Composition, morphology, and structure of hydration products in hardened pastes of three kinds of blended cement（cement-silica fume, cement-quartz powder and cement-silica fume-quartz powder） hydrated under differen...Composition, morphology, and structure of hydration products in hardened pastes of three kinds of blended cement（cement-silica fume, cement-quartz powder and cement-silica fume-quartz powder） hydrated under different curing regimes（standard curing, 90 ℃ steam curing, 200 ℃ and 250 ℃ autoclave curing） were investigated by X-ray diffraction and field emission scanning electron microscope equipped with EDAX system. Results showed that the main hydration products in three kinds of hardened pastes under standard curing condition are all C-S-H gels, CH, and AFt. Under 90 ℃ steam curing condition, the main hydration products of cement-silica fume and cement-silica fume-quartz powder are C-S-H gels, whereas those of cement-quartz powder are C-S-H and CH. Under 200 or 250 ℃ autoclave curing condition, no obvious crystallized CH phase is found in hardened pastes of three kinds of blended cement, and C-S-H gels are transformed into one or more crystalline phases such as tobermorite, jennite, and xonotlite. The chemical composition and morphology of these crystalline phases depend on the composition of mixture and autoclave temperature.展开更多
Si2N2O powder was synthesized by car-bothermal reduction and nitridation natural quartz powder. At the same time, the effects of the process parameters such as SiO2/C ratio, temperature and time on the compositions of...Si2N2O powder was synthesized by car-bothermal reduction and nitridation natural quartz powder. At the same time, the effects of the process parameters such as SiO2/C ratio, temperature and time on the compositions of products were analysed. It is found that the compositions of products depend closely on the parameters mentioned above, and that the product containing higher Si2N2O phase could be obtained by choosing suitable process parameters.展开更多
Powder quartz(PQ)/nano-TiO2composite was prepared by a mechanochemical method. Based on as-prepared PQ/nano-TiO2composite, we prepared interior paints and investigated the degradation efficiency of formaldehyde(DEF). ...Powder quartz(PQ)/nano-TiO2composite was prepared by a mechanochemical method. Based on as-prepared PQ/nano-TiO2composite, we prepared interior paints and investigated the degradation efficiency of formaldehyde(DEF). Scanning electron microscopy showed that nano-TiO2got well dispersed by the adding of PQ. Thermogravimetric analysis indicated that the mass ratio of 4:1 was a relatively good proportion for the most production of PQ/nano-TiO2composite. Fourier transform-infrared spectrometry showed that the peak position of Ti-O-Si bond varied with the milling time. At the early stage, no characteristic peak of Ti-O-Si bond was observed, while at the later stage, new peaks at 902 cm-1and 937 cm-1appeared. Meanwhile, PQ/nano-TiO2composite-based interior paint exhibited significant DEF of 96.3% compared to that consisting of sole nanoTiO2of 92.0% under visible light illumination. As an abundant mineral resource, PQ would make interior paints with HCHO purifying effect much more efficient and cheaper.展开更多
The characteristic study of powder quartz is the basis of the comprehensive utilization of quartz powder resources.In this paper,the characteristic of a powder quartz mine in Yunnan Province is analyzed, through the a...The characteristic study of powder quartz is the basis of the comprehensive utilization of quartz powder resources.In this paper,the characteristic of a powder quartz mine in Yunnan Province is analyzed, through the analysis of X-ray diffraction,chemical composition,SEM analysis of the different samples those purified to different extent,etc.The results indicated that the powder quartz’s whiteness is 81.4, and the main mineral compositions are quartz,clay mineral(mostly kaolinite and illite) and a little of feldspar,and the content of quartz is about 85%。展开更多
This research focuses on investigating the effect of quartz particle size and cement replacement on their physicomechnical properties.Portland limestone cement(PLC)was employed and replaced with quartz powder(QP)at va...This research focuses on investigating the effect of quartz particle size and cement replacement on their physicomechnical properties.Portland limestone cement(PLC)was employed and replaced with quartz powder(QP)at various particle sizes(1.19 mm,425μm,300μm,212μm,<212μm)and cement replacement between 2.5 wt.%~15 wt.%at interval of 2.5 wt.%to study their impact on the cement properties.The PLC chemical composition revealed a relatively low lime and high silica content compared to the conventional cement.QP revealed a high silica,lime and sulphur contents compared to natural sand.A high consistence,elongated setting times and lower strengths and specific gravities were observed as cement was replaced with QP at a given particle size respectively.The effect of replacing cement with QP content between 2.5 wt.%and 15 wt.%at various particle sizes resulted in average increments by 45.32%,23.13%and 36.06%for initial setting time,final setting time and water demand respectively.This increase could be related with clinker diminution coupled with enhanced QP surface area and clinker diminution.Similarly,an increase in the QP surface area at a given cement replacement led to higher water consistence,retarded setting times and lower strength.The effect of enhancing the QP’surface area between 1.19 mm and below 212μm at a given cement replacement resulted in average increments by 26.27%,8.61%and 7.49%for initial and final setting times and water demand respectively.The strength gain of the QP cement blend diminished significantly above 30%up to 15 wt.%cement replacement especially beyond 3 days.The low strength could be due to the high-water consistence linked with silica content resulting in setting time retardation.The optimal QP content was determined at 5 wt.%owing to the fact that the physicomechnical properties did not significantly deviate from the properties of control.展开更多
基金Funded by the National Natural Science Foundation of China(Nos.51272193,51372183,51072150)Program for New Century Excellent Talents in University(No.NCET-10-0660)the National Key Research Projects(No.2016YFB0303501)
文摘Composition, morphology, and structure of hydration products in hardened pastes of three kinds of blended cement（cement-silica fume, cement-quartz powder and cement-silica fume-quartz powder） hydrated under different curing regimes（standard curing, 90 ℃ steam curing, 200 ℃ and 250 ℃ autoclave curing） were investigated by X-ray diffraction and field emission scanning electron microscope equipped with EDAX system. Results showed that the main hydration products in three kinds of hardened pastes under standard curing condition are all C-S-H gels, CH, and AFt. Under 90 ℃ steam curing condition, the main hydration products of cement-silica fume and cement-silica fume-quartz powder are C-S-H gels, whereas those of cement-quartz powder are C-S-H and CH. Under 200 or 250 ℃ autoclave curing condition, no obvious crystallized CH phase is found in hardened pastes of three kinds of blended cement, and C-S-H gels are transformed into one or more crystalline phases such as tobermorite, jennite, and xonotlite. The chemical composition and morphology of these crystalline phases depend on the composition of mixture and autoclave temperature.
文摘Si2N2O powder was synthesized by car-bothermal reduction and nitridation natural quartz powder. At the same time, the effects of the process parameters such as SiO2/C ratio, temperature and time on the compositions of products were analysed. It is found that the compositions of products depend closely on the parameters mentioned above, and that the product containing higher Si2N2O phase could be obtained by choosing suitable process parameters.
基金Funded by the National Natural Science Foundation of China(No.41130746)
文摘Powder quartz(PQ)/nano-TiO2composite was prepared by a mechanochemical method. Based on as-prepared PQ/nano-TiO2composite, we prepared interior paints and investigated the degradation efficiency of formaldehyde(DEF). Scanning electron microscopy showed that nano-TiO2got well dispersed by the adding of PQ. Thermogravimetric analysis indicated that the mass ratio of 4:1 was a relatively good proportion for the most production of PQ/nano-TiO2composite. Fourier transform-infrared spectrometry showed that the peak position of Ti-O-Si bond varied with the milling time. At the early stage, no characteristic peak of Ti-O-Si bond was observed, while at the later stage, new peaks at 902 cm-1and 937 cm-1appeared. Meanwhile, PQ/nano-TiO2composite-based interior paint exhibited significant DEF of 96.3% compared to that consisting of sole nanoTiO2of 92.0% under visible light illumination. As an abundant mineral resource, PQ would make interior paints with HCHO purifying effect much more efficient and cheaper.
文摘The characteristic study of powder quartz is the basis of the comprehensive utilization of quartz powder resources.In this paper,the characteristic of a powder quartz mine in Yunnan Province is analyzed, through the analysis of X-ray diffraction,chemical composition,SEM analysis of the different samples those purified to different extent,etc.The results indicated that the powder quartz’s whiteness is 81.4, and the main mineral compositions are quartz,clay mineral(mostly kaolinite and illite) and a little of feldspar,and the content of quartz is about 85%。
文摘This research focuses on investigating the effect of quartz particle size and cement replacement on their physicomechnical properties.Portland limestone cement(PLC)was employed and replaced with quartz powder(QP)at various particle sizes(1.19 mm,425μm,300μm,212μm,<212μm)and cement replacement between 2.5 wt.%~15 wt.%at interval of 2.5 wt.%to study their impact on the cement properties.The PLC chemical composition revealed a relatively low lime and high silica content compared to the conventional cement.QP revealed a high silica,lime and sulphur contents compared to natural sand.A high consistence,elongated setting times and lower strengths and specific gravities were observed as cement was replaced with QP at a given particle size respectively.The effect of replacing cement with QP content between 2.5 wt.%and 15 wt.%at various particle sizes resulted in average increments by 45.32%,23.13%and 36.06%for initial setting time,final setting time and water demand respectively.This increase could be related with clinker diminution coupled with enhanced QP surface area and clinker diminution.Similarly,an increase in the QP surface area at a given cement replacement led to higher water consistence,retarded setting times and lower strength.The effect of enhancing the QP’surface area between 1.19 mm and below 212μm at a given cement replacement resulted in average increments by 26.27%,8.61%and 7.49%for initial and final setting times and water demand respectively.The strength gain of the QP cement blend diminished significantly above 30%up to 15 wt.%cement replacement especially beyond 3 days.The low strength could be due to the high-water consistence linked with silica content resulting in setting time retardation.The optimal QP content was determined at 5 wt.%owing to the fact that the physicomechnical properties did not significantly deviate from the properties of control.
