Facile fabrication of encryption composite materials with trilayer quasi-amorphous heterostructure

Encryption materials represent a major direction of information security,but it is challenging to realize the ideal security combining the complete hiding of complex coding,stability in transmission,camouflage,and reliable decoding.Herein,we report an innovative strategy for rationally constructing encryption composite materials with high security and portability.Compared with common colloidal photonic watermarks,our encrypted optical devices are composed of thermoplastic polyurethanes(TPU)protective layers,polystyrene(PS)switching layers and a Cd S coding layer.The optical shielding properties and phase state transition of PS layers enable high-level encoding and decoding security through thermal activation of light transmittance control.Meanwhile,the Cd S layer can be clearly revealed in decoding mode because of the high refractive index.Besides,the confinement protection of integrated TPU films prevents the trilayer quasi-amorphous heterostructure from damage.To establish the practical advantage,portable information carriers can be prepared for camouflage.Accordingly,the reliable encoding and decoding system,and ability to integrate with easy-to-carry products,make our composites a potentially high-security encryption device for anti-fraud technology.

Microstructural Exploration of the High Capacitance in RuO_(2)-ZrO_(2) Coating

A high capacitance RuO_(2)-ZrO_(2) coating was prepared by thermal decomposition method.Extended X-ray absorption fine structure(EXAFS),X-ray diffraction(XRD),high-resolution transmission electron microscope(HRTEM)and ab initio calculations were applied to understand the role of the microstructure in the acquisition of high specific capacitance of RuO_(2)-based oxides.The results show that the RuO_(2)-ZrO_(2) oxide prepared at critical crystallization temperature can be considered to be quasi-amorphous or microcrystalline(A short-range ordered crystal structure can be seen from the TEM image,but no diffraction peaks can be seen from the XRD diffraction patterns).And this RuO_(2)-ZrO_(2) was identified as a solid solution with high solid solubility.It referred to herein as a quasi-amorphous solid solution.Such a special microstructure was conducive for"synergistic catalysis"owing to the cationic interaction and thus could gain high"active site density"and high"active surface",thus developing high specific capacitance.