭示了太原组砂岩缝合线的几何形态、矿物组成及其成因机理。研究表明,太原组砂岩缝合线振幅大小差异明显,可划分出波浪型、尖峰型、长方柱型、复合型及网状交织型5种类型。缝合线物质组成主要包括有机碳、石英、伊利石、高岭石、黄铁矿、金红石和锆石,黏土矿物中伊利石的含量远高于围岩,而高岭石含量远低于围岩。缝合线内有机质与黏土矿物具有典型的沉积成因标志,它们可以作为硅质迁移与沉淀的催化剂,导致缝合线内及两侧砂岩孔隙中的硅质沉淀和碎屑石英颗粒的增生。这些缝合线构造是埋藏过程中沉积有机质压溶的产物,是沉积黏土矿物与有机质成岩作用的综合响应。缝合线相关的硅质沉淀与石英加大是研究区太原组石英砂岩致密的主要因素,但沿缝合线易发育裂缝,起到改善岩石渗透性的作用。 展开更多
关键词 缝合线构造 石英砂岩 有机质成岩作用 太原组 鄂尔多斯盆地
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β-FeOOH/SiO_(2)复合非均相Fenton催化剂制备及对甲基橙溶液的降解
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作者 陈爽 于萍 +2 位作者 李星华 白建军 张林琳 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第3期198-206,共9页
采用简单、环保的方法合成β-FeOOH/SiO_(2)复合非均相Fenton催化剂,采用红外光谱仪(FT-IR)、X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)、透射电子显微镜(TEM)对催化剂进行表征分析,考察质量比、合成温度和合成时间对催化剂催化活性的... 采用简单、环保的方法合成β-FeOOH/SiO_(2)复合非均相Fenton催化剂,采用红外光谱仪(FT-IR)、X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)、透射电子显微镜(TEM)对催化剂进行表征分析,考察质量比、合成温度和合成时间对催化剂催化活性的影响,通过分析催化剂类型、用量及双氧水用量,探究β-FeOOH/SiO_(2)复合催化剂处理染料废水的最佳工艺条件。结果表明:β-FeOOH/SiO_(2)复合催化剂制备工艺简单,操作条件温和,易于工业化生产;β-FeOOH/SiO_(2)复合催化剂在满足m(β-FeOOH)/m(SiO_(2))=1∶1,反应温度为90℃,反应时间为8 h时,具有最佳的催化活性;在30℃条件下,β-FeOOH/SiO_(2)的加入量为5 g/L,过氧化氢的加入量为0.1 L/L时,200 mg/L甲基橙染料废水的去除率最大,达到98.85%,对亚甲基蓝和罗丹明B的去除率分别达到90.44%和99.25%;β-FeOOH/SiO_(2)复合催化剂对染料废水具有良好的降解效果。 展开更多
关键词 β-FeOOH 石英砂 异构芬顿 染料废水
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水合阳离子对煤泥矿物颗粒表面水化的影响机理
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作者 闵凡飞 束庆东 +2 位作者 陈军 刘春福 凌云嘉 《煤炭学报》 EI CAS CSCD 北大核心 2024年第2期1111-1122,共12页
为探索水合阳离子对煤泥矿物颗粒表面水化的微观影响机理,以煤泥中主要矿物高岭石和石英为研究对象,依据煤泥水溶液环境构建了[Na(H_(2)O)_(5)]+及[Ca(H_(2)O)_(8)]^(2+)两种煤泥水中常见的水合阳离子构型,并采用密度泛函理论对这2种水... 为探索水合阳离子对煤泥矿物颗粒表面水化的微观影响机理,以煤泥中主要矿物高岭石和石英为研究对象,依据煤泥水溶液环境构建了[Na(H_(2)O)_(5)]+及[Ca(H_(2)O)_(8)]^(2+)两种煤泥水中常见的水合阳离子构型,并采用密度泛函理论对这2种水合阳离子在高岭石(001)面、(001)面和α-石英(001)面的单一吸附及与水分子间的竞争吸附进行了模拟计算。模拟结果表明,单一水合阳离子在3种表面的吸附能均比水分子的吸附能低出50%以上,其在矿物表面的吸附稳定性顺序为:α-石英(001)面>高岭石(001)面>高岭石(001)面;在竞争吸附作用下,竞争稳定构型的吸附能比单一水合阳离子在高岭石、石英表面上的吸附能低出34%~57%,其中2种吸附条件下[Ca(H_(2)O)_(8)]^(2+)构型均比[Na(H_(2)O)_(5)]+构型更稳定。水合阳离子在3种表面上单一吸附时,与表面形成强氢键作用,比水分子与高岭石、石英表面间的氢键作用更强,2种水合阳离子在矿物表面的氢键强弱顺序均为:高岭石(001)面>α-石英(001)面>高岭石(001)面;在竞争吸附作用下,[Na(H_(2)O)_(5)]+与矿物表面间的氢键作用增强,[Ca(H_(2)O)_(8)]^(2+)与矿物表面间的氢键作用减小;由于氢键作用不能完全对应吸附能的变化,经分析可知,吸附构型中存在静电作用,水合阳离子单一吸附构型中的静电作用比水分子吸附时更强,而在竞争吸附作用下,水合阳离子与矿物表面间静电作用增强,同时[Ca(H_(2)O)_(8)]^(2+)比[Na(H_(2)O)_(5)]+与对应矿物表面间的静电作用更强。由于水合阳离子在高岭石、石英表面的强吸附作用,导致煤泥颗粒脱水更加困难,同时可能增加颗粒间的水化斥力,从而导致颗粒在煤泥水中分散更稳定。 展开更多
关键词 煤泥颗粒 表面水化 水合阳离子 高岭石 石英 密度泛函理论
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石英脉型钨多金属矿床的扇状成矿实例及找矿模型
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作者 方贵聪 王登红 +6 位作者 黄长帅 杨富强 许以明 冯佐海 李学彪 曾强 严长华 《矿床地质》 CAS CSCD 北大核心 2024年第3期613-628,共16页
石英脉型钨矿床是中国数量最多的钨矿床类型,但保有储量消耗迅速,迫切需要创新找矿模型,指导找矿突破。文章结合二十余年的找矿实践,通过详细分析扇状成矿矿床实例,构建了石英脉型钨矿床新的找矿模型。该模型强调赋矿裂隙为岩浆动力成因... 石英脉型钨矿床是中国数量最多的钨矿床类型,但保有储量消耗迅速,迫切需要创新找矿模型,指导找矿突破。文章结合二十余年的找矿实践,通过详细分析扇状成矿矿床实例,构建了石英脉型钨矿床新的找矿模型。该模型强调赋矿裂隙为岩浆动力成因,在花岗岩体顶部呈扇状分布型式,岩浆期后热液恰在裂隙张开时充填其中而形成扇状成矿系统;提出“就岩找矿”、“就矿找矿”、“就矿找岩”的地质、地球化学和地球物理标志,指导矿床尺度的勘查工程部署。截至目前,该模型已在广东禾尚田钨锡矿床、广西珊瑚钨锡矿床、广西社垌钨钼矿床、江西盘古山钨铋矿床等获得了验证,找矿成效显著。 展开更多
关键词 扇状成矿 成矿规律 找矿模型 花岗岩 石英脉型钨矿床
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基于深度融合的全自动石英坩埚气泡检测方法
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作者 赵谦 郑轩 +1 位作者 李蓉蓉 赵曼 《国外电子测量技术》 2024年第3期190-198,共9页
针对石英坩埚透明层中气泡检测依赖于人工肉眼检测,存在着效率低、准确性不高的问题,提出了一种基于深度融合气泡检测算法(DFBDA)。首先,利用智能机械臂夹持工业显微镜,自动采集石英坩埚透明层的气泡视频图像;然后,使用融合形态学变换... 针对石英坩埚透明层中气泡检测依赖于人工肉眼检测,存在着效率低、准确性不高的问题,提出了一种基于深度融合气泡检测算法(DFBDA)。首先,利用智能机械臂夹持工业显微镜,自动采集石英坩埚透明层的气泡视频图像;然后,使用融合形态学变换的气泡分割和轮廓提取算法,以确保对气泡的准确分割;最后,通过深度融合方法对多帧相似气泡进行融合,实现了对气泡准确位置的三维重建。针对不同坩埚样品的测试验证,实验结果表明,方法对气泡的平均识别准确率达到了98.7%,速度和精度都满足工业需求。 展开更多
关键词 石英坩埚 气泡检测 形态学 自动化 图像处理
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川东二叠系龙潭组不同沉积环境下的页岩弹性波速度特征
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作者 王艳 张兵 +3 位作者 姚永君 林晓杨 曹高权 肖威 《物探化探计算技术》 CAS 2024年第2期180-189,共10页
笔者选取川东地区FT1井龙潭组页岩进行实验测试,在岩相划分的背景下,通过主微量元素研究川东龙潭组不同岩相的沉积环境,结合沉积环境对石英成因、TOC的影响,探讨不同沉积环境下的弹性波速度变化特征。研究结果表明:①混合质页岩和黏土... 笔者选取川东地区FT1井龙潭组页岩进行实验测试,在岩相划分的背景下,通过主微量元素研究川东龙潭组不同岩相的沉积环境,结合沉积环境对石英成因、TOC的影响,探讨不同沉积环境下的弹性波速度变化特征。研究结果表明:①混合质页岩和黏土质页岩处于低古生产力、富氧、陆源碎屑输入较高的沉积环境,其石英以陆源碎屑石英为主,TOC含量偏低;硅质页岩处于高古生产力、缺氧、陆源碎屑输入较低的沉积环境,其石英以生物成因石英为主,TOC含量较高。②混合质页岩和黏土质页岩以黏土颗粒作为岩石骨架,弹性波速度较低,且弹性波速度随石英含量呈上升趋势;硅质页岩以石英颗粒作为岩石骨架,弹性波速度较高,且弹性波速度随石英含量呈下降趋势。研究结果可为龙潭组页岩优势岩相勘探提供依据。 展开更多
关键词 龙潭组 沉积环境 石英成因 TOC 弹性波速度
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新疆阿尔泰可可托海矿区伟晶岩成因与矿化潜力研究:来自石英SEM-CL和微量元素的指示
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作者 曹冲 申萍 +3 位作者 冯浩轩 罗耀清 楚翔凯 任文斌 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第3期889-906,共18页
新疆阿尔泰可可托海3号脉矿床是世界瞩目的伟晶岩型稀有金属Li-Be-Nb-Ta-Rb-Cs-Hf矿床。尽管前人对3号脉伟晶岩矿床已经进行了大量的研究工作,然而在伟晶岩稀有金属成矿潜力以及伟晶岩成因问题上仍存在一些争议。本文以发育在可可托海... 新疆阿尔泰可可托海3号脉矿床是世界瞩目的伟晶岩型稀有金属Li-Be-Nb-Ta-Rb-Cs-Hf矿床。尽管前人对3号脉伟晶岩矿床已经进行了大量的研究工作,然而在伟晶岩稀有金属成矿潜力以及伟晶岩成因问题上仍存在一些争议。本文以发育在可可托海矿区不同规模的伟晶岩脉以及淡色花岗岩为研究对象,利用石英SEM-CL和原位微量元素技术手段,查明各伟晶岩脉和花岗岩的稀有金属禀赋差异及成因联系。研究结果表明,石英的Li和Al含量可以用来指示伟晶岩的矿化潜力。与1号和2号伟晶岩脉相比,3号伟晶岩脉具有更宽的分异范围,以石英中Ge/Ti变化于1.83×10^(-6)~159×10^(-6)范围为特征,更高的Li含量,其中外侧带平均Li含量为39×10^(-6),因而成矿潜力最大。此外,证实了白云母钠长花岗岩为矿化花岗岩,其微量元素组成和演化程度与3号脉伟晶岩外侧带相当,而白云母碱长花岗岩为贫矿花岗岩。更重要的是,本文利用各伟晶岩结构分带内的石英中Ge/Ti-Ge以及Ge/Ti-Al/Ti图解,确定了各伟晶岩脉具有相似的演化趋势,指示它们可能源于相同的花岗岩母岩。与世界上典型的RMG(花岗岩浆演化后残余熔浆结晶)和DPA(直接深部地壳熔融)成因的伟晶岩相比,可可托海矿区含矿伟晶岩和花岗岩中石英微量元素与RMG成因伟晶岩存在地球化学亲和性,这指示它们来源于花岗质岩浆的残留熔浆。 展开更多
关键词 可可托海稀有金属伟晶岩型矿床 石英微量元素 成矿潜力 岩石成因
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南岭湘南吴家坪锡矿成岩成矿时代研究
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作者 夏杰 卢友月 +6 位作者 付建明 张遵遵 程顺波 李剑锋 宁勇云 冯经平 张吉梼 《地质通报》 CAS CSCD 北大核心 2024年第4期572-581,共10页
南岭吴家坪锡矿为湖南大义山地区近年新发现的具有中型以上远景规模的云英岩型矿床,矿体呈脉状产于大义山复式花岗岩体内部,受NE向断裂控制。为确定其成岩、成矿时代,总结大义山地区成矿规律,指导区域找矿及勘查工作,对赋矿围岩中粗粒... 南岭吴家坪锡矿为湖南大义山地区近年新发现的具有中型以上远景规模的云英岩型矿床,矿体呈脉状产于大义山复式花岗岩体内部,受NE向断裂控制。为确定其成岩、成矿时代,总结大义山地区成矿规律,指导区域找矿及勘查工作,对赋矿围岩中粗粒斑状黑云母二长花岗岩(PM21-19)、中细粒斑状黑云母二长花岗岩(PM21-27)进行了LA−ICP−MS锆石U−Pb定年研究。测年结果表明,其成岩年龄为157.1±1.1 Ma(MSWD=0.55)和153.7±1.2 Ma(MSWD=0.55),属燕山早期。同时,获得云英岩型锡矿石中石英Rb−Sr等时线年龄为148.1±2.1 Ma(MSWD=0.52)。结合区域资料认为,吴家坪锡矿成岩成矿时代为燕山早期,属南岭地区中生代成岩成矿高峰期(160~150 Ma)的产物。 展开更多
关键词 锆石U−Pb年龄 石英Rb−Sr定年 锡矿床 吴家坪 南岭 矿产勘查工程
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